Conference Session: A11 6015 Disclaimer — This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not be provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. SILVER AND COPPER NANOPARTICLES; THE FUTURE OF WATER PURIFICATION Nicholas Youwakim, ney6@pitt.edu, Mahboobin 4:00, Derek Sellers, dls138@pitt.edu, Bursic 2:00 Revised Proposal — According to World Health Organization, 1.6 billion people globally have no clean and safe source of water (mostly in developing countries) [1]. As a result, 1.5 million people die globally each year due to preventable waterborne diseases such as giardiasis, cholera, cryptosporidiosis, viral gastroenteritis, etc. [1]. Thus, research has been done with the objective of creating a safe and sustainable way to treat water in places of the world that are without clean water. In this paper, we will explore the use, production, and safety of copper and silver nanoparticles in point-of-use water purification systems, as well as possible advances and immediate effects that a product created through this technology can have on the world community. In order for this science to work, nanoparticles must be embedded into a specifically designed paper sheet that will be described in depth in the paper. This technology can currently be produced by either soaking the paper sheet in a solution containing the chosen metal nanoparticles (silver/copper) or using microwave irradiation to embed the chosen nanoparticles and speed up synthesis. The Drinkable Book, which contains paper sheets of this nanoparticle technology, is the most popular product [2]. Point-of-use water filtration is essential to any part of the world at any time due to the fact that it is quick and inexpensive. In July of 2015, the first field study was conducted in Limpopo, South Africa and was a success. Limpopo had a waterborne illness report 1.7 times higher than anywhere else in the world due to its highly polluted streams, at which most residents get their water from [3]. In some instances, the nanoparticles were able to remove 99.9% of bacteria [2]. Residents praised the technology because it was so easy to use and because each sheet could be used up to 30 times each [3]. Unlike large and expensive water treatment plants that the town could not install, the filter paper was readily available, inexpensive, and could be used anywhere [3]. In this paper, we will include situations in which this filtration paper can be utilized other than in the developing world including natural disasters. Additionally, we will examine the possible risks involved with this technology which include possible nanoparticle leakage and efficient production. Moving forward, we will also include a brief section of other applications of this technology University of Pittsburgh Swanson School of Engineering 1 2016/01/29 other than water filtration, which include wound care and food packaging. These applications will demonstrate the rapid growth of this field that can prove quite beneficial against various antimicrobial issues. In conjunction, we plan to consult various different types of sources in order to make the paper stand out. The planned sources include interviews of professionals, journals, articles, etc. that will all help to reinforce our knowledge of this specific technology. Most importantly, we plan to take advantage of advice given by upperclassmen and advisors in order to produce the best paper that we possibly can. REFERENCES [1] “Health through safe drinking water and basic sanitation.” (2015). World Health Organization. (online article). http://www.who.int/water_sanitation_health/mdg1/en [2] M. Gunther. (2015). “‘Drinkable Book’ Turns Dirty Water Clean for a Thirsty World.” Scientific American. (online article). http://www.scientificamerican.com/article/drinkablebook-turns-dirty-water-clean-for-a-thirsty-world/ [3] T.A Dankovich, N. Potgieter, R. Dillingham, J.A Smith, J.S Levine. (2015). “Inactivation of bacteria from contaminated streams in Limpopo, South Africa by silver- or copper-nanoparticle paper filters.” ResearchGate. (online journal). Environ. Sci.: Water Res. Technol 10/2015; DOI: 10.1039/C5EW00188A ANNOTATED BIBLIOGRAPHY A.Y. Booshehri, R. Wang, R. Xu. (2014). “Simple method of deposition of CuO nanoparticles on a cellulose paper and its antibacterial activity.” Chemical Engineering Journal. (online article). DOI: 10.1016/j.cej.2014.09.096. pp. 9kr99-1008. This article, released by Chemical Engineering Journal, an international research journal, explains the benefits of the use of copper nanoparticles in water purification on multiple filtration surfaces, such as cellulose paper and polymeric Nicholas Youwakim Derek Sellers membranes. The article details the methods used to produce copper nanoparticles on such materials and details their distribution and possible leakage. This article will be used to explain how these filters are produced, along with the effectiveness and stability of these particles. This scientific article from Water Research, a scholarly journal released by the International Water Association, explains the in situ production of filter paper embedded with copper nanoparticles. This article explains the studies conducted in order to determine the distribution, characterization, and bactericidal effects of copper nanoparticles, as well as further possible studies to enhance them. We intend to use this article to explain the financial and chemical benefits of using copper nanoparticles over silver. T.A Dankovich. (2014). “Microwave-assisted incorporation of silver nanoparticles in paper for point-of-use water purification.” Environmental Science Nano. (online article). DOI: 10.1039/c4en00067f. pp. 367-378. This scholarly article in Environmental Science Nano, a journal released by the Royal Society of Chemistry, explains the production of silver nanoparticles on cellulose paper. The article details the effect of glucose and heating sources on the production of silver nanoparticles and gives the characterization of the nanoparticles when using two different production methods. We plan to use this article to describe the improvements in development of nanoparticle infused filter paper and its effects on contaminated water. M. Gunther. (2015). “‘Drinkable Book’ Turns Dirty Water Clean for a Thirsty World.” Scientific American. (online article). http://www.scientificamerican.com/article/drinkablebook-turns-dirty-water-clean-for-a-thirsty-world/ This article from Scientific America, a popular science magazine, gives detailed information about the “drinkable book” and updates on how the application and production of the product is progressing. The article includes information as to how copper and silver nanoparticles are being applied and utilized in this water filtration technology. The material from this article will help us describe the importance and application of our technology. T.A Dankovich, D.G. Gray. (2011). “Bactericidal Paper Impregnated with Silver Nanoparticles for Point-of-Use Water Treatment.” Environmental Science and Technology. (online article). DOI: 10.1021/es103302t. pp. 1992-1998. In this article from Environmental Science and Technology, a journal released by the American Chemical Society, the production and bactericidal effectiveness of silver nanoparticles are analyzed and reported. The article also details one in situ method by which silver nanoparticles can be produced, along with possible health issues that can arise due to nanoparticle leakage into filtered water. We plan to use this article to enforce the history of this technology and explain the effectiveness of silver nanoparticles compared to copper nanoparticles. “Health through safe drinking water and basic sanitation.” (2015). World Health Organization. (online article). http://www.who.int/water_sanitation_health/mdg1/en/ This scientific article from World Health Organization provides information that demonstrates the need for a sustainable and quick point-of-use water source. The article contains updated information about the amount of people in the world without clean drinking water and current actions being taken to improve global health. We will use this source to demonstrate the impact that nanoparticle filtration could have on the world. B. Khodashenas. (2015). “The Influential Factors on Antibacterial Behaviour of Copper and Silver Nanoparticles.” Indian Chemical Engineer. (online article). DOI: 10.1080/00194506.2015.1026950. This article from The Indian Institute of Chemical Engineers, a national organization, analyzes the physical and chemical properties of both copper and silver nanoparticles. The article shows how conditions such as size, shape and concentration of the nanoparticles can alter their effectiveness of eliminating bacteria. The data from this article will help us understand why copper and silver nanoparticles are used and in what conditions they are most effective. T.A Dankovich, N. Potgieter, R. Dillingham, J.A Smith, J.S Levine. (2015). “Inactivation of bacteria from contaminated streams in Limpopo, South Africa by silver- or copper-nanoparticle paper filters.” ResearchGate. (online journal). Environ. Sci.: Water Res. Technol 10/2015; DOI: 10.1039/C5EW00188A. This recent article from ResearchGate, a professional research website, contains a study that highlights the effectiveness of bacterial inactivation from the use of paper embedded with copper and silver nanoparticles. The study takes place in Limpopo, South Africa a location known to have high concentrations of waterborne diseases and was successful in this field test. This information will highlight the impact that this sustainable point-of-use water filtration system could make on the world. M. Tiwari, K. Narayanan, M.B Thakar, H.V Jagani, J.V Rao. (2013). “Biosynthesis and wound healing activity of copper nanoparticles.” IET Digital Library. (online article). DOI: 10.1049/iet-nbt.2013.0052. This article from IET Digital Library, a respected engineering and technology database, demonstrates how copper nanoparticles can be used in the medical field to reduce bacteria and prevent infections. This article provides a study T.A. Dankovich, J.A. Smith. (2014). “Incorporation of copper nanoparticles into paper for point-of-use water purification.” Water Research. (online article). DOI: 10.1016/j.watres.2014.06.022. pp. 245-251. 2 Nicholas Youwakim Derek Sellers that examines the use of nanoparticles in the medical field healing wounds faster and preventing infections. We intend to use this article to show another bactericidal application of nanoparticles in hospitals and emergency medical situations. 3