CHE 251 Elementary Organic Chemistry Fall 2011 Instructor: Lecture Period: Office: Office Hours: Telephone: E-mail: Website: Ms. Sara L. Johnson MWF 9:00 am – 9:50 am in Bobby Chain Technology Building (TEC) 101 TEC 429 Mondays and Wednesdays 10:00 – 11:00 a.m. Thursdays 2:00 – 4:00 p.m. or by appointment (e-mail preferable) 601.266.4702 Sara.Johnson@usm.edu http://ocean.otr.usm.edu/~w328039 COURSE DESCRIPTION The goal of this course is to prepare you for Principles of Biochemistry (CHE 420). With this in mind, we will cover topics in general and organic chemistry. The topics covered in this chemistry course include but are not limited to acids & bases, reaction kinetics, organic molecules and reactions. As the instructor, it is my job to facilitate your learning. To do this, I will strive to present the material in a clear and organized fashion. However, it is not my responsibility to make you learn. As a student, it is your responsibility to learn the material and perform at your best. This includes completing all class assignments, attending any review sessions when possible and making this class a top study priority. This course introduces a variety of chemical concepts and requires maximum effort for success. Because the material builds on itself throughout the semester and is necessary for future science courses, it is imperative that you keep up! CHE 251 L is a co-requisite for this lecture. All questions concerning the lab portion of this course should be directed toward the lab coordinator, Mrs. Tina Masterson at Tina.Masterson@usm.edu. COURSE MATERIALS A. Required Text: General, Organic, and Biological Chemistry: A Guided Inquiry by Michael P. Garoutte ISBN 978-0-471-76359-8. B. Calculator: Graphing calculators are permitted, but not necessary, for this class; however, some type of scientific calculator is required. Your calculator needs to be able to handle exponential and logarithmic functions. Cell phones may not be used as calculators during quizzes or exams. C. Suggested Materials: I will reference many books to help teach this class; these books are not required. On occasion, I will provide handouts, online resources or reserve materials at the campus library. Along with these materials, I would suggest obtaining a copy of a general chemistry textbook, organic chemistry textbook or both (depending on your current level of comfort with chemistry). These can be purchased used at low cost. If you would like to look through a text before purchasing it, I have a variety of textbooks in my office, including: Organic Chemistry as a Second Language by David R. Klein Basic Concepts of Chemistry by Leo J. Malone & Theodore O. Dolter Introduction to Organic Chemistry by William H. Brown Organic Chemistry by Janice G. Smith Organic Chemistry: A Short Course by Harold Hart, et al. EVALUATION AND GRADING A. Exams: Four exams will be given over the course of the semester (100 points each): three class exams and one comprehensive final exam. If the score on your final exam is higher than the lowest score of your class tests, the lower score will be replaced with the final exam grade. No makeup exams will be given. A missed exam will be replaced with your final exam grade. Late students will not be admitted into a test after 20 minutes have passed or after the first test has been turned in. I reserve the right to add points uniformly to class scores. B. Quizzes: Ten in-class quizzes (10 to 15 points each) will be given throughout the semester. Quizzes will not be announced and will cover current class topics. C. Participation: 150 participation points will be awarded based on involvement in the class (i.e. attendance, participating in class discussions, in class assignments, etc.) D. Final Grade: Points for the semester will be awarded as follows. No extra credit will be given. In class exams (3) Final exam (1) Quizzes (10) Participation Total 300 points 100 points 150 points 150 points 700 points Your course percentage can be determined by dividing your total points by 7. Students with less than 60 % will receive an F in the class. All other grades will be assigned as follows: A 100 – 90% B 89 – 80% C 79 – 70% D 69 – 60% CLASSROOM CONDUCT A. Attendance: Classroom attendance has been shown to have a positive effect on grades. For this reason, you are expected to attend all lectures and exams and to arrive on time. Attendance may occasionally be taken. Experience shows that students who do not come to class do not do well. In fact, most failures are directly related to poor class attendance. B. Tardiness: Sometimes tardiness is unavoidable. If you know ahead of time you will have to leave early or be late for class, please try not to disturb the class. This is best achieved by informing me before class if you must leave early and planning to sit on the outside of a row or in the back of the room on such days. If for some reason you must leave in an emergency situation, please be courteous to both your fellow students and myself. C. Electronic devices: Computers, recording devices and other educational aids may be used in class; however, these privileges will be revoked if they are abused (e.g. Facebook, e-mail, etc.). Please turn all cell phones, pagers, etc. off during class. Such devices are a distraction and discourteous to your fellow students. No communication devices are to be used during tests. If you disrupt the class in any way you may be asked to leave and you forfeit your right to turn in any quizzes or assignments due that day. COURSE SCHEDULE Course Topic Outline Atomic Structure, Molecular Structure & Bonding Quantitative Chemistry Kinetics & Equilibria Acids, Bases & Buffers Introduciton to Organic Molecules Nomenclature Functional Groups Alkanes & Their Reactions Alkenes & Their Reactions Isomerism Physical Properties Organic Molecules in Biochemistry TEST 1 TEST 2 TEST 3 FINAL EXAM These topics are listed in order of appearance in the course; however, the time we spend on each topic will be determined as we progress. We may not get to all topics listed. Test occurrences are approximate and subject to change; tests will be announced at least one week in advance. Important Dates September 7 October 5 December 15 Last day to drop and receive 100% financial credit Last day to drop without academic penalty Comprehensive Final Exam (1:30 p.m. – 4:00 p.m.) Department of Chemistry and Biochemistry Syllabus Statements Professionalism Students are required to maintain a professional attitude during the class. Disrespect of the instructor and/or of other students will not be tolerated. Not permitted in the classroom during class time will be distractions such as eating, cell phone use, or laptop computer use. Academic Honesty “When cheating is discovered, the faculty member may give the student an F on the work involved or in the course. If further disciplinary action is deemed appropriate, the student should be reported to the Dean of Students. In addition to being a violation of academic honesty, cheating violates the Code of Student Conduct and may be grounds for probation, suspension, and/or expulsion. Students on disciplinary suspension may not enroll in any courses offered by The University of Southern Mississippi.” Plagiarism is included in this policy. Dropping Courses “A student is permitted to drop a course without academic penalty up to and including approved dates published in the Class Schedule Guide. After the deadline, a student may drop a course only in the event of extenuating circumstances and with permission of the instructor, department chair, and dean of the college offering the course, at which time the student will receive a grade of WP or WF.” Extenuating circumstances are normally defined as circumstances which are unexpected, significantly disruptive and beyond a student’s control. Examples of this might include an extended illness, experience of assault, robbery or other traumatic event, eviction/homelessness, unavoidable involvement in extended legal proceedings, and call up to full time military duty during the semester. Other disruptive circumstances will be considered if they are judged to have an extended impact on the student's ability to attend and prepare for the class and are beyond the student's control. In each case, documentation of the circumstances is required. Extenuating circumstances do NOT include academic reasons such as poor performance in class, missed too many classes without valid excuses, lost textbook or notes, class is no longer needed, cannot understand the material or the teacher, had a period of brief illness, missed classes due to athletic or other school responsibilities, too busy with other classes, did not know the class would take this much time, thought they could handle the class and work at the same time, and change of major. Disability Accommodation If a student has a disability that qualifies under the American with Disabilities Act (ADA) and requires accommodations, he/she should contact the Office for Disability Accommodations (ODA) for information on appropriate policies and procedures. Disabilities covered by ADA may include learning, psychiatric, physical disabilities, or chronic health disorders. Students can contact ODA if they are not certain whether a medical condition/disability qualifies at: The University of Southern Mississippi, Office for Disability Accommodations; 118 College Drive # 8586, Hattiesburg, MS 39406-0001 Voice Telephone: (601) 266-5024 or (228) 214-3232; Fax: (601) 266-6035 Individuals with hearing impairments can contact ODA using the Mississippi Relay Service at 1-800-582-2233 (TTY) or email Suzy Hebert at Suzanne.Hebert@usm.edu. CHE 106 Atomic Structure -protons, neutrons, electrons -atomic weight -the periodic table (names, how it relates to electrons, etc.) -molecules, compounds, formulas: structures and naming of -anions, cations Bonding and Molecular Structure -ionic, covalent bond formation -lewis structures -formal charge -orbitals and electron configuration notation -hybridization? -double bonds? -molecular shapes -polarity and electronegativity Math -atoms, molecules, moles -concentration CHE 107 From Kotz and Treichel 12 15 16 17 19 20 Organic Intermolecular Forces and Liquids Chemical Kinetics: The Rates of Chemical Reactions Principles of Chemical Reacitivity: Equilibria Acids and Bases: Titrations? Principles of Chemical Reactivity: Entropy and Free Energy Principles of Chemical Reactivity: Electron Transfer Reactions Functional Groups Nomenclature Shapes Biochem 05 06 09 10 11 12 13 16 17 18 19 20 23 24 Chapter 2.4-2.6/Chapter 3.1 – 3.3 (Organic Compounds) Chapter 3.4-3.13 Chapter 4.1-4.4 (Alkenes); EXAM 2 (8.5-9.12, Chapter 2&3) Chapter 4.5-4.8/Chapter 5.1-5.5 (Reactions of Alkenes) Chapter 5.6- 5.15/ Chapter 6.1-6.5 (Delocalized Electrons) Chapter 6.6-6.12/Chapter 7.1-7.4 (Aromaticity) Chapter 7.5-7.15/Chapter 8.1-8.6 (Isomers/Stereochemistry) Chapter 8.7-8.14/ EXAM 3 (Chapters 4-8.6) Chapter 10.1 – 10.8 (Substitution and Elimination Rxns) Chapter 10.9-10.11/Chapter 11.1 – 11.5 (Rxns of Alcohols/Amines) Chapter 11.6-11.9/Chapter 12.1-12.6 (Carbonyl Compounds) Chapter 11.6-11.9/Chapter 12.7-12.3 Chapter 17 (Amino Acids, Peptides, and Proteins) FINAL EXAM (Chapter 8.7-17) Atomic Structure, Molecular Structure & Bonding ChemActivity 3: Model 1 ChemActivity 7: Models 1-3 ChemActivity 10 Quantitative Chemistry Chemistry Activity 4: Models 2-4 Kinetics & Equilibria Acids, Bases & Buffers Organic Molecules & Functional Groups Organic Molecules in Biochemistry Reactions of Organic Molecules