Name:__________________________________ Equilibrium/Le Chat Review On a separate piece of paper, do the following: 1. Write the expression for the equilibrium constant (Keq) for each of the reactions given. a. N2(g) + 3H2(g) ↔ 2NH3(g) b. 2KClO3(s) ↔ 2KCl(s) + 3O2(g) c. H2O(l) ↔ H+1(aq) + O-1 (aq) d. 2CO(g) + O2(g) ↔ 2CO2(g) e. Li2CO3(s) ↔ 2Li+1(aq) + CO3-2(aq) f. 2NO2(g) ↔ N2O4(g) g. 2BrNO(g) ↔ 2NO(g) + Br2(g) h. H2O(l) + HF(aq) ↔ H3O+1(aq) + F-1(aq) 2. Consider the following reaction: 2H2S(g) ↔ 2H2(g) + S2(g) . Find the mistakes in the following equilibrium expression, fix them, and explain. Keq = [H2] [S2] / [H2S] 3. Consider the following reaction: CO(g) + Cl2(g) ↔ COCl2(g) . Find the mistakes in the following equilibrium expression, fix them, and explain. Keq = [CO] [Cl2] / [COCl2] 4. Go back to Question 1 and calculate the value of Keq for each reaction when given the following concentrations: a. [N2]=0.0200 M, [H2]=0.0200 M, [NH3]=0.0100 M b. [O2]=0.0500 M c. [H+1]=1x10-8 M, [OH-1]=1x10-6 M d. [CO]=2.0 M, [O2]=1.5 M, [CO2]=3.0 M 5. For each of the following equilibrium constants, indicate whether you would expect an equilibrium reaction mixture to be dominated by reactants, dominated by products, or to contain significant amounts of both: a. 5.2x1017 b. 12.4 c. 3.22x10-21 d. 0.047 e. 0.95 f. 8.5x10-7 g. 1.4x1019 6. An equilibrium mixture of the following reaction (SbCl5(g) ↔ SbCl3(g) + Cl2(g) ) was found to have [SbCl3]=0.0298 M and [Cl2]=0.105 M at 248 deg C. Keq at 248 deg C = 4.9x10-4. What is the concentration of the SbCl5? 20. Fill out the tables below, using Le Chatelier’s Principle for the following reactions: N2(g) + 3H2(g) ↔ 2NH3(g) + heat Stress Direction of Shift [N2] [H2] [NH3] Add N2 Add H2 Remove N2 Remove H2 Remove NH3 Increase Temp Decrease Temp Increase Pressure Decrease Pressure Heat + H2(g) + I2(g) ↔ 2HI(g) Stress Add H2 Add I2 Add HI Remove H2 Remove I2 Remove HI Increase Temperature Increase Pressure Direction of Shift [H2] [I2] [HI3]