Supported contact mechanics models The relation between indentation and force depends on the shape of the tip and the thickness of the sample. AtomicJ supports several tip shapes – Sphere, Cone, Pyramid, Power-shaped, Hyperboloid, Blunt cone, Blunt pyramid, Truncated (flat-ended) cone and Truncated pyramid. For sphere and cone it also implements corrections for finite thickness of the sample. All equations assume that the material behaves as linear elastic (i.e. that the indentations are relatively small). a b Fig. 1. Tip shapes: a. Paraboloid that approximates sphere in the Hertz’s equation. R – radius of curvature at the apex. b. Hyperboloid. R – radius of curvature at the apex, θ – half angle between the asymptotes. c d e Fig. 1. (cont.). Tip shapes. c. Cone. θ – half angle. d. Blunt cone (cone capped by a sphere). R- radius of curvature at the apex, b – tip radius at the level of transition between the capping sphere and the cone, θ – half angle. If the transition from sphere to cone is smooth, then b = RCos[θ]. e. Truncated cone. b – truncation radius, θ – half angle In the equations, we will use the following symbols: E – Young’s modulus; ν – Poisson’s ratio δ – depth of indentation; a – contact radius h – sample thickness Tip geometry parameters are explained in Fig. 1. 1. Sphere (Hertz). An approximation of the sphere by a paraboloid. It is accurate when the contact radius a is much smaller than the sphere radius R, which means that 4E P 3 1 2 R R R. 3 2 2. Sphere (Sneddon). Unlike Hertz’s, Sneddon’s solution (Sneddon 1965) does not require that R R. P E R2 a2 Ra Log aR 2 1 2 Ra δ a Ra Log 2 Ra 3. Sphere, thin sample (Dimitriadis et al. 2002) 3 2 4E 4 2 2 8 3 4π 2 3 16 3 3π 2 4 2 P R 1 2 3 4 π π π 15 π 5 3 1 2 where χ R h Coefficients α and β depends on whether the sample is adherent to the substrate or not. For adherent sample: 3 2 1 5 2 0.056 1 0.347 For non-adherent sample: 1.2876 1.4678 1.3442 2 1 0.6387 1.0277 1.5164 2 1 4. Hyperboloid (Akhremitchev and Walker 1999) P R Cot 1 Ea3 2 2 π 1 ArcTan where a 2 2 1 2 R 2 2 1 a2 π ArcTan 2R 2 2 2 5. Cone (Harding and Sneddon 1945) P 2 E Tan π 1 2 2 6. Cone, thin sample (Gavara and Chadwick 2012) P 8E Tan 3π 2Tan π2h 2 1 16 2Tan 2 2 h2 For adherent sample, α = 1.7795, for non-adherent α = 0.388. 7. Power-shaped (Galin 1946). The tip is modeled as a solid obtained by revolving a power function along the y axis. It is thus axisymmetric and its profile is given by the power function f(r) = A rλ. The load P and indentation depth δ can be expressed in terms of contact radius a as: 2 E A 2 P 2 a 1 2 1 2 1 2 2 a 2 A 2 2 where Γ is Euler’s gamma function. Hertz’ equation for sphere and Sneddon’s equation for cone are special cases of the equation for the power-shaped tip, with λ = 2, A = 1/(2R) and λ = 1, A = 1/Tan[θ], respectively. In the AtomicJ interface, A is termed the factor and λ is termed the exponent. 8. Blunt cone (Briscoe et al. 1994). The Hertz solution for the sphere is applied for small indentations, for which the contact radius a is smaller than the transition radius b. This is the case as long as P 2E 1 2 b2 . For larger indentations: R a2 a 2 Tan 3 π b a 2 2 ArcSin a 3R a b 2 a π b a 2 2 ArcSin a b Tan 2 a R 1 2 1/2 b a 2 b 2 3R 2 Tan a 9. Truncated cone (Briscoe et al. 1994). Truncated cone can be treated as a special case of blunted cone, for which the radius of curvature at the apex is infinite. Substituting R = ∞ into the equations for blunt cone, we get: P 2E 1 2 a2 a 2 Tan π b 2 2 ArcSin a b 2 a 1 2 b 2 Tan a π b ArcSin Tan θ 2 a 10. Pyramid, regular, four sided (Bilodeau 1992) P 1.4906 ETan[ ] 2 2 1 2 11. Blunt pyramid, regular, four-sided (Rico et al. 2005). The Hertz solution for the sphere is applied for small indentations, for which the contact radius a is smaller than the transition b2 radius b. This is the case as long as . For larger indentations R 3 2E 21/2 a 2 π b a P a 2 b2 a ArcSin 2 π Tan 2 1 a 3R 23/2 a π b a 2 2 ArcSin a b π Tan 2 a R 1 2 21/2 b a 2 b 2 3R π Tan 1/2 a 12.Truncated pyramid (Rico et al. 2005). Truncated pyramid can be treated as a special case of blunted pyramid, for which the radius of curvature at the apex is infinite. Substituting R = ∞ into the equations for blunt pyramid, we get: P 2E 1 2 21/2 a 2 π b 2 2 a ArcSin a b π Tan 2 a 23/2 a π b ArcSin π Tan 2 a 1 2 21/2 b π Tan HYPERELASTIC MODELS 13. Sphere, Fung’s hyperelastic model (Fung 1979) .The equation for force – indentation depth relation was derived by Lin et al (2009), who found that the equation for sphere’s contact radius a from Hertz’z model (used here) holds for hyperelastic materials as long as 0.4 . R P a 3 15Ra 2 20 E0 a5 15Ra 4 75R 2 a 3 exp b 2 2 3 2 3 9 1 ν 2 5Ra 50 R a 125R 25R a 125R a R 14. Sphere, Ogden’s hyperelastic model (Ogden 1972).The equation for force – indentation depth for single-term Ogden’s model relation was derived by Lin et al (2009): /2 1 1 a a P 1 0.2 1 0.2 R R 9 1 ν 2 40 E0 a 2 a R ADHESIVE CONTACT 15. Derjaguin-Muller-Toporov (DMT) (Derjaguin et al. 1975). DMT model was derived for indentation with a sphere (approximated by a paraboloid) in the presence of adhesion forces. We implemented the most commonly referenced form of the DMT model, in which the additional load due to adhesive forces equals 2πγR and is independent of indentation. This formulation is due to Maugis (1992). DMT model gives good approximation of the load – indentation relationship only for stiff samples, small values of tip radius R and small surface energy γ. P 4E R 3/2 2 R 2 3 1 16. Johnson-Kendall-Roberts (JKR) (Johnson et al. 1971). JKR model was derived for indentation with a sphere (approximated by a paraboloid) in the presence of adhesion forces. JKR model is a good approximation of the load – indentation relationship for soft samples, large value of radius R and large energy of adhesion (Maugis 1992). P= 4Ea 3 E a 3 2 2π 3R 1- 2 1- 2 a2 R 2 a E (1 2 ) 17. Sphere, Maugis solution. Maugis (1995) derived the load – indentation relationship in the presence of adhesion, which takes into account the true shape of a spherical tip (as opposed to the JKR model, which uses parabolic approximation). 2𝐸𝑎 𝑅 2 + 𝑎2 𝑅+𝑎 𝑅 2𝜋𝛾𝑎 𝑃= Log [ ]− −√ 2 𝐸 1−𝜈 4𝑎 𝑅−𝑎 2 1 − 𝜈2 ( ) 𝛿= 𝑎 𝑅+𝑎 2π𝛾𝑎 Log [ ]−√ 𝐸 2 𝑅−𝑎 1 − 𝜈2 18. Hyperboloid, Sun-Akhremitchev-Walker (SAW). Sun et al (2004) derived the load – contact radius and indentation – contact radius relations for indentation with a hyperboloidal tip in the presence of adhesion. 𝑎 2 (𝐴 ) − 1 2𝐸 𝐴 𝑎2 − 𝐴2 𝜋 2𝑎𝛾𝜋(1 − 𝜈 2 ) √ 𝑃= ( 𝑎𝐴 + ( + ArcSin [ ]) − 𝑎 ) 𝑎 2 1 − 𝜈 2 2𝑅 2 2 𝐸 (𝐴 ) + 1 ( ) 𝑎 2 (𝐴) − 1 𝑎𝐴 𝜋 2𝜋𝑎𝛾(1 − 𝜈 2 ) √ 𝛿= ( + ArcSin [ ]) − 𝑎 2 2𝑅 2 𝐸 (𝐴) + 1 where 𝐴 = 𝑅Cot[𝜃] References: 1. Akhremitchev BB, Walker GC, Finite Sample Thickness Effects on Elasticity Determination Using Atomic Force Microscopy. Langmuir 15: 5630 – 5634 (1999). 2. Bilodeau G Regular Pyramid Punch Problem. ASME J Appl Mech. 59: 519 – 523 (1992). 3. Briscoe DJ, Sebastian KS, Adams MJ, The effect of indenter geometry on the elastic response to indentation. J Phys D: Appl Phys 27: 1156 – 1162 (1994). 4. Derjaquin BV, Muller VM, Toporov YP, Effect of contact deformations on the adhesion of particles. J Colloid Interface Sci 53: 314-326 (1975). 5. Dimitriadis EK, Horkay F, Maresca J, Kachar B, Chadwick RS, Determination of elastic moduli of thin layers of soft material using the atomic force microscope. Biophys J 82:2798–2810 (2002). 6. Fung YC, Fronek K, Patitucci P, Pseudoelasticity of arteries and the choice of its mathematical expression. Am J Physiol-Heart C 237:H620–H631 (1979). 7. Galin LA, Spatial contact problems of the theory of elasticity for punches of circular shape in planar projection. J. Appl. Math. Mech. (PMM) 10: 425–448 (1946). 8. Gavara N and Chadwick RS, Determination of the elastic moduli of thin samples and adherent cells using conical AFM tips. Nat Nanotechnol. 7: 733–736 (2012). 9. Harding JW, Sneddon IN, The elastic stresses produced by the indentation of the plane surface of a semi-infinite elastic solid by a rigid punch. Proc Camb Philol Soc. 41:16 (1945). 10. Johnson KL, Kendall K, Roberts AD, Surface energy and the contact of elastic solids. Proc. R. Soc. Lond. A 324: 301-312 (1971). 11. Lin DC, Schreiber DI, Dimitriadis EK, Horkay F, Spherical indentation of soft matter beyond the Hertzian regime: numerical and experimental validation of hyperelastic models. Biomech Model Mechanobiol 8:345–358 (2009). 12. Maugis D Extension of the Johnson-Kendall-Roberts theory of the elastic contact of spheres to large contact radii. Langmuir 11: 679 – 682 (1995). 13. Ogden RW, Large deformation isotropic elasticity—on the correlation of theory and experiment for incompressible rubberlike solids. Proc R Soc Lond A Math Phys Sci 326: 565–584 (1972). 14. Rico F, Roca-Cusachs P, Gavara N, Farre R, Rotger M and Navajas D, Probing Mechanical Properties of Living Cells by Atomic Force Microscopy With Blunted Pyramidal Cantilever Tips. Phys Rev E 72, 021914 (2005). 15. Sneddon IN, The relation between load and penetration in the axisymmetric Boussinesq problem for a punch of arbitrary profile. Int J Eng Sci 3: 47 – 57 (1965). 16. Sun Y, Akhremitchev B, Walker G, Using the adhesive interaction between atomic force microscopy tips ad polymer surfaces to measure the elastic modulus of compliant samples. Langmuir 20: 5837 – 5845 (2004).