Publications by Russell J. Hemley related to the DCO (2009-2015) Rus Hemley’s publications related to carbon research have spanned a wide range of topics, including the synthesis and characterization of vapor-deposited diamonds, the applications of those diamonds to new experimental techniques at extreme conditions, the behavior of carbon compounds at extreme conditions, characterization of new C-bearing materials, and explorations of the high-pressure limits of microbial life. Much of this work leverages DCO funding by employing major national facilities for UV, X-ray, and neutron studies. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Goncharov, A. F., J. A. Montoya, N. Subramanian, V. V. Struzhkin, A. I. Kolesnikov, M. Somayazulu, and R. J. Hemley, Laser heating in diamond anvil cells: Developments in pulsed and continuous techniques, J. Synch. Radiation, 16, 769-772 (2009). Hemley, R. J., G. W. Crabtree, and M. V. Buchanan, Energy challenges for materials in extreme environments, Phys. Today, 62, 32-37 (2009). Liang, Q., C. Y. Chin, J. Lai, C. S. Yan, Y. F. Meng, H. K. Mao, and R. J. Hemley, Enhanced growth of high quality single crystal diamond by MPCVD at high gas pressures, Appl. Phys. Lett., 94, 024103 (2009). Liang, Q., C. S. Yan, Y. Meng, J. Lai, S. Krasnicki, H. K. Mao, and R. J. Hemley, Recent advances in high-growth rate single-crystal CVD diamond, Diamond Rel. Mater., 18, 698703 (2009). Liang, Q., C. S. Yan, Y. F. Meng, J. Lai, S. Krasnicki, H. K. Mao, and R. J. Hemley, Enhancing the mechanical properties of CVD single-crystal diamond, J. Phys. Cond. Matt., 21, 364215 (2009). Sharma, A., G. D. Cody, and R. J. Hemley, In situ diamond-anvil cell observations of methanogenesis at high pressures and temperatures, Energ. Fuel., 23, 5571-5579 (2009). Strobel, T. A., M. Somayazulu, and R. J. Hemley, Novel pressure-induced interactions in silane-hydrogen, Phys. Rev. Lett., 103, 065701 (2009). Struzhkin, V. V., H. K. Mao, and R. J. Hemley, High-pressure synchrotron x-ray spectroscopy with diamond anvil cells, in Perspectives in Materials Characterization (eds. G. Amarendra, Raj, B. and Manghnani, M.), 151-178 (University Press (India), Hyderabad, India, 2009). Zha, C. S., S. Krasnicki, Y. F. Meng, C. S. Yan, J. Lai, Q. Liang, H. K. Mao, and R. J. Hemley, Composite chemical vapor deposition diamond anvils for highpressure/hightemperature experiments, High Press. Res., 29, 317-324 (2009). Emmons, E. D., V. K. Kamisetty, J. C. Fallas, W. M. Chien, A. M. Covington, R. S. Chellappa, S. A. Gramsch, R. J. Hemley, and D. Chandra, High-pressure Raman spectroscopy of tris(hydroxymethyl)aminomethane, J. Phys. Chem. B, 144, 5649-5656 (2010). Wang, L., Y. Ding, W. Yang, W. Liu, Z. Cai, J. Kung, J. Shu, R. J. Hemley, and H. K. Mao, Nanoprobe measurements of materials at megabar pressures, Proc. Nat. Acad. Sci., 107, 6140-6145 (2010). Subramanian, N., V. V. Struzhkin, A. F. Goncharov, and R. J. Hemley, A virtual experiment control and data aquisition system for in situ laser heated diamond anvil cell Raman spectroscopy, Rev. Sci. Instrum., 81, 093906 (2010). 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. Shen, G., L. Wang, R. Ferry, H. K. Mao, and R. J. Hemley, A portable laser heating microscope for high pressure research, J. Phys.: Conf. Series, 215, 012191 (2010). Shu, J., X. J. Chen, I. M. Chou, W. Yang, J. Hu, R. J. Hemley, and H. K. Mao, Structural stability of methane hydrate at high pressures, Geosci. Frontiers, 21, 93-100 (2011). Griffin, P. L., A. Kish, A. Steele, and R. J. Hemley, Differential high-pressure survival in stationary phase Escherichia coli MG1655, High Press. Res., 31, 325-333 (2011). Lin, Z. J., J. Z. Zhang, B. S. Li, L. P. Wang, H. K. Mao, R. J. Hemley, and Y. Zhao, Superhard diamond/tungsten carbide nanocomposites, Appl. Phys. Lett., 98, 121914 (2011). Strobel, T. A., A. F. Goncharov, C. T. Seagle, Z. Liu, M. Somayazulu, V. V. Struzhkin, and R. J. Hemley, High pressure study of silane to 150 GPa, Phys. Rev. B, 83, 144102 (2011). Litasov, K. D., A. F. Goncharov, and R. J. Hemley, Crossover from melting to dissociation of CO2 under pressure: Implications for the lower mantle, Earth Planet. Sci. Lett. 309, 318323 (2011). Dalton, D. A., M. Somayazulu, A. F. Goncharov, and R. J. Hemley, Static compression of tetramethylammonium borohydride (TMAB), J. Phys. Chem. A, 115, 11033-11038 (2011). Hemawan, K. W., C. S. Yan, Q. Liang, J. Lai, Y. Meng, S. Krasnicki, H. K. Mao, and R. J. Hemley, Hot spot formation in microwave plasma CVD diamond synthesis, IEEE Trans. Plasma Sci. 39, 2790-2791 (2011). Meng, Y., C. S. Yan, S. Krasnicki, Q. Liang, J. Lai, H. Shu, T. Yu, A. S. Steele, H. K. Mao and R. J. Hemley, High optical quality multicarat single crystal diamond produced by chemical vapor deposition, Phys. Stat. Sol. (a). 209, 101-104 (2012). Hazen, R. M., R. J. Hemley, and A. J. Mangum, Carbon in Earth's interior: Storage, cycling, and life, Eos, 93, 17-18 (2012). Kish, A., P. L. Griffin, K. L. Rogers, M. L. Fogel, R. J. Hemley, and A. Steele, Cellular adaptations enabling high-pressure tolerance in Halobacterium salinarum NRC-1 and other non-piezophilic prokaryotes, Extremophiles 16, 355-361 (2012). Wang, S., Y. F. Meng, N. Ando, M. Tate, S. Krasnicki, C. S. Yan, Q. Liang, J. Lai, H. K. Mao, S. M. Gruner, and R. J. Hemley, Single-crystal CVD diamonds as small-angle x-ray scattering windows for high pressure research, J. Appl. Cryst. 45, 453-457 (2012). Irifune, T. and R. J. Hemley, New diamond windows into the Earth, Eos 45, 453-457 (2012). Benjamin, A. S., M. Ahart, S. A. Gramsch, L. L. Stevens, E. B. Orler, D. M. Dattelbaum, and R. J. Hemley, Acoustic properties of Kel F-800 copolymer up to 85 GPa, J. Chem. Phys. 137, 014514 (2012). Stevens, L. L., D. M. Dattlebaum, M. Ahart, and R. J. Hemley, High-pressure elastic properties of a flourinated copolymer: Poly(chlorotrifluoroethylene-co-vinylidene flouide) (Kel-F 800), J. Appl. Phys. 112, 023523 (2012). Oganov, A. R., R. J. Hemley, R. M. Hazen, and A. P. Jones, Chapter 3: Structure, bonding, and mineralogy of carbon at extreme conditions, in Carbon in Earth: Reviews in Mineralogy and Geochemistry (eds. R. M. Hazen, A. P. Jones, A. P. and J. A. Baross), 75, 47-77 (2013). Loubeyre, L., M. Ahart, S. A. Gramsch, and R. J. Hemley, Density dependence of dynamical heterogeneity in fluid methanol, J. Chem. Phys. 138, 174507 (2013). Rotundu, C. R., T. Cuk, R. L. Greene, Z. X. Shen, R. J. Hemley, and V. V. Struzhkin, High-pressure resistivity apparatus for quasi-hydrostatic compression experiments, Rev. Sci. Instrum. 8/4, 063903 (2013). 31. 32. 33. 34. 35. 36. 37. 38. 39. Naumov, I. I., R. E. Cohen, and R. J. Hemley, Graphene physics and insulator-metal transition in compressed hydrogen, Phys. Rev. B 88, 045125 (2013). Liang, Q., Y. F. Meng, C. S. Yan, S. Krasnicki, J. Lai, K. W. Hemawan, H. Shu, D. Popov, T. Yu, W. Yang, H. K. Mao, and R. J. Hemley, Developments in synthesis, characterizations, and applications of large, high-quality CVD single crystal diamond, J. Superhard Mater. 35, 195-213 (2013). Doherty, M. W., V. V. Struzhkin, D. A. Simpson, L. P. McGuinness, Y. Meng, A. Stacey, T. J. Karle, R. J. Hemley, N. B. Manson, L. C. L. Hollenberg, and S. Prawer, Electronic properties and metrology of the diamond NV- center under pressure, Phys. Rev. Lett. 112, 047601 (2014). Potter, R. G., M. Somayaulu, G. Cody, and R. J. Hemley, High pressure equilibria of dimethylamine borane, dihydridobis(dimethylamine)boron(III) tetrahydridoborate(III), and hydrogen, J. Phys. Chem. C 118, 7280-7287 (2014). Potter, R., M. Somayazulu, G. Cody, and R. J. Hemley, In-situ Raman spectroscopy and synchrotron x-ray diffraction studies on NNNN-tetramethylcyclotriborazane at high pressures, J. Phys. Chem. C 118, 9871-9879 (2014). Liang, Q., C. S. Yan, J. Lai, Y. F. Meng, S. Krasnicki, H. Shu, H. K. Mao, and R. J. Hemley, Large area single crystal diamond synthesis by 915 MHz microwave plasmaassisted chemical vapor deposition, Cryst. Growth Design 14, 3234-3238 (2014). Hemawan, K. W. and R. J. Hemley, Optical emission diagnostics of microwave plasma CVD single crystal diamond synthesis, Plasma Chem. Plasma Proces., submitted. Meng, Y. F., C. S. Yan, K. W. Hemawan, Q. Liang, S. Krasnicki, J. Lai, H. Shu, S. A. Gramsch, H. K. Mao, and R. J. Hemley, Spectroscopic characterization of ultrahigh purity single crystal CVD diamond, Solid State Comm., submitted. Hemley, R. J., V. V. Struzhkin, R. E. Cohen, and G. Shen, Theory and practice - Measuring high-pressure electronic and magnetic properties, in Treatise on Geophysics, 2nd ed. (Elsevier, in press). Publications by Robert M. Hazen related to the DCO (2009-2015) Publications by Bob Hazen related to carbon in Earth science include studies of mineral evolution (Earth’s changing mineralogy through deep time), mineral ecology (statistical studies of the diversity and distribution of minerals on Earth), interactions between biomolecules and mineral surfaces (especially as related to life’s origins), the evolution of complex systems, the co-evolution of the geosphere and biosphere, and uses and applications of deep-time data. He also has contributed many books and articles written to engage a wider general audience readership. These works highlight aspects of the DCO research portfolio. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. Hazen, R.M. and J.S. Trefil (2009) Science Matters, 2nd Edition. New York: Doubleday, 360 p. Trefil, J.S. and R.M. Hazen (2009) The Sciences: An Integrated Approach, 6th edition. Hoboken, NJ: John Wiley & Sons, 555 p. Hazen, R.M. and J.S. Trefil (2009) Great Ideas of Science: A Reader. San Diego, CA: Cognella, 256 p. Hazen, R.M. (2009) The emergence of patterning in life’s origin and evolution. International Journal of Developmental Biology, 53, 683-692. Hazen, R.M. (2009) Emergence and the experimental pursuit of the origin of life. In C. M. Bertka, editor, Exploring the Origins, Extent, and Future of Life: Philosophical, Ethical, and Theological Perspectives. New York: Cambridge University Press, pp. 21-46. Hazen, R.M., Ewing, R.J and Sverjensky, D.A. (2009) Evolution of uranium and thorium minerals. American Mineralogist 94. 1293-1311. Jonsson, C.M, C.L. Jonsson, D.A. Sverjensky, H.J. Cleaves II, R.M. Hazen (2009) Attachment of L-glutamate to rutile (a-TiO2): A potentiometric, adsorption and surface complexation study. Langmuir 25, 12127-12135. Hazen, R.M. (2009) Chemical evolution: An introduction. In L. Zaikowski, J.M. Friedrich & S.R. Seidel [editors], Chemical Evolution II: From Origins of Life to Modern Society. American Chemical Society Symposium Series 1025, 3-13. Hazen, R.M. (2009) Les minéraux évoluent aussi. La Recherche 430 (May 2009), 60-63. Hazen, R.M. (2009) The descent of minerals [in Korean]. Science Donga, 282, 54-59. Hazen, R.M. and J. M. Ferry (2010) Mineral evolution: Mineralogy in the fourth dimension. Elements 6, #1, 9-12. Hazen, R.M. and N. Eldredge (2010) Themes and variations in complex systems. Elements 6, #1, 43-46. Hazen, R.M. (2010) The evolution of minerals. Scientific American 303, #3, 58-65. Cleaves, H.J. II, C.M. Jonsson, C.L. Jonsson, D.A. Sverjensky, R.M. Hazen (2010) Adsorption of nucleic acid components on rutile (TiO2) surfaces. Astrobiology, 10, 311323. Hazen, R.M. and D.A.Sverjensky (2010) Mineral Surfaces, Geochemical Complexities, and the Origins of Life. In D.W. Deamer & J.W. Szostak (Editors), The Origins of Life, Cold Springs Harbor Perspectives in Biology, 157-177. Jonsson, C.M., C.L. Jonsson, D.A. Sverjensky, H.J. Cleaves II, R.M. Hazen (2010) Adsorption of L-asparate to rutile (a-TiO2): Experimental and theoretical surface complexation studies. Geochemica et Cosmochemica Acta 74, 2356-2367. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. Hazen, R.M. (2010) How old is Earth, and how do we know? Evolution: Education and Outreach 3, 198-205. K. Marshall-Bowman, S. Ohara, D. A. Sverjensky, R. M. Hazen, and H. J. Cleaves (2010) Catalytic peptide hydrolysis by mineral surface: Implications for prebiotic chemistry. Geochimica et Cosmochimica Acta 74, 5852-5861. Bahri, S., C.M. Jonsson, C.L. Jonsson, D. Azzolini, D.A. Sverjensky, R.M. Hazen (2011) Adsorption and surface complexation study of L-DOPA on rutile (TiO2) in NaCl solutions. Environmental Science and Technology, 45, 3959-3966. Grew ES, Bada JL, Hazen RM (2011) Borate minerals and the origin of the RNA world, Origins of Life and Evolution of the Biosphere, 41, 307-316. Hazen RM, Bekker A, Bish DL, Bleeker W, Downs RT, Farquhar J, Ferry JM, Grew ES, Knoll AH, Papineau D, Ralph JP, Sverjensky DA, Valley JW (2011) Needs and opportunities in mineral evolution research. American Mineralogist, 96, 953-963. Parikh, SJ, JD Kubicki, CM Jonsson, CL Jonsson, RM Hazen, DA Sverjensky, DL Sparks (2011) Evaluating glutamate and aspartate binding mechanisms to rutile (a-TiO2) via ATRFTIR spectroscopy and quantum chemical calculations. Langmuir, 27, 1778-1787. Hazen, R.M. (2011) Exciting frontiers await at scientific boundaries: An example from the Deep Carbon Observatory. Earth 56, #7, 71. Cleaves, H.J.II, E. Crapster-Pregont, C.M. Jonsson, C.L. Jonsson, D.A. Sverjensky, R.M. Hazen (2011) The adsorption of short single-stranded DNA oligomers to mineral surfaces. Chemosphere, 83, 1560-1567. Hazen, R.M. (2011) What’s new in mineral evolution. Italy Symposium publication Hazen, R.M. (2012) The Story of Earth: The First 4.5 Billion Years, from Stardust to Living Planet. New York: Viking, 306 p. Softcover edition (2013). Foreign language: Spanish, Japanese, Korean, Russian, Polish, and Czech editions. Hazen, R.M., J.Golden, R.T.Downs, G.Hysted, E.S.Grew, D.Azzolini, D.A.Sverjensky (2012) Mercury (Hg) mineral evolution: A mineralogical record of supercontinent assembly, changing ocean geochemistry, and the emerging terrestrial biosphere. American Mineralogist, 97, 1013-1042. Hazen, R.M. and D.Papineau (2012) Mineralogcal co-evolution of the geosphere and biosphere. In A. H. Knoll, D. E. Canfield and K. O. Konhauser (Editors), Fundamentals of Geobiology. Oxford UK: Wiley-Blackwell, pp.333-350. Hazen, R.M., Hemley, R.J., and Mangum, A.J. (2012) Carbon in Earth’s interior: storage, cycling, and life. EoS Transactions of the American Geophysical Union 93, 17-28. Hazen, R.M. (2012) Geochemical origins of life. In A. H. Knoll, D. E. Canfield and K. O. Konhauser (Editors), Fundamentals of Geobiology. Oxford UK: Wiley-Blackwell, pp.315332. Hazen, R.M. (2012) An accident waiting to happen (That’s Life). Eureka, The Times, #33 (June 2012), 14-19. Cleaves, H.J.II, A.M.Scott, F.C.Hill, J.Leszczynski, N.Sahai, and R.M.Hazen (2012) Mineral-organic interfacial processes: potential roles in the origins of life. Chemical Society Reviews, 41, 5502-5525. DOI: 10.1039/c2cs35112a Lee, N., Hummer, D.R., Sverjensky, D.S., Rajh, T., Hazen, R.M., Steele, A., and Cody, G.D. (2012) Speciation of L-DOPA on nanorutile as a function of pH and surface coverage using surface-enhance Raman spectroscopy (SERS). Langmuir, 28, 17322-17330. doi: 10.1021/la303607a. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. Hazen, R.M. (2013) Paleomineralogy of the Hadean Eon: A preliminary list. American Journal of Science, 313, 807-843. Hazen, R.M., A.P.Jones, and J.A.Baross [Editors] (2013) Carbon in Earth. Reviews in Mineralogy and Geochemistry volume 75. Washington, DC: Mineralogical Society of America, 698 p. Hazen, R.M. and C.Schiffries, C. (2013) Why carbon? In Hazen, R.M., A.Jones, and J.Baross [Editors]. Carbon in Earth. Washington, DC: Mineralogical Society of America, pp. 1-6. Hazen, R.M., R.T.Downs, A.Jones, and L.Kah (2013) The mineralogy and crystal chemistry of carbon. In Hazen, R.M., A. Jones, and J.Baross [Editors]. Carbon in Earth. Washington, DC: Mineralogical Society of America, pp. 7-46. Oganov, A., R.Hemley, R.M.Hazen, and A.Jones (2013) Deep carbon mineralogy. In Hazen, R.M., A. Jones, and J.Baross [Editors]. Carbon in Earth. Washington, DC: Mineralogical Society of America, pp. 47-77. Hazen, R.M., A.Jones, L.Kah, D.A.Sverjensky (2013) Carbon mineral evolution. In Hazen, R.M., A. Jones, and J.Baross [Editors]. Carbon in Earth. Washington, DC: Mineralogical Society of America, pp. 79-107. Sephton, M. and R.M.Hazen (2013) On the origins of deep hydrocarbons. In Hazen, R.M., A.Jones, and J.Baross [Editors]. Carbon in Earth. Washington, DC: Mineralogical Society of America, pp. 449-465. Golden, J., M.McMillan, R.T.Downs, G.Hystad, H.J.Stein, A.Zimmerman, D.A.Sverjensky, J.Armstrong, R.M.Hazen (2013) Rhenium variations in molybdenite (MoS2): Evidence for progressive subsurface oxidation. Earth and Planetary Science Letters, 366, 1-5. Hazen, R.M. (2013) Mineral evolution. In McGraw-Hill Yearbook of Science & Technology 2013. New York: McGraw-Hill, pp.247-249. Hazen, R.M., Sverjensky, D.A., Azzolini, D., Bish, D.L., Elmore, S., Hinnov, L., and Milliken, R.E. (2013) Clay mineral evolution. American Mineralogist, 98, 2007-2029. Grew, E.S., and Hazen, R.M. (2013) Evolution of the minerals of beryllium. Stein, 2013, 419. Also Norwegian language version (translated by Roy Kristiansen), “Evolusjon av Berylliummineraler, Stein 3, 2014, 4-20. Noffke, N., D.Christian, D.Wacey, and R.M.Hazen (2013) Microbially induced sedimentary structures recording an ancient ecosystem in the ca. 3.48 billion-year-old Dresser Formation, Pilbara, Western Australia. Astrobiology Journal, 13, #12, 1103-1124. Bolukbasi, B., et al. (2013) Open data: Creating a culture of cooperation. Science, 342, 1041-1042. Grew, E.S. and R.M.Hazen (2014) Beryllium mineral evolution. American Mineralogist, 99, 999-1021. Hazen, R.M. (2014) Enantioselective adsorption on rock-forming minerals: A thought experiment. Surface Science, 629, 11-14. Lee, N., D.I.Foustoukos, D.A.Sverjensky, G.D.Cody, and R.M.Hazen (2014) The effects of temperature, ph and redox state on the stability of glutamic acid in hydrothermal fluids. Geochimica et Cosmochimica Acta, 135, 66-86. Hazen, R.M. (2014) Data-driven abductive discovery in mineralogy. American Mineralogist, 99, 2165-2170. Hazen, R.M., Liu, X.-M., Downs, R.T., Golden, J., Pires, A.J., Grew, E.S., Hystad, G., 52. 53. 54. 55. 56. 57. 58. 59. 60. Estrada, C., and Sverjensky, D.A. (2014) Mineral evolution: Episodic metallogenesis, the supercontinent cycle, and the co-evolving geosphere and biosphere. Economic Geology, Special Publication 18, 1-15. Hazen, R.M. (2014) Mineral fodder. Aeon Magazine, published online June 24, 2014, 7 pp. Trefil, J.S., and Hazen, R.M. (2015) The Sciences: An Integrated Approach. 8th edition. Hoboken, NJ: Wiley. Hazen, R.M. (2014) Deep carbon and false dichotomies. Elements, 10, 407-409. Lee, N., D.A.Sverjensky, and R.M.Hazen (2014) Cooperative and competitive adsorption of amino acids with Ca2+ on rutile (α-TiO2). Environmental Science and Technology, 48, 9358-9365. Lee, N., D.I.Foustoukos, D.A.Sverjensky, G.D.Cody, and R.M.Hazen (2013) Hydrogen enhances the stability of amino acids in hydrothermal environments. Chemical Geology, 386, 184-189. Hazen, R.M., Grew, E.S., Downs, R.T., Golden, J., and Hystad, G. (2015) Mineral ecology: Chance and necessity in the mineral diversity of terrestrial planets. Canadian Mineralogist, in press. Nance, J.R., J.T.Armstrong, G.D.Cody, M.L.Fogel, and R.M.Hazen (2015) Preserved shellbinding protein and associated pigment in the Middle Miocene (8 to 18 Ma) gastropod Ecphora. Geochemical Perspectives Letters 1, 1-8. Estrada, C., D.A.Sverjensky, M.Pelletier, A.Razafitianamharavo, and R.M.Hazen (2014) interaction between L-aspartate and the brucite [Mg(OH)2]-water interface. Geochimica et Cosmochimica Acta, in press. Hysted, G., Downs, R.T., and Hazen, R.M. (2015) Mineral frequency distribution data conform to a LNRE model: Prediction of Earth’s “missing” minerals. Mathematical Geosciences, in press. 12 additional papers in review