SNC2D – UNIT 1: CHEMISTRY REVIEW CHAPTER 5 – CHEMICALS & THEIR PROPERTIES PROPERTIES & CHANGES Properties are either chemical properties or physical properties Chemical properties describe the ability of a substance to form one or more different substances. Physical properties describe a substance when it is not in the process of forming a new substance. PATTERNS AND THE PERIODIC TABLE Elements are arranged in the periodic table in order of atomic number Atomic number is the number of protons in the nucleus. Electrically neutral elements have the same number of electrons as protons in each atom. Elements in vertical columns (groups or families) in the periodic table all have the same number of electrons in their outer orbits. The number of electrons in the outer orbit (outer valence shell) affects the reactivity of an element. Bohr-Rutherford Diagram vs. Lewis Dot Diagram (Lewis Dot diagrams are more useful because they only show the outer electron configuration, which helps us determine ionic charge.) ATOMS & IONS Ions are atoms that have gained or lost electrons. Many ions have complete outer orbits, so they are stable. Anions have more electrons than protons and therefore have a negative charge. Anions have “ide” at the end of their names. Non-metals are typically anions. Ex. Chloride is the ionic form of the element Chlorine. Cations have fewer electrons than protons and therefore have a positive charge. Their name stays the same as their atom form. Metals are typically cations. Atoms and ions can be represented by both Bohr-Rutherford and Lewis Dot Diagrams IONIC COMPOUNDS Elements (a metal and a non-metal) can react to form an ionic compound. During the reaction, the non-metal atoms pull electrons away from the metal atoms. The ratio of metal ions to non-metal ions in an ionic compound depends on the number of electrons each ion gains or loses. Most ionic compounds have high melting points and are hard, brittle electrolytes Electrolytes dissolve in water to form solutions that conduct electricity. NAMES & FORMULAS OF IONIC COMPOUNDS When writing chemical formulas of ionic compounds, the number of each ion must balance the positive and negative charges so that the overall charge is zero. The numbers of the ions in the chemical formula of an ionic compound must be in the simplest ratio. The subscript “1” is not included in a chemical formula. Ex. H2O is correct. H2O1 is incorrect. 2 The criss-cross method is used to write the chemical formulas for ionic compounds. Ex. Ionic compounds are named with the metal first and then the non-metal. The ending of the non-metal’s name is changed to “ide”. Some metals can form ions with different charges. In the name of an ionic compound containing one of these metals, the charge is written as Roman numerals in brackets after the name of the metal. Ex. Iron (III) or Iron (II). POLYATOMIC IONS Polyatomic ions are made up of more than one atom, with a charge spread over the entire ion. Polyatomic ions are present in many natural and artificial compounds. They are used as food additives, fertilizers, and cleaners. Consider the polyatomic ion as a single unit when writing chemical formula for a compound that includes a polyatomic ion. If the compound contains more than one of the polyatomic, write curved brackets around the ion and write a subscript outside the brackets. MOLECULES AND COVALENT BONDING Molecular compounds both occur naturally and are produced synthetically. Some are beneficial; others are not. Molecular compounds are made up of molecules. A molecule is a group of two or more atoms joined by covalent bonds. A covalent bond forms when two non-metallic atoms share electrons. A variety of strategies are used to reduce the environmental damage resulting from spilled chemicals. 3 The name of a molecular compound includes prefixes to indicate how many atoms of each element are present (for example, dinitrogen pentoxide). If there is only one atom of the first element, the prefix “mono” is omitted. The name of the last element ends in “ide”. Fossil fuels provide valuable energy and petrochemicals. Many important industrial chemicals and consumer products are made from petrochemicals. FORMULA WRITING GUIDE Ionic Compound Determine the charges on each ion (from either periodic table, or list of polyatomic ions) Criss-cross the charges Reduce if possible Check your answer Molecular Compound Determine how many bonds each element will make (combining capacity) Criss-cross the combining capacities Reduce if possible Check your answer 4 NAMING COMPOUNDS GUIDE Does the compound involve a metal? Yes What is the other half of the compound? Are both non-metals the same? Polyatomic Ion Non-Metal Is the metal a multivalent metal? No Yes No Write the name of the metal, followed by the name of the non-metal, but change the ending to “ide” No Yes Write the name of the metal, followed by the name of the polyatomic ion It’s a diatomic gas: element “gas” Use the prefix naming system: don’t include mono for the first element Write the name of the metal, write the Roman Numeral indicating its charge, write the name of the non-metal, but change the ending to “ide” 5 CHAPTER 6 – CHEMICALS & THEIR REACTIONS DESCRIBING CHEMICAL REACTIONS Chemical reactions always involve one or more reactants changing to give one or more products. State symbols are often written after a chemical formula to indicate the state of a substance. Ex. (s) is solid, (l) is liquid, (g) is gas, (aq) is aqueous We can use word or chemical equations to describe a chemical reaction. In both, the reactants are written on the left and an arrow point’s right, toward the products. We use a + sign if there is more than one compound as a reactant or product. CONSERVING MASS IN CHEMICAL REACTIONS Chemical equations contain information about which substances are reactants and which are products, and the ratios of these substances. Chemical equations obey the law of conservations of mass. Coefficients can be added before chemical formulas in a chemical equation to make the number of atoms in reactants and products balance. 6 SUMMARIZED TABLE FOR TYPES OF REACTIONS TYPES OF REACTIONS REACTION GENERAL EQUATION Synthesis X + Y XY Decomposition XY X + Y Single Displacement X + YZ XZ + Y Double Displacement XW + YZ XZ + YW Complete Combustion of a CXHY + O2 CO2 + H2O + Energy Hydrocarbon Incomplete Combustion of a CXHY + O2 CO2 + H2O + CO + C + Hydrocarbon Energy Combustion of Non-Hydrocarbons XZ+ + O2 X2OZ + Energy (Also a Synthesis Reaction) Neutralization Acid + Base Water + Salt (Ionic (Also a Double Displacement Compound) Reaction) CORROSION Corrosion is the chemical breakdown of a metal as it reacts with chemicals in the environment. Corrosion of some metals forms a tough protective layer that prevents further corrosion. Rusting is the corrosion of iron and steel (which contains iron). Rust does not form a protective layer but continues to flake away until the metal is severely damaged. Rusting occurs in the presence of oxygen and water and is made worse by electrolytes such as salt. Corrosion can be slowed or avoided by using corrosion-resistant materials, covering the metal with a protective layer (for example, paint) or galvanizing with thin layer of zinc. CHAPTER 7 – ACIDS & BASES PROPERTIES, NAMES, AND FORMULAS Acids are molecular compounds. In solutions, acids react with metals, conduct electricity, and change the colours of acid-base indicators. Acids can be binary acids or oxyacids. 7 LIST OF BINARY ACIDS ACID NAME Hydrofluoric acid Hydrochloric acid CHEMICAL FORMULA HF (aq) HCl (aq) Hydrobromic acid HBr (aq) Hydrosulfuric acid H2S (aq) USE Etching glass Cleaning concrete To make cleaning compounds Purifying metals GENERAL WAY TO NAME A BINARY ACID Write “Hydro” and then the add the stem name of the second element. Replace of the second element with “ic”. GENERAL WAY TO NAME AN OXYACID Drop the ending “ate” from the polyatomic name and replace it with “ic”. Add the word Acid after. LIST OF OXYACIDS ACID NAME CHEMICAL FORMULA Acetic acid Nitric acid Carbonic acid Sulfuric acid Phosphoric acid HC2H3O2 (aq) HNO3 (aq) H2CO3 (aq) H2SO4 (aq) H3PO4 (aq) RELATED POLYATOMIC ION C2H3O2- (aq) NO3- (aq) CO32- (aq) SO42- (aq) PO43- (aq) POLYATOMIC ION NAME Acetate Nitrate Carbonate Sulfate Phosphate 8 Bases are ionic compounds. Many are hydroxides. In aqueous solutions, they conduct electricity and change the colours of acid-base indicators. Base Name Sodium Hydroxide Chemical Formula NaOH (aq) Calcium Hydroxide Ca(OH)2 (aq) Ammonium Hydroxide Magnesium Hydroxide Aluminum Hydroxide Sodium Hydrogen Carbonate (Baking Soda) Uses Making paper Decreasing the acidity of lakes and soil NH4OH (aq) Window Cleaners Mg(OH)2 (aq) Antacids Al(OH)3 (aq) NaHCO3 (aq) Heartburn medications Making baked goods rise and an abrasive cleaner Acid-base indicators show whether a solution is acidic or basic. pH SCALE pH describes the acidity or basicity of a solution. The pH scale goes from 0 – 14. Solutions with a pH of 7 are neutral. The lower the pH, the more acidic the solution. The higher the pH, the more basic the solution. Solutions that are highly basic or highly acidic are corrosive and reactive. They must be handled with caution. Living things are sensitive to small pH changes in their environment. ACID PRECIPITATION Acid precipitation is any precipitation is any precipitation that has a pH less than the normal pH of rain. Acid precipitation is caused by pollutants (mostly SO2 from burning fossil fuels and NOX from vehicle engines) reacting with water in the air to form acids. Acid precipitation can have serious environmental and economic impacts. Steps taken to reduce the effects of acid precipitation include using lowSulfur fuels, adding scrubbers to smokestacks, installing catalytic converters to vehicles, and enacting stricter anti-pollution laws. The production of pollutants is decreasing but is still causing damage in some areas. Other areas are starting to recover. 9