Texas Commission on Environmental Quality Hazardous Air Pollutants Reference Table (HAPS-RT) for Air Quality Permits This document is used to help facilitate the submission of air quality permit application forms for sources subject to Title 40 Code of Federal Regulations Part 63 (40 CFR Part 63). The Hazardous Air Pollutants (HAPs) list is found in §112(b) of the Federal Clean Air Act and revisions to this list are found in 40 CFR Part 63, Subpart C. CAS No. 75070 60355 75058 98862 53963 107028 79061 79107 Pollutant Acetaldehyde Acetamide Acetonitrile Acetophenone 2-Acetylaminofluorene Acrolein Acrylamide Acrylic acid CAS No. 79118 532274 108907 510156 67663 107302 126998 1319773 107131 107051 92671 62533 90040 Acrylonitrile Allyl chloride 4-Aminobiphenyl Aniline o-Anisidine 95487 108394 106445 98828 94757 1332214 Asbestos 3547044 71432 334883 92875 98077 100447 92524 117817 542881 Benzene (including benzene from gasoline) Benzidine Benzotrichloride Benzyl chloride Biphenyl Bis (2-ethylhexyl) phthalate (DEHP) Bis (chloromethyl) ether 75252 106990 156627 133062 63252 75150 Bromoform 1,3-Butadiene Calcium cyanamide Captan Carbaryl Carbon disulfide 542756 62737 111422 121697 64675 119904 132649 96128 84742 106467 91941 111444 TCEQ - 20169ctbl (APDG 5271v5, Revised 05/14) HAPS Reference Table This table is for use by facilities subject to air quality permit requirements and may be revised periodically Pollutant Chloroacetic acid 2-Chloroacetophenone Chlorobenzene Chlorobenzilate Chloroform Chloromethyl methyl ether Chloroprene Cresols/Cresylic acid (isomers and mixture) o-Cresol m-Cresol p-Cresol Cumene 2,4-D (2,4-Dichlorophenoxyacetic Acid) (including salts and esters) DDE (1,1-dichloro-2,2-bis(p-chlorophenyl) ethylene) Diazomethane Dibenzofuran 1,2-Dibromo-3-chloropropane Dibutylphthalate 1,4-Dichlorobenzene (p) 3,3-Dichlorobenzidene Dichloroethyl ether (Bis[2-chloroethyl]ether) 1,3-Dichloropropene Dichlorvos Diethanolamine N,N-Diethyl aniline (N,N-Dimethylaniline) Diethyl sulfate 3,3-Dimethoxybenzidine Page 1 of 5 Texas Commission on Environmental Quality Hazardous Air Pollutants Reference Table (HAPS-RT) for Air Quality Permits CAS No. 56235 463581 120809 133904 57749 7782505 77781 534521 51285 121142 123911 122667 106898 106887 140885 100414 51796 75003 106934 107062 107211 151564 75218 96457 75343 50000 76448 118741 87683 77474 67721 822060 680319 Pollutant Carbon tetrachloride Carbonyl sulfide Catechol Chloramben Chlordane Chlorine Dimethyl sulfate 4,6-Dinitro-o-ocresol (including salts) 2,4-Dinitrophenol 2,4-Dinitrotoluene 1,4-Dioxane (1,4-Diethyleneoxide) 1,2-Diphenylhydrazine Epichlorohydrin (1-Chloro-2,3-epoxypropane) 1,2-Epoxybutane Ethyl acrylate Ethyl benzene Ethyl carbamate (Urethane) Ethyl chloride (Chloroethane) Ethylene dibromide (Dibromoethane) Ethylene dichloride (1,2-Dichloroethane) Ethylene glycol Ethylene imine (Aziridine) Ethylene oxide Ethylene thiourea Ethylidene dichloride (1,1-Dichloroethane) Formaldehyde Heptachlor Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexamethylene-1,6-diisocyanate Hexamethylphosphoramide CAS No. 60117 119937 79447 68122 57147 131113 74839 74873 71556 60344 74884 108101 624839 Pollutant Dimethyl aminoazobenzene 3,3'-Dimethyl benzidine Dimethyl carbamoyl chloride Dimethyl formamide 1,1-Dimethyl hydrazine Dimethyl phthalate Methyl bromide (Bromomethane) Methyl chloride (Chloromethane) Methyl chloroform (1,1,1-Trichloroethane) Methyl hydrazine Methyl iodide (Iodomethane) Methyl isobutyl ketone (Hexone) Methyl isocyanate 80626 1634044 101144 75092 101688 101779 91203 98953 92933 100027 79469 684935 Methyl methacrylate Methyl tert butyl ether 4,4-Methylene bis (2-chloroaniline) Methylene chloride (Dichloromethane) Methylene diphenyl diisocyanate (MDI) 4,4'-Methylenedianiline Naphthalene Nitrobenzene 4-Nitrobiphenyl 4-Nitrophenol 2-Nitropropane N-Nitroso-N-methylurea 62759 59892 56382 82688 87865 108952 106503 75445 N-Nitrosodimethylamine N-Nitrosomorpholine Parathion Pentachloronitrobenzene (Quintobenzene) Pentachlorophenol Phenol p-Phenylenediamine Phosgene TCEQ - 20169ctbl (APDG 5271v5, Revised 05/14) HAPS Reference Table This table is for use by facilities subject to air quality permit requirements and may be revised periodically Page 2 of 5 Texas Commission on Environmental Quality Hazardous Air Pollutants Reference Table (HAPS-RT) for Air Quality Permits CAS No. 110543 302012 7647010 7664393 123319 78591 58899 108316 67561 72435 75558 91225 106514 100425 96093 1746016 79345 Pollutant 127184 CAS No. Hexane 7803512 Hydrazine 7723140 Hydrochloric acid 85449 Hydrogen fluoride (Hydrofluoric acid) 1336363 Hydroquinone 1120714 Isophorone 57578 Lindane (all isomers) 123386 Maleic anhydride 114261 Methanol 78875 Methoxychlor 75569 1,2-Propylenimine (2-Methyl aziridine) 75014 Quinoline 75354 Quinone 1330207 Styrene 95476 Styrene oxide 108383 2,3,7,8-Tetrachlorodibenzo-p-dioxin 106423 1,1,2,2-Tetrachloroethane Antimony Compounds Tetrachloroethylene (Perchloroethylene) Arsenic Compounds 7550450 Titanium tetrachloride 108883 Toluene 95807 2,4-Toluene diamine 584849 95534 2,4-Toluene diisocyanate o-Toluidine 8001352 Toxaphene (chlorinated camphene) Beryllium Compounds Cadmium Compounds Chromium Compounds Cobalt Compounds Coke Oven Emissions Cyanide Compounds Pollutant Phosphine Phosphorus Phthalic anhydride Polychlorinated biphenyls (Aroclors) 1,3-Propane sultone beta-Propiolactone Propionaldehyde Propoxur (Baygon) Propylene dichloride (1,2-Dichloropropane) Propylene oxide Vinyl chloride Vinylidene chloride (1,1-Dichloroethylene) Xylenes (isomers and mixture) o-Xylenes m-Xylenes p-Xylenes Antimony Compounds Arsenic Compounds (inorganic including arsine) Beryllium Compounds Cadmium Compounds Chromium Compounds Cobalt Compounds Coke Oven Emissions Cyanide Compounds 1 1 120821 79005 79016 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane Trichloroethylene Glycol ethers2 Lead Compounds Manganese Compounds TCEQ - 20169ctbl (APDG 5271v5, Revised 05/14) HAPS Reference Table This table is for use by facilities subject to air quality permit requirements and may be revised periodically Glycol ethers2 Lead Compounds Manganese Compounds Page 3 of 5 Texas Commission on Environmental Quality Hazardous Air Pollutants Reference Table (HAPS-RT) for Air Quality Permits CAS No. 95954 88062 121448 1582098 Pollutant 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Triethylamine Trifluralin 540841 2,2,4-Trimethylpentane 108054 Vinyl acetate 593602 Vinyl bromide CAS No. Mercury Compounds Fine mineral fibers3 Nickel Compounds Polycyclic Organic Matter4 Radionuclides (including radon)5 Selenium Compounds Pollutant Mercury Compounds Fine mineral fibers 3 Nickel Compounds Polycyclic Organic Matter 4 Radionuclides (including radon) 5 Selenium Compounds For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) as part of that chemical's infrastructure. 1 2 3 4 X'CN where X = H' or any other group where a formal dissociation may occur. For example KCN or Ca(CN)2 Glycol ethers include mono- and di-ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n-OR′. Where: n = 1, 2, or 3; R = alkyl C7 or less; or R = phenyl or alkyl substituted phenyl; R′= H or alkyl C7 or less; or OR′ consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate. Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less. Includes organic compounds with more than one benzene ring, and which have a boiling point greater than or equal to 100 º C. TCEQ - 20169ctbl (APDG 5271v5, Revised 05/14) HAPS Reference Table This table is for use by facilities subject to air quality permit requirements and may be revised periodically Page 4 of 5 Texas Commission on Environmental Quality Hazardous Air Pollutants Reference Table (HAPS-RT) for Air Quality Permits 5 A type of atom which spontaneously undergoes radioactive decay. The substance caprolactam (CAS number 105602) is deleted from the list of hazardous air pollutants established by 42 U.S.C. 7412(b)(1). [61 FR 30823, June 18, 1996] The substance methyl ethyl ketone (MEK, 2-Butanone) (CAS Number 78933) is deleted from the list of hazardous air pollutants established by 42 U.S.C. 7412(b)(1). [70 FR 75059, December 19, 2005] The substance ethylene glycol monobutyl ether (EGBE, 2-Butoxyethanol) (CAS Number 111762) is deleted from the list of hazardous air pollutants established by 42 U.S.C. 7412(b)(1). [69 FR 69325, November 29, 2004] A clerical error led to the inadvertent addition of hydrogen sulfide to the Section 112(b) list of Hazardous Air Pollutants. However, a Joint Resolution to remove hydrogen sulfide from the Section 112(b)(1) list was passed by the Senate on August 1, 1991 (Congressional Record page S11799), and the House of Representatives on November 25, 1991 (Congressional Record pages H11217-H11219). The Joint Resolution was approved by the President on December 4, 1991. Hydrogen Sulfide is included in Section 112(r) and is subject to the accidental release provisions. A study (see below) was required under Section 112(n)(5). Hydrogen Sulfide Air Emissions Associated with the Extraction of Oil and Natural Gas, EPA-453/R-93-045, NTIS (publication number is PB94-131224, $36.50 hard copy, $17.50 microfiche). National Technical Information Services (NTIS) 5285 Port Royal Road Springfield, VA 22161 703-487-4650 800-426-4791 703-487-4807 8:30-5:30 EST M-F TCEQ - 20169ctbl (APDG 5271v5, Revised 05/14) HAPS Reference Table This table is for use by facilities subject to air quality permit requirements and may be revised periodically Page 5 of 5