SAFETY DATA SHEET
Citrus Clean
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SECTION 1 - PRODUCT AND COMPANY INFORMATION
Product Name:
Product Use:
Supplier Name and Address:
: Citrus Clean
: Cleaning agent
: Corporate Facility Supply
7 Neilson Street
St. Catharines, ON L2M 5V9
Telephone:
Emergency Telephone:
: (905) 682-8888
: CANUTEC (613) 996-6666
SECTION 2 - HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Physical State:
GHS Classification:
Eye Irritation:
Skin Irritation:
Acute Toxicity
GHS Label Elements:
Hazard Pictograms
: Viscous liquid
Signal Word:
Hazard Statements:
Warning
H315 Causes skin irritation
H320 Causes eye irritation
Prevention
P263 Do not get in eyes, on skin, or on clothing
P280 Wear protective gloves/protective clothing, eye
protection/face protection
Response
P302+P352 IF ON SKIN: Wash with plenty of water
P332+P313 If skin irritation occurs: Get medical
advice/attention
P305+P351+P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
Precautionary Statements:
Potential Health Effects:
Inhalation
Skin
Eyes
Ingestion
Aggravated Medical Condition
: Category 2B
: Category 3
: Category 3
: Moderately irritating to the eyes, nose, throat and lungs.
High concentration of vapours or misting may cause
irritation. Excessive exposure may cause irritation to upper
respiratory tract (nose and throat)
: May cause skin irritation.
: May cause eye irritation.
: May be harmful if swallowed, causing nausea, vomiting
and diarrhea. Possible central nervous system depression,
headache, giddiness and loss of co-ordination.
: None known
SAFETY DATA SHEET
Citrus Clean
Symptoms of Overexposure
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: None known
SECTION 3 - COMPOSITION/ INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENTS
Chemical Name
Sodium metasilicate pentahydrate
Dipropylene glycol monobutyl ether
Fatty alcohol ethoxylate
D'limonene
Coconut diethanolamide
CAS-No.
6834-92-0
34590-94-8
68131-39-5
5989-27-5
68603-42-9
Concentration [%]
3
3
3
3
3
SECTION 4 - FIRST-AID MEASURES
General Advice
: Move out of dangerous area
Consult a physician
Show this Safety Data Sheet to the doctor in
attendance
: Move victim to fresh air. Give artificial
respiration only if breathing has stopped.
Give cardiopulmonary resuscitation (CPR) if
there is no breathing and no pulse. Obtain
medical attention immediately.
: Immediately flush with cool water for 15
minutes while removing contaminated
clothing and shoes. Discard or wash well
before reuse. Seek medical attention if
irritation develops/persists.
: If a contact lens is present, DO NOT delay
irrigation or attempt to remove the lens. Get
medical attention if irritation develops and
persists. Rinse with water. Immediately flush
with cool water. Remove contact lenses, if
applicable, and continue flushing for 15
minutes. Seek medical attention if irritation
develops.
: Do not induce vomiting. Rinse mouth with
water then drink one or two glasses of
water. Seek medical attention, or contact
poison control centre immediately. Never
give anything my mouth if victim is
unconscious, is rapidly loosing
consciousness or in convulsing. If vomiting
occurs, keep head low so that stomach
content doesn't get into the lungs. IF
SWALLOWED: immediately call a POISON
CENTRE or doctor/physician.
Inhalation
Skin Contact
Eye Contact
Ingestion
SECTION 5 - FIRE-FIGHTING MEASURES
Suitable extinguishing media
Specific hazards arising from the chemical
Special protective actions for fire-fighters
Additional advice
: Alcohol foam, carbon dioxide, dry chemical
: None known
: None
: Fire-fighters should wear chemical-resistant
clothing (i.e chemical splash suit) and a
positive pressure self-contained breathing
SAFETY DATA SHEET
Citrus Clean
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apparatus as approved by NIOSH/MHSA
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal precautions
Environmental precautions
Methods and materials for containment/
cleaning up
Additional advice
: Wear appropriate protective equipment.
: Prevent entry into sewers or streams. Dike if needed.
: Isolate hazard area and restrict access. Try to work
upwind of spill. Ventilate area. Prevent spilled material
from entering sewers, confined spaces, drains, or
waterways. Absorb with an inert dry material and place in
an appropriate waste disposal container. Clean up residual
with absorbent material and wash with water.
: None
SECTION 7 - HANDLING AND STORAGE
Precautions for safe handling
Conditions for safe storage
Other data
: Use of nitrile gloves and eye protection is optional.
: Keep out of reach of children. Do not freeze. Store in a
closed container away from incompatible materials as
provided in Section 10.
: Do not freeze.
SECTION 8 - EXPOSURE CONTROLS/ PERSONAL PROTECTION
Control parameters
Engineering Controls
: Not available
: Normal building ventilation is adequate.
Ensure that eyewash stations and safety showers are
close to the workstation location
Personal Protective Equipment
Eye/face protection
Hand protection
Skin protection
Respiratory protection
Hygiene measures
: Safety glasses with side shields when there is potential for
eye contact. Face shield also recommended for handling
large amounts. Contact lenses should not be worn
: Nitrile or rubber gloves are recommended
: Protective coveralls or thick clothing that covers exposed
skin
: Wear a NIOSH/MSHA approved air-purifying respirator
equipped with chlorine cartridges when vapours reach high
levels
: Handle in accordance with good industrial hygiene and
safety practice
When using do not eat or drink
When using do not smoke
Wash hands before breaks and at the end of the workday
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Odor Threshold:
pH:
Melting point/ freezing point:
Initial boiling point and boiling range:
Flash point:
Evaporation rate:
Flammability (solid, gas):
Upper/lower flammability or explosive limits:
Vapour pressure:
: Clear, viscous, orange liquid
: Citrus
: Not available
: 12.0-12.6
: Not available
: Not available
: Not available
: Not available
: Not available
: Not available
: Not available
SAFETY DATA SHEET
Citrus Clean
Vapour density:
Relative density (g/mL):
Water solubility:
Solubility in other solvents:
Partition coefficient: n-octanol/water:
Auto-ignition temperature:
Decomposition temperature:
Viscosity:
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: Not available
: 1.03
: Not available
: Not available
: Not available
: Not available
: Not available
: As water
SECTION 10 - STABILITY AND REACTIVITY
Reactivity
Chemical Stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition products
: Product is stable
: Stable under normal conditions
: Hazardous decomposition products are not known
: Avoid contact with oxidizing chemicals.
: Strong oxidizing agents
: Not available
SECTION 11 - TOXICOLOGICAL INFORMATION
Product Information
Acute toxicity
Skin Corrosion/ Irritation
Serious eye damage/irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT-single exposure
STOT-repeated exposure
Aspiration hazard
Toxicology Data for Ingredients
Sodium Metasilicate Pentahydrate
Acute toxicity
Skin irritation
Eye irritation
Sensitization
Dipropylene glycol monobutyl ether
Acute toxicity
Skin irritation
Eye irritation
Sensitization
Fatty alcohol ethoxylate
Acute toxicity
Skin irritation
Eye irritation
Sensitization
D'limonene
Acute toxicity
Skin irritation
Eye irritation
Sensitization
: LD50 Not available
: Not available
: Not available
: Not available
: Not available
: Not available
: Not Available
: Not available
: Not available
: Not available
: LD50 (oral, rat) 1153 mg/kg
LC50 (inhalation, rat) 20000 ppm/10h
: Not available
: Not available
: Not available
: LD50 (oral, rat) 7292 mg/kg
LD50 (skin, rabbit) 2764 mg/kg
LC50 Not available
: Not available
: Not available
: Not available
: LD50 (oral, rat) 2000 mg/kg
LC50 Not available
: Not available
: Not available
: Not available
: LD50 (oral, rat) 4400 mg/kg
LD50 (skin, rabbit) >2000 mg/kg
LC50 Not available
: Not available
: Not available
: Not available
SAFETY DATA SHEET
Citrus Clean
Coconut diethanolamide
Acute toxicity
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: LD50 (oral, rat) 5000-10000 mg/kg
LC50 Not available
: Not available
: Not available
: Not available
Skin irritation
Eye irritation
Sensitization
SECTION 12 - ECOLOGICAL INFORMATION
Product Information:
Toxicity:
: Not available
Persistence and degradability:
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
Toxicology Data for Ingredients:
Sodium metasilicate pentahydrate
Toxicity:
Persistence and degradability:
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
Dipropylene glycol monobutyl ether
Toxicity:
Persistence and degradability:
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
Fatty alcohol ethoxylate
Toxicity:
Persistence and degradability:
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
D'limonene
Toxicity:
Persistence and degradability:
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
Coconut diethanolamide
Toxicity:
Persistence and degradability:
Bioaccumulative potential:
Mobility in soil:
Other adverse effects:
: Not available
: Not available
: Not available
: Not available
: LC50 Not available
: Not available
: Not available
: Not available
: Not available
: LC50 Not available
: Not available
: Not available
: Not available
: Not available
: LC50 Not available
: Not available
: Not available
: Not available
: Not available
: LC50 Not available
: Not available
: Not available
: Not available
: Not available
: LC50 Not available
: Not available
: Not available
: Not available
: Not available
SECTION 13 - DISPOSAL CONSIDERATIONS
Product
: Sanitary sewer or dry absorbent if available.
For large quantities, contact local environmental
department or government authorities
Do not dispose in drains, waterways, or soil
Do not contaminate ponds, or ditches with chemical or the
used container
SAFETY DATA SHEET
Citrus Clean
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SECTION 14 - TRANSPORT INFORMATION
UN Number
UN Proper Shipping Name
Transport hazard class(es)
Packing group, if applicable
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of
MARPOL 73/78 and the IBC Code
: Not available
: Not available
: Not available
: Not available
: Not available
: Not available
: Not applicable
SECTION 15 - REGULATORY INFORMATION
WHMIS Status
: Not known
WHMIS classification
: D2B
SECTION 16 - OTHER INFORMATION
Prepared by: Technical Services
Telephone number: (905) 682-8888
Preparation date: August 2015
NOTICE: The data and information presented herein are based upon tests, research and reports which are considered by us to be reliable and believed
to be accurate. The data and information are presented without warranty, guarantee or liability on our part, and are presented to the customer for his
own consideration, investigation and verification. If user requires independent information on ingredients in this or any other material, we recommend
contact with Canadian Centre for Occupational Health and Safety (CCOHS) in Hamilton, Ontario (905 572-4400)