Where Can We Put It? A Solution To Storing Excess Renewable Energy Using Batteries Abstract Since the 1800s, the battery has been known to be the ultimate means of storing electrical energy. Over the years, batteries have changed and are still useful in most technological areas. Due to their versatile design, batteries can be used in everything from a small electronic device like a cell phone, to a source of power for an electric vehicle. The next possibility is using batteries to help renewable energy take over as the world’s primary means of electrical generation. Key Words Renewable Energy Batteries Prepared by Andrew J. Logan Author Biography Andrew is currently a Junior studying Electrical Engineering at USC’s Viterbi School of Engineering. He plans to finish his degree in 2013 and go on to either research alternative energy or continue on to graduate school. Contact Information AndrewJL@USC.edu (303) 594-1016 Prepared for: Marc Aubertin, Writing 340 Professor Section 66804 USC Viterbi School of Engineering And Illumin “May the wind always be at your back. May the Sun shine warm upon your face.” - From an old Irish Blessing Sometimes, however, the wind is not blowing and sometimes the Sun is not shining. When looking at shifting from fossil fuels to renewable such as wind or solar, these facts become very important in the design and integration of alternative energy technology. For the current and past systems, utilizing fossil fuels, this was never a problem because the fuels were available when needed. However, due to unchangeable conditions like the rotation of the Earth and the climate in various regions, we cannot control the energy produced using renewable technology. Therefore, to combat this challenge, much research has gone into power storage [1]. The most common way to store power for the last couple hundred years started with Alessandro Volta and the construction of the Voltaic Pile [2], which would eventually lead into battery cells starting in 1836 and all the way to today’s batteries. Batteries are used in everything from small electronics (phones, computers, etc.) to electric vehicles. Their importance can spread far into other realms of technology, like the area of renewable energy generation. Whereas batteries themselves are not new technology, consideration needs to go into what they can be used for in the future. One possibility, the one presented in this article, is the use How A Battery Works Figure 1. The electrons, shown in pink, flow from the negatively charged anode on the bottom to the positively charged cathode on the top. They are created from the chemical reaction in the battery and can only flow when a circuit is completed from the anode to the cathode. [3] of batteries for power storage from alternative energy sources, like solar and wind. With continuing research on increasing storage capacity, creating more powerful cells, and considering new designs, batteries have much potential for helping create a cleaner, more efficient world in the area of energy and power generation. How They Do What They Do Batteries are in almost every handheld device on the market for consumers. They come in many shapes, sizes, uses, and ranges of output. However, all of them work in the same basic manner. As shown in Figure 1, electrons created in the battery flow through the wire to whatever the battery is powering (in this case, a light bulb.) This is a simplistic model of a battery, but a concept all batteries use for producing energy. For rechargeable batteries, this same process works in reverse when the battery is being charged. Beyond the basic charging and discharging, different batteries use different metals and compounds for different features including: energy density (how much energy can be stored), how lightweight the materials are, and the rate at which the materials promote different rates of charging and discharging. For example, batteries used in cell phones and laptop computers are made of lightweight materials with high energy densities to make those devices portable and small. As a trade-off, these devices do not last as long. However, if they were made to last longer, laptops could have ended up staying the same size as the first portable computers (weighing about 20 pounds), even with advances in all of the other technology in a computer. The designs of earlier batteries were simple and followed a design similar to the voltaic pile, in terms of stacking the cathode, electrolyte, and anode. Also, over the years, researchers have found the best chemicals to use for electrolytes. A typical household battery like a AA uses manganese dioxide whereas the original voltaic pile used brine, which is water that is saturated with salt. They have also found the best metals to use which are inexpensive, but still able to build up and carry the most charge. The types of metals vary with the different types of batteries, which are discussed further in a later section. How Powerful They Are To the drag team, shown in Figure 2, batteries are what make their races successful. Currently, this specific motorcycle holds the world record as the quickest electric vehicle of any kind. The motorcycle, called the KillaCycle®, is completely powered by batteries, can be standing still and accelerate to 60 miles-per-hour in less than a second [4]. The batteries used to The KillaCycle® Figure 2. The powerful batteries in the motorcycle allow it to reach speeds of over 150 miles-per-hour in less than 10 seconds and at a distance of only one-fourth of a mile [4]! Fully electric, it can still show power comparable to its fossil fuel counterparts. power the bike are the same kinds that power some cordless power tools. To compare this power with fossil fuels, only drag-racing vehicles can achieve this same acceleration. However, this motorcycle only uses about $0.07 worth of fuel (in this case electricity), whereas the average dragster can use over $200 of nitro-methane fuel [4]. Now take a step back and think if the energy in those batteries was also generated by renewable sources. That would make each run a really clean ride in terms of the environment. One minor drawback to an electric motor, however, is the horsepower compared to a fossil-fuel dragster which can exceed 5000 horsepower. The electric drag motorcycle in Figure 2 still boasts over 500 horsepower. This may not be enough to replace some ships engines which can put out about 3700 horsepower [8], but it is plenty to replace engines in many passenger vehicles and even some trucks. Batteries can provide enough clean power to race a motorcycle and power some vehicles, but also plenty to power a phone for more than a day. Due to this versatility, batteries have already shown their dynamic utility, and, therefore are not a farfetched solution to storing large amounts of power from wind or solar sources. There are also many different types of batteries which can be used to store different amounts of power in different places. As previously stated, batteries come in many shapes, sizes and capabilities, which include batteries that would suit the storage of excess renewable energy. The batteries used in smaller electronics give up cycle life for size. In the case of these larger-scale batteries, size would not be as much of an issue. Therefore, batteries with better cycle lives could be used without considering size or weight. Types of Batteries Where it might be possible to have a very large array of AA batteries stacked in a large warehouse somewhere, it would probably be more efficient and useful to choose a battery that suits the situation. Many batteries are made from very rare metals or toxic chemicals because those materials work well together to create a voltage and discharge at a given rate. For example, alkaline batteries have potassium hydroxide as part of the chemical process. The battery casing is made out of metal, but it is not entirely indestructible. Over time, the casing can become brittle or break under pressure or heat. If the potassium hydroxide did manage to leak, it is a very corrosive acid that can cause severe chemical burns [9]. Due to the toxicity and rarity of the materials for some batteries, research has gone into finding alternatives for those batteries. One of those successes is the battery commonly found in cell phones. It no longer uses any toxic chemicals as an electrolyte. Instead, these batteries, Lithium-Ion batteries, rely on the highly reactive lithium metal which can store energy in its atomic bonds [10]. These batteries are very safe chemically, but they still have problems with the highly reactive elements used in the battery. The elements can cause a combustive reaction, but they are very rare [10]. With research also came other batteries like Lead Acid and Capacitive batteries. These are two batteries which are very useful with applications in storing large amounts of power for low cost. Lead Acid batteries are the oldest type of rechargeable batteries (see Figure 3) [6]. The reason that they were replaced in most devices was the fact that toxic chemicals and metals are used in the batteries. However, these are still the most widely used batteries in most automobiles because of their low cost and long life. Eventually, these may be replaced with a more environmentally friendly battery, like a Lithium-ion battery, but are much cheaper for the time being. The problem, beyond the environmental issue, is that these batteries are very Different Batteries Figure 3. The larger battery picture above is a Lead Acid battery most commonly used in automobiles. The ultracapacitor battery is pictured below that and may be the future of batteries. [5] hard to recharge if they become completely discharged. However, they still provide a viable option considering their reliability when charged and the amount of energy that they can store. Capacitive batteries, on the other hand, may not be able to hold as much energy in the space provided, but they are environmentally friendly. They are not composed of any type of toxic chemical or rare metal and they may have an even longer life than the Lead Acid battery. This type of Nanoscale Capacitor Figure 4. Many of the visible features in this picture (i.e. the spaces between the capacitive plates) are only a few microns, which is one one-millionth of a meter. This being done allows for capacitors to be made using dimensions that were previously thought to be improbably achieved. battery is still under a lot of research and has not yet replaced all other types of batteries, but they are expected to perform as well as most batteries on the market [5]. They also provide another low-cost solution. They are lightweight enough and low profile to replace batteries in small electronics, they are made of environmentally friendly materials, and they can hold enough energy to contain excess from renewable energy generation. These may be the future of batteries in most electronics, large and small. They can also be made into nanoscale capacitive batteries to make batteries even smaller. This is achieved using the growing field of nanofabrication. With it, capacitors can be created like the ones pictured in Figure 4. Capacitors are better with more surface area for each plate and with a small distance in between each plate. Due to the advances in fabrication processes, these two features can be achieved with much more ease than using larger plates for capacitors. Hopefully, these will be able to provide an alternative to the more unfriendly batteries like the lead acid batteries. Also, there will continue to be more research on new battery technology that may surpass even the theoretical usefulness of the capacitive batteries. Conclusion Whether or not renewable energy generation will need to utilize battery storage in the future, batteries already posses the capability of doing so. Since so much research has gone into creating better batteries, the technology already existed as the need arose. Batteries are so versatile and powerful that they have the ability to replace the energy source for almost any electronic device that currently receives power from a more conventional, but less environmental, source. Their simple design makes them easy to use, their composition allows for them to store and release large amounts of energy, and their composition also allows for clean and safe use. Batteries can help make the idea of clean energy more realistic and help it move along faster. References [1] J. Luoma. “The Challenge for Green Energy: How to store Excess Electricity.” Yale Environment 360. [On-Line] Available: E360.yale.edu/content/feature.msp?id=2170. [2] M. Bellis. “Battery: History Timeline of the Battery.” About.com Inventors. [On-Line] Available: Inventors.about.com/od/bstartinventions/a/History-Of-The-Battery.htm. [3] Northwestern University Qualitative Reasoning Group. “How do batteries work?” [On-Line] Available: www.qrg.northwestern.edu/projects/vss/docs/power/2-how-do-batteries-work.html. [4] “KillaCycle Specs. And the KillaCycle Team.” Killacycle.com. [On-Line] Available: www.killacycle.com/about/. [5] J. Mulroy. “Nano-scale Ultra Capacitors Challenge the Lithium-Ion Battery.” PC World. [On-Line]. Available: www.pcworld.com/article/192300/nanoscale_ultra_capacitors_challenge_the_lithium_ion_battery.html. [6] Cadex Electronics Inc. “What’s the Best Battery?” Battery University. [On-Line]. Available: http://batteryuniversity.com/learn/article/whats_the_best_battery. [7] A123 Systems Inc. “Core Technology.” [On-Line]. www.a123systems.com/technology-core.htm. [8] K. Bonsor. “How Floating cities will work.” [On-line]. Available: http://science.howstuffworks.com/engineering/structural/floating-city1.htm. [9] “Remote Power Transfer – the end of batteries.” Childlikes.com. [On-line]. Available: http://www.childlikes.com/battery.htm. [10] M. Brain. “How Lithium-ion Batteries Work.” [On-line]. Available: http://electronics.howstuffworks.com/everyday-tech/lithium-ion-battery.htm.