2015-16 Frederick Douglass High School 225 Hamilton Holmes Drive Atlanta, Georgia 30318 Instructor: Miss K. Dixon Tutorials: Thursday 3:45-5PM Email: kdixon@atlanta.k12.ga.us Phone: (404) 802-3100 Conferences: Thursday 4-5PM Room Location: 336 Course Description: The AP Chemistry course is designed, according to College Board, to be equivalent of the general chemistry course usually taken during the first college year. AP Chemistry should meet the objectives of a good college general chemistry course. Students in each course should attain depth of the understanding of fundamentals and a reasonable competence in dealing with chemical problems. The course should contribute to the development of the students’ abilities to think clearly and to express their ideas, verbally and in writing, with clarity and logic. The college course in general chemistry differs qualitatively from the usual first secondary school course in chemistry with respect to the kind of textbook used, the topics covered, the emphasis on chemical calculations and the mathematical formulation of principles, and the kind of laboratory work done by students. Quantitative differences appear, in the number of topics treated, the time spent of the course by the students, and the nature and the variety of experiments done in the laboratory. Course Prerequisites: The AP Chemistry course is designed to be taken only after the successful completion of a first year course in high school chemistry. In addition, the recommended mathematical prerequisite for an AP Chemistry class is successful completion of a second-year algebra course. Textbook: Chemistry: The Central Science 11th edition (Brown, LeMay, Bursten, and Murphy) Course Goals and Objectives: 1. 2. 3. 4. To help students develop a conceptual framework for chemistry. To help students gain an appreciation of science as a process. To help students develop skills that will enable them to be life long learners. To help students develop the ability to demonstrate their knowledge and critical thinking skills about chemistry in written form. 5. To prepare students for the comprehensive AP Chemistry Examination to be given in the Spring. 6. To improve the student’s ability to work, communicate, and learn effectively with others. 7. For the student to recognize that there are common repetitive themes and patterns among the major topics and themes in chemistry. Class Structure: The school operates on a four by four schedule with classes meeting every day for 90 minutes. AP Chemistry classes meet for the same amount of time as other classes. Students must be highly motivated and possess good study habits to do well in the course. Sustaining a solid laboratory program is the Transforming, Teaching, and Learning to Improve Student Achievement most difficult aspect of this course. The class meeting does not allow much time over the course of the year to complete all of the necessary topics and labs, but the labs do reflect major concepts and include a variety of lab techniques for students to learn. Students, therefore, need to be prepared to conduct labs both in class (90 minutes), after school (2 hours), and on occasional Saturdays (2-3 hours). The AP Chemistry class will be taught using a varying combination of techniques with the majority of the material being presented through lecture and laboratory experiences. Instruction will be disseminated using one of the following formats to include instructional strategies such as high level questioning, mentorship/apprenticeship, tiered assignments, independent projects, compacting and learning centers, direct instruction, class discussions and/or Powerpoint presentations, supplemental handouts, videos, technology, research, special projects, individual and group activities, and weekly/bi-weekly assessments. There will be opportunities for which guest speakers will be invited to present current research and laboratory techniques within their fields as it relates to concepts students are expected to master. In addition, field trips will be used as a means of extended learning and field investigations. Below please find a tentative schedule for which concepts and calculations will be covered introduced and covered in depth. The time frame is subsequent to change in regards to unforeseen circumstances (i.e. weather, assemblies, etc.), however all topics will be covered. Assignments, activities, and laboratory investigations will be given during the unit lesson in an effort to reinforce and review content. Topic Outline (according to College Board) The following is an outline of the topics to be covered in AP Chemistry and the correlating percentage of multiple choice questions on the annual spring exam (May 4, 2015): I. Structure of Matter (20%) a. Atomic Theory and atomic structure i. Evidence for the atomic theory ii. Atomic masses; determination by chemical and physical means iii. Atomic number and mass number; isotopes iv. Electron energy levels: atomic spectra, quantum numbers, atomic orbitals v. Periodic relationships including, for example, atomic radii, ionization energies, electron affinities, oxidation states b. Chemical bonding i. Binding forces 1. Types: ionic, covalent, metallic, hydrogen bonding, van der Waals (including London dispersion forces) 2. Relationships to states, structure, and properties of matter 3. Polarity of bonds, electronegativities ii. Molecular models 1. Lewis structures 2. Valence bond: hybridization of orbitals, resonance, sigma and pi bonds 3. VSEPR iii. Geometry of molecules and ions, structural isomerism of simple organic molecules and coordination complexes; dipole moments of molecules; relation of properties to structure c. Nuclear chemistry: nuclear equations, half-lives, and radioactivity; chemical applications 2 II. States of Matter (20%) a. Gases i. Laws of Ideal Gases 1. Equation of state for an ideal gas 2. Partial pressures ii. Kinetic molecular theory 1. Interpretation of ideal gas laws on the basis of this theory 2. Avogadro’s hypothesis and the mole concept 3. Dependence of kinetic energy of molecules on temperature 4. Deviations from ideal gas laws b. Liquids and solids i. Liquids and solids from the kinetic-molecular viewpoint ii. Phase diagrams of one-component systems iii. Changes of state, including critical points and triple points iv. Structure of solids; lattice energies c. Solutions i. Types of solutions and factors affecting solubility ii. Methods of expressing concentration (use of normalities is not tested) iii. Raoult’s law and colligative properties (nonvolatile solutes); osmosis iv. Nonideal behavior (qualitative aspects) III. Reactions (35-40%) a. Reaction Types i. Acid-base reactions; concepts of Arrhenius, Brønsted-Lowry, and Lewis; coordination complexes; amphoterism ii. Precipitation reactions iii. Oxidation-reduction reactions 1. Oxidation number 2. The role of the electron in oxidation-reduction 3. Electrochemistry: electrolytic and galvanic cells; Faraday’s laws; standard halfcell potentials; Nernst equation; prediction of the direction of redox reactions b. Stoichiometry i. Ionic and molecular species present in chemical systems: net ionic equations ii. Balancing of equations, including those for redox reactions iii. Mass and volume relations with emphasis on the mole concept, including empirical formulas and limiting reactants c. Equilibrium i. Concept of dynamic equilibrium, physical and chemical; Le Chatelier’s principle; equilibrium constants ii. Quantitative treatment 1. Equilibrium constants for gaseous reactions: Kp, Kc 2. Equilibrium constants for reactions in solution a. Constants for acids and bases: pK, pH b. Solubility product constants and their application to precipitation and the dissolution of slightly soluble compounds c. Common ion effect; buffers; hydrolysis 3 d. Kinetics i. Concept of rate of reaction ii. Use of experimental data and graphical analysis to determine reactant order, rate constants, and reaction rate laws iii. Effect of temperature changes on rates iv. Energy of activation; the role of catalysts v. The relationship between the rate-determining step and a mechanism e. Thermodynamics i. State functions ii. First law: change in enthalpy; heat of formation; heat of reaction; Hess’s law; heats of vaporization and fusion; calorimetry iii. Second law: entropy; free energy of formation; free energy of reaction; dependence of change in free energy on enthalpy and entropy changes iv. Relationship of change in free energy to equilibrium constants and electrode potentials IV. Descriptive Chemistry (10-15%) Knowledge of specific facts of chemistry is essential for an understanding of principles and concepts. There, descriptive facts, including the chemistry involved in environmental and societal issues, should not be isolated from the principles being studied but should be taught throughout the course to illustrate and illuminate the principles. The following areas will be covered: 1. Chemical reactivity and products of chemical reactions 2. Relationships in the periodic table: horizontal, vertical, and diagonal with examples from alkali and alkaline-earth metals, halogens, and the first series of transition metals. 3. Introduction to organic chemistry: hydrocarbons and functional groups (structure, nomenclature, chemical properties) V. Laboratory (5-10%) The differences between college chemistry and the usual secondary school chemistry course are especially evident in the laboratory work. The AP Chemistry Exam includes some questions based on experiences and skills students acquire in the laboratory: Making observations of chemical reactions and substances Record data Calculating and interpreting results based on the quantitative data obtained Communicating effectively the results of experimental work Instructional Schedule: August 2015 Chapters 1-2 Introduction, Matter and Atoms (Lab: Density; Separation by Chromatography) Chapter 3 Stoichiometry (Nomenclature and Balancing Equations) (Lab: Hydrates; Cu to Cu) 4 September 2015 Chapter 4 Chapter 6 Aqueous Reactions and Solution Stoichiometry (Labs: Preparation of Sodium Bicarbonate and Sodium Carbonate; Reactions in Aqueous Solutions: Metathesis Reactions and NIEs) Electronic Structure of Atoms (Independent Study) October 2015 Chapter 7 Chapter 5 Chapter 10 Periodic Properties of Elements (Independent Study) Thermochemistry (Lab: Hess’ Law) Gas Laws (Labs: Behavior of Gases: Molar Mass of a Vapor; Determination of R) November 2015 Group Presentations (Dates: TBD) Chapter 8 Basic Concepts of Chemical Bonding (Group Presentations) Chapter 9 Molecular Geometry and Bonding Theories (Group Presentations) Chapter 11 Intermolecular Forces, Liquids, and Solids (Group Presentations) December 2015 Chapter 13 Chapter 14 Properties of Solutions Kinetics (Labs: Rates of Chemical Reactions I and II) January 2016 Chapter 15 Chapter 16 February 2016 Chapter 17 Chapter 19 Equilibrium (Labs: LeChâtelier’s Principle; Acid-Base Equilibria Additional Aspects of Aqueous Equilibria (Labs: Hydrolysis of Salts and pH of Buffer Solutions; Chemical Thermodynamics March 2016 Chapter 20 Electrochemistry (Labs: Electrochemical Chemistry and Thermodynamics) April 2016 **Review for AP Exam** Complete Practice AP Exam May 2, 2016 AP Chemistry Exam **SCHEDULE IS SUBJECT TO CHANGE AS NEEDED TO BEST BENEFIT INSTRUCTION** 5 Computation of Grades: Daily Grades/Quizzes/Homework……..……....25% Research Articles/Projects/Lab Reports……….20% Tests………………………………………….…35% Mid-Term/Final………………………………...20% GRADING SCALE A = 90-100 B = 80-89 C = 70-79 F = 69 and below Lab Report Write-Up: **Students will be using Thread Bound Composition Lab Notebooks** Students will be responsible for completing the all components of the lab on the pages provided in the Thread Bound Composition Lab Notebook. The lab write-up will comprised using the following format: I. II. III. IV. V. VI. VII. Title of Laboratory Experiment Introduction and Purpose of Laboratory Experiment Materials Procedure (steps/methods used should be extremely detailed as to possible replication without any assistance being needed) Analysis/Results (all mathematical and graphical components should be included in this section) Conclusion Discussion (students will discuss errors made while completing lab; any changes that may need to be made; possible extension of lab, etc.) Materials Required Daily: 1. 2. 3. 4. 5. 6. 7. 8. Textbook (Chemistry: The Central Science 11th Edition) Three ring binder Pencils (#2) Black/Blue Pens Scientific Calculators Notebook Paper Graphing Paper Supplemental study material for assistance with comprehension of topics/units taught in course. Title to be given to students by instructor. Study guide can usually be found at Barnes and Noble bookstores or ordered online at Amazon.com. 9. A jump drive/thumb drive for saving respective assignments. Attendance: It is truly imperative that all students attend class daily. Please refer to the student handbook addressing student absences and grading policy. It is expected that all students will complete assignments given by instructor and submit them according to the given due date. LATE ASSIGNMENTS MAY BE ACCEPTED ONLY AT THAT SOLE DISCRETION OF THE TEACHER!! If accepted late assignments submitted will be penalized 10 points per day. Make-up assignments will only be administered no later than five (5) calendar days from when the assignment was missed provided proper documentation (illness, family emergency, school related activities, etc.) is submitted. THERE WILL NOT BE MAKE-UP LABS DUE TO THE NATURE OF THE LABORATORY EXPERIENCES. You will however be given an alternative lab to complete—virtual labs or small scale hands on activities. 6