Attempting to Eliminate Oil from Melted Plastic Products Aarti Anand, Carly Dooley, Kathleen Thurmes December 10, 2009 8:05 – 9:17 PM Civil Engineering Building, Room 742 Introduction and Objective We intend to investigate the leaching of oil out of the melted plastic we produce. There are several reasons the oil could be present in the plastic after melting, and we will attempt to address each possible reason: A) The oil leaks out of the plastic immediately after melting, and so the leaching can be stopped by simple removal (wiping or rinsing) directly after it is removed from the oil. B) The leaching is caused by contraction of the plastic during cooling, which essentially pushes the oil out of the plastic and to the surface. This can be determined by dousing the melted plastic in a cold bath immediately following its removal from the oil. C) Flour can be used after cooling to cover up the sliminess of the plastic. Materials Roundy’s all-natural vegetable oil HDPE plastic chips from milk cartons 2 Melting cups of ambiguous silver metal material Hot plate Spoon Stirring knife Metal tray for molding Procedure and Observations Part A: Wipe the plastic with a rag right after melting. We used about half a cup of oil and heated it on a hot plate at a heat setting of 3 out of 12 in a fume hood. After about ten minutes of heating the oil on setting 3, we inserted about 1/8 cup of plastic chips. Ten minutes at setting 3 was not long enough to get the oil hot and the plastic wasn’t melting, so we increased the heat to 11 out of 12. After about three to five minutes, the plastic chips started melting/ fusing together (8:25). After about a minute, the plastic started to turn clear. It didn’t stick to the sides of the vessel, however, even when pushed against them. When the plastic was clear all the way through, it had reached its malleable state. We removed the plastic mass at 8:29. The oil smelled as though it had been heated to fry something, but there was no smell of burning and nothing dark in the oil itself; the oil, in fact, did not appear to be dirty, contaminated, or toxic at all. We molded the plastic with a spoon and immediately wiped the piece with a rag to rid it of oil. This did not rid the plastic of oil – the piece was as slimy/oily as ever. There were no bubbles in the plastic. Part B: Douse the plastic immediately in a cold bath. We started on a heat setting of 5 out of 12 at 00:00:00 (we timed this trial) with a little over half a cup of vegetable oil. We let the oil heat for 12 minutes. We then put in about 1/8 cup of plastic chips, once again. We increased the heat setting to 7 out of 12, then soon increased the heat to 11 out of 12, because the oil was not being heated and the plastic was not melting. Finally, we removed the plastic heap (00:28:32) and put it almost immediately into a cold bath. The water was not very cold however, due to lack of ice in the lab. At 00:30:35 we took the plastic out of the water. The water was a little cloudy from the oil, but the plastic was still very oil from heating. The oil used to melt the plastic itself was very clear still – there appeared to be no junk in it except for a few stray pieces of un-melted plastic shards. Once again, the plastic was giving off the cooked oil smell after removal, suggesting that it was still seeped through with oil. Some oil rose to the surface of the water, but not all the oil from the plastic piece was released in the water, so it was a very thin layer of oil floating on the surface. Part C: Use flour on the slimy piece from Part A. We covered the slimy piece from part A with flour at 8:44 by putting flour in a beaker and dropping the piece in then shaking. We then scooped up flour – after leaving the piece in the beaker for about thirty seconds – and pressed it to the plastic in parts where the flour had not yet adhered. Then at 8:46 we rinsed the piece off with water and dried it; it was still sticky. We put the piece back in the flour, then, and let it sit for 33 minutes. It still appeared to be just a slimy piece of plastic with flour on it. Conclusions Disposal of waste and other experiment materials: We left our labeled samples in the lab room. The oil waste was taken back to the EWB room to be added to the “toxic sludge” waste bucket. The oil water was disposed of down the drain. None of the methods we used here were successful in either stopping the oil leaching or covering it up. However, we only used vegetable oil and HDPE plastic; perhaps our results would be different if we used a different melting medium and/or a different type of plastic.