1. Which form of electromagnetic radiation has the longest wavelengths? a) gamma rays b) microwaves c) radio waves d) infrared radiation e) x-rays Ans: c Algorithm: No Chapter/Section: 7.1 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: electromagnetic radiation 2. Which of the following frequencies corresponds to light with the longest wavelength? a) 3.00 1013 s–1 b) 4.12 105 s–1 c) 8.50 1020 s–1 d) 9.12 1012 s–1 e) 3.20 109 s–1 Ans: b Algorithm: No Chapter/Section: 7.1 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: electromagnetic radiation 3. Which of the following are incorrectly paired? a) wavelength – b) frequency – c) speed of light – c d) hertz – s–1 e) x-rays – shortest wavelength Ans: e Algorithm: No Chapter/Section: 7.1 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: electromagnetic radiation 4. When a strontium salt is ignited, it burns with a red flame. The frequency of the light given off by this flame is greater than a) yellow light b) infrared light c) ultraviolet light d) radio waves e) x-rays Ans: b Algorithm: No Chapter/Section: 7.1 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: electromagnetic radiation 5. Green light can have a wavelength of 512 nm. The energy of a photon of this light is a) 1.02 10–31 J b) 5.12 10–7 J c) 3.88 10–19 J d) 5.86 1014 J e) 2.58 1018 J Ans: c Algorithm: Yes Chapter/Section: 7.2 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: electromagnetic radiation 6. Consider an atom traveling at 1% of the speed of light. The de Broglie wavelength is found to be 3.32 10–3 pm. Which element is this? a) He b) Ca c) Hg d) Be e) P Ans: b Algorithm: Yes Chapter/Section: 7.2 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: quantum mechanics Keyword 5: de Broglie relation 7. T F Diffraction results when light is scattered from a regular array of points or lines. Ans: True Algorithm: No Chapter/Section: 7.2 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light 8. T F All matter exhibits either particulate or wave properties exclusively. Ans: False Algorithm: No Chapter/Section: 7.2 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light 9. The four lines observed in the visible emission spectrum of hydrogen tell us that: a) The hydrogen molecules they came from have the formula H4. b) We could observe more lines if we had a stronger prism. c) There are four electrons in an excited hydrogen atom. d) Only certain energies are allowed for the electron in a hydrogen atom. e) The spectrum is continuous. Ans: d Algorithm: No Chapter/Section: 7.3 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: Bohr theory Keyword 6: atomic line spectra Use the following to answer questions 10-11: Consider the following portion of the energy-level diagram for hydrogen: 10. n=4 –0.1361 10–18 J n=3 –0.2420 10–18 J n=2 –0.5445 10–18 J n=1 –2.178 10–18 J For which of the following transitions does the light emitted have the longest wavelength? a) n = 4 to n = 3 b) n = 4 to n = 2 c) n = 4 to n = 1 d) n = 3 to n = 2 e) n = 2 to n = 1 Ans: a Algorithm: No Chapter/Section: 7.4 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: Bohr theory Keyword 6: atomic line spectra 11. In the hydrogen spectrum, what is the wavelength of light associated with the n = 4 to n = 1 electron transition? a) 5.96 10–25 nm b) 1.46 103 nm c) 1.03 107 cm d) 2.04 10–18 m e) 9.73 10–8 m Ans: e Algorithm: Yes Chapter/Section: 7.4 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: Bohr theory Keyword 6: atomic line spectra 12. Which of the following statements is (are) true? An excited atom can return to its ground state by absorbing electromagnetic I. radiation. II. The energy of an atom is increased when electromagnetic radiation is emitted from it. III. The energy of electromagnetic radiation increases as its frequency increases. IV. An electron in the n = 4 state in the hydrogen atom can go to the n = 2 state by emitting electromagnetic radiation at the appropriate frequency. V. The frequency and wavelength of electromagnetic radiation are inversely proportional to each other. a) II, III, IV b) III, V c) I, II, III d) III, IV, V e) I, II, IV Ans: d Algorithm: No Chapter/Section: 7.4 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light 13. T F Bohr's model correctly describes the hydrogen atom and other small atoms. Ans: False Algorithm: No Chapter/Section: 7.4 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: light Keyword 5: Bohr theory 14. If n = 2, how many orbitals are possible? a) 3 b) 4 c) 2 d) 8 e) 6 Ans: b Algorithm: No Chapter/Section: 7.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: quantum mechanics Keyword 5: quantum numbers 15. A given set of p orbitals consists of ______ orbitals. a) 1 b) 2 c) 3 d) 4 e) 5 Ans: c Algorithm: No Chapter/Section: 7.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: quantum mechanics Keyword 5: quantum numbers 16. Which of the following is an incorrect designation for an atomic orbital? a) 1s b) 3d c) 1p d) 4f e) 6s Ans: c Algorithm: No Chapter/Section: 7.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: quantum mechanics Keyword 5: quantum numbers 17. The number of orbitals having a given value of l is equal to a) 2l + 1 b) 2n + 2 c) 3l d) l + ml e) the number of lobes in each orbital Ans: a Algorithm: No Chapter/Section: 7.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: quantum mechanics Keyword 5: quantum numbers Keyword 6: angular momentum quantum number 18. T F The magnetic quantum number is related to the orientation of the orbital in space relative to the other orbitals in the atom. Ans: True Algorithm: No Chapter/Section: 7.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: quantum mechanics Keyword 5: quantum numbers Keyword 6: magnetic quantum number 19. Which of the following combinations of quantum numbers is not allowed? a) n = 1, l = 1, ml = 0, ms = 1 2 b) n = 3, l = 0, ml = 0, ms = - 1 2 c) n = 2, l = 1, ml = -1, ms = 1 2 d) n = 4, l = 3, ml = -2, ms = - 1 2 e) n = 4, l = 2, ml = 0, ms = 1 2 Ans: a Algorithm: No Chapter/Section: 7.8 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: quantum mechanics Keyword 5: quantum numbers 20. The small, but important, energy differences between 3s, 3p, and 3d orbitals are due mainly to a) the number of electrons they can hold b) their principal quantum number c) the Heisenberg uncertainty principle d) the penetration effect e) Hund's rule Ans: d Chapter/Section: 7.9 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: quantum mechanics 21. The complete electron configuration of antimony is a) 1s22s22p63s23p64s23d104p65s24d105d105p3 b) 1s22s22p63s23p64s23d104d104p3 c) 1s22s22p63s23p64s24p65s24d105d105p3 d) 1s22s22p63s23p64s23d104p65s24d105p3 e) none of these Ans: d Algorithm: Yes Chapter/Section: 7.11 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: electronic structure of atoms Keyword 5: electron configuration Keyword 6: aufbau principle 22. Which of the following statements about quantum theory is incorrect? a) The energy and position of an electron cannot be determined simultaneously. b) Lower energy orbitals are filled with electrons before higher energy orbitals. c) When filling orbitals of equal energy, two electrons will occupy the same orbital before filling a new orbital. d) No two electrons can have the same four quantum numbers. e) All of these are correct. Ans: c Algorithm: No Chapter/Section: 7.11 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory 23. Ti has __________ in its d orbitals. a) one electron b) two electrons c) three electrons d) four electrons e) none of these Ans: b Algorithm: No Chapter/Section: 7.11 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: electronic structure of atoms Keyword 5: electron configuration 24. Germanium has __________ in its 4p orbitals. a) one electron b) two electrons c) three electrons d) four electrons e) none of these Ans: b Algorithm: No Chapter/Section: 7.11 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: electronic structure of atoms Keyword 5: electron configuration Use the following to answer questions 25-26: Nitrogen has five valence electrons. Consider the following electron arrangements. 2s 25. 2p a) b) c) d) e) Which represents the ground state for N? a) option a b) option b c) option c d) option d e) option e Ans: a Algorithm: No Chapter/Section: 7.11 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: electronic structure of atoms Keyword 5: electron configuration Keyword 6: orbital diagram 26. Which represents the ground state for the N– ion? a) option a b) option b c) option c d) option d e) option e Ans: e Algorithm: No Chapter/Section: 7.11 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: electronic structure of atoms Keyword 5: electron configuration Keyword 6: orbital diagram 27. In which group do all the elements have the same number of valence electrons? a) P, S, Cl b) Ag, Cd, Ar c) Na, Ca, Ba d) P, As, Se e) none of these Ans: e Algorithm: No Chapter/Section: 7.11 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: electronic structure of atoms Keyword 5: electron configuration 28. Which of the following electron configurations is correct? a) Ga: [Kr]4s23d104p1 b) Mo: [Kr]5s24d5 c) Ca: [Ar]4s13d10 d) Br: [Kr]4s23d104p7 e) Bi: [Xe]6s24f145d106p3 Ans: e Algorithm: No Chapter/Section: 7.11 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: electronic structure of atoms 94. Which of the following processes represents the ionization energy of bromine? a) Br+(g) + e– Br(s) b) Br+(g) + e– Br(l) c) Br+(g) + e– Br(g) d) Br+(s) + e– Br(s) Br2+(g) + e– e) Br2(g) Ans: c Algorithm: No Chapter/Section: 7.12 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: periodicity of the elements Keyword 5: periodic properties Keyword 6: ionization energy 29. Order the elements S, Cl, and F in terms of increasing ionization energy. a) S, Cl, F b) Cl, F, S c) F, S, Cl d) F, Cl, S e) S, F, Cl Ans: a Algorithm: No Chapter/Section: 7.12 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: periodicity of the elements Keyword 5: periodic properties Keyword 6: ionization energy 30. Order the elements S, Cl, and F in terms of increasing atomic radii. a) S, Cl, F b) Cl, F, S c) F, S, Cl d) F, Cl, S e) S, F, Cl Ans: d Algorithm: No Chapter/Section: 7.12 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: periodicity of the elements Keyword 5: periodic properties Keyword 6: atomic radius 31. Which of the following atoms would have the largest second ionization energy? a) Mg b) Cl c) S d) Ca e) Na Ans: e Algorithm: No Chapter/Section: 7.12 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: periodicity of the elements Keyword 5: periodic properties Keyword 6: ionization energy 32. The first ionization energy of Mg is 735 kJ/mol. The second ionization energy is a) 735 kJ/mol b) less than 735 kJ/mol c) greater than 735 kJ/mol d) More information is needed to answer this question. e) None of these. Ans: c Algorithm: No Chapter/Section: 7.12 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: periodicity of the elements Keyword 5: periodic properties Keyword 6: ionization energy 33. Consider the following orderings. + 2+ 3+ I. Na < Mg < Al < Si II. Be < Mg < Ca < Sr III. I < Br < Cl < F 4+ IV. Al < Si < P < Cl Which of these give(s) a correct trend in ionization energy? a) III b) II, IV c) I, IV d) I, III, IV e) none of them Ans: d Algorithm: No Chapter/Section: 7.12 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: periodic table Keyword 5: periodic properties Keyword 6: ionization energy 34. Which of the following statements is false? a) A sodium atom has a smaller radius than a potassium atom. b) A neon atom has a smaller radius than an oxygen atom. c) A fluorine atom has a smaller first ionization energy than an oxygen atom. d) A cesium atom has a smaller first ionization energy than a lithium atom. e) All are true. Ans: c Algorithm: No Chapter/Section: 7.12 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: atomic theory Keyword 4: periodicity of the elements Keyword 5: periodic properties Keyword 6: atomic radius 35. The ratio of the atomic radius to the nuclear radius is approximately: a) 10–5 b) 105 c) 102 d) 1015 e) 10–15 Ans: b Algorithm: No Chapter/Section: 19.1 Difficulty: Easy Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 1: Chemistry 36. An unstable isotope of rhenium, 191Re, has a half-life of 9.8 minutes and is a beta producer. What is the other product of the reaction? 191 a) Os 191 b) W 192 c) Pt 190 d) W 190 e) Os Ans: a Algorithm: No Chapter/Section: 19.1 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: radioactivity Keyword 6: nuclear equation 37. 214 If 82 Pb undergoes a beta decay and the product of this decay undergoes another beta decay, which nuclide is produced? 212 a) 82 Bi b) 214 82 Pb c) 214 84 Po d) 212 83 Bi 206 82 e) Pb Ans: c Algorithm: No Chapter/Section: 19.1 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: radioactivity Keyword 6: beta emission 38. Electron capture transforms 74 Be into what nuclide? a) 6 3 Li b) 7 5 B c) 7 3 Li d) 6 5 B 12 6 e) C Ans: c Algorithm: No Chapter/Section: 19.1 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: radioactive decay Keyword 6: electron capture 39. Which reaction will produce an isotope of the parent nuclide? 210 a) 84 Po He + ? Br n + ? b) 88 25 c) 227 89 d) 13 7 Ac e– + ? N e– + ? 73 – e) 33 As + e ? Ans: b Algorithm: No Chapter/Section: 19.1 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: radioactive decay 40. T F The so-called “magic numbers” of protons and neutrons produce special chemical stability. Ans: False Algorithm: No Chapter/Section: 19.1 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: radioactivity Keyword 6: nuclear stability 41. T F As atomic mass increases, the proton/neutron ratio of stable nuclides decreases. Ans: True Algorithm: No Chapter/Section: 19.1 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: radioactivity Keyword 6: nuclear stability 42. The rate constant for the beta decay of thorium-234 is 2.881 10–2 / day. What is the half-life of this nuclide? a) 48.11 days b) 1.218 days c) 0.693 days d) 24.05 days e) 96.22 days Ans: d Algorithm: Yes Chapter/Section: 19.2 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: rate of radioactive decay Keyword 6: half-life Use the following to answer questions 43-44: A certain radioactive sample contains 2.4 103 nuclides at a certain time (t = 0); 3.0 h later the sample contains 6.0 102 nuclides. 43. For this sample the ratio of the decay rates at t = 0 to t = 3.0 h is: a) 1.0 b) 8.0 c) 4.0 d) 16 e) none of these Ans: c Algorithm: No Chapter/Section: 19.2 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: rate of radioactive decay 44. The value of the rate constant for this process is: a) 2.2 h–1 b) 4.6 10–1 h–1 c) 1.6 h–1 d) 3.0 h–1 e) none of these Ans: b Algorithm: No Chapter/Section: 19.2 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: rate of radioactive decay 45. The half-life of 90 Sr is 28.1 years. How long will it take a 10.0-g sample of 90 Sr to decompose to 0.77 g? a) 70 years b) 208 years c) 104 years d) 156 years e) none of these Ans: c Algorithm: Yes Chapter/Section: 19.2 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: rate of radioactive decay 46. The rate constant for the decay of 2045Ca is 4.232 10–3 / day. What is the half-life of 2045Ca ? a) 81.88 days b) 163.8 days c) 327.5 days d) 409.4 days e) none of these Ans: b Algorithm: Yes Chapter/Section: 19.2 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: rate of radioactive decay Keyword 6: half-life 47. A sample of wood from an Egyptian mummy case gives a 14 C count of 9.1 cpm/gC (counts per minute per gram of carbon). How old is the wood? (The initial decay rate of 14 C is 15.3 cpm/g C, and its half-life is 5730 years.) a) 2148 yr b) 6796 yr c) 4296 yr d) 5346 yr e) none of these Ans: c Algorithm: Yes Chapter/Section: 19.4 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: rate of radioactive decay Keyword 6: radioactive dating 48. If a tree dies and the trunk remains undisturbed for 13511 years, what percentage of original 14 C is still present? (half-life of 14 C = 5730 years) a) 80.5% b) 19.5% c) 39.0% d) 29.3% e) 2.36% Ans: b Algorithm: Yes Chapter/Section: 19.4 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: rate of radioactive decay Keyword 6: radioactive dating 49. The half-life for electron capture for 1940 K is 1.3 billion years. What will be the 1940 K / 1840 Ar ratio in a rock that is 5.0 billion years old? a) 0.070 b) 13 c) 0.075 d) 3.8 e) 14 Ans: c Algorithm: Yes Chapter/Section: 19.4 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: radioactivity and nuclear bombardment reactions Keyword 5: rate of radioactive decay Keyword 6: radioactive dating 50. Which statement is true about the following reaction? 14 17 4 + 7 N 8 O 2 He + 1 1 H 13.992 4.0015 16.9986 1.0073 amu amu amu amu a) Energy is absorbed in the reaction. b) Energy is released in the reaction. c) No energy change is associated with the reaction. d) Not enough information is given to determine the energy change. e) None of these. Ans: a Algorithm: No Chapter/Section: 19.5 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: nuclear chemistry Keyword 4: energy of nuclear reactions Keyword 5: mass-energy calculations