Supplementary Discussion 1. Derivation of airflow solution in Laplace domain For convenience, the governing equations, as well as the boundary and initial conditions, are transformed into dimensionless forms using the definitions as follows: PD1 3 2 2 2 2 2 2 t z P1 P0 P2 P0 P3 P0 ; ; ; t D 02 ; z D ; 1 1 ; 2 2 ; P P D2 D3 2 2 2 B 0 0 B P0 P0 P0 B k B 3 B1 k b1 ; 2 b2 ; 3 b3 ; b1 b2 b3 1 ; 1 ; 3 . ; B B k2 0 B k2 (S-1) Therefore, the governing equations are transferred into 1 PD1 2 PD1 , 2 1 t D z D (S-2) 1 PD 2 2 PD 2 , 2 2 t D z D (S-3) 1 PD 3 2 PD 3 , 2 3 t D z D (S-4) and the boundary and initial conditions are PD1 z D PD1 z PD 2 PD 3 0, (S-5) z D 0 D b1 PD 2 z D b1 b2 z D 1 z D b1 PD 3 and z D b1 b2 PD1 z D and z D b1 PD 2 z D PD 2 z D , z D b1 b2 PD 3 z D f D (t D ) , PD1 PD 2 PD 3 t D 0 (S-6) z D b1 , (S-7) z D b1 b2 (S-8) 0, (S-9) where the subscript “D” denotes the dimensionless terms; PD is the dimensionless squared air pressure; b1, b2 and b3 are the dimensionless thicknesses of the deep, middle and shallow 1 layers, respectively; 1 , 2 , 3 , and are defined in Eq. S-1; f D (t D ) is the dimensionless squared atmospheric pressure fluctuations. 0 in Eq. S-1 is an arbitrary reference air diffusivity. Without losing generality, one can choose the middle layer as a reference to calculate 0 . For instance, for P0=105 Pa, k2 =10-12 m2, 2 0.5 , 2 0.5 , and 1.8 105 Pa·s, one has 0 2.22 10 2 m2/s. With the Laplace transform upon the dimensionless equation group Eqs. (S-2) to (S-4), the airflow governing equations in Laplace domain can be expressed as ~ d 2 PD1 s ~ P , 2 1 D1 dz D (S-10) ~ d 2 PD 2 s ~ P , 2 2 D2 dz D (S-11) ~ d 2 PD 3 s ~ P , 2 3 D3 dz D (S-12) ~ ~ ~ where the PD1 , PD 2 and PD 3 are the dimensionless subsurface pressure in Laplace domain and s is the Laplace parameters. The boundary conditions are transformed into Laplace domain accordingly ~ dPD1 dz D ~ PD1 ~ PD 2 ~ PD 3 0, (S-13) z D 0 z D b1 ~ PD 2 z D b1 b2 z D 1 z D b1 ~ PD 3 ~ dPD1 and dz D z D b1 b2 and z D b1 dPD 2 dz D ~ dPD 2 dz D , zD b1 b2 (S-14) z D b1 dPD 3 dz D ~ f D ( s) , , (S-15) z D b1 b2 (S-16) ~ where f D ( s ) is time-dependent function of the atmospheric pressure fluctuations in Laplace domain. 2 Combining above boundary conditions, the solution to airflow in Laplace domain can be obtained s ~ PD1 C1 cosh z D , 1 (S-17) s s ~ PD 2 C2 cosh z D C3 sinh z D , 2 2 (S-18) s s ~ PD 3 C4 cosh zD C5 sinh z D , 3 3 (S-19) where C1, C2, C3, C4 and C5 are unknown parameters in the solution, which can be determined based on the boundary conditions in Laplace domain. Substituting Eqs. (S-17) and (S-18) into the continuity condition in Eq. (S-14), one obtains æ s ö æ s ö æ s ö C1 × cosh ç b1 ÷ - C2 × cosh ç b1 ÷ - C3 ×sinh ç b1 ÷ = 0 , è b1 ø è b2 ø è b2 ø C1 (S-20) s s s s s sinh b1 C2 sinh b1 C3 cosh b1 0 . (S-21) 1 2 2 1 2 2 s Substituting Eqs. (S-18) and (S-19) into the continuity condition in Eq. (S-15), one obtains 3 s b1 b2 C3 sinh s b1 b2 C4 cosh s b1 b2 C5 sinh s b1 b2 0 , (S-22) C2 cosh 2 2 3 3 s b1 b2 C3 s cosh s b1 b2 C4 s sinh s b1 b2 C5 s cosh s b1 b2 0 . sinh 2 2 3 3 2 2 3 3 s C2 (S-23) Substituting Eq. (S-19) into the upper boundary condition in Eq. (S-16), one obtains s ~ C5 sinh s f D ( s ) . C 4 cosh 3 3 (S-24) The constants C1 to C5 are obtained correspondingly as C1 M b b 2 ~ 22 ~ 2 f D ( s) cosh A1 cosh A2 1 sinh A1 sinh A2 1 ; f D ( s) ; C2 M 1 3 3 3 b2 b2 C3 b b 22 f D ( s) 2 cosh A1 sinh A2 1 sinh A1 cosh A2 1 ; M 1 3 3 b2 b2 C4 1 ~ 22 f D ( s) 2 cosh A1 cosh A2 cosh A4 sinh A1 sinh A2 cosh A4 cosh A1 sinh A2 sinh A4 2 sinh A1 cosh A2 sinh A4 ; M 13 1 3 C5 22 2 1 ~ f D ( s) 2 cosh A1 cosh A2 sinh A4 sinh A1 sinh A2 sinh A4 cosh A1 sinh A2 cosh A4 sinh A1 cosh A2 cosh A4 ; M 3 1 3 1 ~ where 22 2 M 2 cosh A1 cosh A2 cosh A3 sinh A1 sinh A2 cosh A3 cosh A1 sinh A2 sinh A3 sinh A1 cosh A2 sinh A3 ; 1 3 1 3 4 A1 b1 s 1 ; A2 b2 s 2 ; A3 b3 s 3 ; A4 b1 b2 s 3 . Therefore, the solution to airflow in layered unsaturated zone is obtained by the substitution of C1 to C5 into Eqs. (S-17) to (S-19). 2. Verification of the solution In this section, a comparison between the solution developed in section 2 and a numerical simulation in a three-layer unsaturated zone is demonstrated in order to justify the solution derivation as well as the accuracy of the numerical inverse Laplace transform. The numerical simulation is conducted in COMSOL Multiphysics using the built-in partial differential equation (PDE) mode, which runs the finite element analysis together with adaptive meshing and error control. The airflow in the comparison is one-dimensional vertical airflow in a three-layer unsaturated zone depicted in Fig. S-1. The parameters used in this comparison are listed in Table S-1. Meanwhile, two kinds of atmospheric pressure fluctuations are employed as the boundary condition at the ground surface. One is a single-component sinusoidal function with diurnal cycle and the other one is a summation of diurnal sinusoidal function and semidiurnal sinusoidal function. The two kinds of atmospheric pressure fluctuations are as following f (t ) P0 A1 sin( 1t ) , (S-25) f (t ) P0 A1 sin( 1t ) A2 sin( 2t ) . (S-26) The amplitudes and frequencies of the diurnal and semidiurnal sinusoidal functions are listed in Table S-2. In the numerical simulation, the three layers are vertically divided into 166 5 elements. The element density in the layer near the ground surface is designed denser than those in the other two layers. The reason for such element configurations is to capture the details of pressure changes near the ground surface due to atmospheric pressure fluctuations. Besides, we have doubled and tripled the elements in the vertical coordinate, but no obvious improvement in accuracy is observed in the numerical simulation. The pressure evaluations at three different depths deviating from P0 under two kinds of atmospheric pressure fluctuations are plotted in Figs. S- 2 (a) and (b), respectively. The three depths are z =5, 15 and 25 m which are located in the shallow, middle and deep layers respectively. In Figs. S-2 (a) and (b), it is apparent that the pressure evaluations using the solution developed in this study agree well with those in the numerical simulation using COMSOL Multiphysics. Thus, the derivation of solution based on Laplace transform shows adequate accuracy to calculate the subsurface pressure in layered unsaturated zones. Meanwhile, the solution can be used under flexible boundary conditions at the ground surface, which can be a representation of atmospheric pressure using superposition of sinusoidal functions. 3. Convergence of the Fourier series analysis In this section, convergence of the Fourier series analysis on the discrete air pressure data is checked. For convenience, the discrete air pressure data are transformed into a summation of a series of harmonic functions through the Fourier series analysis. For instance, the harmonic functions have the frequency of 2n T , where n=1, 2, 3…… and T is a reference period of the basic sinusoidal function. 6 These harmonic functions have decreasing amplitudes with increasing frequencies. Fig. S-3 is a plot of the leading five harmonic functions representing the atmospheric pressure fluctuations corresponding to one barometric pumping test reported in Shan (1995) (with the deep observation point of 24.5 m). With the increase of frequency, the amplitude of each individual mode decreases. In Fig. S-4, summations containing different numbers of harmonic functions are plotted, indicating that the accuracy of data representation increases with the number of terms included. For the atmospheric pressure fluctuations discussed in this study, approximation using the leading 100 terms of the Fourier series is sufficiently accurate. Thus, the discrete pressure data can be well represented by the Fourier series summation with proper numbers of the harmonic functions. Reference Shan, C.: Analytical solutions for determining vertical air permeability in unsaturated soils. Water Resour Res 31(9), 2193-2200 (1995) 7 Tables Table S-1 Default parameters for the three-layer unsaturated zone. Parameters Value Unit B1 10 m Thickness of the deep layer B2 10 m Thickness of the middle layer B3 10 m Thickness of the shallow layer B 30 m Total thickness: B=B 1+B 2+B 3 k1 5×10-13 m2 Air permeability in the deep layer k2 -12 2 Air permeability in the middle layer 2 Air permeability in the shallow layer Porosity in three layers Air filled saturation in three layers Air dynamic viscosity k3 1×10 -13 φ 8×10 0.4 0.5 μ 1.8×10 P0 1×10 ε -5 5 m m Pa·s Pa Definition Mean atmospheric pressure 8 Table S-2 The amplitudes and frequencies of the diurnal and semidiurnal sinusoidal functions for atmospheric pressure fluctuations. Parameters Value Unit Definition A1 500 Pa Amplitude of diurnal component in atmospheric pressure fluctuations A2 250 Pa Amplitude of semi-diurnal component in atmospheric pressure fluctuations ω1 2π/86400 s-1 Frequency of diurnal component in atmospheric pressure fluctuations ω2 4π/86400 s-1 Frequency of semi-diurnal component in atmospheric pressure fluctuations 9 Figures Fig. S-1 Schematic diagram of vertical air flow in a three-layer unsaturated zone. 10 Atmospheric pressure fluctuations Numerical simulation in COMSOL Solution in this study 0.6 0 Pressure deviation from P (KPa) 0.8 0.4 z=5 m 0.2 z=15 m 0 z=25 m -0.2 -0.4 -0.6 0 12 24 36 Time (hour) Fig. S-2 (a) 11 48 60 72 0 Pressure deviation from P (KPa) 1 Atmospheric pressure fluctuations Numerical simulation in COMSOL Solution in this study 0.8 0.6 z=5 m 0.4 z=15 m 0.2 z=25 m 0 -0.2 -0.4 -0.6 -0.8 0 12 24 36 48 60 72 Time (hour) Fig. S-2 (b) Figure S-2 Comparison of subsurface pressure at different depths evaluated using the solution in this study and numerical solution in COMSOL Multiphysics (a) the atmospheric pressure is a single sinusoidal function with diurnal cycle; (b) the atmospheric pressure is a summation of a diurnal sinusoidal function and a semidiurnal sinusoidal function. 12 Harmonic functions n=1 n=2 n=3 n=4 n=5 0 0.5 1 1.5 t 2 D Fig. S-3 The leading five harmonic functions in the Fourier series analysis of the atmospheric pressure fluctuations corresponding to the pressure data at the deep observation point of 24.5 m in Shan (1995). 13 0.015 0.01 PD 0.005 0 -0.005 Field data n=10 n=50 n=100 -0.01 -0.015 0 0.5 1 1.5 t 2 D Fig. S-4 Atmospheric pressure fluctuations approximated through the Fourier series analysis with different numbers of harmonic function terms. These atmospheric pressure fluctuations are corresponded to the pressure data at the deep observation point of 24.5 m in Shan (1995) 14