Supplemental Tables. Table S1. WASP hydraulic input parameters for each simulated stream segment under estimated current burial conditions. Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 1 1 1 1 1 6 6 6 6 6 7 7 7 7 7 7 7 7 8 8 8 8 9 9 9 9 9 9 9 16 16 16 16 16 17 17 17 17 17 17 17 17 21 21 21 21 21 21 21 21 Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Surface Area Volume Width Depth (m2) 881 881 881 881 881 1119 1119 1119 1119 1119 1153 1153 1153 1153 1153 1153 1153 1153 427 427 427 427 1188 1188 1188 1188 1188 1188 1188 1550 1550 1550 1550 1550 1577 1577 1577 1577 1577 1577 1577 1577 1668 1668 1668 1668 1668 1668 1668 1668 (m3) 598 598 598 598 598 910 910 910 910 910 958 958 958 958 958 958 958 958 168 168 168 168 1010 1010 1010 1010 1010 1010 1010 1613 1613 1613 1613 1613 1662 1662 1662 1662 1662 1662 1662 1662 1834 1834 1834 1834 1834 1834 1834 1834 (m) (m) 4.41 4.41 4.41 4.41 4.41 5.60 5.60 5.60 5.60 5.60 5.76 5.76 5.76 5.76 5.76 5.76 5.76 5.76 2.14 2.14 2.14 2.14 5.94 5.94 5.94 5.94 5.94 5.94 5.94 7.75 7.75 7.75 7.75 7.75 7.88 7.88 7.88 7.88 7.88 7.88 7.88 7.88 8.34 8.34 8.34 8.34 8.34 8.34 8.34 8.34 Slope 0.68 0.68 0.68 0.68 0.68 0.81 0.81 0.81 0.81 0.81 0.83 0.83 0.83 0.83 0.83 0.83 0.83 0.83 0.39 0.39 0.39 0.39 0.85 0.85 0.85 0.85 0.85 0.85 0.85 1.04 1.04 1.04 1.04 1.04 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.10 1.10 1.10 1.10 1.10 1.10 1.10 1.10 0.006 0.007 0.003 0.003 0.006 0.004 0.006 0.007 0.003 0.003 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.027 0.011 0.015 0.006 0.006 0.007 0.005 0.006 0.002 0.003 0.006 0.000 0.000 0.000 0.000 0.004 0.003 0.006 0.003 0.004 0.017 0.001 0.001 0.004 0.004 0.003 0.004 0.005 0.006 0.002 0.001 0.000 0.000 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 22 22 22 22 22 22 22 23 23 24 24 24 25 25 25 25 25 25 28 28 28 28 28 28 28 28 28 28 29 29 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 31 32 32 Open Open Open Open Open Buried Buried Buried Buried Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open (m 2 ) (m 3 ) 1688 1688 1688 1688 1688 1688 1688 1715 1715 1737 1737 1737 1769 1769 1769 1769 1769 1769 1910 1910 1910 1910 1910 1910 1910 1910 1910 1910 1918 1918 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1968 1985 1985 1873 1873 1873 1873 1873 1873 1873 1926 1926 1969 1969 1969 2034 2034 2034 2034 2034 2034 2329 2329 2329 2329 2329 2329 2329 2329 2329 2329 2345 2345 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2454 2491 2491 (m) (m) 8.44 8.44 8.44 8.44 8.44 8.44 8.44 8.57 8.57 8.68 8.68 8.68 8.84 8.84 8.84 8.84 8.84 8.84 9.55 9.55 9.55 9.55 9.55 9.55 9.55 9.55 9.55 9.55 9.59 9.59 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.84 9.93 9.93 1.11 1.11 1.11 1.11 1.11 1.11 1.11 1.12 1.12 1.13 1.13 1.13 1.15 1.15 1.15 1.15 1.15 1.15 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.25 1.25 1.25 0.000 0.000 0.000 0.000 0.000 0.021 0.021 0.000 0.001 0.002 0.002 0.002 0.005 0.006 0.006 0.006 0.001 0.000 0.000 0.002 0.000 0.005 0.002 0.004 0.002 0.002 0.001 0.004 0.002 0.003 0.002 0.003 0.003 0.003 0.002 0.004 0.003 0.005 0.002 0.010 0.012 0.011 0.012 0.000 0.000 0.000 0.001 0.003 0.001 0.003 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 32 32 32 32 32 34 35 35 35 35 35 35 35 36 36 36 36 36 36 36 36 36 36 36 36 36 36 36 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 46 46 46 46 46 Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Open Open Open Open Buried Buried Buried Buried Buried Buried Buried Buried Buried (m 2 ) (m 3 ) 1985 1985 1985 1985 1985 850 2108 2108 2108 2108 2108 2108 2108 2134 2134 2134 2134 2134 2134 2134 2134 2134 2134 2134 2134 2134 2134 2134 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2374 2374 2374 2374 2374 2491 2491 2491 2491 2491 561 2769 2769 2769 2769 2769 2769 2769 2828 2828 2828 2828 2828 2828 2828 2828 2828 2828 2828 2828 2828 2828 2828 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3411 3411 3411 3411 3411 (m) 9.93 9.93 9.93 9.93 9.93 4.25 10.54 10.54 10.54 10.54 10.54 10.54 10.54 10.67 10.67 10.67 10.67 10.67 10.67 10.67 10.67 10.67 10.67 10.67 10.67 10.67 10.67 10.67 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.87 11.87 11.87 11.87 11.87 (m) 1.25 1.25 1.25 1.25 1.25 0.66 1.31 1.31 1.31 1.31 1.31 1.31 1.31 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.33 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.44 1.44 1.44 1.44 1.44 0.000 0.005 0.014 0.004 0.005 0.004 0.007 0.005 0.008 0.010 0.007 0.011 0.001 0.018 0.018 0.003 0.021 0.008 0.002 0.021 0.019 0.015 0.011 0.013 0.008 0.008 0.009 0.007 0.010 0.008 0.010 0.000 0.000 0.000 0.000 0.000 0.003 0.006 0.005 0.006 0.039 0.006 0.000 0.003 0.025 0.004 0.005 0.001 0.017 0.002 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 46 46 46 50 50 50 50 50 50 50 50 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 4 4 4 4 5 5 5 4 4 4 5 5 5 Buried Buried Buried Buried Buried Buried Buried Buried Buried Buried Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open (m 2 ) (m 3 ) 2374 2374 2374 2510 2510 2510 2510 2510 2510 2510 2510 416 416 416 416 416 416 416 416 416 416 563 563 563 563 563 563 563 563 563 563 563 563 563 563 645 645 645 645 645 645 693 693 693 645 645 645 693 693 693 3411 3411 3411 3762 3762 3762 3762 3762 3762 3762 3762 160 160 160 160 160 160 160 160 160 160 272 272 272 272 272 272 272 272 272 272 272 272 272 272 346 346 346 346 346 346 392 392 392 346 346 346 392 392 392 (m) 11.87 11.87 11.87 12.55 12.55 12.55 12.55 12.55 12.55 12.55 12.55 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.08 2.81 2.81 2.81 2.81 2.81 2.81 2.81 2.81 2.81 2.81 2.81 2.81 2.81 2.81 3.23 3.23 3.23 3.23 3.23 3.23 3.47 3.47 3.47 3.23 3.23 3.23 3.47 3.47 3.47 (m) 1.44 1.44 1.44 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 0.38 0.38 0.38 0.38 0.38 0.38 0.38 0.38 0.38 0.38 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.54 0.54 0.54 0.54 0.54 0.54 0.57 0.57 0.57 0.54 0.54 0.54 0.57 0.57 0.57 0.002 0.002 0.001 0.000 0.002 0.007 0.013 0.002 0.001 0.001 0.001 0.025 0.019 0.013 0.019 0.021 0.010 0.029 0.000 0.017 0.027 0.026 0.016 0.017 0.014 0.012 0.008 0.008 0.009 0.011 0.009 0.013 0.007 0.009 0.010 0.008 0.009 0.013 0.009 0.012 0.005 0.009 0.005 0.007 0.032 0.026 0.023 0.031 0.026 0.021 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 5 6 6 6 6 6 7 7 7 8 8 8 8 8 9 9 9 10 10 10 10 10 10 10 10 10 10 10 10 11 11 11 11 11 11 11 11 11 11 11 11 12 12 12 12 13 13 13 13 13 Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open (m 2 ) (m 3 ) 693 1119 1119 1119 1119 1119 1153 1153 1153 427 427 427 427 427 1188 1188 1188 532 532 532 532 532 532 532 532 532 532 532 532 531 531 531 531 531 531 531 531 531 531 531 531 371 371 371 371 624 624 624 624 624 392 910 910 910 910 910 958 958 958 168 168 168 168 168 1010 1010 1010 246 246 246 246 246 246 246 246 246 246 246 246 245 245 245 245 245 245 245 245 245 245 245 245 131 131 131 131 326 326 326 326 326 (m) (m) 3.47 5.60 5.60 5.60 5.60 5.60 5.76 5.76 5.76 2.14 2.14 2.14 2.14 2.14 5.94 5.94 5.94 2.66 2.66 2.66 2.66 2.66 2.66 2.66 2.66 2.66 2.66 2.66 2.66 2.65 2.65 2.65 2.65 2.65 2.65 2.65 2.65 2.65 2.65 2.65 2.65 1.85 1.85 1.85 1.85 3.12 3.12 3.12 3.12 3.12 0.57 0.81 0.81 0.81 0.81 0.81 0.83 0.83 0.83 0.39 0.39 0.39 0.39 0.39 0.85 0.85 0.85 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.35 0.35 0.35 0.35 0.52 0.52 0.52 0.52 0.52 0.014 0.027 0.021 0.020 0.012 0.036 0.036 0.034 0.022 0.034 0.030 0.005 0.027 0.003 0.044 0.026 0.024 0.022 0.016 0.014 0.012 0.010 0.010 0.013 0.000 0.001 0.001 0.034 0.000 0.032 0.028 0.016 0.014 0.008 0.008 0.008 0.009 0.009 0.009 0.011 0.001 0.030 0.025 0.019 0.010 0.009 0.025 0.015 0.018 0.021 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 13 13 13 13 13 13 13 13 13 13 13 13 13 12 12 12 11 11 10 10 10 10 14 14 14 14 14 14 14 14 14 15 15 15 15 15 15 15 15 15 15 15 15 14 14 14 14 14 14 15 Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Open Buried Open (m 2 ) (m 3 ) 624 624 624 624 624 624 624 624 624 624 624 624 624 371 371 371 531 531 532 532 532 532 982 982 982 982 982 982 982 982 982 598 598 598 598 598 598 598 598 598 598 598 598 982 982 982 982 982 982 1082 326 326 326 326 326 326 326 326 326 326 326 326 326 131 131 131 245 245 246 246 246 246 723 723 723 723 723 723 723 723 723 303 303 303 303 303 303 303 303 303 303 303 303 723 723 723 723 723 723 857 (m) (m) 3.12 3.12 3.12 3.12 3.12 3.12 3.12 3.12 3.12 3.12 3.12 3.12 3.12 1.85 1.85 1.85 2.65 2.65 2.66 2.66 2.66 2.66 4.91 4.91 4.91 4.91 4.91 4.91 4.91 4.91 4.91 2.99 2.99 2.99 2.99 2.99 2.99 2.99 2.99 2.99 2.99 2.99 2.99 4.91 4.91 4.91 4.91 4.91 4.91 5.41 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.52 0.35 0.35 0.35 0.46 0.46 0.46 0.46 0.46 0.46 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.74 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.74 0.74 0.74 0.74 0.74 0.74 0.79 0.008 0.009 0.009 0.010 0.006 0.013 0.010 0.007 0.009 0.010 0.005 0.015 0.012 0.000 0.011 0.010 0.003 0.004 0.002 0.003 0.004 0.005 0.006 0.007 0.005 0.012 0.014 0.000 0.003 0.013 0.012 0.005 0.004 0.004 0.004 0.004 0.003 0.004 0.005 0.001 0.000 0.004 0.058 0.022 0.021 0.019 0.021 0.023 0.028 0.010 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 15 15 15 15 15 15 15 15 16 16 16 16 17 17 17 17 17 17 17 17 17 18 18 18 18 18 18 18 18 18 18 18 18 18 19 19 20 20 20 20 20 18 19 19 19 19 20 20 20 21 Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Open (m 2 ) (m 3 ) 1082 1082 1082 1082 1082 1082 1082 1082 1550 1550 1550 1550 1577 1577 1577 1577 1577 1577 1577 1577 1577 511 511 511 511 511 511 511 511 511 511 511 511 511 366 366 653 653 653 653 653 511 366 366 366 366 653 653 653 1668 857 857 857 857 857 857 857 857 1613 1613 1613 1613 1662 1662 1662 1662 1662 1662 1662 1662 1662 230 230 230 230 230 230 230 230 230 230 230 230 230 128 128 353 353 353 353 353 230 128 128 128 128 353 353 353 1834 (m) (m) 5.41 5.41 5.41 5.41 5.41 5.41 5.41 5.41 7.75 7.75 7.75 7.75 7.88 7.88 7.88 7.88 7.88 7.88 7.88 7.88 7.88 2.56 2.56 2.56 2.56 2.56 2.56 2.56 2.56 2.56 2.56 2.56 2.56 2.56 1.83 1.83 3.26 3.26 3.26 3.26 3.26 2.56 1.83 1.83 1.83 1.83 3.26 3.26 3.26 8.34 0.79 0.79 0.79 0.79 0.79 0.79 0.79 0.79 1.04 1.04 1.04 1.04 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 1.05 0.45 0.45 0.45 0.45 0.45 0.45 0.45 0.45 0.45 0.45 0.45 0.45 0.45 0.35 0.35 0.54 0.54 0.54 0.54 0.54 0.45 0.35 0.35 0.35 0.35 0.54 0.54 0.54 1.10 0.011 0.015 0.021 0.012 0.010 0.008 0.017 0.016 0.025 0.012 0.007 0.046 0.032 0.020 0.016 0.012 0.004 0.008 0.005 0.006 0.005 0.011 0.010 0.011 0.015 0.017 0.012 0.012 0.010 0.007 0.008 0.009 0.009 0.011 0.013 0.004 0.008 0.008 0.008 0.005 0.006 0.015 0.012 0.013 0.013 0.010 0.027 0.032 0.025 0.028 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 351 352 353 354 355 356 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 376 377 378 379 380 381 382 383 384 385 386 387 388 389 390 391 392 393 394 395 396 397 398 399 400 21 21 21 21 21 21 22 22 22 22 22 22 23 23 23 23 23 23 23 24 24 24 24 25 25 25 25 26 26 26 26 26 26 26 26 26 26 26 26 26 26 26 27 27 27 27 27 27 27 27 Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open (m 2 ) (m 3 ) 1668 1668 1668 1668 1668 1668 1688 1688 1688 1688 1688 1688 1715 1715 1715 1715 1715 1715 1715 1737 1737 1737 1737 1769 1769 1769 1769 558 558 558 558 558 558 558 558 558 558 558 558 558 558 558 855 855 855 855 855 855 855 855 1834 1834 1834 1834 1834 1834 1873 1873 1873 1873 1873 1873 1926 1926 1926 1926 1926 1926 1926 1969 1969 1969 1969 2034 2034 2034 2034 268 268 268 268 268 268 268 268 268 268 268 268 268 268 268 567 567 567 567 567 567 567 567 (m) (m) 8.34 8.34 8.34 8.34 8.34 8.34 8.44 8.44 8.44 8.44 8.44 8.44 8.57 8.57 8.57 8.57 8.57 8.57 8.57 8.68 8.68 8.68 8.68 8.84 8.84 8.84 8.84 2.79 2.79 2.79 2.79 2.79 2.79 2.79 2.79 2.79 2.79 2.79 2.79 2.79 2.79 2.79 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 1.10 1.10 1.10 1.10 1.10 1.10 1.11 1.11 1.11 1.11 1.11 1.11 1.12 1.12 1.12 1.12 1.12 1.12 1.12 1.13 1.13 1.13 1.13 1.15 1.15 1.15 1.15 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.48 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.017 0.027 0.022 0.013 0.017 0.024 0.025 0.020 0.012 0.023 0.018 0.000 0.034 0.024 0.022 0.004 0.000 0.007 0.024 0.003 0.000 0.001 0.028 0.024 0.008 0.018 0.018 0.011 0.015 0.009 0.010 0.009 0.006 0.006 0.005 0.005 0.006 0.006 0.001 0.003 0.001 0.006 0.014 0.003 0.003 0.003 0.003 0.003 0.003 0.003 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 401 402 403 404 405 406 407 408 409 410 411 412 413 414 415 416 417 418 419 420 421 422 423 424 425 426 427 428 429 430 431 432 433 434 435 436 437 438 439 440 441 442 443 444 445 446 447 448 449 450 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 28 28 28 28 29 29 29 29 29 29 30 30 30 30 30 30 30 30 30 30 31 31 31 31 31 31 32 32 Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Open Open Open Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Open Open Open Open (m 2 ) (m 3 ) 855 855 855 855 855 855 855 855 855 855 855 855 855 855 855 855 855 855 855 855 855 855 1910 1910 1910 1910 1918 1918 1918 1918 1918 1918 1961 1961 1961 1961 1961 1961 1961 1961 1961 1961 1968 1968 1968 1968 1968 1968 1985 1985 567 567 567 567 567 567 567 567 567 567 567 567 567 567 567 567 567 567 567 567 567 567 2329 2329 2329 2329 2345 2345 2345 2345 2345 2345 2439 2439 2439 2439 2439 2439 2439 2439 2439 2439 2454 2454 2454 2454 2454 2454 2491 2491 (m) (m) 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 4.28 9.55 9.55 9.55 9.55 9.59 9.59 9.59 9.59 9.59 9.59 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.81 9.84 9.84 9.84 9.84 9.84 9.84 9.93 9.93 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.22 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.24 1.25 1.25 1.25 1.25 1.25 1.25 1.25 1.25 0.003 0.003 0.004 0.006 0.005 0.005 0.005 0.006 0.006 0.008 0.007 0.007 0.011 0.012 0.013 0.030 0.020 0.011 0.005 0.012 0.015 0.004 0.032 0.017 0.000 0.005 0.036 0.032 0.015 0.023 0.026 0.012 0.028 0.018 0.016 0.009 0.009 0.009 0.017 0.017 0.024 0.027 0.039 0.015 0.023 0.048 0.039 0.032 0.031 0.024 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 451 452 453 454 455 456 457 458 459 460 461 462 463 464 465 466 467 468 469 470 471 472 473 474 475 476 477 478 479 480 481 482 483 484 485 486 487 488 489 490 491 492 493 494 495 496 497 498 499 500 32 32 32 32 32 32 32 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 34 34 34 34 34 34 34 34 34 34 34 34 34 34 34 34 34 35 35 35 35 35 36 36 36 Open Open Open Open Open Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Open Open Open Open Buried Open Open Open Open Open Open Open Open Open Open Open Open (m 2 ) (m 3 ) 1985 1985 1985 1985 1985 1985 1985 584 584 584 584 584 584 584 584 584 584 584 584 584 584 584 584 584 584 850 850 850 850 850 850 850 850 850 850 850 850 850 850 850 850 850 2108 2108 2108 2108 2108 2134 2134 2134 2491 2491 2491 2491 2491 2491 2491 290 290 290 290 290 290 290 290 290 290 290 290 290 290 290 290 290 290 561 561 561 561 561 561 561 561 561 561 561 561 561 561 561 561 561 2769 2769 2769 2769 2769 2828 2828 2828 (m) 9.93 9.93 9.93 9.93 9.93 9.93 9.93 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 2.92 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 4.25 10.54 10.54 10.54 10.54 10.54 10.67 10.67 10.67 (m) 1.25 1.25 1.25 1.25 1.25 1.25 1.25 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 0.66 1.31 1.31 1.31 1.31 1.31 1.33 1.33 1.33 0.023 0.016 0.024 0.029 0.022 0.009 0.035 0.005 0.021 0.009 0.009 0.009 0.008 0.007 0.007 0.005 0.011 0.011 0.011 0.007 0.011 0.012 0.011 0.009 0.008 0.011 0.011 0.012 0.011 0.009 0.010 0.016 0.021 0.018 0.019 0.020 0.015 0.010 0.000 0.000 0.005 0.013 0.018 0.021 0.044 0.055 0.014 0.044 0.036 0.064 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 501 502 503 504 505 506 507 508 509 510 511 512 513 514 515 516 517 518 519 520 521 522 523 524 525 526 527 528 529 530 531 532 533 534 535 536 537 538 539 540 541 542 543 544 545 546 547 548 549 550 36 36 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 38 38 Open Open Buried Buried Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open (m 2 ) (m 3 ) 2134 2134 657 657 657 657 657 657 657 657 657 657 657 657 657 657 657 657 657 657 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 1112 310 310 2828 2828 357 357 357 357 357 357 357 357 357 357 357 357 357 357 357 357 357 357 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 899 96 96 (m) 10.67 10.67 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 3.29 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 5.56 1.55 1.55 (m) 1.33 1.33 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.54 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.81 0.31 0.31 0.058 0.055 0.014 0.010 0.007 0.025 0.016 0.018 0.010 0.014 0.017 0.018 0.015 0.007 0.008 0.004 0.004 0.004 0.004 0.003 0.005 0.005 0.002 0.004 0.003 0.006 0.004 0.004 0.005 0.010 0.011 0.012 0.012 0.007 0.022 0.019 0.021 0.013 0.017 0.016 0.010 0.017 0.013 0.008 0.016 0.009 0.010 0.009 0.033 0.024 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 551 552 553 554 555 556 557 558 559 560 561 562 563 564 565 566 567 568 569 570 571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 38 38 38 39 39 39 39 40 40 40 40 40 40 39 41 41 41 41 41 41 41 42 42 42 42 42 42 42 42 42 42 42 42 41 41 41 41 43 43 43 43 43 43 43 43 43 44 44 44 44 Open Open Open Open Open Open Open Buried Buried Buried Open Open Open Buried Open Open Open Open Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Buried Open Open Open Open Buried Buried Buried Buried Open Open Open Open (m 2 ) (m 3 ) 310 310 310 359 359 359 359 498 498 498 498 498 498 359 634 634 634 634 634 634 634 525 525 525 525 525 525 525 525 525 525 525 525 634 634 634 634 701 701 701 701 701 701 701 701 701 1112 1112 1112 1112 96 96 96 124 124 124 124 219 219 219 219 219 219 124 336 336 336 336 336 336 336 240 240 240 240 240 240 240 240 240 240 240 240 336 336 336 336 400 400 400 400 400 400 400 400 400 899 899 899 899 (m) (m) 1.55 1.55 1.55 1.80 1.80 1.80 1.80 2.49 2.49 2.49 2.49 2.49 2.49 1.80 3.17 3.17 3.17 3.17 3.17 3.17 3.17 2.62 2.62 2.62 2.62 2.62 2.62 2.62 2.62 2.62 2.62 2.62 2.62 3.17 3.17 3.17 3.17 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 5.56 5.56 5.56 5.56 0.31 0.31 0.31 0.34 0.34 0.34 0.34 0.44 0.44 0.44 0.44 0.44 0.44 0.34 0.53 0.53 0.53 0.53 0.53 0.53 0.53 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.53 0.53 0.53 0.53 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.57 0.81 0.81 0.81 0.81 0.008 0.000 0.001 0.009 0.023 0.019 0.009 0.035 0.033 0.018 0.000 0.018 0.011 0.008 0.025 0.026 0.023 0.020 0.003 0.010 0.028 0.025 0.009 0.009 0.010 0.009 0.008 0.002 0.025 0.006 0.004 0.004 0.000 0.017 0.012 0.020 0.013 0.009 0.005 0.004 0.005 0.005 0.026 0.012 0.008 0.008 0.012 0.013 0.016 0.018 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627 628 629 630 631 632 633 634 635 636 637 638 639 640 641 642 643 644 645 646 647 648 649 650 44 44 44 44 44 44 44 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 45 46 46 46 46 46 46 46 46 46 46 46 46 47 47 47 47 47 47 47 47 47 47 47 Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Buried Open Open Open Open Buried Buried Buried Buried Buried Buried Open Open Buried Open Open Buried Buried Buried Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open Open (m 2 ) (m 3 ) 1112 1112 1112 1112 1112 1112 1112 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2357 2374 2374 2374 2374 2374 2374 2374 2374 2374 2374 2374 2374 793 793 793 793 793 793 793 793 793 793 793 899 899 899 899 899 899 899 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3368 3411 3411 3411 3411 3411 3411 3411 3411 3411 3411 3411 3411 497 497 497 497 497 497 497 497 497 497 497 (m) 5.56 5.56 5.56 5.56 5.56 5.56 5.56 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.78 11.87 11.87 11.87 11.87 11.87 11.87 11.87 11.87 11.87 11.87 11.87 11.87 3.97 3.97 3.97 3.97 3.97 3.97 3.97 3.97 3.97 3.97 3.97 (m) 0.81 0.81 0.81 0.81 0.81 0.81 0.81 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.43 1.44 1.44 1.44 1.44 1.44 1.44 1.44 1.44 1.44 1.44 1.44 1.44 0.63 0.63 0.63 0.63 0.63 0.63 0.63 0.63 0.63 0.63 0.63 0.019 0.025 0.027 0.023 0.025 0.025 0.003 0.013 0.015 0.011 0.010 0.009 0.011 0.003 0.053 0.021 0.029 0.031 0.024 0.016 0.070 0.026 0.024 0.032 0.043 0.077 0.126 0.025 0.031 0.028 0.003 0.002 0.025 0.041 0.020 0.036 0.018 0.072 0.034 0.046 0.032 0.021 0.025 0.025 0.015 0.002 0.000 0.000 0.032 0.000 Table S1. WASP hydraulic input parameters for each simulated stream segment under the estimated current conditions (i.e., the intial model simulation). All stream segment lengths are 200 m. Bottom roughness = 0.04 for open channels; 0.005 for buried channels. This is one of the variables that controls variations in water velocity (and thereby residence times). Uptake Rate Constant = 0.00543 min -1 for open channels; 0.00121 min-1 for buried channels. *See Fig. S1 for the subbasin location in Gywnns Falls Watershed. Segment Subbasin* Burial Type Surface Area Volume Width Depth Slope 651 652 653 654 655 656 657 658 659 660 661 662 663 664 665 666 667 668 669 670 671 672 673 674 675 47 47 47 47 47 49 49 49 49 50 50 47 48 48 48 48 49 49 49 49 50 50 50 50 50 Open Open Open Open Open Open Open Open Open Open Open Open Buried Buried Buried Buried Open Open Open Open Open Open Open Open Open (m 2 ) (m 3 ) 793 793 793 793 793 858 858 858 858 2510 2510 793 677 677 677 677 858 858 858 858 2510 2510 2510 2510 2510 497 497 497 497 497 571 571 571 571 3762 3762 497 376 376 376 376 571 571 571 571 3762 3762 3762 3762 3762 (m) 3.97 3.97 3.97 3.97 3.97 4.29 4.29 4.29 4.29 12.55 12.55 3.97 3.39 3.39 3.39 3.39 4.29 4.29 4.29 4.29 12.55 12.55 12.55 12.55 12.55 (m) 0.63 0.63 0.63 0.63 0.63 0.67 0.67 0.67 0.67 1.50 1.50 0.63 0.56 0.56 0.56 0.56 0.67 0.67 0.67 0.67 1.50 1.50 1.50 1.50 1.50 0.000 0.000 0.000 0.035 0.008 0.007 0.007 0.017 0.032 0.019 0.038 0.043 0.039 0.041 0.022 0.023 0.013 0.011 0.010 0.003 0.007 0.013 0.012 0.001 0.013 1. WASP modeling methods 2.1 Stream Network As a first step in the scenario simulations, we delineated the watershed and stream segments as input data to WASP. We used a 1:24000 NHD stream network as the base data layer. We manually digitized storm drains greater than or equal to 0.8 m wide (equal to or greater than the approximate median pipe size in the watershed) and 200 m long (the length of WASP modeling segments), based on the Baltimore County Storm Drain layer issued from Baltimore County, Maryland, Office of Information Technology. We merged the storm drain layer with the NHD layer to create a modeling stream network for Gwynns Falls Watershed (FS03). We subdivided the stream network into 200m long WASP modeling segments to create a uniform network for the watershed-scale simulations. This length falls near the median of the stream reaches measured in the study and resulted in 675 stream modeling segments. We identified buried streams as the digitized storm drain segments in addition to the NHD stream network segments identified as artificial paths or path connectors. Because WASP can receive a maximum of 50 streamflow inputs as boundary conditions across a river network, simplification of the network in this large watershed was required. This resulted in the removal of several low order streams throughout the watershed, which may result in conservative estimates of the influence of low order streams on downstream NO3- export. 2.2 WASP Model Our goal was to conduct watershed-scale WASP simulations as an exploratory modeling exercise to estimate the relative change in watershed NO3- export in response to various stream burial scenarios. Our approach used a simplified representation of the Gwynns Falls Watershed combined with model parameter values that were directly measured, estimated, or extracted from the literature. Therefore, we did not aim to conduct rigorous model calibration; we developed a model based on estimated current conditions from which we could assess relative changes to nitrate under different levels of urbanization and stream burial in the watershed. WASP is a flexible dynamic, differential mass-balance modeling framework used to simulate the fate and transport of a variety of contaminants in surface water systems. WASP been applied for a variety of research and regulatory questions [Knightes et al., 2009; Lin et al., 2011] and has recently been integrated into a modeling system for environmental assessments [Johnston et al., 2011]. Here, we use WASP7 (referred to as WASP), an enhancement to the original WASP model [R.B. Ambrose Jr, 1987; Robert B. Ambrose Jr, 1988], without additional modifications to the code. The WASP model simulates water volume and velocity in each segment using the kinematic wave option, and simulates NO3- concentration in each segment. Detailed equations for the WASP model can be found elsewhere [R.B. Ambrose Jr, 1987; Robert B. Ambrose Jr, 1988]. We simulated in-stream NO3- uptake as a first order decay rate (k; min-1, see equation 1) estimated from measured data at both the Cincinnati and Baltimore sites. We applied one uptake rate to buried streams (0.00121 min-1) and one to open streams (0.00543 min-1). Based upon measured conditions during the 2011 sampling season, velocity (m d-1) in buried streams was approximately 3.5 times greater than that in open channels. We adjusted stream modeling segment velocities in the WASP model to approximate this trend by modifying the Manning’s roughness coefficient. Based upon these simulations, we applied a final roughness coefficient for buried (Manning’s = 0.005) and open (Manning’s = 0.04) streams. Because the WASP model structure allows a maximum of 50 stream flows as boundary conditions for river systems, we divided the watershed into 50 sub-basins (FS02), each receiving daily streamflow and NO3- concentration inputs. We input uniform average daily summer base flows (m3 s-1) estimated for the 21 June through 22 September 2011 period, the year that summer uptake rates were measured, based on the records from the closest downstream USGS stream gage to each sub-basin (FS03). We calculated average percent baseflow from the streamflow records using the 2006 version of Baseflow Program [Arnold and Allen, 1999; Arnold et al., 1995] and scaled the results using an area to discharge ratio for each sub-basin. We estimated a single average summer NO3- concentration from three of the four USGS station records. We averaged NO3- concentrations for the summer periods of 2000-2009 (N = 127 to 156, depending on the stream gage), which covered a range of hydrological conditions at each gage, but exhibited limited variation in average NO3- concentrations. Because of the shorter period of record at the fourth gage, Dead Run at Franklintown, Maryland (USGS 01589330), we used average summer NO3- concentration data in the Dead Run Watershed from Pennino et al. [Pennino et al., 2014]. We applied these NO3- concentrations as boundary conditions for each of the 50 subbasins based upon values estimated at the stream gage within the closest downstream proximity. WASP requires estimates of multiple hydraulic variables for each modeled stream segment. We estimated widths and depths for each stream segment in the sub-basins using standard regional regression equations from techniques used in the Grid Based Mercury Model (see below) [Dai et al., 2005]. We modified the width regression equation based upon measurements in the watershed during summer 2008 (S. Kaushal, unpublished data, 2013). We estimated slopes for each modeling segment by extracting elevation data at each segment’s upstream and downstream point using Spatial Analyst in ArcGIS 9.3.1 (ESRI, Redlands, California) and calculating the difference in distance (a constant 200 m) and elevation between the points. The full set of WASP stream segment hydraulic input parameters are listed in Table S1. Our simulation approach required several assumptions and simplifications. First, WASP simulates varying depths for each stream segment using the continuity equation for the mass of water and based on roughness coefficients and stream widths. However, to best generalize measurements of uptake across the watershed, we did not simulate variations in uptake rates with depth. Other potentially important features of the system that were not modeled include hydrologic exchanges between the channel, floodplain, and subsurface waters [Helton et al., 2011]. 2.3 Stream Burial Scenarios We used the following stream burial scenarios to assess changes in NO3- export at the watershed outlet: (1) Increasing the proportion of the stream network that was buried by 5% increments. Burial was evenly distributed across the 200 m stream segments; (2) Concentrated burial that reflects potential suburban development (all 85 segments in suburban subbasins (FS03); 1700 m buried, or 12.2% of the total stream network length), and (3) Concentrated burial that reflects urban development along the lower watershed mainstem (85 segments in urban subbasins (FS03) for a total of 1700 m of buried stream channel, same length used for the suburban scenario). We also conducted two simulations to determine whether modeled changes in NO3- export were a result of changes in N-removal rates due to burial, changes in hydrology resulting from burial, or a combination of the two. We held uptake rates constant and modified stream velocity via variations in the Manning’s roughness coefficient for the 50 subbasins in the first scenario and held hydrologic inputs constant and varied N-uptake rates in the second scenario. We based stream velocity and uptake rates upon whether the stream was buried or open. 2.4 WASP stream segment geomorphology calculations Width (m) = 1.7# * Drainage area (km2) 0.3916## (3) # = original coefficient was 2.933 (from Dai et al. [Dai et al., 2005]); final coefficient (1.7) was adjusted based on measurements from summer 2008 (S Kaushal, unpublished data) ## = estimated using techniques from Dai et al. [Dai et al., 2005] Depth (m) = 0.33# * Drainage area (km2) 0.2964## (4) ## = estimated using techniques from Dai et al. [Dai et al., 2005] References Ambrose Jr, R. B. (1987), Modeling volatile organics in the Delaware Estuary, J. Environ. Eng., 113, 703721. Ambrose Jr, R. B. (1988), WASP4, A Hydrodynamic and WATER QUALITY MODEL—Model Theory, User’s Manual, and Programmer’s Guide. Technical Report. U.S. Environmental Protection Agency, Athens, GA. Rep. EPA/600/3-87-039. Arnold, J. G., and P. M. Allen (1999), Automated methods for estimating baseflow and ground water recharge from streamflow records, J. Am. Water Resour. As., 35(2), 411-424. Arnold, J. G., P. M. Allen, R. Muttiah, and G. Bernhardt (1995), Automated base flow separation and recession analysis techniques, Ground Water, 33(6), 1010-1018. Dai, T., R. B. Ambrose, K. Alvi, T. Wool, H. Manguerra, M. Choski, H. Yang, and S. Kraemer (2005), Characterizing Spatial and Temporal Dynamics: Development of a Grid-Based Watershed Mercury Loading Model, Moglen, Glenn E. 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