CP Chemistry Unit 1 Test Review KEY Problems and questions: 1. Round each of the following numbers to 3 significant figures: a) .09882 .0988 b) 123,459 123,000 c) 102.45 102 d) 2.301 x 10-3 2.30 x 10-3 2. Calculate, use sig figs: (12.22 x 14.02 x 120.1 x .555) / 10.00 = 3. A sample of metal having a mass of 12.122 g is added to a graduated cylinder containing 35.2 mL of water. The water level rises to 38.4mL. Calculate the density, use correct significant figures. 𝒅= 4. 1140 𝟏𝟐. 𝟏𝟐𝟐 = 𝟑. 𝟖 𝒈/𝒎𝑳 𝟑. 𝟐 Calculate the % error for an experiment where the student measured 3.45 g and the actual value was 3.00 g? %𝒆𝒓𝒓𝒐𝒓 = |𝟑. 𝟒𝟓 𝒈−. 𝟑. 𝟎𝟎𝒈| × 𝟏𝟎𝟎 = 𝟏𝟓. 𝟎% (𝟑. 𝟎𝟎𝒈) 5. Write the symbol for the following ions: Mg losing 2 e-, Al losing 3 e-, N gaining 3 e-, S gaining 2 eMg2+, Al3+, N3-, S2- 6. 7. a) 2 b) 3 c) 12 d) 5 List three points of Dalton’s atomic theory. A. Elements made of tiny particles, called atoms B. Atoms of a given element are identical; the atoms of different elements are different. C. In chemical reactions, atoms are combined, separated, or rearranged. Atoms cannot be subdivided, created, or destroyed. D. Atoms combine with atoms, in small whole numbers, to form compounds. 8. Describe Thompson’s experiment with the cathode ray tube, what did he discover? Cathode ray tube consists of a cathode (negative) and anode (positive) side. The “ray” could be bent with magnetic or electric fields. The “ray” bent toward a positive EM field and away from a negative EM field. Discovered electron and charge to mass ration of electron. 9. Describe Millikan’s Oil Drop experiment. What exactly did he determine? He suspended a micro oil droplet in an electric field and was able to determine the actual charge of an electron to be -1.6 x 10-19 C. Also, determined the mass of an electron. 10. Explain Rutherford’s Gold Foil experiment. What were three observations and three conclusions? He fired alpha particles at fold foil and observed: 1) most went straight through, 2) small number showed a slight deflection, 3) very few bounced straight back. He concluded: 1) mass of atom is in the nucleus, 2) nucleus is positively charged, 3) atom mostly empty space. 11. What is an isotope? Atoms of the same element that differ by # of electrons. 12. Write the symbol of the most abundant copper isotope if the average atomic mass is 63.55? 𝟔𝟒 𝟐𝟗𝑪𝒖 13. Write the nuclear symbol for an isotope with Z=40, and 45 neutrons? 𝟖𝟓 𝟒𝟎𝒁𝒓 14. Consider the diagram and match the letters with the appropriate particle A= electron, B= neutron, C= proton 15. Place the forms of hydrogen (H, H+, H-, H2) in the table. Atom Cation + H H Anion H Molecule H2 1 16. Symbol Mass (amu) Mass in (g) Charge Location Who Discovered proton p+ 1 1.67 x 10-24 g 1 nucleus Rutherford neutron n0 1 1.67 x 10-24 g 0 nucleus Chadwick electron e- 0 9.11 x 10-28 g -1 nucleus Thompson 17. mass molar mass # moles #atoms, molecules 2.50 g NH3 17.04 g/mol 0.15 moles NH3 8.8x1022 molecules NH3 55.85 g/mol 0.50 moles Fe atoms 3.01x1023 atoms Fe 3.07 moles CO2 1.85x1024 molecules CO2 27.93 g Fe 44.01 g/mol 135.25 g CO2 18. sdf Z CO2 𝐴 𝑍𝑋 A p+ n0 e- 23 43 23 20 23 43 23𝑉 35 71 35 36 35 71 35𝐵𝑟 15 31 15 16 15 31 15𝑃 symbol 19. What is the unit used to measure masses of atoms and what is it based upon? the atomic mass unit (amu) is based on 1/12 the mass of a C-12 isotope. 20. Describe the two forces involved in containing protons and neutrons in the nucleus of an atom. The electromagnetic force is responsible for the protons in a nucleus repelling, the range is infinite. The strong nuclear force attracts protons and neutrons, but it has a very short range force. 21. The electromagnetic force is stronger than the strong nuclear force and the nucleus breaks apart releasing radiation. 22. The half-life of 210 83 Bi is 1.0 year. If you begin with 500g of this isotope, how many grams will you have left 1 decade later 𝑵 = (𝟓𝟎𝟎). 𝟓𝟏𝟎 = . 𝟒𝟗𝒈 23. The half-life of francium is 21 minutes. Starting with 4x1018 atoms of francium, how many atoms would disintegrate in 1 hour and 45 minutes? What fraction of the original sample remains? 105 21 N = (4x10 ).5 18 =1.25x1017 24. If 87.5 % of a sample of pure Pb-210 decays in 36 days, what is the half-life of Pb-210? 100---50---25---12.5; if only 12.5% remains that means 87.5% has decayed. 36 divided by 3 ½ lives, is 12 days. 25. Calculate the average atomic mass of the following atom: Zn-64 63.95 amu 38.25% Zn-65 64.02 amu 6.25% Zn-66 65.22 amu 55.50% (63.95x.3825) + (64.02x.0625) + (65.22x.555)= 64.66 amu 2 3 4 5