GEOLOGY 235 (2015) LAB 5 PYROCLASTIC MAGMATISM Introduction: Silicic volcanism is common on the continents, and the subject of this week’s lab. Most volcanism on the continents is related to either subduction or rifting; however, much of the recent volcanism in the western U. S. is not clearly related to either tectonic process. One school of thought is that silicic volcanism in "fundamentally basaltic" in the sense that the heat energy and mass flux necessary to produce it are mainly derived from basaltic magma which migrates upward from the mantle and into the upper crust. In terms of volume most rhyolitic volcanic centers are "bimodal", in other words, they are composed mainly of basalt and rhyolite, with lesser amounts of intermediate composition rocks. Magma viscosity (which is a function of melt composition and temperature), as discussed in lecture, is a key control on the nature of volcanic eruption style. Silicic magmas are extremely viscous due to the highly polymerized nature of high-silicate melts. They are also relatively rich in volatile components relative to more mafic magmas since volatiles are fractionated into the liquid during crystallization of anhydrous minerals like plagioclase, olivine, pyroxenes, and opaque oxides. Due to their high volatile content and high viscosity silicic eruptions are often explosive, giving rise to pyroclastic deposits. Pyroclastic rocks have a wide array of textures resulting from the highly variable nature of their eruption, temperature, transport, and deposition. Hopefully this lab exercise will give you a feel for their variability, and an understanding of some of the key factors controlling it. Silicic magmas can also erupt as flows but displaying different characteristics from mafic flows due to their higher viscosities. Steep sided domes and short blocky flows are the most commonly observed forms. Textures developed in lava flows are usually distinct from those produced by pyroclastic eruption, but are similar enough that larger scale (field) relations are often necessary to distinguish a tuff from a lava flow. This lab is divided into three sections. In the first a suite of samples from the Long Valley Caldera is provided. This includes several samples of the Bishop Tuff that illustrate the general character of ash flows (ignimbrite). The chemistry of these rocks is typical of continental margin silicic volcanism. A diagram illustrating the textural zones developed in welded tuffs are also provided (Fig. 1). Use the Bishop Tuff samples to get familiar with the features of welded ash flow tuffs. In the second section there is a suite of andesitic ash-flow tuffs (nuee ardente deposits) from Martinique. They are included to stress that not all pyroclastic deposits are rhyolitic. In the third section there are some samples of silicic lava. You should learn to distinguish their textural features from ash flow textures. Long Valley Caldera and the Bishop Tuff, California Silicic pyroclastic eruptions are the largest of terrestrial eruptions often producing several hundred cubic kilometers of tephra in a matter of days to weeks. The venting of such huge quantities of magma is usually accompanied by collapse of the roof of the magma chamber thus producing a caldera. The Bishop Tuff, erupted 700,000 years ago, provides an excellent example of a large (roughly 200 km3) ash flow tuff. Since ash flow tuffs represent "inverted versions" of rapidly evacuated silicic magma chambers they can tell us things about compositional and physical gradients that existed in those chambers. The Bishop Tuff is probably the most thoroughly studied ash flow in the world. Detailed study has shown that the Bishop Tuff magma chamber was thermally zoned from 720 to 790o C. The observed mineral assemblage, trace element, and volatile content also change systematically from top to bottom. Silicic Lava Flows and Domes Silicic lava flows lose most of their volatiles on eruption and move as a very sluggish fluid with yield strength. Their outer carapace is usually quenched to a glass but, if large, the inner portion of the flow devitrifies. The basal and upper portions of the flow show variable degrees of self-brecciation or flow breccia. During lava flow, banding usually develops. Flow banding is more continuous than the "streaky banding" that characterizes welded ash flows. ASSIGNMENT In the process of studying these rocks in hand sample and in thin section, please complete a full petrographic report on CA-10 (include in petrographic report, labeled ignimbrite diagram, and the answers in your lab hand-in). 1.a) General Features of Silicic Tuffs Bishop Tuff, California. Name all the samples (hint: use the terms provided in Fig. 1). Provide a detailed name that describes the degree of welding, whether it’s glassy and/or if there is devitrification observed. CA-12: . Note this sample is vitrophyric composed of compressed pumice fragments, ash (glassy shards), crystals, and lithic fragments. The pumice lumps and shards are defined by very fine-grained dust and iron oxides that coat their surfaces. Also notice that many of the phenocrysts are broken. This probably was caused by the force of eruption. CA-16B: . This portion of the tuff stayed hot long enough after eruption for devitrification to occur. Most of the pumice and glass shards have converted to very fine-grained intergrowths of alkali feldspar, quartz, and iron oxides. Sketch an example of a devitrification texture. CA-8: . Note that the pumice fragments show less compaction than in the first two samples. What is the phenocryst assemblage? CA-16F: biotite and clay/calcite alteration CA-14: . Note the late stage oxidation of . 1b) Answer the questions for each sample below. RTG: This rhyolite is glassy and displays flow banding. What defines the bands? Examine the hand samples of glassy lava and the thin sections. Question: In one hand sample there are round grey ‘balls’, they are spherulites. How could they form? RTD: This rhyolite is a devitrified equivalent to RTG above. Examine the hand samples of the glassy lava (RTG) and the devitrified equivalent (RTD). Question: Which would weather more easily and therefore be less likely to be preserved in the rock record? CA-10: This rhyolite is from a dome at Long Valley, California. Question: What is the phenocryst assemblage? Figure 1: Cross section through a pyroclastic flow deposit. On the diagram below, place CA-12, CA-16B, CA-8, CA-16F and CA-14 in the most likely locations on the diagram below. Hand in your diagrams with your lab with a BRIEF explanation as to your rock sample placement. 2. Andesitic Pyroclastic and Lahar Deposits Lahars are volcanic mudflows that are emplaced at room temperature. They form the rock agglomerate that is typically polymict with heterogeneous unsupported clasts (up to several feet in diameter) in a finer, unsorted, matrix. Deposits formed by nuee ardentes (glowing cloud) or glowing avalanche eruptions are poorly sorted (gas-charged) material, emplaced at a moderately high temperature (but less than lava flows). During deposition the lava clasts continue to effervesce releasing hot gases which help cushion the avalanche deposit as it moves down slope at speeds in excess of 100 km/hr. Nuee ardentes of the Pelean type are fairly small eruptions, often following stream valleys on the sides of the volcano. The rock type produced is agglomerate similar to lahar except that the clasts are >90X of one rock type (they may be up to 40 ft long!). These deposits have degassing pipes through which the fines have been expelled along with the gas from the effervescing rock. Later infilling with other detritus "fossilizes" this feature. This is the definitive feature distinguishing nuee ardentes from lahars but it may be difficult to find examples of it. "The Killer Rock" of Martinique, Lesser Antilles M-10, M-11 and M-16: These are clasts of vesicular andesite (are they all the same rock?) from the 1902 eruption of Mt Pele which devastated St Pierre, killing 30,000 people (only 2 survived). There were many individual nuee ardentes during the 1902 eruption; these particular samples come from R. Claire, just north of St Pierre. In thin section, note that this material is not pumiceous. The vesicles are not round bubbles of glass; instead they are irregular, elongate, and very probably interconnected. Thus the rock is very porous and the enclosed gas was able to escape during eruption (with catastrophic results). Exercise: Provide a brief description that outlines the key features of each sample and indicate how they are different. How might understanding these rock types and textures help to interpret the threat level of volcanoes that are in proximity to major population centers throughout the world? Also, where might you expect these types of eruptions to occur elsewhere in the world? Provide two potential locations and a reasoning statement.