The Effect of Size and Sorting on Porosity Introduction The objective of this lab was to find how the size and sorting of beads (posing as sediment) affects porosity. Porosity of soil or geological materials is the ratio of the volume of pore space in a unit of material to the total volume of material. In other words, it is the amount of air space or void space between soil particles (1). Generally, larger particles have more space between them; they have a larger porosity than smaller particles (2). Therefore, it was hypothesized that as sediment size increases, porosity increases as the larger particles would have larger spaces between them. It was also hypothesized that as sorting increases, porosity increases as there will be little to no smaller particles to fill in larger particles’ spaces (since they will all be the same size in a good sorting). Sorting is the process by which similar in size, shape, or specific gravity sedimentary particles are selected and separated from associated but dissimilar particles by the agent of transportation (4). In other words, sorting is the process of separating different particles in a mixture of particles. It is known that generally, a mixture of grain sizes and shapes result in a lower porosity, as the smaller particles fill the spaces in the larger particles (1). As an additional factor to porosity, generally as the angularity of the particle increases, the porosity increases due to the fact that the particles would pack tighter together (3). Methods In order for this lab to have been performed small beads, large beads, and 3 graduated cylinders were needed. Firstly, 30 mL of small beads were poured into a graduated cylinder and 30 mL of large beads were poured into another graduated cylinder. Then, 50 mL of water was added to each graduated cylinder. Then, the water level was measured on both filled graduated cylinders and recorded. After, the water was poured out of each (without losing any beads) and the beads were mixed together by pouring one set of beads into the other set. The graduated cylinder containing all the beads was then shaken, with a hand over the mouth of the cylinder. After shaking, the volume of the beads was then measured and recorded. Then, 50 mL of water was poured into the graduated cylinder with all the beads in it. The water level was then measured and recorded. Results Figure 1: Figure 1 shows the porosity of small beads, large beads, and poorly sorted beads. Porosity 40.00% 35.00% 36.67% 36.67% Porosity (%) 30.00% 29.17% 25.00% 20.00% 15.00% 10.00% 5.00% 0.00% Small Beads Large Beads Poor Sorting Calculations: Equation 1: To find the porosity, the following equation was used. (Volume of Water Added – (Volume of Water After Adding – Volume of the Beads)) / Volume of Beads = Porosity The following is an example of how the equation was used in the lab (finding the porosity of the small beads). ( 50 mL – ( 69 mL – 30 mL ) ) / 30 mL = about .3667 or 36.67% Discussion To calculate porosity, the Equation 1 was used. Equation 1 obtains the percentage of air space inside the volume of beads by calculating the volume of water in the beads’ spaces and converting it into a percent. In order to do this the “Volume of Water Added” was first found. In this experiment, this number was 50 mL since 50 mL of water was added to each graduated cylinder. Then the volume of water within the volume of beads was taken. This was done by subtracting “Volume of Beads” (30 mL for the well sorted beads and 60 mL for the poorly sorted beads) from the “Volume of Water After Adding” (69 mL for the well sorted beads and 92.5 mL for the poorly sorted beads). Then this amount (39 mL for the well sorted, 17.5 mL for the poorly sorted) was subtracted from the “Volume of Water Added” (50 mL) to get the volume of water within the volume of beads. This was done because the volume of water within the volume of beads was needed, not the entire volume of water which would include the volume of water above the beads. Since Porosity is the percent of air space in a volume of particles, the volume of water in the particles was divided by the “Volume of Beads” (30 mL for the well sorted, 60 mL for the poorly sorted) (1). This number was then converted into a percent by multiplying by 10 and putting a percent sign (%) after it (36.67% for the well sorted beads, 29.17% for the poorly sorted beads). Based on the data shown in Figure 1, the first hypothesis was not supported. In Figure 1, it can be seen that the porosity of the small beads (36.67%) is the same as the porosity of the large beads (36.67%). This data suggests that as size of particle increases, porosity stays the same. However, as stated before, larger particles have more space between them and, in turn, have a greater porosity than smaller particles (2). One important factor to consider in this statement is the shape of the particle. In the source, it references large rocks to small pebbles instead of the perfect spheres used in the lab. Rocks and pebbles rarely form in perfect spheres and, in turn, while the statement works for non-uniform shaped particles, it clearly does not work for uniform shaped particles. This conclusion is further proven by the fact that the diameter size of the particles does not affect porosity if uniform. For instance, basketballs and Ping-Pong balls, which are both spheres, if compacted uniformly have the exact same porosity (1). Another factor to take into consideration is the size difference between particles. In the example given by source 2, the author compares large rocks to tiny pebbles. The size difference between these two particles is huge compared to the difference between the small beads and large beads. This may have been another factor that caused the same porosity of small and large beads shown in Figure 1. In turn, an improvement to the lab could be using drastically different sized beads. However, size of a particle is not the only factor when considering porosity. The packing of the particles is another huge factor to consider with porosity. Even if the particles are the same size, if the arrangement or packing of particles can change the porosity. If the particles are directly on top of each other, a type of arrangement called cubic packing, there is generally a higher porosity than rhombohedral packing. Rhombohedral packing is when the particles are stacked in a triangular shape so that each single particle is on top of two other particles (which are horizontally touching) (1). Since the experiment did not take this into account, it is possible that a difference between large and small beads’ porosities could have been observed, depending on how the beads landed in the graduated cylinder. The small beads could have been under rhombohedral packing and, in turn, have a smaller porosity than what should have been observed in they were under cubic packing. To improve the experiment, there must be some sort of way to ensure that both beads have the same packing technique. One possible solution would be to get a smaller graduated cylinder which is just large enough to have precise cubic packing for each bead type. Although not apparent in this set of data, the packing type is still a factor which should be controlled in the experiment. Therefore, assuming packing is the same, if all particles are spheres, as size increases porosity remains the same. Figure 1 supports the second hypothesis; as sorting increases, porosity increases. The data shown in Figure 1 supports this hypothesis; as sorting increases, so does porosity. There is a clear difference between the poorly sorted beads (29.17%) and the well sorted large and small beads (36.67%). This makes sense because, generally, a mixture of grain sizes and shapes result in a lower porosity, as the smaller particles fill the spaces in the larger particles (1). However, the experiment only used two sizes of same shaped particles in this experiment. In sediment, there is rarely a case in which there are only two same shaped particles that form an entire layer. There are often multiple sizes and shapes involved in creating sediment. Both size and shape are huge factors that must be taken into account when considering porosity (1). In order to improve the experiment, different mixtures of multiple different sized particles must be used. Again, drastic size differences and different shapes should be used since these properties occur in nature. In order to have accurate representations of porosity in the experiment different shaped, such as cubes, and drastically different sized particles should be used in future experiments. However, this change would only create a greater porosity difference; the data shown seems relatively accurate as the mixed same shaped, different sized particles have a lower porosity than the well sorted particles. The packing of the particles may then be different when the graduated cylinder was shaken since the even smaller particles could have fit into the large particles’ spaces even more than the small beads used in the experiment. If this were to happen, then the porosity would have been even lower than the result found in this experiment. However, this would not change the fact that the porosity of the poorly sorted particles was lower than the sorted particles. Therefore, based on the data, it can still be concluded that, for same shaped slightly different sized particles, as sorting increases, porosity increases. Some factors that could have influenced the outcome of the experiment include the estimation of beads and loss of water when attempting to pour it into the graduated cylinder. Due to the fact that it is almost impossible to get exactly 30 mL of beads, since they do not stack perfectly, the actual volume compared to the estimated volume may be off. If the estimated volume of the beads is 30 mL but is actually 31 mL, the water level after adding water would be higher and vice versa. Because of this, the porosity calculation may be slightly higher, if the beads were lower than estimated, or lower, if the beads were higher than estimated. Although the difference may seem miniscule with only a 1 mL change in water level, if the experiment is not done carefully enough there could be as much as a 3 mL difference resulting in an extremely off porosity calculation. Therefore, although not entirely avoidable, the volume of the beads must be carefully measured to 30 mL for accurate results. The graduated cylinder must be shaken lightly to ensure that the beads are at exactly 30 mL. Another factor to take into consideration is the accidental loss of water before or during the pour into the graduated cylinder. If as much as 1 mL of water is spilled out of the graduated cylinder but still taken as “50 mL”, the water level will drop by 1 mL. In turn, similar to the effect of badly estimated bead volume, the porosity will increase. The calculations will be inaccurate as the measurements will be off. If the water added is still taken as 50 mL when it is actually 49 mL, the porosity will increase. If the experimenter is not careful and more than 1 mL is spilled, the porosity will be even higher than the actual. Although neither of the factors mentioned impacted the outcome of the well sorted beads’ porosities since they are the same, loss of water may have impacted the outcome of the poorly sorted beads’ porosity. If water was lost before or during pouring it into the graduated cylinder, for the poorly sorted beads, the porosity may have risen. However, as stated before, the porosity is still relatively accurate since it is still less than the well sorted beads’ porosity. The loss of beads would have been evident when measuring the volume of the beads again after mixing, so it was not a factor that affected the outcome of the lab. Therefore, the data can still be considered accurate, and the conclusions reached based on the data can still be considered accurate. Porosity is often associated with permeability; the measure of how well a liquid can pass through a given material (5). Low porosity often results in low permeability since there is less air space that liquid can pass through. However, high porosity does not always mean a high permeability. Permeability measures the degree to which the pore spaces are connected and the size of the connections (6). In order for different levels of permeability, there are many factors to take into account besides porosity. Interconnectivity plays a huge part in permeability because it impacts the extent to which a liquid can go through a material. The force of molecular attraction, a factor when considering permeability, says that a thin layer of liquid will always be attracted to particles due to the unsatisfied ionic charge on the surface. If the size of the interconnections is smaller than the zone of molecular attraction then the liquid is unable to move between pores (6). In other words, if the pores are not connected or barely connected to the extent of which liquid cannot pass between them, the material is barely, if at all, permeable. If the particles within a material are extremely small, this effect will take place since the connections between particles will be smaller than the zone of molecular attraction; the water will stay stuck to the particle. Therefore, it can be concluded that as particle size increases permeability increases and vice versa. However, as stated before, particle sizes and shapes are not completely uniform in nature, thus there will be some pores and interconnections that are larger than others since the particles will not stack evenly. Therefore, depending on the shape, permeability will either increases or decrease. As an example, when considering the effect of size and shape, clay has a low permeability due to small grain sizes and flat particle shapes. The flat shape results in larger surface area, leading to increased friction. The increased friction leads to less permeability because the liquid has a harder time passing through the material (1). Both size and shape are huge factors when considering permeability since these factors influence interconnectivity, a key factor when considering permeability. Expanding on factors that affect interconnectivity, sorting also plays a huge role in permeability. As established earlier, when sorting increases porosity increases, and, in turn, vice versa (as shown in Figure 1 with decreased sorting). If the smaller particles fill in the larger particles, the liquid has less ability to move through the material. The size of interconnection, when there is poor sorting is less than good sorting since the pores themselves are smaller. Since there is less porosity in poorer sorted materials, the permeability decreases since the liquid has more trouble passing through. Therefore it can be concluded that as sorting decreases permeability decreases. However, it cannot be concluded that as sorting increases permeability increases. This is due to the fact that as sorting increases porosity increases, but as porosity increases permeability does not necessarily increase. For example, an igneous rock with many gas bubbles in it from quick cooling is considered highly porous. However, since the pockets are not connected, the liquid cannot get through the material and, in turn, the material has a low permeability (6). In order to fully understand how groundwater will flow into a sample of sediment, both porosity and permeability must be taken into account. Permeability measures how well a liquid can move through a material. In this case, permeability will show how well groundwater can flow through a sample of sediment. If the sediment is highly permeable, the groundwater can easily flow through it. If the sediment is barely permeable, if at all, the groundwater will take a long time to flow through it, or if impermeable the groundwater will not be able to flow through the sediment. Although the fact that high porosity does not necessarily mean a higher permeability in an igneous rock, when considering other types of rocks generally, it is known that as porosity increases permeability increases (1). Therefore, when considering permeability, porosity contributes greatly to how groundwater will flow into a sample of sediment. An extremely porous sediment sample allows for groundwater to easily pass through it and it is therefore highly permeable. As concluded before, sediment sample with low porosity will have a lower permeability since there is less space for the groundwater to pass through. As a factor of porosity, the size of sediment, considering the particles are not uniform, plays a huge part in permeability. In order to test for the specific effect that sediment size has on permeability, differently sized and shaped particles must be used. Since, in nature, there are differently shaped particles within a given material, the differently shaped particles must be used. To test specifically for particle size effect on permeability, a few groups of different shaped particles with at least two sizes must be used. Since sorting plays a huge factor in porosity and, in turn (for sediment), permeability, the two sizes must be separated and put into separate containers of small and large particles. Since permeability is the measure of ability of liquid to go through a given material, a time interval must be established. If the particles together have a low permeability, it will take more time for the liquid to go through and, in turn, there will be less liquid in the container meant to catch the liquid. In the experiment, after an interval of time, the liquid collected after passing through the particles will be measured (there will be a constant supply of liquid on top). The size with more liquid will clearly be more permeable since the liquid came through the particles faster. In the lab, when measuring the porosity of the small beads, it was expected that the small beads would have a lower porosity than the larger beads. However, this was not the case; the small beads had the same porosity as the large beads. The differed outcome was intriguing, and, in turn, more research was done to find out why the porosity did not change between sizes. It was found that, with perfect spheres, porosity does not differ. This fact led to a new understanding of the experiment and, in turn, to realizations of how the experiment could be improved using different shapes. Without data contradicting the hypothesis, this further understanding would not have been reached; less would be known about porosity and its factors. With an incorrect hypothesis, more research was done to find out whether there was a calculation error or a flaw in the prediction, leading to more knowledge of the subject. In the real world, scientists also learn from wrong hypotheses; they are intrigued which leads to further experiments and, eventually, further understanding. Advancements in the science world are dependent on incorrect hypotheses, which lead to or are proved wrong by more experiments. In science, it must be considered that wrong hypotheses are not detrimental; instead they are more beneficial to a scientist’s success. It must be considered that if there were no wrong hypotheses, science would not evolve and, in turn, there would be very little understanding of neither nature, nor the world, nor the universe. Appendix Type Volume of Beads Volume After Water Porosity Small Beads 30 mL 69 mL 36.67% Large Beads 30 mL 69 mL 36.67% Poor Sorting 60 mL 92.5 mL 29.17% References 1. "Soil Properties That Affect Groundwater." Portage County, WI. Portage County Government, 2008. Web. 19 Mar. 2012. <http://www.co.portage.wi.us/groundwater/undrstnd/soil.htm>. 2. "How Does Particle Size Affect Porosity? | GreenAnswers." Green Answers to Environmental Questions, Recycling, Nature, Animals & More! Green Answers, 2012. Web. 19 Mar. 2012. <http://greenanswers.com/q/97976/sciencetechnology/chemistry/how-does-particle-size-affect-porosity> 3. "Geology." Enotes.com. Enotes.com. Web. 19 Mar. 2012. <http://www.enotes.com/geology/q-and-a/how-shape-grain-rock-affect-porosity-95301>. 4. "Sorting." Answers.com. Answers, 2012. Web. 19 Mar. 2012. <http://www.answers.com/topic/sorting-2>. 5. Tarbuck, Edward J., and Frederick K. Lutgens. Prentice Hall Earth Science. Boston, MA: Pearson Prentice Hall, 2009. Print. 6. Nelson, Stephen A. "Groundwater." Tulane University. Tulane University, 3 Apr. 2011. Web. 19 Mar. 2012. <http://www.tulane.edu/~sanelson/geol111/groundwater.htm>.