Chemistry Curriculum Map: Learning Goals and Recommended Time of Instruction October 1, 2014 Time Frame Unit Standards Evidence of Understanding Describe how models explain experimental data and use models to make predictions Explain how the atomic model has changed over time as technology improved including a description of the experiment JJ Thompson used to discover the electron and the experiment done by Ernest Rutherford to discover the nucleus Explain the model of the atom developed by Thompson (Plum Pudding Model) Explain the model developed after the discovery of the nucleus Describe what atomic emission spectra and atomic absorption spectra are and how Bohr used atomic emission spectra to develop the planetary model of the atom Describe the planetary model of the atom Define orbitals Explain the quantum mechanical model of the atom (Schrödinger) 1st 9 weeks Structure and Properties of Matter Explain how electrons move in the quantum mechanical model Atomic Structure Explain how electron location can be predicted in the quantum mechanical model of the atom Describe that atomic emission spectra and/or atomic absorption spectra predict that electrons can exist at only specific energy levels Explain that atoms generatlly exist in the ground state Define photon Explain how an atom becomes excited Describe that an atom must absorb a specific amount of energy to become excited Identify the relative energies of photons based on the frequency Explain that an atom must absorb a specific amount of energy to become excited Identify the relative energies o photons based on the frequency Explain that an excited atom is unstable and short-lived Describe how an atom loses energy to move from an excited state to the ground state Chemistry Curriculum Map: Learning Goals and Recommended Time of Instruction October 1, 2014 Relate the energy of the photon released by an excited atom to the energy levels Identify that frequency of photons can be measured Relate the energy released by an excited state atom to its atomic emission spectrum Identify that atomic absorption spectra and atomic emission spectra are unique for each element Describe why each element has unique atomic emission and atomic absorption spectra using electron configurations Identify that the quanutm mechanical model is the currently accepted model of the atom Define sublevels (s, p, d, f) Relate energy levels to the shape and number of orbitals available Draw the correct orbital diagrams for atoms in the first three periods Write correct electron configurations for atoms in the first three periods in extended and noble gas notations Explain that the chemical properties of elements result from their valence electron arrangements Define valence electrons and valence shells Periodic Table 2nd 9 weeks Intramolecular Chemical Bonding Show that the elements of a family/group have similar valence electron arrangements Write electron configurations from the position of the element on the periodic table Explain that the valence shell electron arrangement (as shown in electron configurations) result in similar properties for elements in a group/family Identify trends in the periodic table for atomic radii, ionic radii, first electron energy, electronegativity and state of matter at room temperature Explain that atoms bond with each other to become more stable and relese energy in the process Relate how the electron configurations determine how atoms interact with each other Define molecules, ionic lattices and covalent structures Explain that substances have predictable properties based on elements that make them up and the bonding that occurs Define ionic and covalent bonds and polarity Chemistry Curriculum Map: Learning Goals and Recommended Time of Instruction October 1, 2014 Use electronegativity to predict the type of bond (ionic, polar covalent, nonpolar covalent) that will form Explain how electronegativity and bond length affect the polarity of the bond Differentiate between ionic, covalent and metallic bonding Discuss how metallic bonding influences the properties of metals (conductivity, malleability, ductility) Recognize that a single substance can contain different numbers and types of bonds Recognize that carbon has the ability to bond with other atoms (hydrogen, oxygen, nitrogen, sulfur) to produce important compounds (fuels, organic/life, polymers) Predict the formula for ionic compounds made up of elements in groups 1, 2, 17, hydrogen, oxygen and polyatomic ions Write names for compounds that are both ionic or covalent Representing Compounds Name a compound using the appropriate Greek prefixes and Roman numerals, as necessary Use a variety of models (chemical formulas, Lewis structures, ball and stick) to represent compounds Use these models (chemical formulas, Lewis structures, ball and stick) to predict properties of substances Describe the information provided by different models of a compound Synthesize the information provided by a variety of models of a compound to describe the properties of a substance Draw correct Lewis structures for covalent compounds Explain the components of VSEPR (valence shell electron repulsion theory) Use VSEPR to predict the shape and geometry of a covalent compound containing hydrogen, carbon, nitrogen, oxygen, phosphorus, sulfur and the halogens Understand the difference between accuracy and precision Understand and use the significant figure rules Use scientific notation appropriately Quantifying Matter Perform an appropriate type of error analysis, when necessary Understand and use the appropriate scale (macroscopic, cosmic, submicroscopic) when making measurements Identify that making measurements in the cosmic and submicroscopic scales requires specialized instrumentation Chemistry Curriculum Map: Learning Goals and Recommended Time of Instruction October 1, 2014 Explain that measuring mass can represent the number of particles present in a sample Explain that a sample of an element is really made up of the isotopes of that element Calcualte the average atomic mass of an element when given the isotopes' masses and relative abundance Define mole and Avogadro's number Use the mole to convert between atomic and macroscopic levels Recognize that the mass of one mole is equal to the formula mass in grams Use density, formula mass and Avogadro's number to convert between moles, mass, volume and number of particles Define plasma and Bose-Einstein condensate Explain how plasmas form and how they become charged Explain how Bose-Einstein condensates form Phases of Matter 3rd 9 weeks Intermolecular Chemical Bonding Recognize the relationship between plasmas and Bose-Einstein condensates Connect how the discovery of new substances/forms of substances is demonstrated with this very specific example (plasmas and Bose-Einstein condensates) Recognize that intermolecular forces are much weaker than intramolecular forces Recognize that some intermolecular forces are stronger than others Describe how the composition, shape and polarity of the molecule can help prdict the strength and type of intermolecular forces Define and describe London dispersion forces, dipole-dipole forces and hydrogen bonding Compare and contrast the strength of London dispersion, dipoledipole and hdyrogen bonding forces Know that London dispersion forces exist between all molecules Know that dipole-dipole forces exist between polar molecules Know that hydrogen bonding is a special case of dipole-dipole forces that exists in molecules with highly electronegative atoms (fluorine, nitrogen, oxygen) Explain that the arrangement of atoms in a molecule determines the strength of the bonds and/or intermolecular forces Connect the arrangement of the atoms to the physical properties of the substance Chemistry Curriculum Map: Learning Goals and Recommended Time of Instruction October 1, 2014 Explain that a change of state occurs when the average kinetic energy of the particles is enough to overcome the intermolecular forces between the particles Describe how the melting point and boiling point of a substance depends on the intermolecular forces of the substance Recognize that substances with strong intermolecular forces have 3D networks of ionic or covalent bonds Recognize that substances with strong intermolecular forces will be solids at room temperature and have high melting and boiling points Recall that nonpolar organic molecules are held together with London dispersion forces Recognize that extending the length of the chains in organic molecules will generally increase interactions, therefore, increasing London dispersion forces and melting and boiling points Recognize that branching in organic molecules tends to reduce the melting and boiling temperatures because it reduces the interactions and, therefore, reduces the London dispersion forces Define solubility and dissolve Understand that solubility is related to intermolecular forces between substances and within substances Explain why substances have a greater solubility when dissolved in a substance with similar intermolecular forces Explain why substances with different intermolecular forces do not dissolve in each other Explain that all changes of state, and the temperatures at which they occur, depend on the strength of intermolecular forces Recognize that substances with 3D networks of ionic or covalent bonds tend to have high melting and boiling points Recognize that nonpolar substances with long chains will have higher melting and boiling points because because of increased London dispersion forces, however, branches will reduce these and decrease the melting and boiling points of the substance Explain why the polarity of water makes it a good solvent and how it causes other substances to dissolve (ionic and covalent) Differentiate between evaporation and boiling Explain vapor pressure and the factors that influence it (temperature, intermolecular forces, molecular vs. ionic) Recognize that liquids boil at their vapor pressure when it matches atmospheric pressure Chemistry Curriculum Map: Learning Goals and Recommended Time of Instruction October 1, 2014 Define volatile and volailize and recognize that volatile substances can often be detected by odor Explain what happens at a particle level for water when it freezes and how this afects its density Classify chemical reactions, based on patterns, such as oxidation/reduction, synthesis, decomposition, single replacement, double replacement (which includes acid/base neutralization and precipitation reactions) and combustion Recognize that the combustion of organic molecules releases energy that has societal and biological uses Explain that precipitates form when two ionic aqueous solutions mix because the newly formed bonds are stronger than the original ion-dipole interactions of the ions in solution Explain that reactions only occur when particles collide with appropriate orientation and sufficient energy Interactions of Matter 4th 9 weeks Chemical Reactions Explain that stable reactants require an input of energy (activation energy) to make the reaction proceed and that the use of a catalyst (like enzymes) usually reduces the activation energy Describe that the rate of reaction indicates how successful the collisions of reactant particles are, and that it can be altered by manipulating the concentration of reactants, temperature or pressure of gaseous reactants Use collision theory to explain why reactions are more likely to occur between particles in the liquid or gas phases Recognize that potential energy is in the form of chemical energy and kinetic energy is in the form of thermal energy Use calorimetry to calculate changes in energy for a system because total energy cannot be measured Explain that the thermal energy of a system depends on the mass, temperature and chemical composition, and that different materials require different amounts of thermal energy to change their temperatures Use specific heat to calculate thermal energy change, temperature or the mass of the material Recognize the importance of water's high specific heat capacity Explain that chemical reactions involve valence electrons breaking, rearranging and reforming bonds to form more stable products Recognize that breaking and reforming bonds requires the addition or the release of energy Chemistry Curriculum Map: Learning Goals and Recommended Time of Instruction October 1, 2014 Explain that exothermic reactions occur when the products are more stable than the reactants and energy is released while endothermic reactions require the addition of energy to break more stable bonds of the reactants and form weaker bonds in the products Use bond energies to predict whether the reactions will be endothermic or exothermic and draw the corresponding graph representing the activation energy for the reaction Explain that reactions are reversible (to some degree) and can establish a dynamic equilibrium because the rate of the forward reaction is equal to the rate of the reverse reaction which can be shown graphically Recognize that rections which release a large amount of energy and appear to proceed in one direction will not likely work in reverse Explain and use Le Chatelier's Principle (concentration, temperature, removing/adding products/reactants, pressure of gases) Explain that acids result when hydrogen is bound to an electronegative element and is released in aqueous solutions to form the hydronium ion such that the acidity of a solution is described by the pH (negative logarithm of the hydronium ion concentration) Explain that bases will dissociate in water to form the hydroxide ion Gas Laws 3rd 9 weeks Stoichiometry Write and balance neutralization reactions that result from the reaction of an acid and base to form a salt and water Use the kinetic molecular theory to explain the properties of gases (pressure, Kelvin temperature and volume) through motion and particle interactions Quantify and describe two (pressure, Kelvin temperature, volume) of the gas properties when one is constant Explain that the Kelvin temperature can be extrapolated back to absolute zero where the gas will have no volume and all motion stops Explain Avogadro's law and that it allows calculation using the ideal gas law Use a chemical reaction to convert the amount of one substance into another Recognize that the coefficients of the balanced equation shows the relationship that can be used to calculate both moles and particles Convert from moles of a substance into mass, volume of a gas, volume of a solution or number of particles Use molarity as a conversion factor where appropriate Chemistry Curriculum Map: Learning Goals and Recommended Time of Instruction October 1, 2014 Calcualte percent and theoretical yields Explain the concept of limiting reactants 4th 9 weeks Nuclear Reactions Radioactive deay releases radiation (alpha, beta, gamma, positron) with specific properties (mass, charge, ionizing potential, penetration) Recognize that beta decay is the result of the decay of a neutron, and positron decay is the result of the decay of a proton Write balanced nuclear decay equations Explain that fission and fusion are nuclear decays that result in large energy changes that can be controlled as a source of energy production