Wooden Utility Pole – Retreatment Process Wooden Pole – Life Span 40 / 60 Years Treatment every 10 years = 3 Gallons of chemicals per pole year 35,000 poles = 35,000 Gallons of chemicals per year Substance Type Chemical Substance EPA Registry Name Dazomet EPA Registry Name List Chemical Identification Systematic Name 2H-1,3,5-Thiadiazine-2-thione, tetrahydro-3,5-dimethylSystematic Name List Chemical Abstracts Index Name Preferred Acronym CAS Number 533-74-4 EPA Identification Number Molecular Formula C5H10N2S2 Molecular Weight 162.28 1 http://www.coppercare.com/Product/Fumigants http://www.osmose.com/documents/fumigant-literature.pdf DuraFume is a crystallized solid dazomet based product that decomposes to produce smaller quantities of mitc than MITCFUME. It is applied from a metered one-gallon container. 2 3 4 Initially minimize area affected by the spill or leak. Block any potential routes to water systems (e.g., sewers, streams, lakes, etc.). Based on the product’s toxicological and chemical properties, and on the size and location of the spill or leak, assess the impact on contaminated environments (e.g. water systems, ground, air equipment, etc.). There are no methods available to completely eliminate any toxicity this product may have on aquatic environments. Minimize adverse effects on these environments. Determine if federal, state, and/or local release notification is required. Recover as much of the pure product as possible into appropriate containers. Later, determine if this recovered product can be used for its intended purpose. Address clean-up of contaminated environments. Spill or leak residuals may have to be collected and disposed of. Clay, soil, or commercially available absorbents may be used to recover any material that can not readily be recovered as pure product. Flushing residual material to an industrial sewer, if present at the site of a spill or leak incident, may be acceptable if authorized approval is obtained. If product and/or spill/leak residuals are flushed to an industrial sewer, insure that they do not come into contact with incompatible materials. In the event of a spill, Buckaman Laboratories is available for technical assistance at 901-767-2722. WASTE DISPOSAL METHODS: Dispose of in accordance with Federal, State, and Local laws. This product is not specifically listed in 40 CFT 261 as a Resource Conservation and Recovery Act (RCRA) hazardous waste. However, spill or leak residuals may meet the criteria for a characteristic hazardous waste under this Act. Check the characteristics of the material to be diposed of and/or the physical and reactivity data given in this MSDS for the neat product. CONTAINER DISPOSAL: Empty containers, as defined by appropriate sections of RCRA, are not RCRA hazardous wastes. However, insure proper management of any residuals remaining in container. http://www.emsnp.org/news_safety_PPL_pole_treat.pdf 5 https://pubchem.ncbi.nlm.nih.gov/compound/methyl_isothiocyanate#sectio n=Wikipedia http://www.beyondpesticides.org/programs/wood-preservatives/publications/poison-poles/no-title109 http://www3.epa.gov/pesticides/chem_search/ppls/075341-00020-20150514.pdf ACTIVE INGREDIENT: Tetrahydro-3, 5-dimethyl-2H-1, 3, 5-thiadiazine-2-thione ..........91.14% 6 7 http://www.wooddoc.org/assets/2007_AWPA_Proceedings_Freeman.pdf 8 https://pubchem.ncbi.nlm.nih.gov/compound/dazomet#section=Top http://www.fedspending.org/ 9 http://www.nytimes.com/1997/02/05/us/utility-poles-cited-as-chemical-danger.html Utility Poles Cited As Chemical Danger Published: February 5, 1997 WASHINGTON, Feb. 4— An environmental group is advocating the end of using wooden utility poles because they are usually treated with dangerous pesticides and wood preservatives. ''Under, around, in and on every preservative-treated utility pole is a toxic site that poses a real threat to clean air, water and land,'' said a report issued today by the National Coalition Against the Misuse of Pesticides. Instead of using wooden poles, which are protected against decay by chemicals that are banned for many other uses, the coalition said utilities should gradually introduce alternatives like steel, concrete and fiberglass or should bury the lines. But the Environmental Protection Agency said utility poles and other approved uses of wood preservatives did not present an unacceptable risk. ''We did a very extensive risk assessment on wood preservatives in the mid-80's,'' said an agency spokesman, Al Heier. ''And we finally determined that the benefits outweighed the risks.'' Mr. Heier said wood preservatives, which are also used on decks, railroad ties and other wood, usually leach out fairly quickly and should not pose a serious hazard. But there are restrictions on their uses, like using them inside the home, he said. Utility poles account for about 13 percent of the market for wood preservatives used to kill fungus and insects and retard decay, the report said. The chemicals, which include pentachlorophenol, creosote, arsenic and chromium, ''contain some of the most hazardous toxic contaminants on the market,'' the report said. 10