1 Pre-AP Chemistry Notes: Solutions I. Types of Mixtures (p. 395 – 399) Ch. 13 Solutions A. Solution– ____________________________ of 2 or more substances in a single phase 1. Components of Solutions a. __________________ - substance being dissolved --usually ________________ amount b. ______________- dissolving medium --usually present in ________________ amount c. Examples: 2.Types of Solutions air O2 gas and N2 gas _____________________ soda CO2 gas in water _____________________ seawater NaCl in water _____________________ brass copper and zinc _____________________ 3. Characteristics of Solutions a. Have ________________________________ (ions or molecules) b. Are ____________________________ c. __________________________________________ d. ____________________________________________ e. ______________________________________________ 4. Electrolytes a.Substance that dissolves in water to produce a ______________ that _____________________________________________ 1) _______________________ separation of an ionic solid into aqueous ________________ b. Ionic compounds (NaCl) c. Polar cmpds (HCl & other acids) 1) ______________________ - breaking apart of some _____________________________________ into aqueous ions 5. Nonelectrolytes a. Substance that dissolves in water to produce a solution that ______________________________________________________ 1) Molecular Solvation - ________________________________ b. Molecular cmpds (sugar) B. ____________________________ (_____________________________) 1. Characteristics a. Have very ___________________________ (1000x larger than atoms) 2 b. 1000+ nm c. Settle out d. ______________________________________ e. ___________________________________________________ 2. Examples of Suspensions Whole ______________ (with platelets, rbc’s, wbc’s & plasma) Muddy water Calamine lotion (for poison ivy) C. _____________________________ (not solutions) 1. Characteristics a. Have ______________________ size particles b. 1nm to 1000 nanometers c. _____________________________________________ d. Separated with semi-permeable membranes e.Scatter light (______________________________________) 2. Examples of Colloids ______________________________________________________ _______________________________________________________________ _______________________________________________________________ II. The Solution Process (dissolution = dissolving) A. _________________________ – what effects how ________________ something dissolves? 1. _______________ of solute a. Increase surface area of solute – crush the solute – dissolution (the process of dissolving) occurs on the surface of the solute 2. _______________ of solvent a. Agitate the solution – stir it- helps to disperse the solute particles b. opposite for a gas! 3. ____________________________________________ a. Heat the solvent – ______________________ & helps to separate solute particles from each other b. opposite for a gas! 4. ________________________________________ a. _____________________________________________________ _______________________________________________________ b. Gas in contact w/ surface of liquid & some gas is dissolved into the liquid while some gas also escapes the liquid until equilibrium is reached c. If you change the pressure a new _________________ is reached 3 d. __________________________ on the gas (solute) causes more molecules to collide w/ the surface of the liquid so more gas molecules become dissolved in the solvent until a new EQ is reached at the new pressure----____________________ (Le Who?) Principal (apply a stress to a system in EQ & it will eventually reach a new EQ) e. _____________________ (of gas dissolved in a liquid) 1) The solubility of a gas in a liquid is directly proportional to its pressure above the liquid (temp remains constant) SOOOOOOOOOOO… if the pressure of the gas above the liquid increases then the solubility of the gas increases Partial pressure blah, blah, blah B. _____________________________aka dissolution – the process of dissolving 1. _________________________________________________________ ___________________________________________________________ 2. solute particles are _______________________ and pulled into solution C. __________________________ 1. Amt of substance required to form a saturated solution w/ a specific amt of solvent at a specific temp 2. __________________________________ is the opposite of dissoluton! 3. Solution equilibrium – state where the __________________________ = ________________________________ 4. p. 404 Chart shows amt of g of solute that can be dissolve in 100 g water at different temps. 5. Liquids that aren’t soluble in each other are considered ___________________ Liquids that are soluble in each other are considered ___________________ D. Saturated solution 1. A saturated solution contains the ______________________________ ___________________________________________________________ a. If you add any more solute at that temp it will not dissolve but {sink} to the bottom E. Unsaturated 1. An unsaturated solution contains ____________________________ ________________________________________________________________ a. All the solute you put in has dissolved & there is still room in the solution for more solute F. Supersaturated 1. A solution that contains __________________________________ saturated solution can hold under the same conditions! 4 a. Usually prepared by ________________________ & _________________ it, filtering out any excess solute, then letting the solution cool while being careful not to disturb it in any way – if you bump it etc…crystallization begins because it is ______________ __________________! II. Solute-solvent interactions- ____________________________________! A. Ionic compounds dissolve in ____________________________ but not in nonpolar molecular solvents & _____________ substances dissolve in ____________________ substances 1. ___________________ – forming a solution with water as the solvent 2. Some hydrated ionic solutions when crystallized incorporate some of the water molecules in their crystals & are then called _______________ B. Soap/Detergent why does it work on everything? 1______________________ with long ____________________________ 2. dissolves nonpolar grease in polar water C. Heats of Solution 1. ____________________________ goes hand-in-hand w/ an ______________, E can either be absorbed or released dependent on the solute & solvent (can be a really small amount) 2. The ________________________________ is the heat of solution (it’s different for each solute/solvent combo) a. + if heat is absorbed (it gets cold to the touch) endothermic b. - if heat is released (it gets hot to the touch) exothermic III. Concentration of Solutions--The __________________________________. A. Describing Concentration 1. __________________________ - medicated creams 2. __________________________ - rubbing alcohol used by bio 3. ____________________ - water contaminants 4. _________________________- used by chemists 5. _________________________ - used by chemists B. Molarity = ___________________________________________ (not liter of solvent) C. molality = ___________________________________________ D. ______________________________- Preparation of a desired solution by adding water to a concentrate. Moles of solute remain the same. M1V1 = M2V2