Portfolio 7: UV-Vis

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Aaron Pyle
CHM 338-102
3/27/13
Portfolio 7: Ultraviolet Visible Spectroscopy
Block Diagram:
http://www.chem.agilent.com/en-US/products-services/instruments-systems/molecularspectroscopy/8453-uv-vis-diode-array-system/Pages/photodiode_array_benefits.aspx
Vendors:
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Aurora Biomed
Avantes
HORIBA Scientific
Ocean Optics
P&P Optica
Photon Technology International, Inc.
Qubit Systems Inc.
Research Articles:
1. Poindexter, E. F., & Schultz, L. D. (2013). Ultraviolet-Visible Spectroscopic Investigation of
Reaction of Rubidium and Tellurium in Liquid Ammonia Solution. Spectroscopy Letters, (justaccepted).
Aaron Pyle
CHM 338-102
3/27/13
-In this experiment, the reaction of tellurium with rubidium in liquid ammonia solution was monitored
by ultraviolet-visible spectroscopy. The reaction times for rubidium with tellurium in liquid ammonia
were turned out to be slower than those of sodium and potassium.
2. Lamhasni, T., Aitlyazidi, S., Hnach, M., Haddad, M., Desmaële, D., Spanget-Larsen, J., ... &
Ducasse, L. (2013). Photo-physics study of an hydroxy-quinoline derivative as inhibitor of Pim-1
kinase: Ultraviolet-visible linear dichroism spectroscopy and quantum chemical
calculations. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.
-In this experiment, the properties of the antiviral 7-nicotinoyl-styrylquinoline were investigated by
means of UV-Vis linear dichroism spectroscopy. Molecular samples were in stretched polyvinylalcohol
and supported by Time Dependent Density Functional Theory calculations.
3. Koshtyal, Y. M., Malkov, A. A., Vasilyeva, K. L., Zakharova, N. V., & Malygin, A. A. (2013). The role
of a reference sample in the study of the titanium-containing silicas by ultraviolet-visible diffuse
reflectance spectroscopy. Russian Journal of General Chemistry, 83(2), 231-237.
-Silica gel with grown titanium oxide structures were used, in which titanium had two coordination
enviromments: anatase and rutile). The experiment showed the effect of the choice of a reference
(MgO, SiO2) on the shape of the ultraviolet-visible diffuse reflectance spectra and the result of their
mathematical processing.
Common Uses:
-Generally, it is used for the detection of metal ions and organic compounds.
-Specifically, it is can be used for the detection of DNA, RNA, proteins, constituents in blood serum, drug
testing and food testing.
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