Vidic, 2:00 R21 FUEL-CELL CARS: FUELING THE FUTURE Jacob Kuhn (jak217@pitt.edu) INTRODUCTION: ‘FUEL CELL CARS’: MEETING ENERGY, HEALTH AND ENVIRONMENTAL NEEDS Cars, buses, trucks, and sport utility vehicles are all adding to a growing set of problems with their daily usage. These problems affect not only the United States of America, but the world as a whole. The issues being referenced are global warming, human and environmental endangerment, and depletion of fossil fuels. Both the environment and our bodies can’t fight off such pollutants and the fossil fuels of today’s vehicles will eventually run out. Due to the problems associated with combustion engine vehicles, fuel cell technologies need to be further researched and incorporated in the mass production vehicles of today. This research paper will evaluate on the previously stated points and prove the importance of both the engineering ethics to the production of fuel cell vehicles and the importance of this assignment to an engineering student’s education and role in society. FUEL CELL TECHNOLOGY: PERSONAL INTEREST When considering a topic for this research paper, I had many options to choose from. Fuel cell technology stood out to me as the most important topic I could write about for two reasons, the first of which being my engineering field of choice. I aspire to be a mechanical engineer upon graduation from the University of Pittsburgh. Mechanical engineering is defined as the branch of engineering that encompasses the generation and application of heat and mechanical power and the design, production, and use of machines and tools [1]. Therefore, cars would be included in this field of study and I will most likely be involved with some type of vehicular work in either college or during my career. The second reason for choosing this topic came from the impact of such subject on my life. When I imagine a world that hasn’t developed the technology to survive University of Pittsburgh, Swanson School of Engineering 10/30/2012 1 without gasoline to power our vehicles, I see a world that will crumble when such time comes. MECHANICAL ENGINEERING: “ETHICS AND ADVANCEMENT” As stated in the preamble of the engineering code of ethics: “Engineering is an important and learned profession. As members of this profession, engineers are expected to exhibit the highest standards of honesty and integrity. Engineering has a direct and vital impact on the quality of life for all people. Accordingly, the services provided by engineers require honesty, impartiality, fairness, and equity, and must be dedicated to the protection of the public health, safety, and welfare. Engineers must perform under a standard of professional behavior that requires adherence to the highest principles of ethical conduct.” With such code of ethics to abide by, I feel that mechanical engineers have a duty to society to advance and perfect fuel cell technology. The first area that mechanical engineers must take into consideration when designing and constructing fuel cell vehicles is the first fundamental canon under the NSPE code of ethics: “Engineers shall hold paramount the safety, health, and welfare of the public”[2]. Therefore, when ethics are in place the public could not be directly put in harm’s way by driving a fuel cell vehicle that was built with their safety, health, welfare in mind. I would rather drive a car that I know is safe for any passengers and myself inside due to a code that holds those who designed this car to assuring it is the best option for the public. I imagine this feeling is almost universal due to the importance of one’s safety while operating a motor vehicle. The code of ethics is also guiding us to fuel cell vehicles based on the idea of the importance of public health. This paper will go into further detail about how combustion engines create harmful byproducts later, but in short, fuel cell vehicles are the public’s best option based on their lack of negative impact on human health. This idea of health impact also ties in with a statement from the ASME’s Jacob Kuhn code of ethics: “Engineers shall consider environmental impact in the performance of their professional duties”[3]. If mechanical engineers did not further research and attempt to develop more efficient fuel cell vehicles, they would not be pursuing what is best for the environment. It has been proven and will be noted later why combustion engines are worse for our environment and therefore, if the cleaner fuel cell vehicles aren’t researched then mechanical engineers would not be following their code of ethics to keep the environment a first priority. Therefore, with the NSPE and ASME’s codes of ethics in place, mechanical engineers should advance and perfect fuel cell technology based on such codes. Considering the ethics and information I have uncovered about my engineering discipline of choice and important projects, I feel I will be an effective part of the engineering community due to the contributions I could make. I feel I will put the environment and the public’s safety, health, and welfare first as I search for new breakthroughs in the mechanical processes of today. My support of fuel cell vehicles is a primary example of my value of ethics and how important they are in engineering. world sea levels rising due to melting ice, increased precipitation, worsening and more commonly occurring natural disasters, lack of fresh water, spread of diseases and changing ecosystems. These effects would destroy the world as we know it and investing more money and research into fuel cell vehicles could help the situation. Fuel cell vehicles could stop the pollution created by combustion engines and in turn extend the span of time that our planet is livable by slowing global warming and not destroying our ecosystems. Fuel cell cars operate while only creating the byproduct of water. While fuel-cell vehicles are similar to battery-electric vehicles, a fuel-cell vehicle uses an onboard storage structure filled with hydrogen, which is today’s best option. Hydrogen can be produced domestically from several sources, reducing our dependence on petroleum imports. Hydrogen also produces no air pollutants or greenhouse gases when used in fuel cells. A fuel-cell car utilizes the fuel cell’s ability to transform hydrogen input into an output of electricity. This electricity produced by the fuel cell is then used to power motors at the vehicle's wheels. Although fuelcell vehicles are similar to battery-electric vehicles due to being powered by electricity, they don’t require recharging and produce distilled water as a clean byproduct [5]. Fuel-cell vehicles require a simple refilling of their onboard storage tanks of hydrogen. The process of refueling a hydrogen tank is almost identical to that of a combustion engine’s refueling process. A customer would pay for hydrogen at a pumping station and hook a hose up to a port in their car to force more hydrogen in to their on board storage tanks. Therefore, when the fuel-cell car’s power system is compared to that a harmful byproduct producing combustion engine, it is clear that time and money must be invested in the development of more fuel-cell vehicles. FUEL CELL BYPRODUCTS: WATER WINS OVER GLOBAL WARMING A major factor in the case against today’s vehicles and for the fuel cell cars of the future, is the waste or byproducts of the processes used to operate each system and the impact they have on our environment. According to the Environmental Defense Fund, cars annually release approximately 333 million tons of carbon dioxide, fifty-two percent of reactive hydrocarbons and seventy-two percent of the nitrogen oxides into the Earth’s atmosphere [4]. When the previously noted byproducts are created, possible health and environmental issues, that will be noted later, are created. The 333 million tons of carbon dioxide previously noted is equivalent to 20 percent of the world’s total. With the introduction of fuel cell cars, this massive amount of pollutant would be eliminated from being created by vehicles. Global warming, which is caused by the large amount of pollutants created due to today’s gasoline combustion engines, can lead to serious problems for our planet. These effects could include but are not limited to: COMBUSTION ENGINE AIR-BORNE POLLUTANTS: ILLNESS CAUSING PARTICLES Today’s combustion engines generate power to move vehicles by burning fuel in an engine. Pollution created in gasoline-burning cars in comparison to clean fuel-cell cars can be broken into two major 2 Jacob Kuhn categories: the byproducts of the combustion and the evaporation of the fuel. When fuel molecules in an engine don’t burn fully or at all, hydrocarbon emissions are created. Sunlight and nitrogen oxides cause hydrocarbons to react and ground-level ozone is formed [4]. Groundlevel ozone is necessary to form smog, a major environmental danger, and such a byproduct isn’t created by a fuel cell car. Ozone is a difficult air pollution to maintain and is widespread. It damages the health and capacity of the lungs, bothers the eyes, and can create respiratory problems [4]. The emissions of today’s gasoline and diesel burning vehicles aren’t limited to just causing ground-level ozone to be formed, but can also cause cancer due to their toxicity. Nitrogen oxides, another pollutant and byproduct of combustion, are formed by oxygen and nitrogen atoms that are placed under the high temperatures and pressures of an engine [4]. These dangerous byproducts, which would not be created by fuel cell vehicles, also aid in forming the previously discussed dangerous ground-level ozone. These byproducts can also contribute to the formation of the destructive acid rain. Incomplete combustion occurs when carbon in the fuel isn’t fully oxidized to from the normal byproduct of carbon dioxide, which will be mentioned following this point. When incomplete combustion occurs, a byproduct of carbon monoxide is created. Reducing the flow of oxygen in the bloodstream is an effect of exposure to carbon monoxide [4]. Carbon monoxide can also be harmful to those with heart conditions. Carbon dioxide is the most commonly recognized byproduct of combustion. It is known to contribute to the “greenhouse gas effect,” and could be a serious health factor if constant deforestation continues to occur. The “greenhouse gas effect,” a problem which fuel-cell cars would not add to, is contributing to global warming by containing the earth’s heat. Besides the previously noted method of combustion causing hydrocarbon production, evaporation of fuel from a gasoline or diesel system contributes to pollution. The four types of evaporation include diurnal, running losses, hot soak, and refueling [1]. Diurnal encompasses gasoline evaporating due to the temperature outside heating the tank of fuel and gasoline vapors leak due to such conditions. Running losses refers to the vaporization of gasoline caused by the heat of the car’s exhaust system and engine. Hot soak follows running losses as the engine remains at a high temperature after turning the vehicle off and more gasoline is evaporated. Refueling causes vapors to be removed from the tank due to the fuel that is now occupying that space. Fuel-cell vehicles don’t create pollutants via combustion or evaporation due to neither process being a possibility. Combustion doesn’t occur in this type of vehicle and the fuel is hydrogen, therefore no leakage of gasoline vapors could occur when it is not present. Fuel-cell cars need to be invested to in to save our health and our environment’s. COMBUSTION BYPRODUCTS: BODILY SYSTEMS IMPACT Although the individual impacts of car emissions vary from person to person, these emissions have proven to cause a variety of health problems. The consensus on emissions is that more exposure leads to more health concerns. Any individual with previous underlying health conditions will be at a greater risk due to such. Car emissions have a large impact on the human respiratory system. An estimated 24,000 premature deaths occur annually in the United Kingdom due to the air pollution [6]. Bronchitis and asthma are two major causes of deaths that are linked to the respiratory system and poor air quality. Poor air quality is linked to the emissions from the today’s combustion engines. Therefore, introducing fuel-cell vehicles to the market would eliminate such problems. According to a Dutch study, an increase in the number of respiratory disorders occurred when the condition of the air worsened due to pollution. This study was of 632 children aged seven to eleven years old. The Dutch study also found that areas of high nitrogen dioxide and emissions particles lead to more illnesses from disorders of the lungs [6]. The blood and coronary system are also affected by the dangerous pollutants of combustion engines. An estimated 50 heart attacks occur annually in London which can be linked to the air pollution due to car emissions [6]. 3 Jacob Kuhn is expected to last the next forty-two years if today’s rate of oil use continues. This is alarming amount of time when there hasn’t been a major push to find alternative fuel sources when oil has been depleted. A primary example of a problem causing byproducts is lead. The normal formation of red blood cells is hindered due to the properties of lead which impede important enzymes. It also causes damage to the membrane of the red blood cells and affects the metabolism of the cell. When the metabolism of the cell is altered, it shortens the life span of each cell which can lead to anemia. Anemia reduces the ability to circulate vital nutrients and oxygen throughout the body. Benzene, a secondary example of harm done to the blood and coronary system, decreases the amount of bone marrow and red blood cells created by the human body. Benzene exposure can cause cytopenia, a total loss of bone marrow, and anemia. Carbon monoxide is another potential danger to our bodies which can be linked to combustion engine exhaust. Carbon monoxide poisoning occurs when carbon monoxide binds to the red blood cells’ hemoglobin and is similar to asphyxiation. The cells’ abilities to transport and release oxygen to the body’s tissues is negatively affected by the bonding of carbon monoxide to the hemoglobin. Fuel-cell vehicles don’t create pollutants which can harm any of the body’s systems and should be focused on by our government as the transportation option of the near future. FUEL-CELL PROGESSION: ROAD BLOCKS TO PRODUCTION With all the positive things for the implementation of fuel-cell vehicles, there are also reasons that have kept them from being mass produced. The first and considerably most consumer important reason is the high cost that is associated with the vehicles. These vehicles would cost up to ten times that of a combustion engine vehicle and the fuel cell vehicle would not be price effective over its duration at this time. Fuel cells are high in price due to the catalyst necessary to split hydrogen to create energy. The best-known catalyst at this is platinum which is driving up the price of these vehicles. Alternative catalysts would be a necessary area of research with an input of research funds from the government. A second major concern is the durability and safety associated with fuel cell vehicles. Fuel cell vehicles require on-board storage tanks of hydrogen to store its fuel source. The storage tanks would have to be able to prevent the hydrogen from freezing. This feature would add to the price and weight of such storage systems. These tanks could also be a concern due to the extra weight they add to the vehicle and the potential problem of an explosion. Although this is a concern with combustion engine vehicles as well, a possible explosion could result from a punctured hydrogen tank exposed to a flame. These factors need to be overcome through research that would make these vehicles more appealing to consumers. A third major step to incorporating fuel cell vehicles in today’s world is the development of hydrogen fueling stations. These stations would have to be as ready available as gas stations. This major step of production would require a government investment to get these established. FUEL CELL TECHNOLOGY: NOT DEPENDENT ON A DYING RESOURCE Although oil has satisfied the past and present needs of the automobile industry, it will run out in the future as it is a non-renewable resource. Before this time comes, the people of earth must be ready to adapt to life without such a resource. Hydrogen will outlast oil due to its properties of renewability. Air and water can be used to generate hydrogen and it can be refined from resources that are non-renewable. Hydrogen is the most common gas in the universe and its power is greater than gasoline’s when measured by weight. BP oil figures revealed global reserves to be at 1.258 trillion barrels, which was three billions less than the previous year’s estimate [7]. This drop in the global oil reserves was the first reported decrease in global reserves in the last decade. This supply of oil 4 Jacob Kuhn EDUCATIONAL VALUE: “RESEARCH AND ETHICS” would lack experience with making a decision on a major engineering issue. I would highly recommend other universities adopting a project similar to this one for their students to take on. An important step to any mechanical engineer’s success is his or her education and what they could take away from that education. I will use examples from my personal experience with this assignment to prove its importance in the education of any freshman engineering student. When a student puts in the research and time towards an engineering issue and the impact of ethics on such issue, they have changed their way of analyzing problems and have put themselves on a side of a critical issue. I personally have learned more about the field of mechanical engineering through this project and about the engineering issues that present themselves in this field. Anne Colby and William M. Sullivan make a great statement in Ethics Teaching in Undergraduate Education about how important a project like this is: “Engineering education cannot fully prepare students to handle successfully the most difficult situations in which their work seems to entail risks to the public, but helping students to understand and deeply internalize the core values of safety and environmental protection can sensitize them to these issues and flag for them the kinds of situation in which action of some kind may be necessary. In order to be prepared for practice that embodies these values, students need to develop a keen awareness of the potential risks of their work, both immediate and long-term; they need to experience grappling with the inevitable trade-offs between safety or environmental sustainability and other concerns, such as cost and time pressures; they need help thinking about whether and how their responsibilities regarding safety and human welfare vary depending on their particular role in their workplace; and they need support in developing personal qualities like the courage needed to make and carry out difficult decisions” [8]. I personally notice how a mechanical engineer would have to balance between making the fuel cell car a great option on the basis of environmental impact, but also a safe and affordable car for a consumer. Without performing the necessary research and dedicating my time to this paper, I would not have thought in such a manner before and CONCLUSION: “FUEL-CELL CARS”: CARS FOR A BETTER FUTURE With a political election quickly approaching our country, voters should look to their environment, their health, and their futures when deciding how to judge a candidate’s standpoint on fuel-cell car development. We must also make ethics a concern in the education of engineering students and in the process of designing and constructing fuel cell vehicles. With a crisis on the horizon and money not invested into the mass development of fuel-cell vehicles, citizens should know how harmful to themselves and their environment standard combustion engines are. Although there are some temporary roadblocks to the success of fuel-cell vehicles, with the investment of the government research can be done to improve and perfect these vehicles. When situations such as safety, cost, and refueling are taken care, fuel cell vehicles would be the best option in the transportation industry. If the eighty-five percent of Americans that travel via combustion engine transportation switched to fuelcell vehicles, the problems previously noted would almost vanish. Dangers such as global warming, anemia, premature deaths, cytopenia, damaged red blood cells and running out of fuel would be fears of the past if fuel-cell cars became the vehicle of choice. Whether the United States plans to deal with these possible crises when they are presented or before they arise, mass production of fuel-cell vehicles is the best option to satisfy the needs of the modern world. RESOURCES [1] Chase, Robin. (2010). "You Asked: Does Everyone in America Own a Car?" U.S. Department of State, Bureau of International Information Programs. (Online Article). http://www.america.gov/st/peopleplaceenglish/2010/ March/20100316154329fsyelkaew0.8109356.html. 5 Jacob Kuhn [2] (2012) "NSPE Code of Ethics for Engineers." NSPE Code of Ethics for Engineers. (Online Article) http://www.nspe.org/Ethics/CodeofEthics/index.html transportation-solutions/advanced-vehicletechnologies/fuel-cell-cars/fuel-cell-vehicles.html. [3] (2012) "Code of Ethics of Engineers." Code of Ethics. (Online Article) http://sections.asme.org/colorado/ethics.html. [6] Macnair, Trisha. (2011). "Exhaust Emissions." BBC News; Health. (Online Article). http://www.bbc.co.uk/health/physical_health/conditio ns/exhaust_emissions.shtml. [4] (2010). "The Environmental Impact of Vehicle Emissions." Illinois Environmental Protection Agency. (Online Lecture Notes). http://www.epa.state.il.us/air/vim/guide/air_pollution. html. [7] Macalister, Terry (2009). "Are We Running out of Oil? The World in Energy Statistics." The Guardian. (Online article). http://www.guardian.co.uk/environment/datablog/200 9/nov/10/energy-statistics-oil-coal. [5] (2010). "Fuel Cell Vehicles." Citizens and Scientists for Environmental Solutions; Union of Concerned Scientists. (Online Blog). http://www.ucsusa.org/clean_vehicles/smart- [8] Colby, Anne, and William M. Sullivan. (2008) "Ethics Teaching in Undergraduate Engineering Education." Journal of Engineering Education. http://www.jee.org/2008/july/10.pdf. ACKNOWLEDGEMENTS I would like to thank my roommate, Mr. Alexandru Pascal, for his support and assistance with this assignment. 6