7 Conservation of Mass in a Chemical Reaction In a chemical reaction, mass is never created or destroyed. This means that if we can keep track of the mass of all reactants used and all products formed, we should find the final mass unchanged. In this reaction, we will combine solution of sodium carbonate, Na2CO3 and calcium chloride, CaCl2. These chemicals will undergo a double replacement reaction. With careful technique, you will find that the total mass of the products equals the total mass of the reactants. Compound “A” + Compound “B” Compound “C” + Compound “D” CaCl2 + Na2CO3 Objectives: To verify with measurements that mass is conserved during a chemical reaction To explain how errors made during the lab contribute to a “gain” or a loss of mass. Materials: Two 250 mL beakers Filter Funnel Filter Paper Pencil Ring Stand Ring Clamp Calcium Chloride Bunsen Burner Drying Oven Sodium Carbonate DI Water Procedure: 1. Use a pencil to label two clean, dry 250 mL beakers –one with “A” and one with “B”. Record each mass of each beaker to the nearest 0.1 g. 2. Obtain approximately 0.5 g of CaCl2 (Compound “A”) and place it in Beaker A. Record the total mass. 3. Obtain approximately 0.5 g of Na2CO3 (Compound “B”) and place it in Beaker B. Record the total mass. 4. Obtain 12-18mL of DI water in a graduated cylinder. Add the water to Beaker A. Obtain another 12-18 mL of DI water graduated cylinder and add it to Beaker B. Swirl the contents of the beakers until all of the solids have dissolved and the solutions are clear. DO NOT use a stirring rod, as this will cause a loss of compound 5. Slowly add the Na2CO3 from Beaker B into the CaCl2 solution in Beaker A. A white precipitate should form. 6. Wash the sides of Beaker B with a SMALL amount of DI water from the squirt bottle. Pour this water into Beaker A. (This step assures that virtually all of the Na2CO3 has been transferred to the second beaker.) 7. Gently heat the mixture in Beaker A until it reaches the boiling point. This will convert all reactants to products. 8. Allow the beaker and contents to cool while setting up the filtering apparatus (ring stand, ring, and funnel) 9. Obtain a piece of filtering paper. Get the mass of the filter paper then fold the paper as shown by the teacher and place it in the funnel. 10. Place the empty Beaker B below the funnel to catch the solution as it passes through the filter 11. Pour the contents of Beaker A through the filter paper, being careful to keep as much of the precipitate in Beaker A as possible. Rinse the precipitate several times with SMALL amounts of DI water. Do not use a stirring rod to decant. 12. When filtering is complete, remove the filter paper from the funnel and place it in Beaker A with the precipitate. Allow filter paper and precipitate to dry in oven overnight. Measure the final mass of dry compound “C”, filter paper, and Beaker A. 13. Place Beaker B containing the filtrate paper on top of a wire mesh and ring stand. Gently heat this solution to evaporate most of the liquid. CAUTION: DO NOT heat to dryness, as this will cause a loss of product or a cracked beaker. 14. Let Beaker B and compound “D” dry overnight. Measure the final mass of Beaker B and compound “D”. 15. After all final mass measurements have been obtained, discard the filter paper and clean all beakers. 7 Conservation of Mass in a Chemical Reaction (M) In a chemical reaction, mass is never created or destroyed. This means that if we can keep track of the mass of all reactants used and all products formed, we should find the final mass unchanged. In this reaction, we will combine solution of sodium carbonate, Na2CO3 and calcium chloride, CaCl2. These chemicals will undergo a double replacement reaction. With careful technique, you will find that the total mass of the products equals the total mass of the reactants. Compound “A” + Compound “B” Compound “C” + Compound “D” CaCl2 + Na2CO3 __________ + __________ Objectives: To verify with measurements that mass is conserved during a chemical reaction To explain how errors made during the lab contribute to a “gain” or a loss of mass. Materials: Two 250 mL beakers Filter Funnel Filter Paper Pencil Ring Stand Ring Clamp Calcium Chloride Bunsen Burner Drying Oven Sodium Carbonate DI Water Procedure: 1. Use a pencil to label two clean, dry 250 mL beakers –one with “A” and one with “B”. Record each mass of each beaker to the nearest 0.1 g. 2. Place 0.5 g of CaCl2 (Compound “A”) in Beaker A. Record the total mass. ____________ g 3. Place 0.5 g of Na2CO3 (Compound “B”) in Beaker B. Record the total mass. ____________ g 4. Fill a small graduated cylinder to the top with distilled water. Add the water to Beaker A. Fill the graduated cylinder again with distilled water and add it to Beaker B. Swirl the contents of the beakers until all of the solids have dissolved and the solutions are clear. DO NOT use a stirring rod, as this will cause you to lose some of the compound. 5. Slowly pour the contents of Beaker B into the solution in Beaker A. You should notice a white precipitate should form. *Remember, a precipitate is a solid formed in a liquid during a reaction. 6. Wash the sides of Beaker B with a SMALL amount of DI water from a squirt bottle. Pour this water into Beaker A. (This step assures that virtually all of the Na2CO3 has been transferred to the second beaker.) 7. Gently heat the mixture in Beaker A until it reaches the boiling point. This will convert all reactants to products. 8. Allow the beaker and contents to cool while setting up the filtering apparatus (ring stand, ring, and funnel) 9. Obtain a piece of filtering paper. Get the mass of the filter paper then fold the paper as shown by the teacher and place it in the funnel. 10. Place the empty Beaker B below the funnel to catch the solution as it passes through the filter. 11. SLOWLY pour the contents of Beaker A through the filter paper, being careful to keep as much of the precipitate (the solid) in Beaker A as possible. Rinse the precipitate several times with SMALL amounts of DI water. Do not use a stirring rod to decant. 12. When filtering is complete, remove the filter paper from the funnel and place it in Beaker A with the precipitate. Allow filter paper and precipitate to dry in oven overnight. Measure the final mass of dry compound “C”, filter paper, and Beaker A. 13. Place Beaker B containing the filtrate paper on top of a wire mesh and ring stand. Gently heat this solution to evaporate most of the liquid. CAUTION: DO NOT heat to dryness, as this will cause a loss of product or a cracked beaker. 14. Let Beaker B and compound “D” dry overnight. Measure the final mass of Beaker B and compound “D”. 15. After all final mass measurements have been obtained, discard the filter paper and clean all beakers. Data Table: Reactants Total mass of beaker A and CaCl2 Mass of beaker A Subtract to get the mass of CaCl2 Total mass of beaker B and Na2CO3 Mass of beaker B Subtract to get the mass of Na2CO3 Add the masses of CaCl2 and Na2CO3 (Reactants) Data Table: Products Mass of the filter paper, Beaker A, CaCO3 Mass of the filter paper Mass of Beaker A Subtract to get just the mass of CaCO3 Mass of the beaker B and NaCl Mass of beaker B Subtract to get the mass of NaCl Add the masses of CaCO3 and NaCl (Products) Analysis Table: Subtract the mass of the Reactants from the products (the last line from the reactant and product tables)