MATERIAL SAFETY DATA SHEET SERIAL NO: ISSUE DATE: Sunday, 07 February 2016 PRODUCT NAME: AMMONIA LIQUID-AQUA AMMONIA PRODUCT USE: Cleaning FORMULA NO: 200762 SECTION 1: HAZARDOUS INGREDIENT INFORMATION Chemical identity Ammonium Hydroxide Conc. 10-35% CAS No. 1336-21-6 PIN No. UN 2672 SECTION 11: PREPARATION INFORMATION Prepared by : SUBRAMANIAM MASILAMANY Telephone : 416-286-3336 Date of preparation : Sunday, 07 February 2016 SECTION 111: PRODUCT INFORMATION Product identifier : AMMONIA LIQUID-AQUA AMMONIA Manufacturers Name : Tidol Corporation Street Address : 120-2A Mc Levin Avenue City : Scarborough Province : Ontario Postal Code : M1B 3E9 Emergency Tel. : 416-286-3336 Product's Use : Cleaning Supplier Information Suppliers Name : Street Address : City : Province : Postal Code : Emergency Tel : Product's Use : SECTION 1V: PHYSICAL DATA Physical State Odour and Appearance Odour Threshold Specific Gravity (Water = 1) : Liquid : Fishy, highly pungent & colorless liquid : 1-5 ppm : 0.8974 at 29.40% 1 Coefficient of water/ oil distribution Vapour Pressure (mm Hg, 20C) Boiling Point Freezing Point pH Vapour Density (Air = 1) Evaporation Rate Percent volatile by Volume : Not available : 475mm Hg at 30% : 100 C for 1% solution : 0 C for 1% solution : 13 at 10% : 0.618 at 15C (30%) : Not available : 100% SECTION V: FIRE AND EXPLOSION HAZARD. Condition of Flammability : Non flammable Means of Extinction : Use dry chemical powers, water, foam or carbon dioxide Explosion Data Sensitivity to Mechanical Impact : Not applicable Sensitivity to Static Discharge : Not applicable Flash Point and Method : Not applicable Upper Flammable Limit % : Not applicable Lower Flammable Limit% : Not applicable Auto ignition Temperature : Not applicable Hazardous Combustion Products : None SECTION V1: REACTIVITY DATA Stability Incompatible Materials Conditions of Reactivity Hazardous Decomposition Products : Stable under normal temperature : Oxidizers, salts of heavy metals (silver, gold, lead, mercury, zinc), chlorine, copper, brass, aluminum, dimethylsulphate, acrolein. : None known to the manufacturer : Ammonia and oxides of nitrogen SECTION V11: TOXICOLOGICAL PROPERTIES. LD50 Species and Route : LC50(inhalation, rat, 4 hrs): 3670ppm LD50(oral, rat): 350mg/kg LC50 Species and Route : Not Available Route of Entry : Skin contact -Yes Skin Absorption -Yes Eye Contact -Yes Inhalation -Yes Ingestion -Yes Effects of Acute Exposure to Product : Skin irritation and eye damage. Exposure Limits : Do not permit direct contact. Irritancy to Product : Moderate to skin, Severe to eyes. Synergistic Products : Not known to the manufacturer. 2 SECTION V111: PREVENTIVE MEASURES. Personal Protective Equipment : Applicable Gloves (specify) : Required Respiratory (Specify) : Required Eye (Specify) : Necessary Footwear (specify) : Necessary Other Equipments (Specify) : Consult your supervisor Engineering Controls (Specify) : Natural ventilation sufficient. Leak and Spill Procedures : Absorb with sand and oil dry Waste Disposal : Observe all Local, Provincial & Federal regulations. Handling Procedures and Equipments : Avoid contact with eyes, skin and clothing. Do not ingest. Do not breathe vapour or mist. Keep container closed. Avoid contact of spilled material and runoff with soil and surface waterways. Follow Normal Procedures. Storage Requirements : Store away from food Special Shipping Information : Secure containers (full and/or empty) with suitable hold down devises during shipment. Corrosive Liquid Class 8 UN 2672 PK III SECTION 1X: HEALTH DATA Inhalation Ingestion Eye contact Skin Contact : Move to fresh air : Do not induce vomiting, give milk & seek medical advice. : Flush with water and see doctor : Flush with water and see doctor. ADDITIONAL INFORMATION Detergents are products made by blending different chemicals possessing different degrees of different hazards. It is difficult to determine the combined effect of these chemicals. Therefore discretion on the part of the Supervisor and operators are kindly requested. Sources Used : Merck's Index, TDG Act, WHMIS etc NON WARRANTY: Prior testing for fitness for use by the purchaser and purchaser's compliance with applicable statues is a strict condition of sale. The information given above are prepared from our knowledge of the product. All recommendations and suggestions are believed reliable but should not be construed as warranties. Tidol Corporation disclaims any liability incurred in connection with the use of the product or the data given above. 3