Towards Quantitative Understanding of the Design of Nanostructured Catalysts Hong Yang Department of Chemical and Biomolecular Engineering, University of Illinois at UrbanaChampaign, 206 Roger Adams Laboratory, 600 S. Mathews Avenue, Urbana, IL 61801, USA; hy66@illinois.edu Preparation of nanoparticle catalysts becomes more and more sophisticated in order to meet the increasingly stringent structural requirements for advanced performance in high activity and selectivity. New approaches have been developed in recent years in the control of nanocrystal size, facet, composition and various core-shell structures in order to tackle the challenges. Such research endeavors result in a new push for better quantitative understanding of nucleation and growth kinetics in solution. In this talk, I will focus on our recent work in the following topical areas: 1) the solution processing of metal nanoparticles, especially the production of uniform, facet-defined catalysts using carbon monoxide as a processing gas. The formation of shape- and composition-controlled multimetallic nanostructures will be discussed, including alloys in their so-called immiscibility regime of their bulk counterparts; 2) theoretical and experimental understanding of ligand chemistry in the design and controlled synthesis of metal catalysts; 3) in situ liquid flow cell technology for transmission electron microscopy technique in the understanding of nucleation and growth of heterogeneous nanoparticle catalysts; 4) in situ, variable temperature environmental TEM (ETEM) study of structural behavior of catalyst under reactive conditions; and 5) structure and property relationship of catalysts for the electrochemical reduction of oxygen and other reactions. Biosketch: Prof. Hong Yang is the Richard C. Alkire Professor of Chemical Engineering at the University of Illinois at Urbana-Champaign (UIUC). He received his B.Sc. degree from Tsinghua University (1989), M.Sc. degree from University of Victoria (1994), and Ph.D. degree from University of Toronto (1998). For his PhD work, he was warded one of the two NSERC Canada Doctoral Prize in Science. After working at Harvard University as an NSERC postdoctoral fellow, he started his independent research and rose through the academic ranks at University of Rochester before joining the faculty of UIUC in 2012. Dr. Yang is an NSF CAREER Award recipient. He is a Section Editor for Current Opinion in Chemical Engineering (Elsevier) and serves on the Editorial Boards of Nano Today (Elsevier), ChemNanoMat (VCH), Science China Materials (Springer), and other journals. His research interests include understanding the formation of nanocrystals, surface modification, catalysis, and nanomaterials for energy and biological applications.