ANSWER KEY Chemistry CPA Unit 6: Chemical Quantities Test Study Guide Test Date(s): Your test will be taken in two parts: 1. Written Exam: Tuesday, April 1 2. Lab Practical: Wednesday, April 2 Main Ideas for Unit 6: Define the mole as a counting number Relate counting particles to weighing samples of substances Calculate the percent composition of atoms of elements within substances Solve stoichiometric problems using molar mass (converting between grams and moles) Determine mole ratios from balanced chemical equations Determine the limiting reactant of a chemical reaction based on mole ratios Unit 6 Materials to Review: Green Notes Packet Purple Assignment Packet Coral Lab Packet Do-Quizzes and Exit Passes Graded Quizzes Unit 6 Equations and Calculations: Molar Mass Percent Composition Moles Grams Grams Moles Comparing Mole Ratios Percent Yield Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 1 ANSWER KEY Define the following terms (SEE TEXTBOOK) 1. Mole 2. Avagadro’s Number 3. Molar Mass 4. Stoichiometry 5. Percent Yield 6. Theoretical Yield 7. What is the purpose of the mole? Why do we need it? To be able to correctly work with microscopic atoms at the macroscopic level in the lab. 8. The mole has two different equivalent statements/definitions. What are they, and which one is practical and necessary for lab work? 1 mole = 6.02x1023 particles 1 mole = molar mass of a substance (most practical for lab work) Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 2 ANSWER KEY 9. Find the molar mass of the following substances. The first two types are done for you as a model. SHOW ALL WORK!! CaCl2 Silver nitrate Ca: 1 X 40.08 = 40.08 1x107.87=107.87 Cl: 2 x 35.45 = 70.90 Ag1+ = 110.98 g (NO3)1- Ag: N: 1 x 14.01= 14.01 = AgNO3 O: 3 x 16.00 = 48.00 = 169.88 g C2H4O2 Calcium hydroxide Ca(OH)2 60.06 g 74.1 g (NH4)2CO3 sodium phosphate 96.1 g Na3PO4 163.94 g Fe3(PO4)2 diboron hexahydride 357.49 g B2H6 27.68 g Zn(C2H3O2)2 sulfur hexachloride 183.43 g SCl6 244.76 g Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 3 ANSWER KEY Find the percent composition of each element in the compounds below. 10. Silver perchlorate, AgClO4 %Ag=___52.03%_______ %Cl= ___17.10%___ %O= ____30.87%______ MM = 207.32 g ________________________________________________________________ 11. Barium acetate, Ba(C2H3O2)2 %Ba = 53.78% %C = 18.79% %H = 2.37% %O = 25.06% MM = 255.39 g ________________________________________________________________ 12. Acetone, C3H6O %C =62.00% %H =10.44% %O = 27.56% MM = 58.06 g ________________________________________________________________ Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 4 ANSWER KEY For # 13-16, convert the following quantities from grams to moles. Use the example below to help you: “How many moles are in 98.3 grams of aluminum hydroxide, Al(OH)3?” Step 1: Find the molar mass. Al(OH)3 is 26.98 + (3 x 16.00) + (3 x 1.01) = 78.01 g/ mole Step 2: Set up the equation and solve 98.3 grams x 1 mole____ = 1.2601 moles Al(OH)3 = 1.26 moles 78.01 grams 13. How many moles are there in 12.3 grams of carbon dioxide? 0.27 mol 14. How many moles are there in 89 grams of Pb(C2H3O2)4? 0.20 mol 15. How many moles are there in 110 grams of sodium bicarbonate? 1.31 mol 16. How many moles are there in 98.3 grams of aluminum hydroxide, Al(OH)3? 1.26 mol Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 5 ANSWER KEY For # 17-20, convert the following quantities from moles to grams. Use the example below to help you: “How many grams are in 4.5 moles of sodium fluoride, NaF?” Step 1: Find the molar mass of NaF: 22.99 + 19.00 = 41.99 g/ mole Step 2: Set up the equation and solve 4.5 moles x 41.99 grams 1 mole = 188.955 g NaF = 190 g NaF 17. How many grams are in 0.02 moles of beryllium iodide? BeI2, 5.35 g 18. How many grams are in 5.6 moles of C6H6? 437.14 g 19. How many grams are in 1.2 moles of (NH4)3PO3? 159.74 g 20. How many grams are in 5.4 moles of potassium sulfate? K2SO4, 941.00 g Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 6 ANSWER KEY Stoichiometry – Mole Ratios 21. Zn + 2HCl ZnCl2 + H2 A. How many moles of Zn are needed to completely react with 2 moles of HCl? 1 mol B. How many moles of H2 are produced with 1 mole of Zn? 1 mol C. How many moles of Zn are needed to completely react with 4 moles of HCl? 2 mol 22. 2 Ag2O 4 Ag + O2 A. How many moles of oxygen are produced by the decomposition of 2 moles of Ag2O? 1 mol B. How many moles of oxygen are produced by the decomposition of 4 moles of Ag2O? 2 mol C. How many moles of Ag are produced by the decomposition of 4 moles of Ag2O? 8 mol Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 7 ANSWER KEY 23. 2NaBr + CaF2 2NaF + CaBr2 A. Balance the reaction. B. For every one mole of CaF2, how many moles of NaBr are needed? 2 mol C. How many moles of NaF are produced from the reaction of 4 moles of NaBr? 4 mol Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 8 ANSWER KEY Stoichiometry - Percent Yield 24. Balance the following equation: 2KClO3 2KCl + 3 O2 A. For every 2 moles of KClO3, ____2___ moles of KCl should be produced. B. For every 2 moles of KClO3, ___3_____ moles of O2 should be produced. C. For every 4 moles of KClO3, __3______ moles of O2 should be produced. 25. Lab Scenario The above decomposition reaction was completed in the lab using 245.1 g KClO3. Use the steps below to find the mole ratio between KClO3 and O2. A. Find the molar mass of KClO3. 122.55 g B. Convert the amount of KClO3 used in the lab (245.1 g KClO3) to moles of KClO3. 2 mol C. After the reaction was completed, 90 grams of O2 were produced and collected. Convert this to moles of O2 2.81 mol D. Determine the mole ratio of KClO3 to O2 from the lab data. This would be your answer from B and C written as a ratio. 2 mol KClO3 : 2.81 mol O2 E. Compare your ratio from D to the ratio in the balanced equation (answer to #2). Determine the percent yield. % yield = Actual moles of O2 x 100 Theoretical # of moles O2 = 93.67% Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 9 ANSWER KEY 26. Stoichiometry – Limiting Reagent The following chemical reaction was performed: 3H2 N2 + 2NH3 A. Balance the chemical equation. B. 7 grams of N2 were reacted with 0.5 grams of H2. Fill in the information below to find out which reactant was the limiting reactant: 1. How many moles are in 7 grams of N2? 0.25 mol 2. How many moles are in 0.5 grams of H2? .25 mol 3. What is the mole ratio of N2:H2 according to the balanced chemical equation? __1__ mol N2 : __3__ mol H2 4. What is the mole ratio of N2:H2 according to the calculations you did for 1 and 2? __0.25__ mol N2 : __0.25__ mol H2 5. Which must be the limiting reactant, N2 or H2? Explain why using your answers from 3 & 4. H2 is the limiting reactant Unit 6 Test Study Guide Callahan, Pengitore & Ricafort - 2014 10