Classification of the substance or mixture

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Revision 1
SAFETY DATA SHEET
Final Dressing
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifier
Product name
Final Dressing
Product No.
M0107CLM
Product Description: A Finish for Plastics and Coatings
Relevant identified uses of the substance or mixture and uses advised against
Details of the supplier of the safety data sheet
Supplier
Clemas & Co Limited
Unit 5, Ashchurch Business Centre
Alexandra Way
Tewkesbury
Gloucestershire
GL20 8NB
TEL: 01684 8507777
FAX: 01684 850707
SECTION 2: HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification (1999/45/EEC) Xn;R65. R66, R67. Human health
In high concentrations, vapours and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. Irritating to eyes.
Environment
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Physical and Chemical Hazards
The product is flammable, and heating may generate vapours which may form explosive vapour/air mixtures.
Label elements
Contains
HYDROTREATED PETROLEUM HYDROCARBON
Labelling
Harmful
Risk Phrases
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Safety Phrases
R65
Harmful: may cause lung damage if swallowed.
R66
Repeated exposure may cause skin dryness or cracking.
R67
Vapours may cause drowsiness and dizziness.
S37
Wear suitable gloves.
S62
If swallowed, do not induce vomiting: seek medical advice immediately and
show this container or label.
Other hazards
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
HYDROTREATED PETROLEUM HYDROCARBON
CAS-No.:
30-60%
EC No.: 919-857-5
Classification (EC 1272/2008)
Classification (67/548/EEC)
Flam. Liq. 3 - H226
Xn;R65.
R66,R10,R67.
EUH066
STOT SE 3 - H336
Asp. Tox. 1 - H304
d-LIMONENE
CAS-No.: 5989-27-5
< 1%
EC No.: 227-813-5
Classification (EC 1272/2008)
Classification (67/548/EEC)
Flam. Liq. 3 - H226
R10
Skin Irrit. 2 - H315
R43
Skin Sens. 1 - H317
Xi;R38
Aquatic Acute 1 - H400
N;R50/53
Aquatic Chronic 1 - H410
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown are in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
Description of first aid measures
General information
General first aid, rest, warmth and fresh air. Do not give victim anything to drink if they are unconscious. Get medical attention if any
discomfort continues. Inhalation
Place unconscious person on the side in the recovery position and ensure breathing can take place. If respiratory problems, artificial
respiration/oxygen. Get medical attention if any discomfort continues.
Ingestion
Immediately rinse mouth and drink plenty of water or milk. Keep person under observation. Do not induce vomiting. If vomiting occurs, keep
head low. Transport immediately to hospital and bring along these instructions.
Skin contact
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Immediately remove contaminated clothing. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked
through and flush skin with water. Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Get medical attention promptly if symptoms occur after washing.
Most important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in
doubt, GET MEDICAL ATTENTION PROMPTLY!
SECTION 5: FIREFIGHTING MEASURES
Extinguishing media
Extinguishing media
Fire can be extinguished using: Water spray, fog or mist. Foam, carbon dioxide or dry powder. Dry chemicals, sand, dolomite etc.
Special hazards arising from the substance or mixture
Unusual Fire & Explosion Hazards
Fire causes formation of toxic gases.
Advice for firefighters
Special Fire Fighting Procedures
Use pressurised air mask if product is involved in a fire. Cool containers exposed to flames with water until well after the fire is out. Keep
run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
Environmental precautions
Do not discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material.
Methods and material for containment and cleaning up
Keep combustibles away from spilled material. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb
in vermiculite, dry sand or earth and place into containers. Wash thoroughly after dealing with a spillage.
Reference to other sections
SECTION 7: HANDLING AND STORAGE
Precautions for safe handling
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved
respirator if air contamination is above accepted level.
Conditions for safe storage, including any incompatibilities
Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and
well-ventilated place. Keep in original container. Avoid contact with oxidising agents. Storage Class
Flammable liquid storage.
Specific end use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Name
STD
TWA - 8 Hrs
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STEL - 15 Min
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d-LIMONENE
OEL
30 ppm
150 ppm
OEL = Occupational Exposure Limit.
Ingredient Comments
WEL = Workplace Exposure Limits
Exposure controls
Protective equipment
Process conditions
Provide eyewash station.
Engineering measures
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded. All handling to take place in well-ventilated area. Respiratory equipment
Wear suitable respiratory protection.
Hand protection
Use protective gloves made of: Neoprene. Nitrile. Rubber (natural, latex).
Eye protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly
remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or
smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance
Transparent paste.
Colour
White / off-white.
Odour
Solvent.
Solubility
Insoluble in water
Relative density
0.82
PH-Value, Conc. Solution
Not applicable.
Other information
SECTION 10: STABILITY AND REACTIVITY
Reactivity
There are no known reactivity hazards associated with this product.
Chemical stability
No particular stability concerns.
Possibility of hazardous reactions
Not applicable.
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Hazardous Polymerisation will
not polymerise.
Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid contact with strong oxidisers.
Incompatible materials
Materials to Avoid
Strong oxidising substances.
Hazardous decomposition products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on toxicological effects
General information
Prolonged and repeated contact with solvents over a long period may lead to permanent health problems.
Inhalation
In high concentrations, vapours may irritate throat and respiratory system and cause coughing.
Ingestion
Gastrointestinal symptoms, including upset stomach.
Skin contact
Acts as a defatting agent on skin. May cause cracking of skin and eczema.
Eye contact
Irritating and may cause redness and pain.
SECTION 12: ECOLOGICAL INFORMATION
Eco toxicity
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
SECTION 13: DISPOSAL CONSIDERATIONS
General information
Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.
Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements. Make sure containers are empty before discarding
(explosion risk). Absorb in vermiculite or dry sand and dispose of at a licenced hazardous waste collection point.
SECTION 14: TRANSPORT INFORMATION
UN number
UN No. (ADR/RID/ADN)
1993
UN No. (IMDG)
1993
UN No. (ICAO)
1993
UN proper shipping name
Proper Shipping Name
Flammable Liquid, N.O.S. (Contains Petroleum Products)
Transport hazard class (is)
ADR/RID/ADN
Class
3
Packing group
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ADR/RID/ADN Packing group
III
IMDG Packing group
III
ICAO Packing group
III
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
SECTION 15: REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
National Regulations
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689. Workplace Exposure Limits 2005 (EH40)
Chemical Safety Assessment
SECTION 16: OTHER INFORMATION
Revision Date
17/09/2013
Revision
1
Risk Phrases in Full
R10
Flammable.
R65
Harmful: may cause lung damage if swallowed.
R38
Irritating to skin.
R43
May cause sensitisation by skin contact.
R66
Repeated exposure may cause skin dryness or cracking.
R67
Vapours may cause drowsiness and dizziness.
R50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Hazard Statements In Full
H315
Causes skin irritation.
H226
Flammable liquid and vapour.
H304
May be fatal if swallowed and enters airways.
H317
May cause an allergic skin reaction.
H336
May cause drowsiness or dizziness.
EUH066
Repeated exposure may cause skin dryness or cracking.
H410
Very toxic to aquatic life with long lasting effects.
H400
Very toxic to aquatic life.
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