TEXTURAL ANAYLSIS OF MAFIC ENCLAVES AS AN INSIGHT INTO MAGMA MIXING PROCESSES AT CHAOS CRAGS, LASSEN VOLCANIC CENTER, CALIFORNIA Crystal Dawn Hootman B.A., California State University, Sacramento, 2007 THESIS Submitted in partial satisfaction of the requirements for the degree of MASTER OF SCIENCE in GEOLOGY at CALIFORNIA STATE UNIVERSITY, SACRAMENTO SUMMER 2011 TEXTURAL ANAYLSIS OF MAFIC ENCLAVES AS AN INSIGHT INTO MAGMA MIXING PROCESSES AT CHAOS CRAGS, LASSEN VOLCANIC CENTER, CALIFORNIA A Thesis by Crystal Dawn Hootman Approved by: __________________________________, Committee Chair Dr. Lisa Hammersley __________________________________, Second Reader Dr. Diane Carlson __________________________________, Third Reader Dr. David Evans ____________________________ Date ii Student: Crystal Dawn Hootman I certify that this student has met the requirements for format contained in the University format manual, and that this thesis is suitable for shelving in the Library and credit is to be awarded for the thesis. __________________________, Department Chair Dr. David Evans Department of Geology iii ___________________ Date Abstract of TEXTURAL ANAYLSIS OF MAFIC ENCLAVES AS AN INSIGHT INTO MAGMA MIXING PROCESSES AT CHAOS CRAGS, LASSEN VOLCANIC CENTER, CALIFORNIA by Crystal Dawn Hootman The Chaos Crags are a series of volcanic domes located in Lassen Volcanic Center, southernmost Cascades Range. The six domes erupted approximately 1100 years ago. The host rock is dacite, which is compositional similar in all domes at (66-69 wt. % SiO2), and differs from the mafic enclaves that range in composition from (53-61 wt. % SiO2). The enclaves result from two distinct and thermally different magmas mixing and can provide an insight into the processes of magma mixing. Five texturally different enclaves types were identified. To determine abundance of the enclaves in each dome, 113 point count stations were completed in the dome complex talus slopes. Previously collected and new samples were photomircrographed and plagioclase crystals were hand traced to be processed in Crystal Size Distribution (CSD), which determines nucleation and growth time of crystals. Previously completed geochemical data was used to determine if the enclaves and host were similar or different in composition. The results of observation at Chaos Crags were 1) The total abundance of enclaves increases with eruption of domes. 2) There are distinctive abrupt increases in the total abundance of enclaves between eruption of domes B and C, domes C and D. iv 3) There are more modest increases in the total abundance of enclaves between eruption of domes A and B, domes E and F. 4) Although it seems likely that all enclave types are present in each dome, changes in distribution of enclave type seem to correlate with the increase in total abundance. 5) Host dacites show a narrow range in composition while enclaves show a mixing trend from a more mafic source toward the host dacite. 6) There is a clear link between enclave type and geochemistry. The most mixed enclave types are type 1. The least mixed are types 3 and 4. The magma mixing model proposed is one of repeated injections of small batches of mafic magma, either injected as a fountain or ponded at the base of the magma chamber. Also the mafic magma injections are the suggested cause of eruption. Enclaves present are directly related to the type of recharge event. Disaggregation of the enclaves occurred in the conduit during the eruption. This thesis was just an initial step using CSD and geochemical data leading to some surprising results and further research should be conducted. _______________________, Committee Chair Dr. Lisa Hammersley _______________________ Date v ACKNOWLEDGMENTS This thesis would have never been completed without the support of my graduate advisor, Dr. Lisa Hammersley. She was patient with me during the times I could not work on my thesis, yet would remind me that I could finish and remind me of my goal that I wanted that to teach. She helped my understanding of want it takes to be a scientist. I feel privileged to be Lisa’s first graduate student. I would also like to thank my committee members, Dr. Diane Carlson and Dr. David Evans, willing to take time out of their summer schedule to help me complete my Master’s Degree. I will always be appreciative, especially to Dr. Diane Carlson, throughout the last nine years, who would witness my change from being a horrible field mapper in Field Geology to signing off on my Master’s Degree. This project would have not even been started, if it were not for Dr. Michael Clynne of the USGS graciously allowing me to use his samples collected from Chaos Crags before I collected my own sample set. Christiana Stout, an undergraduate student at the time I started my project, introduced me to the Chaos Crags field area. Christine O’Neill was an undergraduate that also had a project at the Chaos Crags Jumbles and it was a privilege to spend time in the field and determining the enclave types with her. To my friend Melinda Fredericksen, she helped me complete field work and was excellent company out in the field. I appreciate the National Association of Geoscience Teachers for giving me a scholarship that helped with field work and tuition. Also I need to thank my son Justin, he means the world to me. Lastly, I need to thank my better half, Ed Shakespeare, he was encouraging me every day to finish my thesis, eventually it sunk in and I completed the task in hand. It feels incredible that my thesis is done! vi TABLE OF CONTENTS Page Acknowledgments.................................................................................................................... vi List of Tables ........................................................................................................................... ix List of Figures ............................................................................................................................ x Chapter 1. INTRODUCTION ……………...……………………………………………………….... 1 1.1 Purpose of the Study…………………...……………………………………….... 1 1.2 Geologic Setting of the Lassen Region ................................................................... 2 1.3 Geology of the Chaos Crags .................................................................................. 5 2. METHODS ......................................................................................................................... 8 2.1 Identification of Enclave Types ............................................................................. 8 2.2 Field Work ............................................................................................................. 8 2.3 Crystal Size Distribution Analysis (CSD) ........................................................... 11 3. RESULTS ......................................................................................................................... 16 3.1 Classification of Enclave Types........................................................................... 16 3.2 Enclave abundance in the Chaos Crags ............................................................... 23 3.3 Crystal Size Distribution ...................................................................................... 27 3.4 Geochemistry ....................................................................................................... 33 4. DISCUSSION ................................................................................................................... 41 4.1 Magma Mixing Models........................................................................................ 41 4.2 The Lassen Peak Magma Mixing Model ............................................................. 42 4.3 Mixing studies at Chaos Crags………………………………………………… .. 45 4.4 Observations from Chaos Crags………………………………………………… 47 4.5 Chaos Crags Magma Mixing Model…………………………………………… 50 5. CONCLUSION………………………………………………………………………… 56 Appendix A. Point Count Locations ..................................................................................... 58 Appendix B. Hand Sample list.............................................................................................. 62 Appendix C. Theory of Crystal Size Distribution................................................................. 64 Appendix D. Background to CSDCorrections Program ....................................................... 67 vii Appendix E. Individual Crystal Size Distribution Graphs .................................................... 68 References ............................................................................................................................. 166 viii LIST OF TABLES Page 1. Table 1 Total Enclave Abundance for each dome at Chaos Crags…………… 24 2. Table 2 Major Element Composition of Host and Enclave Rocks…………… 35 ix LIST OF FIGURES Page 1. Figure 1 Location map of the major volcanoes in Cascade Range.…………….. 3 2. Figure 2 Simplified Geologic Map of Chaos Crags, Lassen Volcanic Center, California…………………………...………………………………………….. 6 3. Figure 3 Point count grid with 361 points and example of point count sample location.………………………………...……………………………………… 9 4. Figure 4 Location map of point count locations for each of the domes at Chaos Crags…………………………..…..................................................................... 10 5. Figure 5 (A) Photomicrograph of sample #88-1283, which is enclave type 2 in Dome B. …………………………………………………...………………….. 12 6. Figure 6 An example of the CSDCorrections Program data entry page from http://depcom.uqac.ca/~mhiggins/csdcorrections.html……………........…….. 14 7. Figure 7 Crystal shape of 3D sections calculated from the 2D image by using short axis and normalized frequency.…………………………………………. 15 8. Figure 8 Example of a logarithmic CSD graph of #88-1283…………………... 15 9. Figure 9 Different textural types of enclaves present at Chaos Crags…………. 17 10. Figure 10 Different types of enclaves margins observed in various dome locations…………………………...…………………...…………………….. .19 11. Figure 11 Disequilibrium textures present in the host and enclaves………….. 23 12. Figure 12 Abundance of enclaves by dome…………………………………….24 13. Figure 13 Abundance of different enclave types in each dome...…….. ..……. .26 x 14. Figure 14 CSD curves for the host dacite of each dome….……...……………. 29 15. Figure 15 CSD curves for each enclave type………………………….………. 30 16. Figure 16 CSD curves for enclave types for each dome……..………..………. 33 17. Figure 17 CaO vs. SiO2 host dacite and enclave samples analyzes as part of this study for CSD………………………………………………………………… 37 18. Figure 18 A comparison of major element compositions at Chaos Crags of host dacite (diamonds) and mafic enclaves (squares) …………………......……… 38 19. Figure 19 CaO vs. SiO2 for all samples analyzed by Dr. Michael Clynne …… 39 20. Figure 20 Vesiculation model of the mafic foam layer ………………………. 42 21. Figure 21 Magma mixing and enclave formation model for Lassen Peak…..... 44 22. Figure 22 Enclave formation model proposed for Chaos Crags by Tepley et al., (1999)……………….………………………………………….………... 46 23. Figure 23 Magma mixing model for Chaos Crags………………...………….. 52 xi 1 Chapter 1 INTRODUCTION 1.1 Purpose of the Study Magmatic recharge of mafic magma into a shallow reservoir has been shown to be the trigger for volcanic eruptions, yet our understanding of this process is still incomplete (e.g. Crater Lake (Bacon, 1986); Pinatubo (Pallister et al., 1992); Lassen Peak (Clynne, 1999); El Chichón (Tepley et al., 2000)). Mafic enclaves (also called magmatic inclusions or inclusions) provide the physical evidence that mixing has taken place in a magma chamber between two distinct compositionally and thermally different magmas and can be used as a tool to provide insight into the process of magma mixing (Heiken and Eichelberger, 1980; Bacon, 1986; Clynne, 1999, Browne et al., 2006; Feeley et al., 2008). Good outcrop exposure and the abundance of several different textural types of mafic enclaves make Chaos Crags an ideal location to study magma mixing processes. Early studies of the abundance of enclaves at Chaos Crags suggest that the volume of magma mixing into the system increased during the eruption of domes (Stout, 2007). Questions remain as to whether the enclaves represent a single mixing event or whether the formation of each dome was preceded by a unique mixing event. This study aims to more completely understand the magma mixing processes that occurred during the eruption of Chaos Crags. The study is made up of three components: (1) identification and sampling of different textural types of enclaves from each dome, (2) field mapping the distribution for each different textural type of enclave for each dome 2 (measured in talus slopes of the domes), and (3) a detailed petrographic study of the sampled material using crystal size distribution (CSD) and geochemical composition. While this study is a focused study of the volcanic domes at Chaos Crags, the results could provide insight in magma mixing that is widely applicable to other locations; both ancient and currently active volcanic systems. In particular, a better understanding of the timescales of magma mixing may be important in assessing volcanic hazard. 1.2 Geologic Setting of the Lassen Region The Chaos Crags are located in the Lassen Volcanic Center (LVC), the southernmost active volcanic system in the Cascade Range (Figure 1). Subduction of the Explorer, Juan de Fuca, and Gorda plates beneath the North American plate is associated with the development of the Cascades (Guffanti and Weaver, 1988). Specifically in the Lassen region, volcanism has been influenced by subduction of the Gorda plate, migration of the Mendocino triple junction and Walker Lane, and extension in the Basin and Range Province (Guffanti et al., 1990; Blakely et al., 1997, Unruh et al., 2003). Late Quaternary northwest trending normal faults extend from Medicine Lake Highlands to south of Lassen and connect the southern Cascades Range to the Walker Lane and Basin and Range Province (Guffanti et al., 1990; Blakely et al., 1997; Unruh et al., 2003). The Lassen volcanic region is located between the Lake Almanor and Hat Creek grabens (Guffanti and Weaver, 1988). 3 Figure 1. Location map of the major volcanoes in Cascade Range. Lassen Peak and Chaos Crags are found in the Lassen Volcanic Center and are designated by the white triangle. Modified from Clynne (1990). 4 Volcanic rocks types found in the Lassen region include basalt, basaltic andesite, andesite, dacite and rhyolite. Two types of basalt are represented in the region: 1) a low potassium olivine tholeiite basalt (LKOT); and 2) a calc-alkaline basalt. The calcalkaline basalts represent typical subduction-related melts. A possible origin for the discontinuous LKOT volcanism in the Lassen region is the propagation of northwest trending faults of the Walker Lane seismic area that extends slip back to the Cascadia subduction zone (Guffanti et al., 1990; Unruh et al., 2003). The youthful faults may also be the source for the growth of long-lived volcanic centers (Guffanti et al., 1990). Volcanism in the region can be classified into two classes: short-lived coalescing volcanoes compositionally ranging from basaltic to andesitic; and long-lived centers compositionally ranging from basaltic to dacitic (Clynne, 1990; Guffanti et al., 1990). Over the last 3 Ma, five different volcanic centers have been identified within the Lassen region, but older ones probably existed (Clynne, 1990; Guffanti et al., 1990). The volcanic centers identified in the region, in order of age are Snow Mountain, Dittmar, Yana, Maidu, and Lassen. LVC has an active hydrothermal system progressing to terminal stage, while the four older centers have extinct hydrothermal systems. Evolution of the LVC is divided into three phases, stage one and two (600-400 ka), involved the growth and destruction of the Brokeoff volcano, an 80 km3 andesitic stratovolcano. Stage 1 lavas tend to be heterogeneous while stage 2 lavas are homogenous (Clynne, 1990). Stage three (< 400ka) consists predominantly of silicic volcanism. Stage 3 began with the eruption of the Rockland sequence, a widespread rhyolitic pumice fall and ash flow (with an estimated volume of 50 km3), then continued 5 with the Bumpass (250-200 ka) and Loomis sequences (100-0 ka) (Clynne, 1990). Recent silicic volcanic domes that consist of similar magma mixing textures include the 28.3 ka Lassen Peak (Turrin et al., 1998), which was last active from 1914-1917, and the 1.1 ka Chaos Crags (Clynne and Muffler, 1989). 1.3 Geology of the Chaos Crags The Chaos Crags are a series of young silicic volcanic domes, named A-F, located north of Lassen Peak (Figure 2). Eruption of the domes began 1230 years ago with three pyroclastic flows that traveled down the Manzanita and Lost Creek drainages (Heiken and Eichelberger, 1980). This was followed 1129 years ago by more pyroclastic flows, named A and B and eruption of dome A. Approximately 1062 years ago eruption of a larger pyroclastic flow C destroyed dome A, which is believed to have blocked the conduit. Domes B-F were then emplaced sequentially. After a hiatus and unrelated to volcanic activity, three rockfall avalanches collapsed from dome C, 275 years ago (Clynne and Muffler, 1989). The total volume of erupted materials at Chaos Crags is approximately 2km3 (Tepley et al., 1999). 6 Figure 2. Simplified Geologic Map of Chaos Crags, Lassen Volcanic Center, California. The petrology of lavas at Chaos Crags has been described by Heiken and Eichelberger, (1980); Clynne and Muffler, (1989); and Tepley et al., (1999). The dominant rock type at Chaos Crags is a porphyritic hornblende-biotite dacite containing a variety of mafic enclaves. Based on slight differences in host rock composition and the number and size of enclaves, Tepley et al. (1999) grouped the lava into groups 1 and 2. Group 1 lavas contain Dome A and B and their associated pyroclastic flows. Group 2 lavas contain Dome C, D, E, F and associated dome collapse deposits. The phenocryst 7 assemblage in both groups, comprise 30% of the rock and includes plagioclase, quartz, biotite, hornblende, hypersthene, and low-Ti titanomagnetite in a glassy to devitrified groundmass; which is similar to Lassen Peak. Enclaves are individual blobs of mafic lava that have been undercooled with respect to the silicic lava after mixing between the two different compositional magmas. Previous studies at Chaos Crags by Tepley et al. (1999) indentified three different types of enclaves, a fine grained porphyritic, a coarse grained non-porphyritic, and a medium grained porphyritic. Common phenocryst phases in the enclaves are plagioclase, hornblende, orthopyroxenes, clinopyroxenes, opaques and some rare olivine. Related to mixing processes are xenocrysts, which are reacted host phenocrysts found within enclaves (Bacon, 1986). Xenocrysts in Chaos Crags enclaves include hornblende and quartz that exhibit resorption rims, plagioclase and hornblende can have sieve textures and plagioclase may have new crystal growth rims. Tepley et al. (1999) observe that enclaves in the earlier domes have a fine-grained texture, crenulated margins and little vesiculation while enclaves in the later domes have more vesiculation and many do not have crenulated margins due to disaggregation. 8 Chapter 2 METHODS 2.1 Identification of Enclave Types Prior to conducting field work, samples of enclaves from prior studies (personal communication by Dr. Michael Clynne of the United States Geological Survey and Dr. Lisa Hammersley) were examined in hand sample and thin section. The enclaves were classified into five types based on texture and mineralogy. Type 1 enclaves are characterized by an aphantic appearance with abundant small vesicles and large host plagioclase. Type 2 enclaves have a distinctive fine grained “salt and pepper” appearance in hand sample. Type 3 enclaves are easily distinguished by the presence of acicular hornblende crystals up to 3mm in length and a plagioclase groundmass. Type 4 enclaves are identified by the presence of visible olivine crystals. Type 5 enclaves display a coarse grained “salt and pepper” appearance. Complete descriptions of the texture and mineralogy of the five enclave types are provided in Chapter 3 (results). 2.2 Field Work Field work commenced in the summer of 2007 and lasted through the summer of 2011. The primary method used in the field was point counting. Outcrop scale point counting has been shown to be an effective method for determining the distribution of enclaves in the field (Wolfe et al., 2007; Feeley et al, 2008). The point count process involved taping a 1m2 grid on to an outcrop (Figure 3). Grid lines were spaced 5 cm 9 apart, with a total of 361 points where the lines crossed. When an enclave was present on an intersection of the grid it was counted and classified into its textural type. This method provided a volume estimate for each enclave type. Each time a point count was completed a photograph was also taken. Figure 3. Point count grid with 361 points and example of point count sample location. Due to the steep and craggy nature of the Crags, point counting was not conducted on the domes themselves but on large boulders within the talus slope of each dome. Feeley et al. (2008) show that enclave distribution can vary within a dome due to flow regimes. The talus slopes represent an averaging of material from different points on the dome and it is assumed that they give a fair representation of the total abundance of enclaves. 10 A total of 113 point count stations were recorded over the six domes (Figure 4). The distance between most point count stations was approximately 100m. A station consists of two points counts completed on two different boulders in the vicinity of the GPS coordinate to get an average. The exact location of each point station is given in Appendix A. 1000m Figure 4. Location map of point count locations for each of the domes at Chaos Crags. A total of 38 new samples were collected during field work. Sampling focused on creating a complete set of enclave types for each dome. Collected samples ranged from 3 11 to 6 inches and were selected based on determined textural difference. Some of the new samples were thin sectioned for petrography and use in Crystal Size Distribution Analysis. A complete list of samples is provided in Appendix B. 2.3 Crystal Size Distribution Analysis (CSD) Crystal size is a function of nucleation and growth time (Marsh, 1988, 1998). The theory of Crystal Size Distribution (CSD) was developed by two chemical engineers, Randolph and Larson (1971), as a quantitative approach to measure the crystallization process independent of an exact kinetic theory. CSD was first applied to geologic systems in two different studies: the development of CSD theory (Marsh, 1988) and application to igneous rocks (Cashman and Marsh, 1988). The equations developed by Randolph and Larson and adapted by Marsh form the foundation of CSD theory. A summary of the background and formulas for CSD analysis can be found in Appendix C. Digital photomicrographs of thin sections were analyzed for representative host rock and enclaves from each dome at Chaos Crags. Maximum information for rock textures is achieved by selecting many different spots in thin sections for each dome (Higgins, 2000). Individual plagioclase crystals were traced by hand using tracing paper and afterwards verified with the use of a polarizing microscope (Figure 5). Tracing by hand removes any bias and allows for a more accurate total crystal number (Martin et al., 2006). For example, digital analysis programs are more likely to count touching crystals as a single crystal. 12 A B 10x 10x Figure 5. (A) Photomicrograph of sample #88-1283, which is enclave type 2 in Dome B. (B) Example of hand traced plagioclase overlay. The tracings were scanned at 300 dpi, converted to TIFF’s and opened in the program Image J, a public domain Java image processing program that can calculate dimension and area of objects in an image. (ImageJ is downloadable for free at http://rsbweb.nih.gov/ij/.) Image J was used to calculate volume, average size, and location sites of crystals in each thin section tracing. Data from Image J was inserted as a plug-in into the CSDCorrections 1.39 program (Figure 6; Higgins, 2000; downloadable for free at http://wwwdsa.uqac.uquebec.ca/~mhiggins/CSD.html), which converts 2D data into 3D based on assumptions regarding the crystal shape. These assumptions are entered by the user in the form of (S: I: L), S=shortest crystal dimension, I= intermediate 13 crystal dimension, and L= longest crystal dimension. A 1:1:1 ratio reflects cubes, 1:1:3, acicular crystals, and 1:10:10, tablets (Figure 7). The CSD analysis is typically presented as a logarithmic scale graph that compares size against population density of crystals and evenly distributes maximum intersection size across the total crystal size range (Figure 8; Marsh 1988, Marsh, 1998). To obtain an accurate 3D shape using the CSDCorrections program, at least 200 phenocrysts must be represented and have a R2 value over 0.8 to be reliable (Morgan and Jerram, 2006). R2 is determined as a fractional variation that best fits an example in the database of 703 shapes with crystal habits. For more information on the background of the CSDCorrections program, see Appendix D. 14 Figure 6. An example of the CSDCorrections Program data entry page from http://depcom.uqac.ca/~mhiggins/csdcorrections.html. 15 Figure 7. Crystal shape of 3D sections calculated from the 2D image by using short axis and normalized frequency. From Morgan and Jerram (2006). Ellipse Major axis 10 9 8 ln (population density) 7 6 5 4 3 2 1 0 -1 0 1 Size Figure 8. Example of a logarithmic CSD graph of #88-1283. 16 Chapter 3 RESULTS 3.1 Classification of Enclave Types The enclaves were classified into five types based on texture and mineralogy (Figure 9). Type 1 enclaves are characterized by an aphantic appearance. Very fine grained crystals of plagioclase and hornblende comprise a gray groundmass. Large reacted plagioclase crystals (from the host dacite) up to 6mm in length are present as well as rarer hornblende crystals up to 6mm are also present. Vesicles up to 3mm in size are common in type 1 enclaves. Type 2 enclaves have a fine grained “salt and pepper” appearance. Plagioclase and hornblende are blocky in shape. Reacted host plagioclase crystals, up to 5mm in length are present. Type 3 enclaves are easily distinguished by the presence of acicular hornblende crystals up to 3mm in length and a plagioclase groundmass. Occasional reacted host plagioclase crystals are present. Type 4 enclaves have visible olivine crystals up to 3mm in size. The groundmass consists of both blocky and acicular hornblende crystals up to 2mm. Plagioclase crystals also are both blocky and acicular. Reacted plagioclase crystals are up to 4mm in length. Type 5 enclaves display a coarse grained “salt and pepper” appearance. Hornblende crystals are blocky and up to 2mm. 17 A B C D E Figure 9. Different textural types of enclaves present at Chaos Crags. A) Type 1; B) Type 2; C) Type 3; D) Type 4; E) Type 5 Enclave size rarely exceeds 1m in length, but can also be as small as 10mm, (the smallest enclaves that could be recognized in the field). Weathering in some of the domes also made distinguishing the different types of enclaves difficult. Dome C is highly altered especially in the jumbles debris avalanche field with the dacite and mafic enclaves altered to a salmon color. Dome A, B, and E also have experienced more 18 weathering in certain locations, such as talus slopes debris covered in lichens due to other geomorphological controls, such as precipitation. The margins of the enclaves can vary from crenulated to disaggregated (Figure 10). Crenulated margins have a convoluted, wavy appearance. Disaggregation of enclaves occurs during transport of mostly cooled enclaves within the magma chamber. Disaggregated margins are those where smaller portions of the enclave are found in the host rock close to the margin. Some enclaves have sharp margins. These may represent the cores of enclaves that have disaggregated and then been transported. It appears that enclaves are more crenulated and less disaggregated in domes A and B. In domes C-F, the enclave margins are less crenulated and more disaggregated. 19 A B C D E Figure 10. Different types of enclave margins observed in various dome locations. (A) Chilled margin from Dome B, note pen for scale (B) A disaggregated margin from Dome D, note 12 inch ruler for scale (C) A crenulated margin from Dome C, also note the inherited plagioclase host dacite in the enclave. Size of enclave is 15cm (D) Crenulated margins between the two different textural types of enclaves. Size of enclave is 30cm. (E) Disaggregated enclaves in Dome B, note field notebook for scale. 20 Disequilibrium textures are present in both host and enclaves. Common disequilibrium textures include sieved crystals, embayments, compositional zoning, and resorption rims (Figure 11). The phenocryst phases present in the host and enclaves are plagioclase, amphibole, orthopyroxene, clinopyroxene, biotite, quartz, olivine and iron oxides. Plagioclase is the most common phenocrysts, present as large crystals up to 7mm. The crystals are typically euhedral to subhedral and can vary in habit from prismatic to acicular. The larger crystals plagioclase crystals in the enclaves are incorporated host dacite crystals that exhibit unreacted or reacted textures. Sieve textures and zoning in both host and enclaves are quite common. Sieve textures can vary from just a few microns from the rim to the entire crystal. Amphiboles usually are 1mm in size but can be larger and vary from anhedral to euhedral. The crystals exhibit good cleavage planes. The majority of the amphibole phenocrysts exhibit opaque reaction rims of, most likely, magnetite. Orthopyroxene is rare, but can be found in glomerocrysts. When present, it ranges from 0.1mm to 0.5mm in size and is anhedral to subhedral. Clinopyroxenes range from 0.1mm to 1mm in size and exhibit a crystal shape from anhedral to euhedral. Occasionally, clinopyroxene can be found intergrown with amphibole. Biotite crystals range in size from 0.1mm to 1mm, but rarer crystals up to 2mm are present. Good cleavage is present and grains can range from anhedral to euhedral. Quartz is not that common, but when present can range in size from 1mm to 5mm. The crystals are usually embayed and anhedral to subhedral. Olivine is also rare, but ranges from 0.1mm to 1.0mm, with an occasional larger crystal 21 up to 4mm in the type 4 enclave. The crystals are anhedral in enclaves but can be euhedral in the host. Oxides range in size from 0.1mm to 0.5mm. 22 A B C D E F G H 23 Figure 11. Disequilibrium textures present in the host and enclaves. All pictures were taken under crossed polars at 4x magnitude. (A) Sieve textured plagioclase with new growth rim from Dome A #85-715. (B) Eroded plagioclase phenocrysts from Dome B #85-717. (C) An outer rim sieve texture plagioclase from Dome C #84-434. (D) Biotite with an opaque reaction rim in Dome D #84-435. (E) A composition zoned plagioclase at Dome F #84-455. (F) A small glomerporphyric clast in Dome D #84-435 (G) Compositionally normal zoned host plagioclase crystals and hornblende crystals from Dome F #84-455 (H) A compositionally zoned, sieve textured new growth rim plagioclase in Dome F #93-1963A. 3.2 Enclave abundance in the Chaos Crags From the initial eruption of Dome A through to final eruption of Dome F, enclave abundance increases from 2.3-13.9 vol.% (Table 1 and Figure 12). This observation is consistent with the conclusions of Stout (2007) that the abundance of enclaves increased throughout the eruption of Chaos Crags. The increase in total abundance is not monotonic. There is a clear jump from Dome B to Dome C (3.9% - 9.0%). A second significant jump occurs between the eruption of Dome C and Dome D (9.0% - 12%). More modest jumps appear to occur between eruptions of Dome A and B (2.3% - 3.9%) and between the eruption of Dome E and Dome F (11.8% - 13.9%). 24 Table .1 Total Enclave Abundance for each dome at Chaos Crags. Total Enclave Abundance (Vol%) N = number of point counts A 2.3% 4 B 3.9% 125 C 9.0% 26 D 12.0% 17 E 11.8% 28 F 13.9% 28 Dome Total enclaves (Volume %) 16 13.90 14 11.99 11.79 Dome D Dome E 12 8.98 10 8 6 4 3.93 2.29 2 0 Dome A Dome B Dome C Dome F Figure 12. Abundance of enclaves by dome. Jumps in abundance are indicated by solid lines (significant jumps) and dashed lines (modest jumps). 25 Figure 13 shows the volume abundance of each enclave type for each dome. Only enclave types 2 and 3 were observed in Dome A. However, it should be noted that one sample provided by Dr. Michael Clynne was identified as a type 1 enclave and another identified as a type 4, so these enclaves are likely present but in very small amounts. The modest jump in total enclave abundance in Dome B is accompanied by the appearance of enclave types 1, 4, and 5 and an increase in the abundance of type 2 enclaves relative to type 3. The large jump in total enclave abundance between eruption of Domes B and C is marked by an increase in the volume of enclave types 1 and 3 relative to type 2. Type 4 disappears and type 5 remains present in small amounts. The volume of enclave types 2 and 3 increases with the eruption of Dome D with type 2 becoming the most abundant enclave type. Type 1 enclaves decrease in abundance. Type 4 remains absent and the abundance of type 5 increases significantly although this enclave type is still relatively rare. The relative abundance of enclave types is somewhat similar in Dome E, with type 2 remaining the dominant enclave type. The eruption of Dome F is marked by a clear change in the character of the enclaves with type 1 becoming the most abundant type. 26 10 10 Dome A 8 Dome B 8 6 6 4 2 0.00 0.76 4 1.52 0.00 0.00 1.21 2 1.59 0.89 0 Type 1 Type 2 Type 3 Type 4 Type 1 10 10 Dome C 8 2.35 Type 2 Type 3 Type 4 Type 5 Dome D 5.62 6 3.71 0.13 8 6 4 0.10 Type 5 0 3.42 4 2.86 2.18 2 2 0.00 0.06 Type 4 Type 5 0 0.00 0.77 0 Type 1 Type 2 10 Type 3 10 Dome E 8 2 Type 2 8.41 6 3.50 Type 3 Type 4 Type 5 0.10 0.18 Dome F 8 6.54 6 4 Type 1 4.15 4 1.49 0.05 0.21 1.05 2 0 0 Type 1 Type 2 Type 3 Type 4 Type 5 Type 1 Type 2 Figure 13: Abundance of different enclave types in each dome. Type 3 Type 4 Type 5 27 3.3 Crystal Size Distribution Overall, 52 hand tracings of thin sections were completed and processed using ImageJ and CSDCorrections 1.39. The CSD output for each thin section is provided in Appendix E. It should be noted that not every enclave type represented in each dome was analyzed for this study. Type 4 and 5 enclaves were hard to collect in the field since they were rarer and usually contained within large boulders. The goal of this study was to assess the relative abundance of different enclave types in each dome and to use CSD on a small set of samples representing each enclave type to determine whether significant differences exist between them that could be connected to magmatic processes. A complete set of enclaves for each dome was collected and will be analyzed as part of a future study by Dr. Hammersley and Dr. Clynne. Figure 14 shows CSD curves for the host dacite of each dome. These are relatively consistent showing little variation between the domes. All curves are concave upwards indicating at least two plagioclase populations (Martin et al., 2006). Figure 15 shows CSD curves for the different enclave types. The domes from which each sample was collected are indicated by the color of the line. For most enclave types, the curves are consistent regardless of which dome the enclave was collected from. Types 1 and 2 show very similar distributions with steep curves indicating large populations of small crystals and fewer large crystals. The curves for type 3 show some variability with two types of curve, one steep like that for types 1 and 2, and one more gentle curve, with a much lower abundance of small crystals. The CSD analysis for the steeper curves was done on higher magnification images, which may have affected the 28 count as fewer crystals were visible. Type 4 enclaves show CSD curves very similar to those for types 1 and 2 but with fewer small crystals overall. The type 4 images analyzed also lack the larger crystals common in types 1 and 2. CSD curves for type 5 enclaves have a lower abundance of smaller crystals and a more noticeably concave upward shape. 29 5 0 0 -10 2 4 6 10 10 5 0 -5 -10 2 4 6 8 10 0 2 4 6 8 10 Dome D 10 5 0 -5 0 2 4 6 8 10 Corrected Crystal Size (mm) 15 10 5 0 0 2 4 6 8 Corrected Crystal Size (mm) 10 ln (population size) ln (population size) -5 -10 Corrected Crystal Size (mm) Dome E -10 0 15 15 -5 5 Corrected Crystal Size (mm) Dome C 0 Dome B 10 -10 Corrected Crystal Size (mm) 15 ln (population size) 8 ln (population size) 10 -5 15 Dome A ln (population size) ln (population size) 15 Dome F 10 5 0 -5 0 -10 Figure 14 . CSD curves for the host dacite of each dome. 5 Corrected Crystal Size (mm) 10 30 Type 1 10 6 2 -6 1 2 3 ln (population size) 4 Corrected Crystal Size (mm) 18 10 6 2 -2 0 1 2 3 4 10 6 2 -2 0 -6 1 2 3 4 Corrected Crystal Size (mm4 Type 4 14 10 6 2 -2 0 -6 Corrected Crystal Size (mm) 18 14 18 Type 3 14 -6 ln (population density) ln (population size) 14 -2 0 Type 2 18 ln (population density) ln (population density) 18 1 2 3 4 Corrected Crystal Size (mm) Type 5 14 10 6 2 -2 0 -6 1 2 3 4 Corrected Crystal Size (mm) Figure 15. CSD curves for each enclave type. The color of the curves indicates the dome from which each enclave was collected: Blue(small stipples) = Dome A; green(thicker solid lines) = Dome B; red(solid lines) = Dome C; purple(dotted lines) = Dome D; orange(large stipples)= Dome E; teal(thinner solid lines)= Dome F. 31 Figure 16 shows CSD curves each dome. The enclave type is indicated by the color of the line. While not every enclave present in each dome is represented by this data set, it is still worthwhile noting some of the differences apparent between the domes. The type 1 and 4 enclaves analyzed for domes A and B show very similar curves, relatively steep and lacking a pronounced curvature. The curves for dome C show a greater population of small crystals and the curve is clearly concave upward, indicative of mixing. It is interesting to note that the type 3 enclaves analyzed for dome C are the ones with large populations of small crystals and fit well with other enclave types measured in that dome. The curves for dome D only represent type 3 enclaves and show the gentler slope with fewer small crystals. Only type 2 enclaves are analyzed for domes E and F and they show similar slopes but it appears that the enclaves in dome F have more small crystals. The CSD data shows that some enclave types have very similar crystal populations even if the larger scale texture of the enclaves may be quite different. Types 1 and 2 are almost identical and strongly similar to type 4. Type 3 enclaves, while showing some variability, appear to be distinct from types 1, 2 and 4. Type 5 also appears to be distinct from the other enclave types. The comparison between domes suggests that there may be some relationship between the texture of the enclave and which dome it in found in. With the somewhat limited data set presented here, it is very difficult to ascertain whether the differences between domes are dominant or between enclave types. Further analysis of the complete set of samples will help clarify this issue. 32 Dome A 14 10 6 2 -2 0 -6 ln (population size) ln (population size) 18 22 18 14 10 6 2 -2 0 -6 2 Dome C 2 3 Corrected Crystal Size (mm) 10 6 2 14 10 6 2 1 2 3 Corrected Crystal Size (mm) 4 1 2 3 4 Corrected Crystal Size (mm) Dome D 22 18 14 10 6 2 -2 -6 0 1 2 3 4 Corrected Crystal Size (mm) 22 ln (population size) 18 -2 0 -6 14 Dome E 22 ln (popluation size) 4 18 -2 0 -6 4 Corrected Crystal Size (mm) 1 Dome B 22 ln (population size) ln (population size) 22 Dome F 18 14 10 6 2 -2 -6 0 1 2 3 Corrected Crystal Size (mm) Figure 16. CSD curves for enclave types for each dome. Type 1 is represented by blue(thinner lines). Type 2 = green(dotted lines). Type 3 = red(solid lines). Type 4 = purple(stippled lines). Type 5 = orange(thicker lines). 4 33 3.4 Geochemistry Bulk-rock major element data for samples of host dacite and enclaves were provided by Dr. Michael Clynne. Analyses were completed at the USGS Analytical Laboratory in Lakewood, Colorado. Major element concentrations were determined by wavelength-dispersive X-ray fluorescence analysis following the methods of Taggart et al. (1987). Major element composition data for host and enclaves are presented in Table 2 and figures 17 and 18. Figure 17 shows a graph of CaO versus SiO2 wt % for the host and different enclave types that were analyzed by CSD as part of this study. Graphs of K2O, Na2O, FeOt, Al2O3, and MgO against SiO2 wt. % are shown in Figure 18. The host dacite does not show much chemical variation, ranging from approximately 66-69 wt. % SiO2. This is consistent with the CSD analysis of host dacites that showed very little variation between domes. The enclaves show a wide range in composition from 53 wt.% SiO2 in the most mafic samples to 61 wt. % SiO2 in the more felsic samples. The samples form an approximately straight line between the most mafic samples and the host dacites, indicative of mixing. An interesting and somewhat unexpected feature of the geochemical data is that the different enclave types group together chemically. Type 1 enclaves show the greatest degree of mixing, plotting close to the host dacite. Types 3 and 4 are the most mafic samples, representing the least degree of mixing. Type 2 enclaves are chemically intermediate between types 1 and 3. No geochemical data was available for type 5 enclaves analyzed for CSD as part of this study. There are two samples that do not cluster with other samples of the same enclave type: Sample #88-1283 was classified 34 texturally as a type 1 enclave but geochemically it is similar to type 2 enclaves. Texturally, sample #84-632 has the appearance of a type 3 enclave but is geochemically similar to type 4 enclaves. 35 Table 2. Major Element Composition of Host and Enclave Rocks. These samples were provided by Dr. Michael Clynne. Samples analyzed for CSD as part of this study are highlighted in blue. Sample types are marked H for host and by type for enclaves. Sample # Type SiO2 Al2O3 FeOt MgO CaO Na2O K2O TiO2 P2O5 MnO 84-428 H 69.62 15.53 2.65 1.29 3.38 4.33 2.62 0.35 0.13 0.06 85-715 4 53.61 18.91 7.67 5.08 10.16 2.71 0.77 0.69 0.08 0.14 3 fine 56.05 17.35 6.95 4.62 7.78 3.68 1.45 1.46 0.37 0.12 LT96-3I 2 55.02 18.58 7.02 4.94 9.35 2.83 1.17 0.66 0.15 0.13 LT96-17I 2 55.97 18.93 6.72 4.3 8.63 3.1 1.26 0.67 0.14 0.12 LT96-18I 2 57.55 18.39 6.6 3.77 7.97 3.22 1.44 0.67 0.16 0.13 LT96-26I 2 57.16 18.34 6.49 4.11 8.27 3.16 1.39 0.66 0.14 0.12 LT96-27I 2 57.25 18.34 6.56 4.08 8.3 3.22 1.14 0.67 0.16 0.13 LT96-28I 2 56.45 18.75 6.73 4.01 8.58 3.27 1.11 0.66 0.15 0.13 LT96-29I 2 56.82 18.26 6.6 4.44 8.5 3.1 1.18 0.66 0.15 0.12 LT96-30I 2 56.34 18.58 6.72 4.43 8.56 3.2 1.08 0.66 0.15 0.13 84-443 H 69.81 15.60 2.54 1.20 3.31 4.30 2.64 0.35 0.12 0.06 88-1283 1 55.61 18.57 7.76 3.96 8.56 3.35 0.97 0.79 0.12 0.13 85-717 4 53.54 18.91 7.62 5.15 10.31 2.74 0.65 0.70 0.07 0.14 LC88-1281 2 53.65 19.57 7.36 4.67 9.98 2.84 0.87 0.67 0.10 0.13 LC88-1282 2 53.83 19.59 6.76 5.05 10.00 3.03 0.71 0.63 0.12 0.13 LC93-1961 1&2 54.08 18.81 7.64 4.83 9.51 2.88 1.10 0.73 0.11 0.14 LC93-1962 3 fine 55.63 18.61 6.87 4.70 9.04 2.95 1.14 0.66 0.11 0.13 LT96-33I 2 55.60 18.80 6.95 4.47 8.85 3.19 1.02 0.68 0.15 0.13 LT96-34I 2 57.05 18.31 6.53 4.21 8.35 3.18 1.30 0.66 0.15 0.12 LT96-4I 2 57.34 18.37 6.41 4.11 8.18 3.31 1.21 0.65 0.16 0.12 LT96-5I 2 57.25 18.41 6.46 4.14 8.13 3.33 1.22 0.65 0.15 0.12 LT96-6I 2 56.46 18.21 6.79 4.64 8.61 3.16 1.03 0.66 0.15 0.13 LT96-7I 2 56.00 18.60 6.82 4.49 8.80 3.14 1.04 0.68 0.14 0.13 Dome A LC89-1512 Dome B 36 Sample # Type SiO2 Al2O3 FeOt MgO CaO Na2O K2O TiO2 P2O5 MnO 84-434 H 68.88 15.76 2.77 1.46 3.71 4.30 2.50 0.38 0.11 0.06 00-2352 H 68.35 15.81 3.19 1.74 3.91 3.75 2.51 0.43 0.16 0.07 84-634 1 61.39 17.77 5.22 1.91 4.50 4.93 2.66 0.91 0.47 0.12 3 fine 55.64 18.35 7.13 4.40 9.01 3.06 1.37 0.66 0.09 0.13 LT96-12I 2 57.37 18.35 6.46 4.06 8.31 3.23 1.11 0.68 0.16 0.13 LT96-20I 2 56.28 18.76 6.69 4.18 8.76 3.21 1.04 0.67 0.14 0.13 87-1235A 1 59.81 17.59 5.88 2.56 5.51 4.7 2.17 0.99 0.53 0.12 87-1235B 2 56.74 18.21 6.94 4.19 8.56 3.19 1.1 0.68 0.11 0.12 87-1235C 3&5 55.11 18.81 6.16 4.75 10.11 2.93 1.01 0.63 0.24 0.11 84-435 H 67.78 15.81 3.34 1.77 4.08 4.01 2.52 0.42 0.12 0.07 84-632 3 fine btw 1&2 53.26 19.35 7.48 4.96 10.27 2.77 0.81 0.71 0.09 0.14 59.56 17.62 5.16 3.77 7.14 4.31 1.38 0.63 0.13 0.17 2 btw 1&2 56.25 18.21 6.50 4.52 8.80 3.15 1.33 0.76 0.19 0.13 59.28 17.20 5.56 3.73 6.86 4.11 1.83 0.82 0.37 0.12 H 69.73 15.34 2.70 1.36 3.12 4.21 2.84 0.41 0.16 0.07 84-433 H 66.97 16.26 3.40 1.81 4.48 4.15 2.25 0.41 0.12 0.07 84-635 2 57.91 18.17 6.41 3.91 8.04 3.27 1.26 0.63 0.11 0.13 2&3 btw 2&3 57.10 18.43 6.93 3.78 8.15 3.37 1.08 0.74 0.13 0.13 54.46 19.20 7.24 4.60 9.40 2.95 0.99 0.72 0.15 0.14 55.77 18.83 6.87 4.34 8.93 3.11 1.03 0.68 0.16 0.13 LT97-23I 2 btw 1&2 58.78 17.98 6.14 3.69 7.64 3.35 1.35 0.65 0.16 0.12 LT96-24I 2 57.63 18.54 6.26 3.84 8.03 3.35 1.31 0.63 0.15 0.12 84-455 H 68.17 16.10 2.98 1.50 4.16 4.23 2.25 0.36 0.11 0.06 93-1963A 2 56.12 18.81 6.86 4.23 8.71 3.11 1.08 0.68 0.12 0.13 LT96-13I 2 57.69 18.59 6.34 3.71 7.88 3.48 1.21 0.67 0.16 0.13 LT96-14I 57.64 17.77 6.61 4.09 7.76 3.44 1.39 0.74 0.27 0.14 LT96-25I 2 btw 2&3 54.64 19.12 7.22 4.59 9.26 3.12 0.89 0.71 0.15 0.14 LT96-31I 2 56.92 18.80 6.49 3.91 8.29 3.35 1.16 0.66 0.15 0.13 LT96-32I 2 56.35 18.65 6.75 4.22 8.60 3.25 1.08 0.68 0.15 0.13 Dome C LC81-661A Dome D LC86-961 LT96-8I LT96-9I LC01-2363 Dome E LC84-637 LT96-11I LT96-22I Dome F 37 CaO vs SiO2 12 Type 4 Type 3 10 Type 2 CaO 8 6 Host Type 1 4 2 0 50 55 60 65 70 75 SiO2 Figure 17. CaO vs. SiO2 host dacite and enclave samples analyzes as part of this study for CSD. Host samples are represented by black diamonds. Enclave samples are represented by squares. Enclave type is represented by the color of the squares: Type 1 enclaves are blue. Type 2 = green. Type 3 = red. Type 4 = purple. Type 5 samples are not represented here as geochemical data was not available for samples analyzed by CSD. 38 25 15 FeOt Al2O3 20 10 5 0 50 60 70 9 8 7 6 5 4 3 2 1 0 80 50 60 80 70 80 SiO2 SiO2 3.0 6 2.5 5 2.0 4 MgO K2O 70 1.5 3 1.0 2 0.5 1 0 0.0 50 60 SiO2 70 80 50 60 SiO2 6 5 Na2O 4 3 2 1 0 50 60 70 80 SiO2 Figure 18. A comparison of major element compositions at Chaos Crags of host dacite (diamonds) and mafic enclaves (squares). Enclave types are color coded: Type 1 = blue; Type 2 = green; Type 3 = red; Type 4 = purple; Type 5 = orange. 39 After observing the relationship between enclave type and geochemistry, a visit was made to Menlo Park to examine Dr. Clynne’s collection of samples. Hand samples of each of the enclaves for which geochemical data was available were examined and classified into enclave type. Most of the samples were type 2, which might be due to sampling bias (pers. comm. Clynne). Figure 19 shows a plot of CaO vs. SiO2 for all samples examined. Those samples shown in figure 17 are shown with saturated colors. Samples classified as Menlo Park are shown with paler colors. 12 10 Described as transitional between type 2 and 3 8 CaO (wt%) Described as transitional between 6 4 2 Host Type 4 Type 3 this study Type 1 Type 5 Type 4 this study Type 2 Type 1 this study Type 3 Type 2 this study 0 50 55 60 SiO2 (wt%) 65 70 Figure 19. CaO vs. SiO2 for all samples analyzed by Dr. Michael Clynne. Samples analyzed for CSD for this study are highlighted. The host dacite are represented by diamonds and the mafic enclaves by squares. 75 40 It can clearly be seen from figure 19 that the relationship between enclave type and geochemistry is more complex than indicated in figures 17 and 18. Type 2 enclaves exhibit a wide range in composition. One group of type 2 samples that plot between type 1 and the main group of type 2 were identified as having textures transitional between type 1 and type 2. Another group of type 2 samples was described as having textures transitional between type 2 and type 3. These plot as a cluster at the more mafic end of the type 2 trend. A small cluster of type 3 enclaves plot within the main type 2 cluster. These were described in hand samples as “type 3 fine” because although they contained the acicular hornblende diagnostic of type 3 enclaves, the crystals were fine grained. Type 2 and 3 enclaves both contain hornblende, the main difference being the habit of the hornblende crystals, with type 3 being distinctly acicular. A small cluster of type 2 enclaves plot with the type 3 enclaves at the more mafic end of the spectrum. It is interesting to note that CSD analysis of type 3 enclaves produced two trends. One very similar to type 2, with a steep curve and a large population of small crystals, another with a much gentler curve. 41 Chapter 4 DISCUSSION 4.1 Magma Mixing Models Magma chambers are not closed systems, but are dynamic open systems that evolve from more mafic to more silicic compositions through some combination of processes such as fractional crystallization, crustal assimilation, and magma mixing (Sparks et al., 1984; Marsh 1998). Magma mixing is the direct interaction between two compositionally and thermally distinct magmas. Classic studies suggest that mixing will initiate with an injection of hotter less dense mafic magma into a silicic magma chamber (Eichelberger, 1980; Huppert et al., 1982; Kouchi and Sunagawa, 1983, 1985; Campbell and Turner, 1986). If direct mixing and hybridization does not occur, the mafic magma cools to the temperature of the silicic magma and a less dense mafic foam interface layer will form from extruded water vapor. If the interface becomes unstable, the mafic foam will vesiculate enclaves into the silicic magma and convection will then cause dispersal of mafic enclaves in the silicic magma (Eichelberger, 1980; Huppert et al., 1982; Figure 20). Campbell and Turner (1985) have shown that, even with a forced injection of the magma, if the magmas are close in density, mixing is little or non-existent. Another factor that can affect mixing is the size of the interface layer (Huppert et al., 1982) and if the enclaves form pre or post dispersal (Coombs et al., 2002). If the layer is only a few 42 centimeters thick, large scale mixing will not occur, but will occur when phenocrysts, vesicles and exsolution of the water vapor decrease the density of the mafic magma. Figure 20. Vesiculation model of the mafic foam layer. From Eichelberger, 1980. An intermediate magma may form over a relatively short period of time in the magma chamber. Kouchi and Sunagawa (1983, 1985) performed laboratory experiments, mixing a basaltic and dacitic magma with forced convection and in less than 2 hours, a homogeneous layer of andesite formed in the basalt, along with banded layers in the dacite. 4.2 The Lassen Peak Magma Mixing Model A classic study of magma mixing worth discussing in detail due to its proximity to Chaos Crags is the 1915 Lassen Peak eruption and initiation of mixing in the volcanic vent. Lassen Peak exhibits some of the same enclaves and disequilibrium texture as Chaos Crags. It should be noted however, that there are distinct differences, such as the 43 presence of hybridized magma at Lassen Peak. Clynne (1999) proposed that an injection of basaltic andesite magma into the dacite magma chamber as a turbulent fountain formed an andesite foam layer (Figure 21a). By rapidly cooling, the foam layer became unstable and formed enclaves. The less dense enclaves floated into the dacite magma and were distributed by convection currents in the dacite (Figure 21b). Andesite enclaves then disaggregated and mixed in the main part of the dacite chamber to form a black dacite layer. With continued mixing, this layer left the interface to rise through the magma chamber to fracture the wallrock (Figure 21c). Fracturing of the conduit and later eruption suggest that mixing processes can trigger an eruption (Sparks et al., 1977; Kouchi and Sunagawa, 1985). The eruption ceased with banded pumice and light dacite, (Figure 21d). 44 Figure 21. Magma mixing and enclave formation model for Lassen Peak. (a) Basaltic andesite magma intruded into the base of a dacite chamber. A mafic foam interface layer forms, vesiculates and produces enclaves (b) Enclaves disaggregate, mix, and form a black dacite layer (c) Black dacite is less dense and rich in volatiles rising up in the magma chamber, fracturing a conduit, triggering an eruption (d) Mixing continues and the eruption ceases with a banded pumice and light dacite. From Clynne (1999). 45 4.3 Mixing studies at Chaos Crags Tepley et al. (1999) developed a magma mixing model for Chaos Crags based on enclave textures (Figure 22). They conclude that large scale mixing did not occur at Chaos Crags since rocks of intermediate composition are not present, as they are at Lassen Peak. They propose that a dacite magma chamber was injected by a basaltic magma that ponded at the base of the dacite. A small portion of dacite and basalt mixed homogeneously at the mafic interface since some of the host phenocrysts are found in the enclaves. Enclaves range in size and texture and some have disaggregated. However, this suggestion does not explain all of the chemical and mineralogical changes seen in Chaos Crags. 46 Figure 22. Enclave formation model proposed for Chaos Crags by Tepley et al., (1999) (a) Rhyodacite magma chamber is injected with basalt (b) Mixing occurs between the two magmas (c) Formation of a hybrid layer and enclaves (d) All different types of enclaves are now present in host rhyodacite (e) Enclaves disaggregate and disperse resorbed crystals back into host magma. 47 4.4 Observations from Chaos Crags In order to interpret the magma mixing processes and sequence of events at Chaos Crags, there are a number of observations from this study that must be explained: 1. The total abundance of enclaves increases as the eruption progressed. 2. There are distinct increases in the total abundance of enclaves between eruption of domes B and C, domes C and D. 3. There are more modest increases in the total abundance of enclaves between eruption of domes A and B, domes E and F. 4. Although it seems likely that all enclave types are present in each dome, changes in distribution of enclave type seem to correlate with the increases in total abundance. 5. Host dacites show a narrow range in composition while enclaves show a mixing trend from a more mafic source toward the host dacite. 6. There is a clear link between enclave type and geochemistry. The most mixed enclave types are type 1. The least mixed are types 3 and 4. Geochemically, the enclaves form a clear mixing trend between a mafic endmember (53 wt% SiO2) and the dacite host (66-69 wt% SiO2). This suggests that the mafic input had a relatively consistent composition most closely represented by type 3 and 4 enclaves. Type 3 enclaves are distinguished by the presence of acicular hornblende phenocrysts. Feeley et al. (2008) note that acicular crystals can form in injected mafic 48 magma that ponds at the base of the magma chamber. Type 4 enclaves contain olivine, which is also indicative of ponding of the mafic magma and restricted mixing with the dacitic host. Type 1 enclaves show the most mixed composition. They are fine-grained in texture with no prominent phenocrysts except for reacted host crystals. Vesicles are common in type 1 enclaves. It seems likely that type 1 enclaves formed during forceful injection of mafic magma into the magma chamber. Fountaining formed numerous small enclaves that cooled rapidly. The relatively large surface area of numerous small enclaves allowed for extensive mixing with the dacite host. The presence of large plagioclase crystals from the host indicate incorporation of the dacitic magma into the enclaves as they rose through the magma chamber. Geochemically, type 2 enclaves form a broad trend between the highly mixed type 1 and less mixed type 3 enclaves. Coarser-grained textures suggest a longer mixing time than type 1 enclaves, perhaps in a boundary layer between the mafic magma and the dacite, as suggested by Tepley et al. (1999). Little geochemical data exists for type 5 enclaves. Texturally, they are coarse grained suggesting they cooled more slowly allowing larger blocky phenocrysts of amphibole and plagioclase to form. The increase in the total abundance of enclaves over the eruptive sequence of Chaos Crags suggests continued injection of mafic magma into the dacitic magma chamber. The large increases in total enclave abundance between eruption of Domes B and C, C and D, and E and F are accompanied by distinct changes in the population of enclave types. A more modest increase in enclave abundance between eruption of Domes A and B is also accompanied by a change in enclave type distribution. 49 The relatively modest increase in enclave abundance between eruption of Domes A and B is accompanied by a marked increase in the abundance of type 1 and 2 enclaves, which are geochemically the most mixed. The large increase in total abundance of enclaves between eruption of domes B and C is marked by an increase in the abundance of type 1 enclaves. Types 2 and 3, which form a continuous trend from relatively primitive compositions to more mixed compositions also increase, in particular type 3. CSD curves for Dome C show a large population of small crystals and a markedly concave upward form that is indicative of extensive mixing. The large increase in total abundance of enclaves with eruption of Dome D is marked by a large increase in the amount of type 2 enclaves and a decrease in the amount of type 1 enclaves. Dome E is very similar to Dome D. CSD curves for Dome D have a more gentle slope with fewer small crystals. Eruption of dome F is marked by a modest increase in the total abundance of enclaves. The distribution of enclave types changes markedly, being dominated by type 1. Type 2 enclaves decrease in abundance. The CSD curves for dome F are steeper than those for dome E, with more small crystals. From these observations it seems likely that there were numerous injections of mafic magma into the dacite magma chamber beneath Chaos Crags during the eruption sequence of Domes A-F. An initial injection occurred prior to the eruption of Dome A. The dominance of type 2 and 3 enclaves suggests the mafic magma ponded at the base of the magma chamber, forming a mixing boundary layer. The increase of type 1 enclaves and increase of types 2 and 3 in Dome B suggests an overturning of the magma chamber, dispersing enclaves throughout the dacite. This may have been caused by forceful 50 injection and fountaining or simple overturn of the ponded mafic magma caused by vesiculation. There was a hiatus between the eruption of Domes B and C (Clynne and Muffler, 1989). During this hiatus, another forceful injection of mafic magma intruded the silicic magma chamber, marked by another significant increase in type 1 enclaves. The increased abundance of types 2 and 3, which are more mafic in composition, suggest the mafic magma ponded at the base of the chamber. The CSD curves for Dome C show a distinctive kink suggestive of a new mixing event. Another injection of mafic magma may have occurred prior to eruption of Domes D and E. This is indicated by the large increase in total abundance of enclaves. Type 2 enclaves become the most dominant. It is possible that eruption of Domes D and E were caused by overturn of the mafic layer formed after the eruption of Dome C rather than a separate mixing event (Huppert at el., 1982, Feeley et al., 2008). Another final injection of mafic magma occurred prior to eruption of Dome F. The dominance of type 1 enclaves suggests that this injection was a forceful injection, forming a fountain of mafic enclaves within the magma chamber. 4.5. Chaos Crags Magma Mixing Model Figure 23 shows a model of the mixing processes and sequence of events that formed the Chaos Crags. Type 1 and 2 enclaves are the most abundant enclaves and have direct correlation with a forceful injection of magma. When the magma is injected forcefully into the silicic chamber, it forms a fountain. Type 1 enclaves form first and cool quickly as 51 indicated by their fine-grained appearance. Type 2 enclaves form when the dense mafic magma falls back to the bottom of the magma chamber and forms a mafic interface between the magmas. Enclaves vesiculate and form pre-dispersal (Campbell and Turner, 1986; Coombs et al., 2002). Type 3, 4 and 5 enclaves form below the mafic interface at a slower rate as indicated by their more mafic composition and coarser grain size. The sieved textures in host phenocrysts were caused by the baking and recooling due to recharge events. New growth rims formed most likely due to volatile loss in the conduit during eruption phase (Rutherford and Hill, 1993). There was an initial dacitic magma chamber (Figure 23 A). The chamber then received a small forceful injection that caused the pyroclastic flows. More mafic magma injected and ponded at the base of the chamber and caused eruption of Dome A, the smallest of the domes to erupt with the smallest population of enclaves (Figure 23 C). Mixing occurred within a mafic foam interface (Eichelberger, 1980) as evidenced by the dominance of enclave types 2 and 3. The significant increase of type 1 enclaves in Dome B suggests that eruption of Dome B may have been triggered by a second, more forceful injection of mafic magma (Figure 23 D). Although the total population of enclaves in Dome B is relatively small, this injection of magma may have been one of the largest. Martin et al. (2006) state that the volume of erupted material is directly proportional to the amount of magma injected. Dome B is the largest of the domes at Chaos Crags. Another injection of mafic magma caused the increased volume of enclaves seen from Dome B to Dome C. The dominance of type 2 enclaves in Domes C, D and E suggest most mixing occurred across a boundary between ponded mafic magma and the 52 host dacite, perhaps formed after eruption of Dome B. The new influx of magma raises the pressure in the magma chamber causing the wall rock to fracture and eruption of Dome C (Figure 23 E). More mixing and disaggregation occurred in the conduit during eruption. Mixing was still continuing while the chamber was cooling and when the mixing boundary reached a certain vesiculation level, the layer overturned and Dome D erupted (Figure 23 F). Once again mixing and disaggregation occurred in the conduit during the eruption from the formation of enclave margins. This process was repeated, culminating with the eruption of Dome E (Figure 23 G). Dome F erupted from a final injection of mafic magma, once again increasing the volume of enclaves (Figure 23 H). Type 1 enclaves recur as the most abundant enclave suggesting forceful injection and fountaining. Once again more mixing and disaggregation occur in the conduit during eruption. 53 54 55 Figure 23. Magma mixing model for Chaos Crags. A) The initial dacitic magma chamber. Plagioclase is represented as white rectangles and hornblende is black rectangles. B) A forceful injection of mafic magma in the dacitic magma chamber causing enclaves to form. Type 1 are represented as blue. Type 2 = green. Type 3 = red. Type 4 = purple. Type 5 = orange. C) The injection of more mafic magma caused the eruption of Dome A and presence of enclaves type 14. D) Another forceful injection of magma caused the eruption of Dome B due to the increase of type 1 enclaves. E) More mafic magma injected and caused the eruption of Dome C and an overall increase of enclaves. F) Another small amount of mafic magma ponded to cause the eruption of Dome D and another increase of overall enclave abundance. G) The overall abundance slightly decreased, so the mafic interface vesiculated and caused the eruption of Dome E. H) The eruption of Dome F was caused by another forceful injection of mafic magma and overall enclave abundance increase again. 56 Chapter 5 CONCLUSION This study presents field observations, textural and geochemical data that the Chaos Crags formed through multiple mixing events in a single shallow silicic magma chamber. The magma chamber experienced a series of influxes of mafic magma that either injected as a turbulent fountain or ponded at the base of the silicic chamber. These injections caused the sequential eruption of the domes. Depending on the injection type of fountaining or ponding of mafic magma at the base of the chamber, different types of enclave form. Aphantic enclaves (type 1) form from the forceful injection of mafic magma and are found near the top of the magma chamber. All other enclave types form as a result of ponding of mafic magma. Salt and pepper appearance enclaves (type 2) form within a hybrid interface layer between the two magmas, prior to dispersal. Enclaves that contain olivine and acicular crystals (types 3, 4 and 5) form below the mafic-felsic interface. CSD analysis of enclaves shows that to a limited extent, it is possible to distinguish between enclave type by looking at the crystal population. From the limited data available from this preliminary study of the CSD of Chaos Crags enclaves, there appears to be some relationship between the shape of the CSD curves and the domes from which the enclaves were erupted. The clear relationship between enclave texture and geochemistry was a surprising finding of this study and should be explored further. 57 APPENDICES 58 APPENDIX A Point Count Locations Point Count Locations of Enclaves at Chaos Crags, Lassen Volcanic National Park Location 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 Dome F F F F F F C/D C/D C C/D C/D D D D D D B/D B B B B B B B B B B B B B B 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T Northing Easting 626361 4487829 626362 626325 626413 626506 624323 624325 624453 624392 624347 624336 62432 624327 624318 624317 624247 624225 624196 624172 624135 624109 624162 624191 624189 624226 4487668 4487508 4487413 4487463 4487326 4487324 4487410 4487316 4487289 4487252 4487206 4487184 4487166 4487116 4487062 4487011 4486970 4486915 4486840 4486758 4486711 4486665 4486699 4486437 624232 4486398 624273 4486347 59 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 624286 4486288 624323 4486233 624332 4486181 624346 4486134 624347 4486122 624353 4486088 624363 4486044 624381 4485968 624400 4485940 624431 4485844 624481 4485771 624499 4485725 624582 4485687 624650 4485637 624692 4485576 626158 626142 626118 626100 626100 626105 626071 626051 625957 4486735 4486683 4486612 4486508 4486506 4486446 4486286 4486180 4486013 60 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 B A A B B B B B B C E E E E E E E/F E E E E E E/F E/F B/E/F E/F F F F F F F F C C C C C C 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 10T 625887 625864 625861 625568 625748 626161 626135 626088 626085 624914 625024 625164 625200 625249 625466 625664 625788 625941 626025 625959 625972 625963 626017 626116 626135 626214 626231 626261 626270 626331 626391 626448 626371 623301 623339 623475 624590 624522 624469 4485938 4485678 4485653 4485677 4485678 4486805 4486853 4486880 4486934 4488281 4488233 4488274 4488320 4488472 4488442 4488347 4488320 4488241 4487053 4487067 4487111 4487135 4487151 4487116 4487054 4487079 4487176 4487262 4487325 4487375 4487482 4487604 4487886 4488035 4488877 4488993 4488135 4488053 4487892 61 110 111 112 113 114 115 C C C C 10T 10T 10T 10T 624575 624669 624775 624903 4487914 4487837 4487851 4488105 62 APPENDIX B Hand Sample List Hand samples collected by Dr. Michael Clynne of the USGS and by Crystal Hootman Textural Enclave type Sample # Location Host/Enclave 84-428 A H 84-433 E H 84-434 C H 84-435 D H 84-443 B H 84-455 F H 84-632 D E 3 fine 84-635 E E 2 85-715 A E 4 4 85-717 B E 87-1235 871235A 871235B 871235C 871235D C H C E 1 C E 2 C E 5&3 C E 3 88-1283 B E 1 89-1511 931963A A E 1 F E 2 00-2352 C H 07-01 D E 07-02 D E 07-03 D E 07-04 D E 07-05 D E 07-06 D E 07-07 B E 07-08 B E 07-09 B E 63 07-10 B E 07-11 B E 08-01 C E 2 08-02 C E 1 08-03 C E 2 08-04 C E 2 08-05 C H 4 08-06 C E 3 08-07 C H 08-08 C Banded lava 08-09 C H&E 2 08-10 C H&E 3 08-11 C H 08-13 E E 08-14 E H 08-15 E E 2 08-16 E E 3 08-17 E E 5 09-01 F E 2 09-02 F H 09-03 F E 3 09-04 F E 2 fine 09-05 F E 2&3 09-06 C or D? H 09-07 C or D? E 3 09-08 D E 1 09-09 D E 3 09-10 D E 2 09-11 D E 1 09-12 D E 2 09-13 B E 5 09-14 A E 2 09-15 A E 09-16 A H 09-17 A E 09-18 B H 09-19 B or E? E 09-20 C H 09-21 C E 4 3 2 3 64 APPENDIX C Theory of Crystal Size Distribution The following section is the core of CSD theory. Population density is the overall size and unit volume of crystal numbers. It can be graphed either as a histogram or cumulatively (Figure 1). Population density is given by (Marsh, 1988; p. 278), π(πΏ) = ππ(πΏ) ππΏ (1) where n is the number of crystals, n(L) is the number of crystals per unit length, and (L) is per unit volume of magma. Figure 1. Examples of population density graphs (A) Histogram. (B) Cumulatively. From Marsh (1988). The population balance is determined by the rate of new crystal growth during influx and outflux of the population density, and essentially records the birth and death of crystals. Population balance is given by (Marsh, 1988; p. 279), π(ππ) π(πΊπ£π) + = ππ ππ − ππ ππ ππ‘ ππΏ (2) where Vn is crystal population per volume, Gvn is growth rate for crystal population per volume, Q is flux rate (cm3/s), ππ ππ is inflow and ππ ππ is outflux of crystals. 65 When a batch of magma is injected into a new system, a new residence time is developed and records either a change in volume, recharge rate, or possibly both (Figure 2A). If the new residence time is shorter than the original residence time, old crystals leave the system and the new overall crystal size becomes smaller (Figure 2B). An increase in residence time increases the overall crystal size (Figure 2C). Figure 2. Residence time. (A) Increase or decrease of time against total population. (B) Residence time decreases and forms smaller crystals. (C) Residence time increases and forms larger crystals. From Marsh (1998). If nucleation rate and growth rate are known, the rate of nucleation can be determined. Typical crystal numbers in a sample are given by (Marsh, 1998; p. 555), ππ = 3⁄ 4 π―π πΆπ ( ) πΊ0 (3) 66 where CN is constant, To is the nucleating rate and Go is growing rate. This means if more nucleated crystals are produced, the overall size is going to be limited, whereas, if crystal nucleation is small, the overall crystal size will be larger. It should be noted that nucleation does not have to be constant. Crystal size is determined by (Marsh, 1998; p. 555), πΊ 1⁄ 4 πΏπ = πΆπΏ ( π―π ) 0 (4) where CL is constant. The longer the crystal resides the in the melt, the larger the crystal will grow, but is inversely proportional to nucleation rate. Actual crystal size is dependent on growth rate and crystallization time. Volcanic rocks typically have a nucleation rate of 10-3 and 10-5 cm-3 s-1 to reach 1 mm diameter (Marsh, 1988, 1998). Crystallization time is dependent on nucleation and growth rate. It is determined by (Marsh, 1998, p. 555), π‘π = πΆπ‘ (πΊπ3 π―π )−1⁄4 (5) where Ct is constant. The presence of larger crystals will greatly decrease the time needed to crystallize the melt completely. Nucleation and growth adjust to the thermal regime to complete solidification. The degree of undercooling in magma is most likely a minor role in real magmas, since magmas are rarely superheated and the cooling rate is affected by heterogeneous nucleation (Marsh, 1998). The final CSD graph is a result of 95% crystallization for the system and a decrease is noticeable in smaller crystals as the melt is diminished (Marsh, 1998). 67 APPENDIX D Background to CSDCorrections Program Conversion to 3D is important because crystal habit and roundness are only a measurement of the crystal intersection in the plane and cannot be used to discuss petrological processes (Higgins, 2000). Stereological solutions ease the problems that arise during 2D to 3D conversions, by direct or indirect methods (Higgins, 2000). Indirect methods include parametric solutions by Peterson (1996), to calculate population densities as linear variations from the theoretical studies by Marsh (1988). A problem with this assumption is that natural systems are not always linear and more parameters are needed for any non-isotropic fabric. There are two direct methods: the cut-section effect and Saltikov method. The cut-section effect, in which it is assumed a crystal in 2D will have an intersection that passes through the center of the longest axis. This is problematic since only a sphere has an intersection close to the maximum (Higgins, 2000). Another direct method is the Saltikov method, which uses the intersections of the overall crystal population to indicate true length as a function of intersection lengths. This method only works well for spheres and near equant shapes (Higgins, 2000). Higgins (2000) created the CSDCorrections program by modifying the Saltikov Method to use a more complex algorithm to allow for varying crystal habit. 68 APPENDIX E Individual Crystal Size Distribution Graphs The CSD graphs were completed for each thin section using the ellipse major axis measurement, a massive fabric, and 5 bins per decade. Each thin section has an excluded and included graph. Excluded means if large crystals were not fully contained on the page they were not counted and included means the crystals were counted. It is noted whether the sample number is excluded or included or if it was the first or second spot on the thin section. Dome A #84-428 host 4x excluded Ellipse Major axis 12 11 10 9 ln (population density) 8 7 6 5 4 3 2 1 0 -1 0 1 Size 69 Dome A #84-428 host 4x included Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 1 Size 70 Dome A #84-428 enclave in host 4x excluded Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 71 Dome A #84-428 enclave in host 4x included Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 72 Dome A #84-428 host second spot 4x excluded Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 2 73 Dome A #84-428 host second spot 4x included Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 2 74 Dome A #85-715 enclave 4x excluded Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 0 1 Size 75 Dome A #85-715 enclave 4x included Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 0 1 Size 76 Dome A #85-715 enclave second spot 4x excluded Ellipse Major axis 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 77 Dome A #85-715 enclave second spot 4x included Ellipse Major axis 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 2 Size 3 78 Dome A #85-715 enclave 10x excluded Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 0 0.05 0.1 0.15 0.2 0.25 Size 0.3 0.35 0.4 0.45 0.5 79 Dome A #85-715 enclave 10x included Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 0 0.05 0.1 0.15 0.2 0.25 Size 0.3 0.35 0.4 0.45 0.5 80 Dome A #89-1511 enclave 4x excluded Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 81 Dome A #89-1511 enclave 4x included Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 82 Dome A #89-1511 enclave second spot 4x excluded Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 2 83 Dome A #89-1511 enclave second spot 4x included Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 1 Size 2 84 Dome A #89-1511 enclave 10x excluded Ellipse Major axis 20 19 18 17 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 0.05 0.1 0.15 0.2 0.25 Size 0.3 0.35 0.4 0.45 0.5 85 Dome A #89-1511 enclave 10x included Ellipse Major axis 20 19 18 17 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 0.05 0.1 0.15 0.2 0.25 Size 0.3 0.35 0.4 0.45 0.5 86 Dome B #84-443 host 4x excluded Ellipse Major axis 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 Size 3 87 Dome B #84-443 host 4x included Ellipse Major axis 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 Size 3 88 Dome B #84-443 host second spot 4x excluded Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 89 Dome B #84-443 host second spot 4x included Ellipse Major axis 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 90 Dome B #85-717 enclave 4x excluded Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 91 Dome B #85-717 enclave 4x included Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 92 Dome B #85-717 enclave second spot 4x excluded Ellipse Major axis 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 93 Dome B #85-717 enclave second spot 4x included Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 0.05 0.1 0.15 0.2 0.25 Size 0.3 0.35 0.4 0.45 0.5 94 Dome B #88-1283 enclave 10x excluded Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 95 Dome B #88-1283 enclave 10x included Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 96 Dome B #88-1283 enclave second spot 10x excluded Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 97 Dome B #88-1283 enclave second spot 10x included Ellipse Major axis 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 98 Dome C #84-434 host glomerporphyric 4x excluded Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 -7 -8 -9 0 1 2 3 4 Size 5 6 7 8 99 Dome C #84-434 host glomerporphyric 4x included Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 -7 -8 -9 0 1 2 3 4 Size 5 6 7 8 100 Dome C #84-434 host second spot 4x excluded Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 101 Dome C #84-434 host second spot 4x included Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 102 Dome C #87-1235 host 4x excluded Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 103 Dome C #87-1235 host 4x included Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 104 Dome C #87-1235 host second spot 4x excluded Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 105 Dome C #87-1235 host second spot 4x included Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 106 Dome C #00-2352 host 4x excluded Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 107 Dome C #00-2352 host 4x included Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 108 Dome C #00-2352 host second spot 4x excluded Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 Size 3 109 Dome C #00-2352 host second spot 4x included Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 110 Dome C #84-634 enclave 4x excluded Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 111 Dome C #84-634 enclave 4x included Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 112 Dome C #84-634 enclave second spot 4x excluded Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 1 Size 2 113 Dome C #84-634 enclave second spot 4x included Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 114 Dome C #87-1235A enclave 4x excluded Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 115 Dome C #87-1235A enclave 4x included Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 116 Dome C #87-1235A enclave second spot 4x excluded Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 2 117 Dome C #87-1235A enclave second spot 4x included Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 2 118 Dome C #87-1235B enclave 10x excluded Ellipse Major axis 20 19 18 17 16 15 14 13 12 11 10 9 8 7 6 0 0.02 0.04 0.06 0.08 0.1 Size 0.12 0.14 0.16 0.18 0.2 119 Dome C #87-1235B enclave 10x included Ellipse Major axis 20 19 18 17 16 15 14 13 12 11 10 9 8 7 6 0 0.02 0.04 0.06 0.08 0.1 Size 0.12 0.14 0.16 0.18 0.2 120 Dome C #87-1235B enclave second spot 10x excluded Ellipse Major axis 22 21 20 19 18 17 16 15 14 13 12 11 10 9 8 0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 Size 0.08 0.09 0.1 0.11 0.12 0.13 121 Dome C #87-1235B enclave second spot 10x included Ellipse Major axis 22 21 20 19 18 17 16 15 14 13 12 11 10 9 8 0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 Size 0.08 0.09 0.1 0.11 0.12 0.13 122 Dome C #87-1235C enclave 4x excluded Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 123 Dome C #87-1235C enclave 4x included Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 124 Dome C #87-1235C enclave second spot 4x excluded Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 3 Size 4 5 125 Dome C #87-1235C enclave second spot 4x included Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 3 Size 4 5 126 Dome C #87-1235D enclave 10x excluded Ellipse Major axis 21 20 19 18 17 16 15 14 13 12 11 10 9 8 0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 Size 0.08 0.09 0.1 0.11 0.12 0.13 127 Dome C #87-1235D enclave 10x included Ellipse Major axis 21 20 19 18 17 16 15 14 13 12 11 10 9 8 0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 Size 0.08 0.09 0.1 0.11 0.12 0.13 128 Dome C #87-1235D enclave second spot 10x excluded Ellipse Major axis 19 18 17 16 15 14 13 12 11 10 9 8 7 6 5 4 3 0 0.05 0.1 0.15 0.2 0.25 Size 0.3 0.35 0.4 0.45 0.5 129 Dome C #87-1235D enclave second spot 10x included Ellipse Major axis 19 18 17 16 15 14 13 12 11 10 9 8 7 6 5 4 3 0 0.05 0.1 0.15 0.2 0.25 Size 0.3 0.35 0.4 0.45 0.5 130 Dome D #84-435 host 4x excluded Ellipse Major axis 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 2 131 Dome D #84-435 host 4x included Ellipse Major axis 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 Size 2 132 Dome D #84-435 host second spot 4x excluded Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 133 Dome D #84-435 host second spot 4x included Ellipse Major axis 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 134 Dome D #84-632 enclave 4x excluded Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 2 Size 3 135 Dome D #84-632 enclave 4x included Ellipse Major axis 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 2 Size 3 136 Dome D #84-632 enclave second spot 4x excluded Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 137 Dome D #84-632 enclave second spot 4x included Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 138 Dome D #84-632 enclave 10x excluded Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 Size 3 139 Dome D #84-632 enclave 10x included Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 Size 3 140 Dome D #84-632 enclave second spot 10x excluded Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 141 Dome D #84-632 enclave second spot 10x included Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 142 Dome E #84-443 host 4x excluded Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 143 Dome E #84-443 host 4x included Ellipse Major axis 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 3 Size 4 5 144 Dome E #84-443 host second spot 4x excluded Ellipse Major axis 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 0 1 2 3 Size 4 5 145 Dome E #84-443 host second spot 4x included Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 146 Dome E #84-635 enclave 4x excluded Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 147 Dome E #84-635 enclave 4x included Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 148 Dome E #84-635 enclave second spot 4x excluded Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 3 Size 4 5 149 Dome E #84-635 enclave second spot 4x included Ellipse Major axis 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 3 Size 4 5 150 Dome E #84-635 enclave 10x excluded Ellipse Major axis 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 151 Dome E #84-635 enclave 10x included Ellipse Major axis 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 152 Dome E #84-635 enclave second spot 10x excluded Ellipse Major axis 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 153 Dome E #84-635 enclave second spot 10x included Ellipse Major axis 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 154 Dome F #84-455 host 4x excluded Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 155 Dome F #84-455 host 4x included Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 156 Dome F #84-455 host second spot 4x excluded Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 -6 0 1 2 3 Size 4 5 157 Dome F #84-455 host second spot 4x included Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 -5 0 1 2 3 Size 4 5 158 Dome F #93-1963a enclave 4x excluded Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 0.05 0.1 0.15 0.2 0.25 Size 0.3 0.35 0.4 0.45 0.5 159 Dome F #93-1963a enclave 4x included Ellipse Major axis 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 3 Size 4 5 160 Dome F #93-1963a enclave second spot 4x excluded Ellipse Major axis 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 161 Dome F #93-1963a enclave second spot 4x included Ellipse Major axis 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 0 1 Size 162 Dome F #93-1963a enclave 10x excluded Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 163 Dome F #93-1963a enclave 10x included Ellipse Major axis 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 -4 0 1 2 Size 3 164 Dome F #93-1963a enclave second spot 10x excluded Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 165 Dome F #93-1963a enclave second spot 10x included Ellipse Major axis 8 7 6 5 4 3 2 1 0 -1 -2 -3 0 1 Size 2 166 REFERENCES Bacon, C.R., 1986, Magmatic Inclusions in Silicic and Intermediate Volcanic Rocks: Journal of Geophysical Research, v. 91, p. 6091-6112. Blakely, R.J., R.L. Christiansen, M. Guffanti, R.E. Wells, J.M. Donnelly-Nolan, L.J.P. Muffler, M.A. Clynne, and J.G. Smith, 1997, Gravity anomalies, Quaternary vents and Quaternary faults in the southern Cascades Range, Oregon and California: Implication for arc and backarc basins evolution: Journal of Geophysical Research, v. 102, p. 22513-22527. Browne, B.L., J.C. Eichelberger, L.A. Patino, T.A. Vogel, J. Dehn, K. Uto, and H. Hoshizumi, 2006, Generation of Porphyritic and Equigranular Mafic Enclaves during Magma Recharge Events at Unzen Volcano, Japan: Journal of Petrology, v. 47, p. 301328. Campbell, I.H., and J.S. Turner, 1985, Turbulent mixing between fluids with different viscosities: Nature, v. 313, p. 39-42. Campbell, I. H., and J.S. Turner, 1986, The Influence of Viscosity in Fountains in Magma Chambers: Journal of Petrology, v. 27. p. 1-30. Cashman, K.V., and B.D. Marsh, 1988, Crystal size distribution (CSD) in rocks and the kinetics and dynamics of crystallization ΠΏ. Makaopuhi lava lake: Contributions to Mineralogy and Petrology, v. 99, p. 292-305. Clynne, M.A., and L.J.P. Muffler,1989, Lassen Volcanic National Park and Vicinity, in South Cascades Arc Volcanism, California and Southern Oregon, Field Trip Guidebook T312, American Geophysical Union, 52p. Clynne, M.A., 1990, Stratigraphic, lithologic, and major element geochemical constraints on magmatic evolution at Lassen Volcanic Center, California: Journal of Geophysical Research, v. 95, p. 19651-19669. Clynne, M.A, 1999, A Complex Magma Mixing Origin for rocks Erupted in 1915, Lassen Peak, California: Journal of Petrology, v. 40, p. 105-132. Coombs, M.L, J.C. Eichelberger, and M.J. Rutherford, 2002, Experimental and textural constraints on mafic enclave formation in volcanic rocks: Journal of Volcanology and Geothermal Research, v. 119, p. 125-144. Eichelberger, J.C., 1980, Vesiculation of mafic magma during replenishment of silicic magma reservoirs: Nature, v. 288, p. 446-450. 167 Feeley, T.C., L.F Wilson, and S.J. Underwood, (2008), Distribution and compositions of magmatic inclusion in the Mount Helen dome, Lassen Volcanic Center, California: Insights into magma chamber processes: Lithos, v. 106, p. 173-189. Guffanti, M., and C.S. Weaver, 1988, Distribution of Late Cenozoic volcanic vents in the Cascade Range: Volcanic arc segmentation and regional tectonic considerations: Journal of Geophysical Research, v. 93, p. 6513-6529. Guffanti M., M. A. Clynne, J.G. Smith, L.J.P. Muffler, and T. D. Bullen, 1990, Late Cenozoic volcanism, subduction, and extension in the Lassen Region of California, Southern Cascade Range: Journal of Geophysical Research, v. 95, p. 19452-19464. Heiken, G. and J.C. Eichelberger, 1980, Eruptions at the Chaos Crags, Lassen Volcanic National Park, California: Journal of Volcanology and Geothermal Research, v.7, p. 443-481. Higgins, M.D., 2000, Measurement of crystal size distributions: American Mineralogist, v. 85, p. 1105-1116. Huppert H.E., R.S.J. Sparks, and J.S. Turner, 1982, Effects of volatiles on mixing in calcalkaline magma systems; Nature, v. 297, p. 554-557. Kouchi, A. and I. Sunagawa, 1983, Mixing basaltic and dacitic magmas by forced convection: Nature, v. 304, p. 527-528. Kouchi, A. and I. Sunagawa, 1985, A model for mixing basaltic and dacitic magma as deduced from experimental data: Contributions to Mineralogy and Petrology, v. 89, p. 17-23. Marsh, B.D., 1988, Crystal size distribution in rocks and the kinetics and dynamics of crystallization Ι. Theory: Contributions to Mineralogy and Petrology, v. 99, p. 277-291. Marsh, B.D., 1998, On the Interpretation of Crystal Size Distributions in Magmatic Systems: Journal of Petrology, v. 39, p. 553-599. Martin, V.M., M. B. Holness, and D.M. Pyle, 2006a, Textural analysis of magmatic enclaves from the Kameni Islands, Santorini, Greece: Journal of Volcanology and Geothermal Research, v. 154, p. 89-102. Morgan, D.J., and D.A. Jerram, 2006, On estimating crystal shape for crystal size distribution analysis: Journal of Volcanology and Geothermal Research, v. 154, p. 1-7. 168 Pallister, J.S., Hoblitt, R.P., Reyes, A.G., 1992, A basalt trigger for the 1991 eruptions of Pinatubo volcano?: Nature, v. 356, p. 426–428. Peterson, T.D., 1996, A refined technique for measuring crystal size distributions in thin sections: Contributions to Mineralogy and Petrology, v. 124, p. 395-405. Randolph, A.D., and M.A. Larson, 1971, Theory of particulate process; Academic Press, New York, 251 p. Rutherford, M. J. & Hill, P. M., 1993, Magma ascent rates from amphibole breakdown: an experimental study applied to the 1980–1986 Mount St. Helens eruptions: Journal of Geophysical Research v. 98, p. 19667–19685. Sparks, R.S.J., H. Sigurdsson, and L. Wilson, 1977, Magma mixing-a mechanism for triggering acid explosive eruptions: Nature, v. 267, p. 315-318. Sparks et al., 1984, The fluid dynamics of evolving magma chambers: Phil. Trans. R. Soc. Lond. Ser. A, 310, p. 511-534. Stout, C., 2007, Field measurements of mafic enclave population density at Chaos Crags: Abstracts with Programs-Geological Society of America, v. 39, p. 73. Taggart, J. E., Jr., Lindsey, J. R., Scott, B. A., Vivit, D. V., Bartel, A. J. & Stewart, K. C., 1987, Analysis of geologic materials by wavelength-dispersive X-ray fluorescence spectrometry: US Geological Survey 1170, p. E1–E19. Tepley, F.J., J.P. Davidson, and M.A. Clynne, 1999, Magmatic Interactions as Recorded in Plagioclase Phenocrysts of Chaos Crags, Lassen Volcanic Center, California: Journal of Petrology, v. 40, p. 787-806. Tepley et al., 2000, Magma mixing, recharge, and eruption histories recorded in plagioclase phenocrysts from El Chichón volcano, Mexico: Journal of Petrology, v. 41, p. 1397-1411. Turrin B.D., R.L. Christiansen, M.A. Clynne, D.E. Champion, W.J. Gerstel, L.J.P. Muffler, and D.A. Trimble, 1998, Age of Lassen Peak, California, and implications for the ages of late Pleistocene glaciations in the southern Cascades Range: GSA Bulletin, v. 110, p. 931-945. Unruh, J., J. Humphrey, and A. Barron, 2003, Transtensional model for the Sierra Nevada frontal fault system, eastern California: Geology, v. 31, no.4, p. 327-330. 169 Wolfe et al., 2007, Petrologic constraints on eruption triggering and magma ascent at Mammoth Mountain, California: Abstracts with Programs-Geological Society of America, v. 39, p. 73.