Nick DiPreta Jonny Masci 4/27/10 Pre-Lab- Acids ionize in aqueous solution and produce hydrogen ions. The strength of the acid is directly related to how much the acid dissolved. The more ions are produced in dissolution, the stronger the acid. Acidic and Alkalinic properties are related to the amount of hydronium and hydroxide ions produced. Purpose- The purpose of this lab is to observe and study typical properties and reactions of acids and bases. Equipment- page 183 of the lab. Exception: no glass tubing Materials- Refer to page 184 on the lab. Safety: • Handle acid and base solutions with care and avoid spills • Flush or wash any spills with water immediately • Always wear safety goggles and lab apron while working in the lab Procedure: Part A Add 5 drops of 6M HCl, 6M HC₂H₃O₂ and .5 NaOH in the spot plate Test the blue litmus, red litmus, ph paper and phenolphthalein with each depression Clean spot plate and dry Part B Add Zinc, magnesium, iron copper to a depression in the spot plate Add 6M HCl and observe the reactions Repeat the first two steps using 6M HC₂H₃O₂ Clean and dry spot plate Place zinc in a test tube and add 6M HCl Invert a test tube and collect the gas and add a burning splint Part C Add limewater solution to a test tube Add CaCO₃ and 6M HCl into another test tube Use the glass tubing to insert the gas into the limewater solution and observe Part D Add 10 drops of 1M HCl and one drop of phenolphthalein to a test tube and test with pH paper Count the number of drops .5 M NaOH to the acid until it changes color Test with pH paper Part E Add vinegar, lemon juice, tomato juice, milk, household ammonia into each depression in a spot plate Test each one with red litmus, blue litmus, pH paper, and phenolphthalein Observations and DataPart A- 6M HCL 6M HC2H3O2 0.5 M NaOH Red litmus Turns pink A little darker blue Blue Litmus Stronger Weaker than HCL blue pH paper 2 3 10 Phenolphthalein More cloudy Nothing pink Part B Reactivity in decreasing order The reactivity from fastest to slowest is Fe, Mg, Zn, Cu. 2. Comparative Reactivities with HCl and HC2H3O2 Zinc Magnesium Iron copper With HCL slow fast Very fast No change With HC2H302 No change Fast Very slow No change 3. Results of Burning Splint TestThe gases ignited and caused a loud popping noise as a result of the burning flame test. Part DNumber of drops of .5 NaOH to neutralize 10 drops of 1 M HCl: 1 drop pH of neutral solution: 7 Part E: Data Table Red litmus Vinegar Turns Red Lemon juice Turns Red Tomato juice Turns Red Milk Turns Red Ammonia Turns Blue Blue litmus Turns red Turns red Turns red No change Turns Blue pH paper 2 3 5 7 10 Phenolphthalein No change Turns cloudy No change No change turns Dark Red Equations 1. Write The Balanced molecular equations for the reaction of each metal with 6 M HCL Mossy Zinc: Zn + 2 HCl H2 + ZnCl2 Magnesium Ribbon: Mg + 2 HCl H2 + MgCl2 Iron Filings: Fe + 2 HCl H2 + FeCl2 Copper wire: Cu + 2 HCl H2 + CuCl 2. Write the Balanced molecular equations for the reaction of each metal with 6 M HC2H3O2 Mossy Zinc: Zn + 2 (HC2H3O2) Zn(C2H3O2)2 + H2 Magnesium Ribbon: Mg + 2 HC2H3O2 Mg(C2H3O2)2 + H2 Iron Filings: Fe + 2 HC2H3O2 Fe(C2H3O2)2 + H2 Copper Wire: Cu + 2 HC2H3O2 Cu(C2H3O2)2 + H2 3. CaCO3 with HCl CaCO3 + 2 HCl CaCl2 + H2O + CO2 4. HCl with NaOH HCl + NaOH H2O + NaCl Questions1. A single replacement reaction occurs between a metal and an acid. A general equation for this type of reaction is: Metal+ Acid Metal ion + Water+ Hydrogen (g) 2. The rates of reaction between a metal and the different acids has to do with reactivity between the metal and nonmetal in the acid. If the metal is more reactive than the non metal, due to the fact that the reaction is a single replacement, it will occur faster. On the other hand, if the metal is not significantly greater in reactivity than the other metal in the acid, than the reaction will not occur at a fast rate. 3. The balanced reaction between CO2 gas and limewater, Ca(OH)2, is: CO2 + Ca(OH)2 Ca(CO3) + H2O Calcium carbonate is the name of the milky precipitate that forms. 4. For some reason, it only took one drop in our experimental data for a neutral solution in part D to be found. However, due to the fact that the concentration of the NaOH is 0.5 M and the HCL is 1.0M one would expect to find under standard conditions, around two times the amount of drops of NaOH to neutralize the 10 drops of HCL. 5. Vinegar, lemon juice, and tomato juice were all acidic. Milk was close to neutral but was more acidic. Ammonia was basic. Conclusion: In this experiment, the properties of acids and bases were investigated. We learned about neutralization reactions as well as learned how to tell if something was an acid or a base using indicators.