Electronic Supplementary Material for
Calorimetric Study on the Ion Pairing and Aggregation of
1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([C2mim][NTf2]) and
Related Ionic Liquids in the Low-Dielectric Solvent Chloroform
Nathan T. Scharf1, Annegret Stark2, Markus M. Hoffmann1,*
1
Department of Chemistry, The College at Brockport, State University of New York, Brockport,
NY, 14420, USA.
2
Institute for Chemical Technology, Universität Leipzig, Linnéstr 3-4, 04107 Leipzig, Germany.
425
Mass (g)
420
y = -1.983x + 428.16
R² = 0.9983
415
25°C
45°C
410
0
2
4
6
8
Trial Number
Fig. S1: Chloroform masses of successive filling and emptying of reaction calorimeter vessel at
25°C. The decline in mass is due to some evaporation of solvent during filling and emptying. The
trend line was used to obtain the expected recovered chloroform mass at the 7th filling and
emptying of the reaction vessel. The mass of recovered chloroform was lower because the reactor
vessel was heated and equilibrated to 45°C before emptying and more chloroform remained in
the vessel because it condensed at the colder top walls of the reaction vessel. The mass loss of
chloroform due to evaporation at 45°C was thus found to be 2.48g or 0.0208mol based on the
difference between the extrapolated value from the trend line and the actual mass of collected
chloroform at 45°C.
1
As shown in Fig. S1, we accounted for the loss of solvent during experimentation at elevated temperatures
due to condensation onto the colder reactor lid. For the experiments with added acetone the condensate is no
longer a pure solvent and we would like to briefly address in how far this would affect the solvent
composition. For simplicity we assume the mixed solvent to behave ideal and therefore apply Raoult’s law as
shown in equation (S1) to obtain the partial pressures, Pj, of the two components from the mole fractions, xj,
and the vapor pressures, Pj* and to predict the relative amounts that condense for the two components in the
mixture.
𝑃𝑗 = 𝑥𝑗 𝑃𝑗∗
(S1)
We further assume that the same number of molecules condense on the walls of the vessel at higher
temperatures as we determined for pure chloroform.
The vapor pressures of pure chloroform and acetone needed in equation 2 can be obtained from the Antoine
equation, shown in equation S2, where the needed Antoine coefficients were obtained from the literature (D.
R. Stull, Indust. Engin. Chem. 39, 517-540 (1947); D. Ambrose, C. H. S. Sprake, and T. R., J. Chem. Thermodyn. 6,
693-700 (1974).
𝐵
𝑙𝑜𝑔10 𝑃(𝑏𝑎𝑟) = 𝐴 − 𝑇(𝐾)+𝐶
(S2)
Specifically, the Antoine coefficients A, B, and C are 4.20772, 1233.129 and -40.953 respectively for CHCl3,
and 4.42448, 1312.253, and -32.445 respectively for acetone. For 318 K the vapor pressure of pure
chloroform amounts to 0.574 bar and for acetone 0.678 bar. The partial pressures for each compound were
calculated using equation S1 and added to obtain the total vapor pressure. The mole fractions of the vapor
phase, yi, were calculated using Dalton’s law as the ratio of partial pressure and total vapor pressure Ptot, as
shown in equation S3
𝑦𝑖 =
𝑥𝑖 𝑃𝑖∗
𝑃𝑡𝑜𝑡
(S3)
Since we assume same number of molecules condense as we determined for pure chloroform, the amount of
each component that forms condensation can be directly calculated. At 318.2K, xi was 0.0442 while the
corrected value would be 0.0444. This results in a difference of only 0.46%. For CHCl 3 the percent
difference between corrected and uncorrected xi is even less, since the relative amount of CHCl3 is much
higher. Since there is no significant difference in the concentrations from the partial pressures, the original
concentration of mixed solvent added was used for calculations.
2
Temperature of the reactor, Tr (°C)
25.029
25.024
25.019
25.014
25.009
25.004
24.999
5600
5610
5620
5630
5640
5650
5660
5670
5680
Time (s)
Fig. S2: Temperature versus time of a 0.8 mL injection of [C2mim][NTf2] into
CHCl3 at 25°C. The change in temperature is 0.029°C.
Table S1: Heat capacity data from Differential Scanning Calorimetry
[C6mim][CTf3]
[C6mim][NTf2]
T/
Cp/
T/
Cp/
T/
Cp/
T/
Cp/
-1 -1
-1 -1
-1 -1
K
J·g ·k
K
J·g ·k
K
J·g ·k
K
J·g-1·k-1
run 1
run 2
run 1
run 2
286.19
1.261
286.18
1.259
286.20
1.399
286.18
1.400
286.25
1.261
286.25
1.260
286.27
1.399
286.25
1.401
286.31
1.262
286.31
1.261
286.33
1.400
286.31
1.402
286.38
1.264
286.37
1.262
286.39
1.400
286.37
1.402
286.44
1.264
286.43
1.262
286.45
1.400
286.43
1.402
286.50
1.264
286.50
1.261
286.52
1.400
286.50
1.402
286.57
1.264
286.56
1.261
286.58
1.399
286.56
1.402
286.63
1.266
286.62
1.264
286.64
1.400
286.62
1.403
286.69
1.267
286.69
1.265
286.71
1.400
286.69
1.404
286.76
1.269
286.75
1.267
286.77
1.401
286.75
1.404
286.82
1.269
286.81
1.268
286.83
1.401
286.81
1.404
286.88
1.270
286.88
1.269
286.90
1.401
286.88
1.404
286.95
1.270
286.94
1.270
286.96
1.401
286.94
1.404
287.01
1.271
287.00
1.271
287.02
1.401
287.00
1.404
287.07
1.270
287.07
1.270
287.09
1.402
287.07
1.403
287.14
1.271
287.13
1.270
287.15
1.402
287.13
1.403
287.20
1.272
287.19
1.271
287.22
1.401
287.20
1.403
[C2mim][NTf2]
T/
Cp/
K
J·g-1·k-1
286.19
286.25
286.31
286.37
286.44
286.50
286.56
286.63
286.69
286.75
286.82
286.88
286.94
287.01
287.07
287.14
287.20
1.298
1.296
1.295
1.296
1.297
1.297
1.296
1.295
1.295
1.295
1.294
1.294
1.294
1.294
1.294
1.295
1.295
3
287.27
287.33
287.39
287.46
287.52
287.59
287.65
287.72
287.78
287.85
287.91
287.97
288.04
288.10
288.16
288.23
288.29
288.36
288.42
288.49
288.55
288.62
288.68
288.75
288.81
288.88
288.94
289.01
289.07
289.14
289.20
289.27
289.33
289.40
289.46
289.53
289.59
289.66
289.73
289.79
289.85
289.92
289.98
1.272
1.273
1.273
1.273
1.273
1.273
1.274
1.276
1.275
1.275
1.275
1.276
1.277
1.278
1.279
1.278
1.278
1.278
1.279
1.280
1.279
1.279
1.279
1.280
1.281
1.280
1.281
1.282
1.282
1.281
1.281
1.281
1.282
1.282
1.282
1.281
1.281
1.281
1.281
1.281
1.281
1.281
1.282
287.26
287.32
287.39
287.45
287.51
287.58
287.64
287.71
287.77
287.84
287.90
287.97
288.03
288.09
288.16
288.22
288.29
288.35
288.42
288.48
288.54
288.61
288.68
288.74
288.81
288.87
288.93
289.00
289.07
289.13
289.19
289.26
289.33
289.39
289.46
289.52
289.59
289.65
289.72
289.78
289.84
289.91
289.98
1.272
1.274
1.275
1.274
1.273
1.274
1.275
1.276
1.276
1.276
1.275
1.276
1.278
1.279
1.279
1.278
1.278
1.279
1.278
1.279
1.278
1.278
1.279
1.281
1.282
1.281
1.281
1.282
1.282
1.283
1.282
1.282
1.283
1.283
1.284
1.283
1.283
1.282
1.281
1.282
1.282
1.281
1.282
287.28
287.34
287.41
287.47
287.54
287.60
287.67
287.73
287.79
287.86
287.92
287.99
288.05
288.12
288.18
288.25
288.31
288.37
288.44
288.51
288.57
288.63
288.70
288.76
288.83
288.89
288.96
289.02
289.09
289.15
289.22
289.28
289.35
289.41
289.48
289.54
289.61
289.67
289.74
289.80
289.87
289.93
290.00
1.402
1.402
1.403
1.403
1.404
1.404
1.403
1.403
1.402
1.402
1.402
1.403
1.403
1.403
1.403
1.403
1.405
1.404
1.403
1.404
1.404
1.405
1.404
1.404
1.404
1.402
1.403
1.404
1.405
1.406
1.405
1.404
1.404
1.403
1.403
1.405
1.406
1.405
1.405
1.406
1.406
1.406
1.406
287.26
287.32
287.39
287.45
287.52
287.58
287.64
287.71
287.77
287.84
287.90
287.97
288.03
288.10
288.16
288.23
288.29
288.35
288.42
288.48
288.55
288.61
288.68
288.74
288.81
288.87
288.94
289.00
289.07
289.13
289.20
289.26
289.33
289.39
289.46
289.52
289.59
289.65
289.72
289.78
289.85
289.92
289.98
1.403
1.404
1.405
1.406
1.406
1.406
1.405
1.404
1.404
1.403
1.404
1.405
1.405
1.405
1.406
1.405
1.406
1.405
1.404
1.404
1.404
1.405
1.404
1.404
1.405
1.404
1.404
1.405
1.406
1.406
1.406
1.405
1.405
1.404
1.405
1.406
1.407
1.407
1.406
1.407
1.407
1.407
1.407
287.26
287.33
287.39
287.46
287.52
287.58
287.65
287.71
287.78
287.84
287.91
287.97
288.03
288.10
288.16
288.23
288.29
288.36
288.42
288.49
288.55
288.62
288.68
288.75
288.81
288.88
288.94
289.01
289.07
289.14
289.20
289.26
289.33
289.40
289.46
289.53
289.59
289.66
289.72
289.79
289.85
289.92
289.98
1.294
1.294
1.294
1.294
1.295
1.294
1.293
1.296
1.298
1.299
1.296
1.294
1.292
1.292
1.293
1.293
1.294
1.294
1.294
1.294
1.295
1.296
1.296
1.297
1.297
1.297
1.297
1.297
1.296
1.295
1.295
1.295
1.294
1.295
1.297
1.297
1.293
1.294
1.294
1.295
1.296
1.297
1.296
4
290.05
290.11
290.18
290.24
290.31
290.37
290.44
290.50
290.57
290.63
290.70
290.77
290.83
290.90
290.96
291.03
291.09
291.15
291.22
291.28
291.35
291.42
291.48
291.55
291.61
291.68
291.74
291.81
291.87
291.94
292.00
292.07
292.13
292.20
292.26
292.33
292.39
292.46
292.53
292.59
292.66
292.72
292.79
1.282
1.282
1.283
1.283
1.282
1.282
1.282
1.282
1.283
1.282
1.283
1.284
1.285
1.283
1.283
1.282
1.282
1.284
1.284
1.284
1.284
1.283
1.284
1.285
1.285
1.285
1.285
1.284
1.285
1.286
1.288
1.289
1.289
1.288
1.287
1.286
1.286
1.285
1.285
1.286
1.285
1.285
1.285
290.04
290.11
290.17
290.23
290.30
290.37
290.43
290.50
290.56
290.63
290.69
290.76
290.82
290.89
290.95
291.02
291.08
291.15
291.21
291.28
291.35
291.41
291.47
291.54
291.61
291.67
291.74
291.80
291.87
291.93
292.00
292.06
292.13
292.19
292.26
292.32
292.39
292.45
292.52
292.58
292.65
292.71
292.78
1.284
1.284
1.284
1.283
1.283
1.282
1.282
1.283
1.283
1.282
1.283
1.284
1.285
1.284
1.285
1.285
1.284
1.286
1.286
1.285
1.285
1.285
1.285
1.285
1.286
1.286
1.286
1.285
1.286
1.288
1.289
1.289
1.288
1.287
1.287
1.286
1.287
1.288
1.288
1.288
1.286
1.285
1.286
290.06
290.13
290.19
290.26
290.32
290.39
290.45
290.52
290.58
290.65
290.71
290.78
290.84
290.91
290.98
291.04
291.11
291.17
291.24
291.30
291.37
291.43
291.50
291.56
291.63
291.69
291.76
291.82
291.89
291.95
292.02
292.09
292.15
292.21
292.28
292.35
292.41
292.48
292.54
292.61
292.67
292.74
292.80
1.405
1.406
1.406
1.405
1.404
1.406
1.406
1.406
1.407
1.407
1.407
1.408
1.407
1.407
1.406
1.406
1.407
1.407
1.408
1.409
1.407
1.406
1.405
1.406
1.407
1.407
1.408
1.408
1.408
1.408
1.407
1.409
1.408
1.407
1.406
1.405
1.407
1.408
1.408
1.408
1.408
1.407
1.407
290.04
290.11
290.17
290.24
290.30
290.37
290.43
290.50
290.57
290.63
290.69
290.76
290.82
290.89
290.95
291.02
291.09
291.15
291.22
291.28
291.35
291.41
291.48
291.54
291.61
291.67
291.74
291.80
291.87
291.93
292.00
292.06
292.13
292.19
292.26
292.32
292.39
292.46
292.52
292.59
292.65
292.72
292.78
1.407
1.407
1.407
1.407
1.406
1.407
1.407
1.407
1.408
1.407
1.408
1.409
1.409
1.408
1.408
1.408
1.408
1.408
1.410
1.410
1.409
1.408
1.407
1.407
1.408
1.407
1.409
1.409
1.409
1.408
1.408
1.410
1.409
1.408
1.406
1.406
1.407
1.409
1.409
1.409
1.409
1.408
1.408
290.05
290.11
290.18
290.24
290.31
290.37
290.44
290.50
290.57
290.63
290.70
290.76
290.83
290.89
290.96
291.02
291.09
291.15
291.22
291.28
291.35
291.42
291.48
291.55
291.61
291.68
291.74
291.81
291.87
291.94
292.00
292.07
292.13
292.20
292.26
292.33
292.39
292.46
292.52
292.59
292.65
292.72
292.78
1.296
1.295
1.296
1.297
1.298
1.297
1.296
1.295
1.293
1.295
1.296
1.296
1.295
1.296
1.297
1.296
1.297
1.297
1.297
1.297
1.296
1.296
1.296
1.297
1.299
1.298
1.296
1.295
1.295
1.295
1.296
1.298
1.297
1.297
1.296
1.295
1.295
1.295
1.295
1.298
1.297
1.297
1.295
5
292.85
292.92
292.98
293.05
293.11
293.18
293.24
293.31
293.37
293.44
293.51
293.57
293.64
293.70
293.77
293.83
293.90
293.96
294.03
294.09
294.16
294.22
294.29
294.35
294.42
294.49
294.55
294.62
294.68
294.75
294.81
294.88
294.94
295.01
295.07
295.14
295.21
295.27
295.34
295.40
295.47
295.53
295.60
1.285
1.286
1.286
1.286
1.286
1.286
1.287
1.286
1.286
1.286
1.288
1.288
1.287
1.287
1.286
1.285
1.287
1.287
1.287
1.288
1.288
1.288
1.287
1.287
1.287
1.288
1.289
1.289
1.289
1.290
1.289
1.290
1.290
1.291
1.289
1.289
1.289
1.290
1.290
1.290
1.290
1.290
1.291
292.85
292.91
292.98
293.04
293.11
293.17
293.24
293.30
293.37
293.43
293.50
293.56
293.63
293.69
293.76
293.82
293.89
293.96
294.02
294.09
294.15
294.22
294.28
294.35
294.41
294.48
294.54
294.61
294.67
294.74
294.80
294.87
294.94
295.00
295.07
295.13
295.20
295.26
295.33
295.39
295.46
295.53
295.59
1.286
1.286
1.287
1.287
1.287
1.287
1.287
1.287
1.288
1.287
1.288
1.289
1.289
1.288
1.287
1.287
1.287
1.287
1.288
1.289
1.290
1.290
1.289
1.289
1.289
1.289
1.290
1.291
1.291
1.291
1.291
1.291
1.291
1.291
1.289
1.289
1.290
1.291
1.291
1.291
1.291
1.291
1.291
292.87
292.93
293.00
293.06
293.13
293.19
293.26
293.32
293.39
293.46
293.52
293.59
293.65
293.72
293.78
293.85
293.91
293.98
294.04
294.11
294.17
294.24
294.30
294.37
294.43
294.50
294.57
294.63
294.70
294.76
294.83
294.89
294.96
295.02
295.09
295.15
295.22
295.29
295.35
295.42
295.48
295.55
295.61
1.408
1.408
1.409
1.410
1.410
1.411
1.411
1.411
1.411
1.411
1.411
1.411
1.412
1.411
1.411
1.411
1.411
1.411
1.411
1.411
1.411
1.410
1.411
1.411
1.411
1.410
1.410
1.410
1.410
1.411
1.411
1.412
1.412
1.411
1.410
1.409
1.411
1.412
1.411
1.411
1.412
1.412
1.409
292.85
292.91
292.98
293.04
293.11
293.17
293.24
293.30
293.37
293.43
293.50
293.57
293.63
293.70
293.76
293.83
293.89
293.96
294.02
294.09
294.15
294.22
294.28
294.35
294.42
294.48
294.55
294.61
294.68
294.74
294.81
294.87
294.94
295.00
295.07
295.13
295.20
295.26
295.33
295.40
295.46
295.53
295.59
1.409
1.410
1.410
1.410
1.410
1.410
1.411
1.410
1.410
1.410
1.410
1.410
1.411
1.411
1.411
1.411
1.411
1.411
1.411
1.411
1.410
1.409
1.409
1.410
1.410
1.410
1.411
1.411
1.410
1.411
1.411
1.411
1.411
1.411
1.410
1.409
1.410
1.411
1.411
1.411
1.412
1.412
1.411
292.85
292.91
292.98
293.05
293.11
293.18
293.24
293.31
293.38
293.44
293.51
293.57
293.63
293.70
293.76
293.83
293.90
293.96
294.03
294.09
294.16
294.22
294.29
294.35
294.42
294.48
294.55
294.61
294.68
294.74
294.81
294.88
294.94
295.01
295.07
295.14
295.21
295.27
295.34
295.40
295.47
295.53
295.60
1.295
1.294
1.294
1.294
1.295
1.295
1.296
1.297
1.298
1.297
1.298
1.297
1.295
1.295
1.295
1.296
1.299
1.299
1.299
1.296
1.297
1.298
1.297
1.295
1.299
1.300
1.299
1.299
1.299
1.298
1.298
1.299
1.301
1.300
1.299
1.299
1.298
1.298
1.298
1.298
1.298
1.296
1.296
6
295.66
295.73
295.79
295.86
295.93
295.99
296.06
296.12
296.19
296.25
296.32
296.38
296.45
296.52
296.58
296.65
296.71
296.77
296.84
296.91
296.97
297.04
297.10
297.17
297.23
297.30
297.37
297.43
297.50
297.56
297.63
297.69
297.76
297.82
297.89
297.95
298.02
298.09
298.15
298.22
298.28
298.35
298.42
1.291
1.291
1.292
1.291
1.290
1.291
1.290
1.290
1.291
1.291
1.291
1.291
1.291
1.291
1.290
1.290
1.290
1.290
1.289
1.288
1.289
1.291
1.293
1.296
1.296
1.294
1.293
1.292
1.292
1.292
1.292
1.292
1.292
1.293
1.293
1.292
1.292
1.293
1.294
1.294
1.294
1.293
1.293
295.66
295.72
295.79
295.85
295.92
295.98
296.05
296.11
296.18
296.24
296.31
296.38
296.44
296.51
296.57
296.64
296.70
296.77
296.83
296.90
296.97
297.03
297.10
297.16
297.23
297.29
297.36
297.42
297.49
297.56
297.62
297.68
297.75
297.82
297.88
297.95
298.01
298.08
298.14
298.21
298.27
298.34
298.41
1.291
1.291
1.291
1.290
1.291
1.292
1.291
1.291
1.291
1.292
1.292
1.293
1.292
1.291
1.292
1.291
1.292
1.292
1.291
1.291
1.293
1.294
1.294
1.295
1.295
1.294
1.293
1.293
1.294
1.294
1.294
1.294
1.293
1.293
1.294
1.293
1.293
1.293
1.293
1.294
1.293
1.293
1.294
295.68
295.74
295.81
295.88
295.94
296.01
296.07
296.14
296.20
296.27
296.33
296.40
296.46
296.53
296.60
296.66
296.72
296.79
296.85
296.92
296.99
297.05
297.12
297.18
297.25
297.32
297.38
297.45
297.51
297.58
297.64
297.71
297.77
297.84
297.90
297.97
298.03
298.10
298.17
298.23
298.30
298.36
298.43
1.409
1.409
1.411
1.412
1.411
1.412
1.413
1.413
1.414
1.414
1.413
1.412
1.412
1.413
1.414
1.413
1.412
1.413
1.415
1.415
1.416
1.415
1.414
1.414
1.416
1.417
1.416
1.416
1.417
1.418
1.416
1.416
1.415
1.415
1.416
1.417
1.418
1.418
1.418
1.417
1.417
1.417
1.417
295.66
295.72
295.79
295.85
295.92
295.98
296.05
296.12
296.18
296.25
296.31
296.38
296.44
296.51
296.57
296.64
296.70
296.77
296.83
296.90
296.97
297.03
297.10
297.16
297.23
297.30
297.36
297.43
297.49
297.56
297.62
297.69
297.75
297.82
297.88
297.95
298.01
298.08
298.15
298.21
298.28
298.34
298.41
1.410
1.412
1.412
1.412
1.411
1.411
1.412
1.412
1.412
1.412
1.412
1.412
1.413
1.413
1.413
1.412
1.410
1.411
1.413
1.414
1.414
1.414
1.413
1.413
1.414
1.415
1.413
1.414
1.415
1.416
1.415
1.414
1.414
1.414
1.415
1.416
1.416
1.416
1.417
1.416
1.417
1.416
1.416
295.66
295.73
295.79
295.86
295.93
295.99
296.06
296.12
296.19
296.25
296.32
296.38
296.45
296.51
296.58
296.64
296.71
296.77
296.84
296.91
296.97
297.04
297.10
297.17
297.23
297.30
297.36
297.43
297.49
297.56
297.63
297.69
297.76
297.82
297.89
297.95
298.02
298.08
298.15
298.21
298.28
298.34
298.41
1.297
1.299
1.300
1.301
1.301
1.300
1.299
1.298
1.297
1.298
1.298
1.299
1.300
1.300
1.298
1.299
1.301
1.301
1.299
1.300
1.302
1.302
1.301
1.300
1.300
1.299
1.300
1.301
1.299
1.298
1.301
1.302
1.302
1.302
1.303
1.301
1.299
1.300
1.301
1.300
1.301
1.302
1.301
7
298.48
298.55
298.61
298.68
298.74
298.81
298.87
298.94
299.00
299.07
299.14
299.20
299.27
299.33
299.40
299.46
299.53
299.59
299.66
299.72
299.79
299.85
299.92
299.98
300.05
300.12
300.18
300.25
300.31
300.38
300.44
300.51
300.57
300.64
300.71
300.77
300.84
300.90
300.97
301.03
301.10
301.16
301.23
1.293
1.293
1.293
1.293
1.294
1.295
1.295
1.295
1.294
1.294
1.295
1.296
1.296
1.296
1.296
1.294
1.293
1.293
1.294
1.295
1.295
1.296
1.296
1.297
1.297
1.297
1.296
1.296
1.296
1.297
1.297
1.297
1.297
1.297
1.297
1.297
1.298
1.298
1.300
1.295
1.295
1.298
1.303
298.47
298.54
298.60
298.67
298.73
298.80
298.87
298.93
299.00
299.06
299.13
299.19
299.26
299.33
299.39
299.46
299.52
299.59
299.65
299.72
299.78
299.85
299.91
299.98
300.04
300.11
300.17
300.24
300.30
300.37
300.44
300.50
300.57
300.63
300.70
300.76
300.83
300.89
300.96
301.02
301.09
301.16
301.22
1.295
1.296
1.296
1.295
1.296
1.296
1.295
1.295
1.295
1.296
1.297
1.299
1.298
1.298
1.297
1.294
1.293
1.293
1.296
1.297
1.297
1.296
1.296
1.298
1.299
1.299
1.298
1.297
1.296
1.296
1.297
1.297
1.298
1.297
1.297
1.297
1.298
1.299
1.301
1.296
1.294
1.298
1.299
298.49
298.56
298.63
298.69
298.76
298.82
298.89
298.95
299.02
299.08
299.15
299.22
299.28
299.35
299.41
299.48
299.54
299.61
299.67
299.74
299.80
299.87
299.93
300.00
300.06
300.13
300.19
300.26
300.33
300.39
300.46
300.52
300.59
300.65
300.72
300.78
300.85
300.92
300.98
301.05
301.11
301.18
301.24
1.418
1.418
1.418
1.418
1.418
1.418
1.417
1.417
1.417
1.416
1.416
1.417
1.417
1.418
1.418
1.418
1.418
1.418
1.418
1.419
1.419
1.419
1.420
1.420
1.419
1.419
1.419
1.419
1.419
1.419
1.419
1.420
1.420
1.420
1.420
1.419
1.419
1.420
1.420
1.420
1.420
1.421
1.422
298.47
298.54
298.60
298.67
298.74
298.80
298.87
298.93
299.00
299.07
299.13
299.20
299.26
299.33
299.39
299.46
299.52
299.59
299.65
299.72
299.78
299.85
299.91
299.98
300.04
300.11
300.18
300.24
300.31
300.37
300.44
300.50
300.57
300.63
300.70
300.77
300.83
300.90
300.96
301.03
301.09
301.16
301.22
1.416
1.417
1.417
1.417
1.416
1.416
1.416
1.416
1.416
1.416
1.416
1.416
1.415
1.416
1.417
1.417
1.418
1.417
1.416
1.417
1.418
1.418
1.418
1.418
1.417
1.417
1.417
1.418
1.418
1.420
1.419
1.419
1.419
1.419
1.419
1.419
1.419
1.419
1.420
1.420
1.419
1.419
1.421
298.48
298.54
298.61
298.67
298.74
298.81
298.87
298.94
299.00
299.07
299.13
299.20
299.26
299.33
299.40
299.46
299.53
299.59
299.66
299.72
299.79
299.85
299.92
299.98
300.05
300.11
300.18
300.24
300.31
300.38
300.44
300.51
300.57
300.64
300.70
300.77
300.83
300.90
300.97
301.03
301.10
301.16
301.23
1.301
1.299
1.301
1.300
1.299
1.301
1.301
1.301
1.301
1.303
1.303
1.301
1.302
1.302
1.302
1.300
1.299
1.301
1.303
1.303
1.304
1.303
1.303
1.303
1.303
1.302
1.304
1.303
1.304
1.304
1.305
1.304
1.302
1.302
1.304
1.304
1.303
1.303
1.303
1.303
1.301
1.302
1.302
8
301.30
301.36
301.43
301.49
301.56
301.62
301.69
301.75
301.82
301.89
301.95
302.02
302.08
302.15
302.22
302.28
302.35
302.41
302.48
302.54
302.61
302.67
302.74
302.80
302.87
302.94
303.00
303.07
303.13
303.20
303.27
303.33
303.40
303.46
303.53
303.59
303.66
303.72
303.79
303.85
303.92
303.99
304.05
1.297
1.294
1.294
1.294
1.297
1.298
1.297
1.297
1.298
1.300
1.301
1.300
1.298
1.298
1.299
1.298
1.299
1.299
1.299
1.299
1.299
1.300
1.300
1.300
1.299
1.297
1.297
1.301
1.303
1.303
1.302
1.300
1.300
1.304
1.302
1.300
1.299
1.300
1.301
1.302
1.302
1.301
1.300
301.29
301.35
301.42
301.48
301.55
301.61
301.68
301.75
301.81
301.88
301.94
302.01
302.07
302.14
302.21
302.27
302.34
302.40
302.47
302.53
302.60
302.66
302.73
302.80
302.86
302.93
302.99
303.06
303.12
303.19
303.26
303.32
303.39
303.45
303.52
303.58
303.65
303.71
303.78
303.84
303.91
303.97
304.04
1.296
1.296
1.296
1.297
1.301
1.302
1.299
1.298
1.299
1.300
1.300
1.300
1.299
1.299
1.299
1.299
1.300
1.301
1.301
1.301
1.301
1.300
1.300
1.299
1.299
1.297
1.298
1.303
1.304
1.303
1.301
1.299
1.300
1.299
1.300
1.301
1.301
1.302
1.302
1.303
1.304
1.303
1.301
301.31
301.38
301.44
301.51
301.57
301.64
301.70
301.77
301.83
301.90
301.96
302.03
302.10
302.16
302.23
302.29
302.36
302.42
302.49
302.56
302.62
302.69
302.75
302.82
302.88
302.95
303.01
303.08
303.15
303.21
303.28
303.34
303.41
303.47
303.54
303.60
303.67
303.74
303.80
303.86
303.93
304.00
304.06
1.422
1.422
1.421
1.421
1.422
1.422
1.420
1.420
1.420
1.422
1.422
1.423
1.423
1.424
1.423
1.423
1.425
1.424
1.424
1.425
1.427
1.427
1.425
1.424
1.423
1.419
1.420
1.420
1.422
1.424
1.425
1.425
1.424
1.424
1.424
1.422
1.421
1.421
1.422
1.423
1.425
1.425
1.424
301.29
301.36
301.42
301.49
301.55
301.62
301.68
301.75
301.81
301.88
301.94
302.01
302.08
302.14
302.21
302.28
302.34
302.40
302.47
302.54
302.60
302.67
302.73
302.80
302.86
302.93
303.00
303.06
303.13
303.19
303.26
303.33
303.39
303.45
303.52
303.59
303.65
303.72
303.78
303.85
303.91
303.98
304.04
1.421
1.420
1.420
1.420
1.419
1.419
1.419
1.419
1.420
1.421
1.422
1.422
1.421
1.421
1.421
1.421
1.421
1.422
1.422
1.424
1.426
1.424
1.422
1.421
1.419
1.417
1.420
1.419
1.420
1.423
1.425
1.424
1.423
1.422
1.422
1.421
1.420
1.420
1.420
1.421
1.423
1.423
1.423
301.29
301.36
301.42
301.49
301.55
301.62
301.69
301.75
301.82
301.88
301.95
302.01
302.08
302.14
302.21
302.28
302.34
302.41
302.47
302.54
302.60
302.67
302.73
302.80
302.87
302.93
303.00
303.06
303.13
303.20
303.26
303.33
303.39
303.46
303.52
303.59
303.65
303.72
303.78
303.85
303.91
303.98
304.04
1.302
1.302
1.302
1.302
1.302
1.302
1.303
1.305
1.304
1.305
1.306
1.304
1.302
1.302
1.304
1.305
1.305
1.304
1.306
1.305
1.303
1.303
1.303
1.306
1.307
1.306
1.306
1.308
1.307
1.306
1.305
1.303
1.303
1.305
1.305
1.304
1.305
1.305
1.304
1.304
1.302
1.306
1.307
9
304.12
304.18
304.25
304.31
304.38
304.44
304.51
304.58
304.64
304.71
304.77
304.84
304.90
304.97
305.04
305.10
305.17
305.23
305.30
305.36
305.43
305.49
305.56
305.63
305.69
305.76
305.82
305.89
305.95
306.02
306.09
306.15
306.22
306.28
306.35
306.41
306.48
306.55
306.61
306.68
306.74
306.81
306.88
1.301
1.301
1.301
1.300
1.300
1.300
1.302
1.302
1.303
1.304
1.303
1.303
1.303
1.303
1.304
1.305
1.305
1.307
1.306
1.304
1.303
1.301
1.301
1.302
1.302
1.303
1.303
1.303
1.306
1.312
1.311
1.310
1.308
1.307
1.304
1.297
1.298
1.300
1.301
1.302
1.303
1.303
1.305
304.11
304.17
304.24
304.30
304.37
304.44
304.50
304.57
304.63
304.70
304.76
304.83
304.90
304.96
305.03
305.09
305.16
305.22
305.29
305.36
305.42
305.49
305.55
305.62
305.68
305.75
305.82
305.88
305.95
306.01
306.08
306.14
306.21
306.28
306.34
306.41
306.47
306.54
306.60
306.67
306.74
306.80
306.87
1.300
1.301
1.302
1.301
1.300
1.300
1.302
1.302
1.303
1.304
1.303
1.304
1.304
1.303
1.304
1.305
1.306
1.307
1.306
1.304
1.304
1.302
1.301
1.301
1.302
1.302
1.303
1.304
1.307
1.312
1.312
1.311
1.309
1.307
1.305
1.300
1.298
1.301
1.302
1.303
1.305
1.305
1.306
304.13
304.20
304.26
304.33
304.39
304.46
304.52
304.59
304.65
304.72
304.79
304.85
304.92
304.98
305.05
305.11
305.18
305.25
305.31
305.38
305.44
305.51
305.58
305.64
305.71
305.77
305.84
305.90
305.97
306.03
306.10
306.16
306.23
306.30
306.36
306.43
306.49
306.56
306.63
306.69
306.76
306.82
306.89
1.425
1.425
1.425
1.427
1.428
1.429
1.429
1.427
1.427
1.427
1.428
1.428
1.428
1.429
1.429
1.431
1.432
1.436
1.435
1.432
1.428
1.427
1.421
1.418
1.420
1.424
1.428
1.430
1.430
1.430
1.435
1.439
1.436
1.433
1.430
1.429
1.427
1.426
1.427
1.427
1.423
1.421
1.426
304.11
304.18
304.24
304.31
304.37
304.44
304.50
304.57
304.63
304.70
304.77
304.83
304.90
304.96
305.03
305.10
305.16
305.23
305.29
305.36
305.42
305.49
305.55
305.62
305.69
305.75
305.82
305.88
305.95
306.02
306.08
306.15
306.21
306.28
306.34
306.41
306.47
306.54
306.61
306.67
306.74
306.80
306.87
1.425
1.425
1.425
1.426
1.426
1.426
1.427
1.425
1.425
1.426
1.427
1.427
1.427
1.428
1.428
1.429
1.430
1.435
1.434
1.431
1.428
1.425
1.418
1.418
1.421
1.424
1.428
1.430
1.430
1.430
1.434
1.437
1.435
1.432
1.429
1.427
1.426
1.425
1.426
1.424
1.420
1.422
1.427
304.11
304.18
304.24
304.31
304.37
304.44
304.51
304.57
304.64
304.70
304.77
304.83
304.90
304.96
305.03
305.10
305.16
305.23
305.29
305.36
305.42
305.49
305.56
305.62
305.69
305.75
305.82
305.88
305.95
306.01
306.08
306.15
306.21
306.28
306.34
306.41
306.48
306.54
306.61
306.67
306.74
306.80
306.87
1.307
1.304
1.302
1.301
1.302
1.302
1.305
1.308
1.308
1.307
1.305
1.304
1.305
1.306
1.305
1.306
1.310
1.310
1.309
1.307
1.305
1.307
1.306
1.305
1.307
1.308
1.307
1.307
1.308
1.309
1.308
1.309
1.308
1.303
1.302
1.305
1.304
1.303
1.306
1.308
1.309
1.309
1.308
10
306.94
307.01
307.07
307.14
307.21
307.27
307.34
307.40
307.47
307.53
307.60
307.67
307.73
307.80
307.86
307.93
307.99
308.06
308.13
308.19
308.25
308.32
308.39
308.45
308.52
308.58
308.65
308.71
308.78
308.85
308.91
308.98
309.05
309.11
309.18
309.24
309.31
309.37
309.44
309.50
309.57
309.64
309.70
1.306
1.306
1.306
1.304
1.304
1.302
1.303
1.306
1.314
1.313
1.311
1.310
1.311
1.310
1.310
1.308
1.303
1.301
1.302
1.304
1.304
1.303
1.304
1.305
1.307
1.306
1.306
1.307
1.307
1.307
1.307
1.308
1.309
1.308
1.308
1.309
1.308
1.308
1.309
1.311
1.310
1.310
1.309
306.93
307.00
307.06
307.13
307.20
307.26
307.33
307.39
307.46
307.53
307.59
307.66
307.72
307.79
307.85
307.92
307.98
308.05
308.12
308.18
308.25
308.31
308.38
308.44
308.51
308.58
308.64
308.71
308.77
308.84
308.90
308.97
309.04
309.10
309.17
309.23
309.30
309.37
309.43
309.50
309.56
309.63
309.69
1.307
1.307
1.306
1.304
1.304
1.302
1.302
1.305
1.313
1.313
1.312
1.311
1.312
1.312
1.308
1.302
1.303
1.306
1.305
1.305
1.305
1.305
1.305
1.306
1.308
1.307
1.307
1.308
1.307
1.306
1.307
1.309
1.310
1.309
1.309
1.309
1.309
1.309
1.309
1.310
1.310
1.309
1.309
306.96
307.02
307.09
307.15
307.22
307.28
307.35
307.42
307.48
307.55
307.61
307.68
307.74
307.81
307.87
307.94
308.00
308.07
308.14
308.20
308.27
308.33
308.40
308.47
308.53
308.60
308.66
308.73
308.79
308.86
308.93
308.99
309.06
309.12
309.19
309.26
309.32
309.38
309.45
309.52
309.58
309.65
309.71
1.437
1.438
1.436
1.433
1.430
1.428
1.429
1.430
1.424
1.424
1.425
1.428
1.429
1.428
1.429
1.429
1.430
1.430
1.431
1.432
1.432
1.431
1.431
1.430
1.431
1.432
1.432
1.432
1.432
1.432
1.432
1.432
1.431
1.431
1.431
1.431
1.431
1.432
1.432
1.431
1.431
1.432
1.432
306.94
307.00
307.07
307.14
307.20
307.27
307.33
307.40
307.46
307.53
307.59
307.66
307.72
307.79
307.86
307.92
307.99
308.05
308.12
308.18
308.25
308.32
308.38
308.45
308.51
308.58
308.64
308.71
308.78
308.84
308.91
308.97
309.04
309.11
309.17
309.23
309.30
309.37
309.43
309.50
309.57
309.63
309.70
1.437
1.437
1.435
1.433
1.429
1.426
1.427
1.426
1.424
1.424
1.425
1.426
1.428
1.428
1.430
1.429
1.430
1.431
1.432
1.433
1.433
1.433
1.432
1.430
1.431
1.431
1.430
1.430
1.431
1.432
1.431
1.431
1.431
1.430
1.430
1.431
1.431
1.432
1.432
1.431
1.431
1.433
1.432
306.94
307.00
307.07
307.13
307.20
307.27
307.33
307.40
307.46
307.53
307.60
307.66
307.72
307.79
307.85
307.92
307.99
308.05
308.12
308.18
308.25
308.32
308.38
308.45
308.51
308.58
308.64
308.71
308.77
308.84
308.91
308.97
309.04
309.11
309.17
309.24
309.30
309.37
309.43
309.50
309.57
309.63
309.70
1.307
1.308
1.309
1.307
1.306
1.307
1.307
1.308
1.309
1.309
1.310
1.309
1.308
1.307
1.305
1.305
1.307
1.308
1.310
1.309
1.310
1.309
1.307
1.307
1.308
1.309
1.309
1.310
1.311
1.312
1.310
1.308
1.309
1.311
1.311
1.311
1.311
1.310
1.309
1.309
1.309
1.310
1.312
11
309.77
309.83
309.90
309.97
310.03
310.10
310.16
310.23
310.29
310.36
310.43
310.49
310.56
310.62
310.69
310.76
310.82
310.89
310.95
311.02
311.09
311.15
311.22
311.28
311.35
311.41
311.48
311.55
311.61
311.68
311.74
311.81
311.87
311.94
312.01
312.07
312.14
312.20
312.27
312.33
312.40
312.47
312.53
1.309
1.311
1.310
1.309
1.309
1.310
1.310
1.310
1.309
1.309
1.310
1.311
1.312
1.310
1.309
1.308
1.308
1.310
1.312
1.313
1.313
1.311
1.311
1.311
1.311
1.312
1.314
1.315
1.314
1.313
1.312
1.311
1.311
1.310
1.310
1.311
1.311
1.311
1.313
1.315
1.315
1.315
1.313
309.76
309.82
309.89
309.96
310.02
310.09
310.15
310.22
310.28
310.35
310.41
310.48
310.55
310.61
310.68
310.75
310.81
310.88
310.94
311.01
311.07
311.14
311.21
311.27
311.34
311.40
311.47
311.53
311.60
311.67
311.73
311.80
311.86
311.93
312.00
312.06
312.13
312.19
312.26
312.32
312.39
312.46
312.52
1.308
1.310
1.311
1.310
1.310
1.310
1.309
1.309
1.309
1.309
1.310
1.310
1.309
1.309
1.310
1.309
1.308
1.309
1.310
1.312
1.312
1.312
1.313
1.313
1.313
1.313
1.314
1.315
1.314
1.314
1.313
1.312
1.312
1.312
1.311
1.311
1.311
1.311
1.313
1.314
1.314
1.313
1.313
309.78
309.84
309.91
309.98
310.04
310.11
310.17
310.24
310.31
310.37
310.44
310.50
310.57
310.64
310.70
310.77
310.83
310.90
310.96
311.03
311.10
311.16
311.23
311.29
311.36
311.43
311.49
311.56
311.62
311.69
311.75
311.82
311.89
311.95
312.02
312.08
312.15
312.22
312.28
312.35
312.41
312.48
312.54
1.432
1.434
1.435
1.432
1.430
1.432
1.432
1.431
1.432
1.434
1.432
1.432
1.433
1.435
1.436
1.435
1.435
1.434
1.432
1.431
1.432
1.434
1.435
1.437
1.436
1.435
1.435
1.433
1.433
1.434
1.434
1.435
1.435
1.435
1.435
1.434
1.435
1.434
1.434
1.436
1.437
1.437
1.435
309.76
309.83
309.89
309.96
310.02
310.09
310.16
310.22
310.29
310.35
310.42
310.49
310.55
310.62
310.68
310.75
310.81
310.88
310.95
311.01
311.08
311.14
311.21
311.28
311.34
311.41
311.47
311.54
311.60
311.67
311.74
311.80
311.87
311.93
312.00
312.07
312.13
312.20
312.26
312.33
312.39
312.46
312.53
1.432
1.433
1.433
1.431
1.430
1.431
1.433
1.433
1.432
1.433
1.431
1.432
1.433
1.435
1.435
1.434
1.434
1.434
1.433
1.432
1.432
1.434
1.435
1.437
1.437
1.435
1.435
1.433
1.433
1.434
1.435
1.437
1.436
1.436
1.435
1.434
1.434
1.432
1.432
1.434
1.435
1.435
1.434
309.76
309.83
309.89
309.96
310.03
310.09
310.16
310.22
310.29
310.35
310.42
310.48
310.55
310.62
310.68
310.75
310.81
310.88
310.95
311.01
311.08
311.15
311.21
311.28
311.34
311.41
311.47
311.54
311.61
311.67
311.73
311.80
311.87
311.93
312.00
312.07
312.13
312.20
312.26
312.33
312.40
312.46
312.53
1.312
1.310
1.311
1.311
1.311
1.310
1.311
1.313
1.311
1.311
1.312
1.312
1.314
1.314
1.313
1.311
1.309
1.309
1.307
1.306
1.309
1.310
1.310
1.310
1.311
1.313
1.315
1.314
1.314
1.313
1.312
1.313
1.313
1.314
1.315
1.314
1.313
1.313
1.311
1.311
1.311
1.313
1.311
12
312.60
312.66
312.73
312.80
312.86
312.93
312.99
313.06
313.13
313.19
313.26
313.32
313.39
313.45
313.52
313.59
313.65
313.72
313.78
313.85
313.91
313.98
314.05
314.11
314.18
314.24
314.31
314.38
314.44
314.51
314.57
314.64
314.70
314.77
314.84
314.90
314.97
315.03
315.10
315.17
315.23
315.30
315.36
1.311
1.311
1.314
1.315
1.314
1.314
1.314
1.314
1.315
1.315
1.316
1.318
1.317
1.314
1.315
1.315
1.315
1.316
1.316
1.316
1.315
1.316
1.316
1.315
1.316
1.316
1.316
1.315
1.316
1.316
1.317
1.319
1.320
1.318
1.317
1.317
1.318
1.319
1.318
1.316
1.316
1.318
1.317
312.59
312.65
312.72
312.79
312.85
312.92
312.98
313.05
313.12
313.18
313.25
313.31
313.38
313.44
313.51
313.58
313.64
313.71
313.77
313.84
313.90
313.97
314.04
314.10
314.17
314.24
314.30
314.37
314.43
314.50
314.56
314.63
314.70
314.76
314.83
314.89
314.96
315.03
315.09
315.16
315.22
315.29
315.36
1.312
1.313
1.315
1.316
1.315
1.315
1.315
1.314
1.314
1.314
1.314
1.316
1.316
1.315
1.315
1.316
1.317
1.317
1.318
1.317
1.315
1.315
1.316
1.316
1.316
1.318
1.318
1.318
1.317
1.315
1.317
1.319
1.319
1.318
1.317
1.317
1.318
1.319
1.318
1.315
1.315
1.317
1.317
312.61
312.67
312.74
312.81
312.87
312.94
313.00
313.07
313.14
313.20
313.27
313.33
313.40
313.47
313.53
313.60
313.66
313.73
313.79
313.86
313.93
313.99
314.06
314.12
314.19
314.26
314.32
314.39
314.45
314.52
314.58
314.65
314.72
314.78
314.85
314.91
314.98
315.05
315.11
315.18
315.24
315.31
315.38
1.434
1.436
1.436
1.436
1.436
1.436
1.435
1.433
1.435
1.437
1.437
1.438
1.436
1.437
1.436
1.437
1.437
1.437
1.440
1.439
1.436
1.434
1.433
1.436
1.439
1.440
1.440
1.440
1.439
1.438
1.439
1.439
1.439
1.438
1.439
1.440
1.439
1.439
1.439
1.438
1.437
1.437
1.439
312.59
312.66
312.72
312.79
312.85
312.92
312.99
313.05
313.12
313.18
313.25
313.31
313.38
313.45
313.51
313.58
313.64
313.71
313.78
313.84
313.91
313.98
314.04
314.11
314.17
314.24
314.30
314.37
314.43
314.50
314.57
314.63
314.70
314.76
314.83
314.90
314.96
315.03
315.10
315.16
315.23
315.29
315.36
1.433
1.435
1.435
1.436
1.436
1.436
1.436
1.435
1.436
1.437
1.437
1.437
1.436
1.437
1.436
1.437
1.438
1.438
1.438
1.437
1.436
1.435
1.434
1.435
1.438
1.440
1.440
1.440
1.439
1.438
1.439
1.439
1.440
1.440
1.440
1.440
1.439
1.439
1.439
1.439
1.438
1.438
1.440
312.59
312.66
312.72
312.79
312.86
312.92
312.99
313.06
313.12
313.19
313.25
313.32
313.38
313.45
313.52
313.58
313.65
313.71
313.78
313.84
313.91
313.98
314.04
314.11
314.17
314.24
314.30
314.37
314.44
314.50
314.57
314.63
314.70
314.77
314.83
314.90
314.96
315.03
315.10
315.16
315.23
315.29
315.36
1.311
1.313
1.312
1.311
1.313
1.312
1.313
1.314
1.312
1.312
1.313
1.314
1.314
1.315
1.315
1.316
1.314
1.314
1.316
1.313
1.313
1.312
1.314
1.316
1.317
1.315
1.314
1.313
1.312
1.312
1.313
1.313
1.312
1.314
1.318
1.318
1.317
1.315
1.313
1.313
1.312
1.312
1.314
13
315.43
315.50
315.56
315.63
315.69
315.76
315.83
315.89
315.96
316.02
316.09
316.16
316.22
316.29
316.35
316.42
316.48
316.55
316.62
316.68
316.75
316.81
316.88
316.95
317.01
317.08
317.14
317.21
317.27
317.34
317.41
317.47
317.54
317.60
317.67
317.73
317.80
317.87
317.93
318.00
318.06
318.13
318.20
1.318
1.318
1.319
1.320
1.319
1.318
1.317
1.318
1.318
1.317
1.318
1.319
1.321
1.321
1.320
1.320
1.320
1.321
1.320
1.318
1.319
1.320
1.320
1.321
1.321
1.322
1.322
1.320
1.320
1.321
1.321
1.323
1.323
1.323
1.320
1.322
1.323
1.322
1.322
1.322
1.322
1.323
1.323
315.42
315.49
315.55
315.62
315.68
315.75
315.82
315.88
315.95
316.01
316.08
316.15
316.21
316.28
316.34
316.41
316.48
316.54
316.61
316.67
316.74
316.80
316.87
316.94
317.00
317.07
317.13
317.20
317.27
317.33
317.40
317.46
317.53
317.59
317.66
317.72
317.79
317.86
317.92
317.99
318.05
318.12
318.19
1.317
1.318
1.319
1.319
1.319
1.318
1.319
1.320
1.320
1.319
1.319
1.320
1.322
1.323
1.322
1.321
1.321
1.321
1.320
1.319
1.321
1.322
1.322
1.321
1.320
1.320
1.320
1.319
1.319
1.320
1.321
1.322
1.324
1.323
1.320
1.321
1.323
1.323
1.323
1.323
1.321
1.323
1.322
315.44
315.51
315.57
315.64
315.71
315.77
315.84
315.90
315.97
316.03
316.10
316.16
316.23
316.30
316.36
316.43
316.50
316.56
316.62
316.69
316.76
316.82
316.89
316.96
317.02
317.09
317.15
317.22
317.28
317.35
317.42
317.48
317.55
317.61
317.68
317.74
317.81
317.88
317.94
318.01
318.08
318.14
318.21
1.439
1.440
1.439
1.439
1.441
1.439
1.438
1.438
1.438
1.439
1.440
1.440
1.438
1.438
1.441
1.442
1.441
1.442
1.442
1.441
1.441
1.441
1.441
1.441
1.441
1.441
1.440
1.441
1.441
1.442
1.442
1.441
1.442
1.443
1.443
1.442
1.443
1.443
1.442
1.443
1.444
1.445
1.444
315.42
315.49
315.55
315.62
315.69
315.75
315.82
315.89
315.95
316.02
316.08
316.15
316.21
316.28
316.34
316.41
316.48
316.54
316.61
316.67
316.74
316.81
316.87
316.94
317.01
317.07
317.14
317.20
317.27
317.33
317.40
317.46
317.53
317.60
317.66
317.73
317.79
317.86
317.93
317.99
318.06
318.12
318.19
1.441
1.440
1.440
1.440
1.440
1.440
1.440
1.438
1.438
1.439
1.441
1.440
1.439
1.440
1.441
1.441
1.440
1.441
1.442
1.442
1.443
1.443
1.442
1.442
1.442
1.441
1.441
1.440
1.440
1.442
1.442
1.441
1.441
1.442
1.442
1.441
1.442
1.443
1.443
1.443
1.443
1.443
1.445
315.42
315.49
315.56
315.62
315.69
315.75
315.82
315.89
315.95
316.02
316.08
316.15
316.21
316.28
316.34
316.41
316.48
316.54
316.61
316.67
316.74
316.81
316.87
316.94
317.01
317.07
317.14
317.20
317.27
317.33
317.40
317.46
317.53
317.60
317.66
317.73
317.79
317.86
317.93
317.99
318.06
318.12
318.19
1.317
1.317
1.316
1.315
1.315
1.315
1.314
1.312
1.310
1.313
1.313
1.312
1.313
1.316
1.316
1.317
1.319
1.320
1.319
1.317
1.314
1.314
1.313
1.316
1.317
1.316
1.317
1.318
1.317
1.318
1.317
1.315
1.315
1.315
1.314
1.315
1.319
1.317
1.315
1.313
1.315
1.318
1.319
14
318.26
318.33
318.39
318.46
318.53
318.59
318.66
318.72
318.79
318.86
318.92
318.99
319.05
319.12
319.19
319.25
319.32
319.38
319.45
319.52
319.58
319.65
319.71
319.78
319.85
319.91
319.98
320.04
320.11
320.18
320.24
320.31
320.37
320.44
320.51
320.57
320.64
320.70
320.77
320.84
320.90
320.97
321.03
1.324
1.325
1.324
1.323
1.323
1.325
1.325
1.323
1.323
1.322
1.323
1.324
1.324
1.323
1.324
1.327
1.327
1.327
1.326
1.325
1.324
1.325
1.326
1.325
1.324
1.325
1.325
1.326
1.327
1.326
1.326
1.327
1.327
1.327
1.327
1.327
1.325
1.324
1.323
1.325
1.327
1.327
1.325
318.25
318.32
318.38
318.45
318.52
318.58
318.65
318.71
318.78
318.85
318.91
318.98
319.05
319.11
319.18
319.24
319.31
319.37
319.44
319.51
319.57
319.64
319.70
319.77
319.83
319.90
319.97
320.03
320.10
320.16
320.23
320.30
320.36
320.43
320.49
320.56
320.63
320.69
320.76
320.83
320.89
320.96
321.02
1.324
1.325
1.324
1.323
1.322
1.324
1.325
1.324
1.324
1.323
1.323
1.324
1.324
1.324
1.326
1.326
1.326
1.325
1.324
1.324
1.324
1.325
1.326
1.326
1.325
1.325
1.326
1.326
1.327
1.327
1.326
1.326
1.326
1.327
1.327
1.327
1.325
1.323
1.324
1.327
1.330
1.329
1.327
318.27
318.34
318.41
318.47
318.54
318.60
318.67
318.74
318.80
318.87
318.93
319.00
319.07
319.13
319.20
319.26
319.33
319.40
319.46
319.53
319.59
319.66
319.73
319.79
319.86
319.92
319.99
320.06
320.12
320.19
320.25
320.32
320.38
320.45
320.52
320.58
320.65
320.71
320.78
320.85
320.91
320.98
321.04
1.445
1.445
1.445
1.445
1.446
1.445
1.445
1.443
1.444
1.444
1.443
1.444
1.444
1.445
1.445
1.445
1.445
1.446
1.445
1.445
1.446
1.446
1.447
1.448
1.447
1.446
1.447
1.447
1.447
1.447
1.446
1.445
1.445
1.446
1.447
1.447
1.447
1.447
1.445
1.446
1.446
1.447
1.446
318.26
318.32
318.39
318.45
318.52
318.58
318.65
318.72
318.78
318.85
318.92
318.98
319.05
319.11
319.18
319.25
319.31
319.38
319.44
319.51
319.58
319.64
319.71
319.77
319.84
319.90
319.97
320.03
320.10
320.17
320.23
320.30
320.37
320.43
320.50
320.56
320.63
320.69
320.76
320.83
320.89
320.96
321.03
1.446
1.447
1.445
1.445
1.446
1.445
1.445
1.445
1.446
1.445
1.444
1.444
1.445
1.446
1.446
1.446
1.445
1.446
1.446
1.446
1.446
1.446
1.446
1.447
1.447
1.446
1.446
1.446
1.446
1.447
1.446
1.446
1.447
1.448
1.448
1.447
1.447
1.447
1.447
1.447
1.448
1.448
1.446
318.25
318.32
318.39
318.45
318.52
318.59
318.65
318.72
318.78
318.85
318.92
318.98
319.05
319.11
319.18
319.25
319.31
319.38
319.44
319.51
319.57
319.64
319.71
319.77
319.84
319.90
319.97
320.04
320.10
320.17
320.24
320.30
320.37
320.43
320.50
320.56
320.63
320.70
320.76
320.83
320.89
320.96
321.02
1.318
1.318
1.317
1.316
1.316
1.316
1.316
1.315
1.315
1.314
1.316
1.316
1.317
1.318
1.320
1.322
1.322
1.318
1.317
1.316
1.315
1.314
1.315
1.314
1.315
1.316
1.317
1.316
1.314
1.313
1.313
1.314
1.315
1.315
1.315
1.315
1.313
1.311
1.311
1.311
1.311
1.312
1.314
15
321.10
321.17
321.23
321.30
1.326
1.328
1.327
1.326
321.09
321.15
321.22
321.29
1.326
1.327
1.328
1.327
321.11
321.18
321.24
321.31
1.447
1.447
1.447
1.446
321.09
321.16
321.22
321.29
1.447
1.448
1.448
1.446
321.09
321.16
321.22
321.29
1.316
1.314
1.312
1.310
Table S2: Complete experimental data for heat released per mol of added IL
into specified solvent, H
Expt
T/K
mIL/mol·kg-1
H/J·mol-1 kJ·mol-1 Avg Stdev
[C2mim][NTf2] in chloroform
10
288.2
0.007
4247
4.24
4.24 0.05
10
288.2
0.015
4176
4.17
3.94 0.10
10
308.2
0.022
3753
3.75
3.83 0.08
10
308.2
0.030
3909
3.9
3.68 0.11
11
288.2
0.008
4242
4.24
11
288.2
0.015
4311
4.31
11
308.2
0.023
3918
3.91
11
308.2
0.031
3787
3.78
12
298.2
0.008
3924
3.92
12
298.2
0.016
3884
3.88
12
318.2
0.024
3760
3.76
12
318.2
0.032
3648
3.64
13
298.2
0.007
4052
4.05
13
298.2
0.014
3791
3.79
13
318.2
0.020
3586
3.58
13
318.2
0.027
3654
3.65
14
298.2
0.007
4023
4.02
14
298.2
0.014
4038
4.03
14
318.2
0.021
3877
3.87
14
318.2
0.028
3589
3.58
[C6mim][NTf2] in chloroform
15
288.2
0.006
4447
4.45
4.71
0.23
15
288.2
0.012
4872
4.87
15
288.2
0.017
4824
4.82
15
318.2
0.023
5584
5.58
5.37
0.18
15
318.2
0.029
5299
5.30
15
318.2
0.034
5236
5.24
16
298.2
0.006
3955
3.96
4.4
0.40
16
298.2
0.012
4741
4.74
16
298.2
0.018
4516
4.52
16
16
16
16
308.2
308.2
308.2
17
17
17
17
17
17
18
18
18
18
18
18
288.2
288.2
288.2
308.2
308.2
308.2
298.2
298.2
298.2
318.2
318.2
318.2
19
19
19
19
19
19
20
20
20
20
20
20
10=
11=
12=
13=
14=
288.2
288.2
288.2
308.2
308.2
308.2
298.2
298.2
298.2
318.2
318.2
318.2
pure, N2
pure, boil
pure, N2
pure, boil
As received
0.024
5104
5.10
4.98
0.030
5340
5.34
0.035
4502
4.50
[C6mim][CTf3] in chloroform
0.005
2444
2.44
2.87
0.010
3064
3.06
0.015
3112
3.11
0.020
2858
2.85
3.04
0.025
3261
3.26
0.030
3033
3.03
0.005
2235
2.23
2.7
0.010
2881
2.88
0.015
2992
2.99
0.020
2924
2.92
3.13
0.025
3165
3.16
0.030
3321
3.32
[C2mim][NTf2] in 96:4 chloroform:acetone
0.007
3280
3.28
3.43
0.014
3374
3.37
0.021
3657
3.65
0.029
3406
3.4
3.41
0.036
3375
3.37
0.043
3469
3.46
0.007
2968
2.96
3.36
0.014
3514
3.51
0.021
3614
3.61
0.028
3280
3.27
3.36
0.036
3448
3.44
0.043
3398
3.39
0.43
0.37
0.2
0.41
0.2
0.19
0.04
0.35
0.08
17