SAFETY DATA SHEET
Resolution 350/99
ACTELLIC ® PLUS
SENASA registration No: 35.298
July, 2009
IN CASE OF EMERGENCY
TAS TOXICOLOGICAL CENTER(24hs)
1.
+54 341-448-0077/424-2727
and/or 0800-888-TOXI(8694)
PRODUCT AND MANUFACTURER IDENTIFICATION.
SYNGENTA (24hs) +54 11 4561-6000
/+54 11 4561-7000
1.1 Product nanme
ACTELLIC ® PLUS
1.2 Manufacturer
ACTELLIC ® PLUS: Rizobacter Argentina S.A., Argentina.
Ruta 32, km 1,5- Parque Industrial, (2700) Pergamino -Bs.As.
Parte líquida 1: Syngenta Protecao de Cultivos Ltda., Brasil.
Rodovia Sp 332 km 130, (13140-000), Paulinia.
Parte líquida 2: Syngenta Chemicals B.V., Bélgica. Rue de
Tyberchamps 37, Seneffe (B-71800) / Syngenta Protecao de
Cultivos Ltda., Brasil. Rodovia Sp 332 km 130, (13140-000),
Paulinia.
1.3 Chemical names
Liquid part 1: pirimifos-methyl 50 % w/v: 2 dietilamino-6-methyl
pirimidin-4-il-dimethyl-phosphorotioato
Liquid part 2: lambdacialotrina 5 % p/v: mezcla de isómeros
(ZR cis S y ZS cis R) del α – ciano-3 fenoxibencil-cis-3(Z-2-cloro3,3,3-trifluoroprop-1-enil)-2,2-dimetilciclopropano carboxilato
1.4 CAS No
Parte líquida 1 (pirimiphos-methyl): 29232-93-7
Parte líquida 2 (lambdacialotrina): 91465-08-6
1.5 Molecular weight
Not available
1.6 Use
Insecticide
ai
2. RISKS CLASSIFICATION.
2.1 Flammability
Flammable, class 2ª
2.2 Toxicological classification
MODERATELY HAZARDOUS PEODUCT. CLASS II.
3. PHYSICO-CHEMICAL PROPERTIES.
3.1 Physical appearance
Liquid part 1: Liquid. Emulsifiable concentrate (EC) / Liquid
part 2: Líquido. Capsule suspension (CS)
3.1.1. Color
Liquid part 1: Brown / Liquid part 2: Beige
3.1.2. Odor
Liquid part 1: Characteristic / Liquid part 2: Slightly aromatic
3.2 Vapor pressure
Not available
3.3 Flash point
Flammable, class 2ª
3.4 Melting point
Not available
3.5 Boiling point
Not available
3.6 Solubility in water
Liquid part 1: Soluble / Liquid part 2: Soluble
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Version 1
SAFETY DATA SHEET
Resolution 350/99
ACTELLIC ® PLUS
SENASA registration No: 35.298
July 2009
3.7 Decomposition temperature Not available
3.8 pH
Not available
3.9 Density
Not available
4. FIRST AID MEASURES
General recommendation
IN CASE OF INTOXICATION, CONTACT THE CLOSEST POISON CENTER.
TAKE THE PATIENT TO A VENTILATED PLACE. Have on hand the label of the
product or the material safety data sheet when you call to the emergency number
of Syngenta, or to the control poison center or to the doctor.
4.1 Inhalation
Take the patient outside. If abnormal breathing activity is detected, provide
immediate medical attention.
4.2 Skin contact
Take off immediately all contaminated clothes and shoes. Wash off immediately
with plenty of water for at least 15 or twenty minutes. In case of skin irritation,
provide medical attention.
4.3 Eyes contact
Wash them with abundant water, also under the eyelids, for at least 15 minutes.
Do not try to neutralize it with chemical products. Give immediate medical
attention.
4.4 Ingestion
Give immediate medical attention. Do not induce vomiting. Rinse out mouth
and drink abundant clean water. Never give anything by mouth to an
unconscious person.
Physician instructions
There is not specific antidote. Symptomatic treatment is recommended.
5. FIREFIGHTING MEASURES
5.1 Extinguishing media
5.2 Firefighting measures
In the event of fire, use an extinguishing agent: powder, foam, carbon
dioxide or water spray. Do not use direct jet of water. Wear protective
and proper clothing and oxygen mask. Evacuate affected areas. During
a fire, irritating and possible toxic gases may be generated by thermal
decomposition or combustion. Avoid the entrance into the affected area
until decontamination. Do not allow fire to spread and enters into drain
or water conducts. Contain and collect spillage with non-combustion absorbent
material (for example, sand, earth, diatomaceous earth vermiculite) and place
them In container for disposal according to local/national regulations.
Combustion products may be toxic and/or irritating. Measures must be taken to
avoid soil filtering or uncontrolled spreading of the contaminated extinguishing
agent. In case of fire, autonomous breathing equipments must be used and proper
protective clothing must be worn. Isolate the affected area and do not use it until
decontamination.
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Version 1
SAFETY DATA SHEET
Resolution 350/99
ACTELLIC ® PLUS
SENASA registration No: 35.298
July, 2009
.
6. HANDLING AND STORAGE
6.1 Precautionary methods for
Personal safety
Read the label carefully before using the product. Do not transport or store
together with food, medicines or clothing. Keep away from children,
inexperienced people and animals. Provide water supply in the work area.
Do not eat, drink or smoke during handling and/or usage of the product. Wear
Protective clothing and globes.
.
6.2 Storage
Store in its original package, well closed, clearly identified, and away from
human food and forages. Keep away from children, inexperienced people
and domestic animals. Store in a locked storage area and out of direct sunlight,
heating sources and oxidizing agents. Avoid temperatures below 0ºC and above
35ºC.
7. STABILITY AND REACTIVITY
7.1 Stability
Stable under normal use and storage conditions.
7.2 Reactivity
Non reactive. Thermal combustion or decomposition may release toxic and
irritating fumes.
8. TOXICOLOGICAL INFORMATION
8.1 Inhalation
Avoid pulverizations contact. Use face protection. In the event of
inhalation, take the patient to a ventilated place. If breathing is abnormal,
provide medical assistance.
8.2 Eyes
Use eye protection. In the event of eye contact, wash them with abundant
water, also under the eyelids for at least 15 minutes. Provide immediate
medical assistance.
8.3 Skin
Use personal protective equipment avoiding skin contact. In the event of contact,
take off contaminated clothing and shoes immediately. Wash with abundant water
and soap the skin, hair and fingernails. In case of skin irritation, provide medical
assistance.
8.4 Ingestion
Ingestion can be harmful. In case of ingestion, do not induce vomiting. Drink and
rinse your mouth with abundant clean water. Never give anything by mouth to an
unconscious person. Provide immediate medical assistance.
8.5 Acute toxicity
8.5.1 Oral DL 50
Liquid part 1: LD50 >1522 mg/kg body weight (rats)
Liquid part 2: LD50 =512 mg/kg body weight (rats)
8.5.1 Dermal DL 50
Liquid part 1: LD50 >2000 mg/kg body weight (rats)
Liquid part 2: LD50 >4000 mg/kg body weight (rats)
8.5.3 Inhalation CL 50
Not available
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SAFETY DATA SHEET
Resolution 350/99
ACTELLIC ® PLUS
SENASA Registration number: 35.298
July 2009
8.5.4 Skin irritation
Moderately irritating
8.5.5 Skin sensitization
Non sensitizing
8.5.6 Eyes irritation
Seriously irritating
8.6 Sub-acute toxicity
Not available
8.7 Chronic toxicity
Not available
8.8 Mutagenicity
Not available
9. ECOTOXICOLOGICAL INFORMATION
9.1 Acute effects to fish
Extremely toxic to fish. Avoid the contact of the product
with aquatic environments. Do not contaminate irrigation water, neither receptacles
such as lakes, ponds or docks. Do not contaminate water sources when eliminating
the cleaning fluids of the equipments and remember to sprinkle the remaining broth
on ploughed fields or dirt roads.
9.2 Toxicity to birds
Moderately toxic to birds. Avoid birds presence in the application area and
impede they contact with the facilities and seeds treated.
9.3 Toxicity to bees
Highly toxic to bees, that is why crops and times of application of this label
must be respected strictly. Remove hives close to 4 km of the application area
at least for 30 minutes. If hives could not be removed, cover them with wet
bags during the application of ACTELLIC ® PLUS, removing the bags after
this process. Avoid air application of ACTELLIC ® PLUS at times when bees
are more active. Precaution must be taken in order not to contaminate the possible
water resources of bees.
9.4 Soil persistence
Not available
9.5 Control effect
Not available
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Version 1
SAFETY DATA SHEET
Resolution 350/99
ACTELLIC ® PLUS
SENASA registration No: 35.298
July 2009
10. EMERGENCY ACTIONS
10.1 Spillages
10.2 Fire
10.3 Final disposition
Cover spillages with absorbent material (dirt or sand). Sweep neatly, pick it
and put it in well identified bags or containers for its subsequent destruction
by authorized companies. Wash contaminated surfaces using carbonated or
soapy and then pack the cleaning fluid. Avoid the contamination of still or
running waters. In the event of water sources spillages, interrupt immediately
the human or animal consumption and contact to the company emergency
center.
In the event of fire, irritating and possible toxic gases may be generated by thermal
decomposition and combustion. Use an extinguishing agent: powder,
alcohol-resistant, foam, carbon dioxide or water spray. Do not use direct jet of
water. Wear protective and proper clothing and oxygen mask. Evacuate affected
areas. Prevent entrance into the affected area until decontamination. Clean the
area using hoses during a prolonged period of time. The spilled product cannot
be reused and it must be eliminated. If a safety removal is possible, contact the
producer, the distributor or the local representative.
Empty containers cannot be used again. Add water until covering ¼ of the
container capacity, close it and agitate for 30 seconds. Then, pour the water
of the container in the dispenser (consider this water volume within the
recommended volume of the mixture). Then, carry out this procedure three
times. Finally, make the container useless by perforating it or trying not to
damage the label when carrying out this operation. The perforated containers
must be placed in containers to be sent to a specialized plant for its final
destruction. Do not bury or carry out open-air burning the containers and other
wastes. Cardboard boxes may be burned or placed together with common
wastes, provided that they have not suffered product spillages.
11. TRANSPORT INFORMATION
11.1 Land transport
ADR/ RID:
UN No:
Class:
Label number for risk:
Packaging group
Proper shipping name:
1993
3
3
III
FLAMMABLE LIQUID (SUBSTITUTED BENZENOID
HYDROCARBONS AND PIRIMIPHOS-METHYL)
11.2 Air transport
IATA-DGR:
UN No:
Class:
Label number for risk :
1993
3
3
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Version 1
Packaging group:
Proper shipping name:
III
FLAMMABLE LIQUID (SUBSTITUTED BENZENOID
HYDROCARBONS AND PIRIMIPHOS-METHYL)
11.3 Sea transport
IMDG:
UN No:
Class:
Label number for ris:
1993
3
3
Packaging group:
Proper shipping name:
III
FLAMMABLE LIQUID (SUBSTITUTED BENZENOID
HYDROCARBONS AND PIRIMIPHOS-METHYL)
Marine pollutant:
Marine pollutant.