W201 Day 2 – Overnight Questions with Answers MEASUREMENT OF AIRBORNE CONTAMINANTS 1. For each of the terms below indicate what is the state of matter (Gas, Liquid or Solid) and define the term. Term State of matter Definition Vapour Gas The gaseous state of a substance which is liquid at 25°C and 760 mm Hg (STP). Mist Liquid Liquid particles, large size generally produced by bubbling, splashing or boiling of a liquid. Fume Solid Solid particles produced by condensation from a liquid or a reaction between two gases. The particle size of a fume <1 micron (µm) diameter anything larger is considered a dust particle. Dust Solid Particles of solid material in the broad size range of 1 micron to 1 millimetre diameter. Anything of a larger particle size is considered to be grit and will be too heavy to remain airborne Aerosol Solid or Liquid General term for the dispersions of solid or liquid particles of microscopic size in a gaseous medium e.g. fog, smoke etc. although commonly used to term fine liquid spray (e.g. ‘aerosol can’). Fibre Solid Solid particulate which is long and thin i.e. has a high aspect ratio of length to breadth. 2. In each of the following pairs indicate which generally involves the larger particles. 1 2 3 4 5 Fume or dust Vehicle exhaust or cement dust Respirable particles or inhalable particles Mist or spray Viruses or bacteria Dust Cement dust Inhalable particles Spray Bacteria Page 1 of 9 W201 Day 2 – Overnight Questions with Answers 3. For each of the following, name the equipment and indicate what substances and what type of sampling it might be used for. IOM sampling head Inhalable dust monitoring Long term sampling Cyclone sampling head Respirable dust Long term sampling Colorimetric tubes Gases and vapours Grab samples Page 2 of 9 W201 Day 2 – Overnight Questions with Answers Passive/diffusion sampler Gases and vapours Long term sampling Charcoal tubes Gases and vapours Long term sampling Direct reading photoionization detector Organic compounds (gases/vapours) Grab samples or continuous monitoring Page 3 of 9 W201 Day 2 – Overnight Questions with Answers 4. The data below represents the information collected during an air monitoring exercise for Total inhalable dust. For each sample calculate the measured concentration of dust in mg.m-3. Sample No: Start (hh:mm) Stop (hh:mm) Flow Rate (l.min-1) Filter Pre weight (mg) Filter post weight (mg) 1 09:00 17:00 2.0 25.34 25.59 2 09:15 12:30 2.0 24.99 27.49 3 13:30 16:58 2.0 26.01 28.09 4 08:00 16:30 2.0 25.45 26.21 5 09:17 15:16 2.0 25.11 26.37 Sampling Time (mins) Weight Change of Filter (mg) Volume of air sampled Concentration (mg.m-3) 480 0.25 960 0.3 195 2.50 390 6.4 208 2.08 416 5.0 510 0.76 1020 0.7 359 1.26 718 1.8 (litres) Page 4 of 9 W201 Day 2 – Overnight Questions with Answers HYGIENE STANDARDS AND OCCUPATIONAL EXPOSURE LIMITS 5. For each of the following measured exposures calculate the appropriate 8hour time weighted average a. The operator works for eight hours on a process in which he is exposed to a substance hazardous to health. The average exposure during that period is measured as 0.15 mg.m-3. The 8-hour TWA = (0.15 x 8) / 8 = 0.15 mg.m-3 b. Working periods may be split into several sessions for the purpose of sampling to take account of rest and meal breaks etc. This is illustrated by the following example: Working period Exposure (mg.m-3) Duration of sampling (h) 0800-1030 0.32 2.5 1045-1245 0.07 2 1330-1530 0.2 2 1545-1715 0.1 1.5 Exposure is assumed to be zero during the periods 1030 to 1045, 1245 to 1330 and 1530 to 1545. The 8-hour TWA = (0.32 x 2.5) + (0.07 x 2) + (0.20 x 2) + (0.10 x 1.5) + (0 x 1.25) 8 0.80 + 0.14 + 0.40 + 0.15 + 0 8 = 0.19 mg.m-3 c. An operator works for eight hours during the night shift on a process in which he is intermittently exposed to a substance hazardous to health. The operator’s work pattern during the working period should be known and the best available data relating to each period of exposure should be applied in calculating the 8-hour TWA. These should be based on direct measurement, estimates based on data already available or reasonable assumptions. Page 5 of 9 W201 Day 2 – Overnight Questions with Answers Working period Task Exposure (mg.m-3) 2200 to 2400 Helping in workshop 0.1 (known to be exposure of full-time group in workshop) 2400 to 0100 Cleaning elsewhere in factory 0 (assumed) 0100 to 0400 Working in canteen 0 (assumed) 0400 to 0600 Cleaning-up after breakdown 0.21 measured in workshop The 8-hour TWA = (0.10 x 2) + (0.21 x 2) + (0 x 4) 8 = 0.078 mg.m-3 d. The operator works a 12-hour shift each day for five days, and then has seven days’ rest. The exposure limits are based on an 8-hour reference period in each 24 hours in which an exposure occurs; the seven days’ rest makes no difference. While at work, the operator is exposed to 4 mg.m-3. The 8-hour TWA = (4 x 12) 8 = 6 mg.m-3 Page 6 of 9 W201 Day 2 – Overnight Questions with Answers BIOLOGICAL MONITORING AND HEALTH SURVEILLANCE 6. What are the three main reasons for undertaking Health Surveillance? to ensure adverse health effects related to the work are identified at an early stage; in some countries there may be statutory requirements. to ensure continued medical fitness for specific tasks like diving or fire fighting to promote general health. 7. What kind of information can biological monitoring provide? the content of a toxic material or its metabolite in blood, urine and breath Its effects on enzyme systems or metabolic pathways Early reversible tissue change Physiological changes Immunological changes. CONTROL 8. Name the elements of the Hierachy of Control and list them in order of performance. Elimination Isolation Segragation Engineering Controls Including LEV Increasing preference Substitution Administrative Controls Personal Protective Equipment Page 7 of 9 W201 Day 2 – Overnight Questions with Answers VENTILATION 9. Name the general components of a Local Exhaust Ventilation system 10. What elements need to be considered when trying to control an airborne contaminant using Local Exhaust Ventilation? Page 8 of 9 W201 Day 2 – Overnight Questions with Answers 11. Give names to each of the hoods shown and describe how they control airborne contaminants. Enclosing hood – surrounds the contaminants and minimises escape by drawing air through open faces. Receptor Hood – receives materials in the direction they are ejected. Capture hood – provides suction beyond the face of the hood to capture contaminants and draw them into the hood. Page 9 of 9