SSME experimental and safety setup: solid state synthesis (example) Name Group Project code Experiment explanation : Chemicals needed for synthesis #1 Chemicals needed for cleaning #1 Hazard statements (H-Codes from MSDS) (Or R-Phrases) : CaCO3 and MnO2 : Synthesis CaMnO3 pellets for target in PLD : HNO3 , HCl and Vim scouring powder : CaCO3: R 37/38: Irritating to respiratory system and skin R 41: Risk of serious damage to eyes MnO2: R 20/22: Harmful by inhalation and if swallowed HNO3 and HCl: H272 : May intensify fire; oxidizer : Oxidising liquids; Oxidising solids H311 : Harmful in contact with skin : Acute toxicity, dermal H314 : Causes severe skin burns and eye damage : Skin corrosion/irritation H331 : Toxic if inhaled : Acute toxicity, inhalation H335: May cause respiratory irritation : Specific target organ toxicity, single exposure; Respiratory tract irritation Vim Scouring powder: None required http://www.ardenwinch.com/Content/Upload/File/DataSheets/6014Vim_Scouring_Powder_MSDS.pdf Precautionary statements (P-Codes from MSDS) (or S-Phrases) : CaCO3: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S 36/37/39: Wear suitable protective clothing, gloves and eye/face protection MnO2: S 25: Avoid contact with eyes HNO3 and HCl: P220: Keep/Store away from clothing/combustible materials P261: Avoid breathing dust/fume/gas/mist/vapours/spray P280: Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue Rinsing P310: Immediately call a POISON CENTER or doctor/physician Vim Scouring powder: Keep away from acids. Provided the product is stored in accordance with the approved guidelines there are no known hazardous decomposition products Personal and others protection : Gloves, lab coat, mask and eye protection for treating powders clean spills immediately to protect coworkers from Disposal and cleaning Equipment Type of crucible Furnace temperature range #1#2 Start and end of experiment Time plan equipment #2 Precaution for out of working hours Signatures inhaling the nanoparticles Gloves, lab coat and eye protection and use of fumehood when cleaning mortars with Kings water (HCl + HNO3) Keep powders in closed jars during transport and storage Facial shield when taking powders from furnace and using the hydraulic press : Dispose all disposables and weighing dishes contaminated with powders (nanoparticles) in the black waste bin Clean the mortar with Vim and dispose the waste into waste bin V (heavy metals) Clean the mortar with Kings water and dispose into waste bin V (heavy metals) Dispose crucibles when contaminated in the black waste bin Clean powder spills from the base of the furnace Clean oil spills from the hydraulic press : Planet mill Fritsch P6 Alumina Crucible Loomis platen press Nabertherm 1300 degree furnace for boiling off carbonic acid Entech 1500 degree furnace for sintering pellets D8 powder diffractometer : Monday 12th september Tuesday 20th september : 1st day calculation the amount of powders and checking disposables and make sure everything is abundant available 2nd day weigh powders use of planet mill and boiling off carbonic acid in Nabertherm furnace 3th day checking powder with D8 and press pellets when the carbonic acid is boiled off and place pellet in Entech else continue boiling off carbonic acid in Nabertherm furnace 4th day check pellet with D8 when phase pure pellet ready else powder sample and make new pellet and place in Entech furnace 5th day check with D8 when phase pure pellet ready else continue with homogenizing sample and repeat step 8th and/ or 9th day check with D8 : No need all lab work is done within 09:00 and 16:00 : Experimentalist: J. Baas Daily supervisor: J. Baas Amico: J. Baas #1 Be aware that use of chemicals or equipment not mentioned here has to be reported to Jacob and will delay your experiment #2 Be sure you reserve the equipment beforehand