Name: __________________ Hour: ________ Date:______ Stoichiometry If your "given" is in moles: If your "given" is in grams: Determine the molar ratio to change from moles of your original substance to moles of the desired substance If you want your answer in grams: use the molar mass of the desired substance to convert from moles back to grams Use the molar mass of the compound to determine the number of moles If you want your answer in moles: You are done! Determine the molar ratio to change from moles of your original substance to moles of the desired substance If you want your answer in moles: You are done! If you want your answer in grams: use the molar mass of the desired substance to convert from moles back to grams Class Examples: MOLEMOLE: Using the reaction 2C(s) + O2(g) 2CO(g) How many moles of CO are produced from the reaction of 2.50 mol of O2 with an excess of C? Want 2.5 mol O2 x 2 mol CO 1 mol O2 Given 2.5 mol O2 x 2 mol CO = 2.5 x 2 mol CO = 5 mol CO 1 mol O2 1 MOLEGRAMS: Using the reaction 2C(s) + O2(g) 2CO(g) How many grams of C are used in the reaction to form 3.00 moles CO? 3.0 mol CO x 2 mol C x 12 g C = 3 x 2 x 12g C = 36 g C 2 mol CO 1 mol C 2 x 1 GRAMSMOLES: Using the reaction 2C(s) + O2(g) 2CO(g) How many moles of C are used in the reaction to form 30.1 grams CO? 30.1 g CO x 1 mol CO x 2 mol C = 30.1 x 1 x 2 mol C = 1.075 mol C 28 g CO 2 mol CO 28 x 2 GRAMSGRAMS: Using the reaction 2C(s) + O2(g) 2CO(g) How many grams of C are used in the reaction to form 9.8 grams CO? 9.8 g CO x 1 mol CO x 2 mol C x 12 g C = 9.8 x 1 x 2 x 12 g C = 4.2 g C 28 g CO 2 mol CO 1 mol C 28 x 2 x 1 Practice Problems Note: the formula ratio is in blue for each problem 1. How many grams of sodium sulfate will be formed if you start with 200 grams of sodium hydroxide and you have an excess of sulfuric acid? MOLAR MASS CALCULATION: NaOH Na2SO4 2 NaOH + H2SO4 2 H2O + Na2SO4 Na: 1 x 23 = 23 Na: 2 x 23 = 46 200 g NaOH x 1 mol NaOH x 1 mol Na2SO4 x 142 g Na2SO4 = 355 g Na2SO4 O: 1 x 16 = 16 S: 1 x 32 = 32 40 g NaOH 2 mol NaOH 1 mol Na2SO4 H: 1 x 1 = 1 O: 4 x 16 = 64 40 2. How many grams of lithium nitrate will be needed to make 250 grams of lithium sulfate, assuming that you have an adequate amount of lead (IV) sulfate to do the reaction? Pb(SO4)2 + 4 LiNO3 Pb(NO3)4 + 2 Li2SO4 MOLAR MASS CALCULATION: 250 g Li2SO4 x 1 mol Li2SO4 x 4 mol LiNO3 x 69 g LiNO3 = 313.64 g LiNO3 110 g Li2SO4 2 mol Li2SO4 1 mol LiNO3 3. Li2SO4 Li: 2 x 7 = 14 S: 1 x 32 = 32 O: 4 x 16 = 64 110 LiNO3 Li: 1 x 7 = 7 N: 1 x 14 = 14 O: 3 x 16 = 48 69 How many grams of calcium carbonate are required to prepare 50.0 g of calcium oxide? CaCO3 CaO + CO2 MOLAR MASS CALCULATION: 50.0 g CaO x 1 mol CaO x 1 mol CaCO3 x 100 g CaCO3 = 89.29 g CaCO3 56 g CaO 1 mol CaO 1 mol CaCO3 4. 142 CaO Ca: 1 x 40 = 40 O: 1 x 16 = 16 56 CaCO3 Ca:1 x 40 = 40 C: 1 x 12 = 12 O: 3 x 16 = 48 100 If 75.0 g of copper react with mercuric nitrate, how many grams of mercury form? Cu + Hg(NO3)2 Cu(NO3)2 + Hg MOLAR MASS CALCULATION: Cu: 64 75.0 g Cu x 1 mol Cu x 1 mol Hg x 201 g Hg = 235.55 g Hg 64 g Cu 1 mol Cu 1 mol Hg Hg: 201 5. How many moles of HCl are needed to form 350 moles of Cl2? 4HCl + O2 2H2O + 2Cl2 350 mol Cl2 x 4 mol HCl = 700 mol HCl 2 mol Cl2 6. How many moles of Na2SO4 is produced when sulfuric acid reacts with 200.0 g of sodium chloride? 2NaCl + H2SO4 2HCl + Na2SO4 MOLAR MASS CALCULATION: NaCl Na: 1 x 23 = 23 Cl: 1 x 35 = 35 58 200.0 g NaCl x 1 mol NaCl x 1 mol Na2SO4 = 1.72 mol Na2SO4 58 g NaCl 2 mol NaCl 7. Na2SO4 Na: 2 x 23 = 46 S: 1 x 32 = 32 O: 4 x 16 = 64 142 How many moles of O2 can be produced by letting 12.00 moles of KClO3 react? 2 KClO3 ---> 2 KCl + 3 O2 12.0 mol KClO3 x 3 mol O2 = 18 mol O2 2 mol KClO3 8. How many moles of Cu are needed to react with 3.50 moles of AgNO3? Cu + 2 AgNO3 ---> Cu(NO3)2 + 2 Ag 3.5 mol AgNO3 x 1 mol Cu = 1.75 mol Cu 2 mol AgNO3 9. The average human requires 120.0 grams of glucose (C6H12O6) per day. How many grams of CO2 (in the photosynthesis reaction) are required for this amount of glucose? The photosynthetic reaction is: 6 CO2 + 6 H2O C6H12O6 + 6 O2 MOLAR MASS CALCULATION: C6H12O6 CO2 120 g C6H12O6 x 1 mol C6H12O6 x 6 mol CO2 x 44 g CO2 = 176 g CO2 C: 6 x 12 = 72 C: 1 x 12 = 12 180 g C6H12O6 1 mol C6H12O6 1 mol CO2 H: 12 x 1 = 12 O: 2 x 16 = 32 O: 6 x 16 = 96 44 180 10. 12.00 moles of NaClO3 will produce how many grams of O2? 2 NaClO3 2 NaCl + 3 O2 12.00 mol NaClO3 x 3 mol O2 x 32 g O2 = 576 g O2 2 mol NaClO3 1 mol O2 MOLAR MASS CALCULATION: O2 O: 2 x 16 = 32