First Semester Practice Problems 1. What is the answer with the correct number of significant figures for these problems? a. 3.900 + .0789 b. 4.511 - 2.3 c. 0.00777 x 340 d. 5401/2220 3.979 2.2 2.6 2.43 2. How many significant figures in these numbers? a. 4.570 b. 6700 c. 0.0098 d. 0.0980 4 2 2 3 3. How much energy is required to raise the temperature of an 225g aluminum pan from room temperature (32C) to 100C? The heat capacity of aluminum is 0.900 J/gC. 13770 J 4. What is the mass of a silver pot if 1575 J of energy raises its temperature 150C? The heat capacity of silver is 0.235 J/gC. m = 44.7 g 5. Fill in the blanks in the following table: Isotope Mass # Atomic # symbol 52 Cr24 52 24 197 Au79 197 79 122 Cd48 122 48 #protons #neutrons #electrons 24 79 48 28 118 74 24 79 48 6. Determine the molar mass of these compounds: a. MgBr2 b. Fe(ClO2)3 c. Al2(CO3)3 184.13g 258.20g 233.99g 7. Determine the percent composition of Mg(NO3)2. 16.3% Mg 18.89% N 64.72% O 8. What is the empirical formula of a compound composed of 88.5% B and 11.5% H? B5H7 9. What is the empirical formula of a compound composed of 92.26% C and 7.74% H? CH 10. Convert to moles: a. 56.7 g H2O b. 301 g Mg(NO2)2 c. 0.667 g MgBr2 3.15 mol 2.03 mol 00.362 mole 11. Convert to grams a. 1.33 mol H2O b. 0.977 mol Mg(NO2)2 c. 22 mol MgBr2 24.0 g 145 g 4100 g 12. Convert 1345 cm to km. 0.01345 km 13. Convert 0.0644 kg to mg. 64400 mg 14. List the discovery each man is credited with making: a. Rutherford nucleus with protons using gold foil experiment b. Thomson electron c. Bohr electrons reside in energy levelsd. Dalton First atomic theory (know the planks) 15. Iridium has two isotopes. Ir-191 has an abundance of 37.30% and Ir-193 has an abundance of 62.70%. What is the average atomic mass of iridium? 192.25 amu 16. Name the following ionic compounds: NaBr: sodium bromide Mn(NO3)2 manganese (II) nitrate PbSO4 lead (II) sulfate Al3(CO3)3 aluminum carbonate C2S4 PBr3 CCl4 B2O5 17. Give the formula for these ionic compounds: copper (II) hydroxide Cu(OH)2 magnesium chloride MgCl2 aluminum nitrite Al(NO3)3 calcium phosphate Ca3(PO4)2 dihydrogen monoxide carbon dioxide diphosphorous pentoxide 18. Identify the correct periodic table family. Answers will be used more than once. alkali metals, alkaline earth metals, transition metals, rare earth metals, metalloids, nonmetals, halogens, noble gases metalloids semi-conductors alkali explosive in water noble gases 8 valence shell electrons rare earth noble gases most difficult to extract from ores lowest melting and boiling points trans/rare high melting and boiling points noble gases gases at room temperature nonmetals form organic compounds alkali metal soft metals alkaline earth two valence shell electrons halogens members in all three states of matter at room temperature. nonmetals “elements of life” alkali metals with lowest densities three fams never found uncombined in nature rare earth some members are radioactive alkali most reactive metals noble gases non-reactive alkaline earth form +2 ions transition metals ductile and malleable alkali 1 valence shell electron rare earth metals thorium is a member of this group transition vanadium is a member of this group nonmetals alkali potassium is a member halogens iodine is a member trans/rare sulfur is a member of this group noble gases krypton is a member transition metals conductors of heat and electricity members may form ions of different charges 19. Determine the electron configuration for the following atoms: Mg: 1s22s22p63s2 Mn: 1s22s22p63s23p64s23d5 Pb: 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p2 How many valence shell electrons will be in each of the following Lewis dot structures? PBr3 CO32CCl4 NH4+