The 10th Int. Conf. on Hydroscience and Engineering (ICHE-2012), Nov. 4 – Nov. 7, Orlando, USA 1 INTERACTION BETWEEN THE PHOSPHORUS AND SUSPENDED SEDIMENT IN KUWAIT BAY Eqbal Al-Enezi1;Nouf Alomani1, Majid Wadi1 and Ahmed. Al-Khabbaz 1 ABSTRACT Phosphorus plays an important role in eutrophication of the marine environment and aquatic systems. Suspended sediment may act both as a source or sink of phosphorus to the water depending on the physico- chemical factors, such as pH, salinity, DO and phosphorus concentration in the water. The adsorption /desorption processes of phosphorus by the suspended sediment were studied to understand the phosphorus behaviour in the Kuwait Bay. The dominant mineralogical composition of the suspended sediment is quartzitic calcareous sandy silt (Khalaf et al. 1985), which is mostly derived from dust fallout in the Kuwait Bay waters. Also, Al-Ghadban and A. El-Sammak, 2005 studied the source and composition of suspended sediment in the Kuwait Bay, and they found that high concentration of quartz and feldspar, and lower carbonate contents towards the eastern part of the bay. They noted that the Shatt Al-Arab, in a major supplier of suspended load into the bay. Also there are many studies have been stated that the Shatt Al-Arab may be a major supplier of suspended sediments in the northern Arabian Gulf, such as Al- Bakri et al., 1984; Al-Ghadban et al., 1999; Khan, 2002. Substantial quantities of inorganic phosphorus are released from suspended sediment of the Kuwait Bay, over periods of few hours. The aim of this study is to defining the physical and biogeochemical processes influencing the transport of phosphorus in the suspended sediment-water interface. In this study, experiments were carried out to determine the equilibrium of phosphorus between suspended sediment and water in Kuwait Bay under a range of variances such as (pH, salinity, DO and temperature). Ten water and suspended sediment samples were collected from the Kuwait Bay during the neap and spring tides. The phosphorus desorption from suspended sediment was determined by the easy exchangeable phosphorus (MgCl2 extractable) methods (Ruttenberg, 1992) and the maximum phosphorus adsorption by suspended sediment was measured (Smith et al. 2006) methods. 1 Environmental Science Department, Kuwait Institute for Scientific Research, P.O. Box 24885, Safat 13109, Kuwait. eenezi@kisr.edu.kw The 10th Int. Conf. on Hydroscience and Engineering (ICHE-2012), Nov. 4 – Nov. 7, Orlando, USA 1 The adsorbed phosphorus concentrations in the suspended sediment range vary between 0.1 to 0.5 mg/l and desorption from suspended sediment into the water range between 0.07 to 0.4 mg/l. This difference was attributed to the chemical composition of the suspended sediment. The range of adsorption concentration varies according to water quality. A positive correlation was found between adsorbed phosphorus and concentration of suspended sediment in the water column. A numerical model such as (Delft 3D) was applied to simulate the effect of the sediment-adsorbed phosphorus to the total phosphorus distribution in the Kuwait Bay. The modelling result indicated that the high concentration of suspended sediment have adverse impact on water quality, especially in western part of Kuwait Bay due to low water circulation in this part in the Bay and other. Figure 1 Locations of suspended sediments samples in the Kuwait Bay REFERENCES Al-Bakri, D., Khalaf, F., Al-Ghahdban, A.N., 1984. Minerology, genesis and sources of surficial sediments in Kuwait marine environment, northern Arabian Gulf. Journal of Sedimentary Petrology 54 (4), 1266–1279. Al- Ghadban; A., and A. Al- Sammak. 2005. Sources, distribution and composition of the suspended sediments, Kuwait Bay, Northern Arabian Gulf. Journal of Arid Environments 60: 647–661. Al-Ghadban, A.N., Saeed, T., Al-Dousari, A.M., Al-Shemmari, H., Al-Mutairi, M., 1999. Preliminary assessment of the impact of drainage of Iraqi marches on Kuwait’s northern marine environment. Part I. Physical manipulation. Water Science Technology 40 (4), 75–87. Khalaf, F.I., Al-Kadi, A., Al-Saleh, S., 1985. Mineralogical composition and potential sources of dust fallout deposits in Kuwait, northern Arabian Gulf. Sedimentary Geology 42, 255–278. Khan, N.Y., 2002. Human and physical geography (Chapter 1). In: Khan, N.T., Munawar, M., Price, A.R.G. (Eds.), The Gulf Ecosystem: Health and Sustainability. Backhuys Publishers, Leiden, The Netherlands. Ruttenberg, K. C. (1992) Development of a sequential extraction method for different forms of phosphorus in marine sediments. Limnology and oceanography. 37:1460-1482. Smith, D., Warnemuende, B., Haggard, B., and Huang, C. (2006) Changes in sediment-water column phosphorus interactions following sediment disturbance. Ecological Engineering. 27: 71-78.