Site Risk Assessment Soil Screening Levels Concentration mg/kg Chloride Arsenic Barium Cadmium Calcium Chromium Lead Magnesium Sodium WV Background Soil Concentration (Range) mk/kg NOAA SQuiRTs Eco-SSL mg/kg EPA Residential Soil mg/kg EPA Soil to Groundwater mg/kg WV Soil to Groundwater mg/kg 2550 16 203 ND 37100 27.9 23.4 6400 1230 EPA Drinking Water MCL mg/l 250 (secondary) 5.9-13 300-500 400-2500 30-70 10-20 2000-5000 1500-7000 5.7 (mammals) 1.04 (mammals) 0.0022 (mammals) 0.389 15300 70 0.292 82.4 0.376 5.8 1600 7.5 0.01 2 5 0.4 (invertebrates) 0.0537 (mammals) 276 400 180000 13.5 270 100 0.015 Notes: EPA considers chromium (CAS number 7440-47-3) as total chromium (Cr VI to Cr III at 1 to 6 ratio). NOAA SQuiRTs treats the same CAS number as chromium III only. West Virginia’s Soil to Groundwater chromium III has a different CAS number and isn’t, for that reason, on this table. SSL stands for Soil Screening Level which is not the same as maximum limit. Some SQuiRTs concentrations are presented in terms of percent. 10,000 mk/kg is equal to 1%. So, in the above table, calcium is 3.7% of sample. SQuiRTs concentrations are all parts per billion. Divide those values by 1,000 to get parts per million, mg/kg or mg/l. Sources: Table 2-3: Natural Background Levels of Inorganics in Soil in West Virginia and Surrounding Areas from West Virginia Department of Environmental Protection. 2001. West Virginia Voluntary Remediation and Redevelopment Act: Guidance Manual Version 2.1. West Virginia Department of Environmental Protection, Office of Environmental Remediation. http://www.wvdep.org/show_blob.cfm?ID=3200& Name=RemediationGuidanceVersion2-1.pdf. Background soil ranges are based on 10 samples or less. NOAA SQuiRTs -- Buchman, M. F. 2008. NOAA Screening Quick Reference Tables. Seattle, WA: Office of Response and Restoration Division, National Oceanic and Atmospheric Administration, NOAA OR&R Report 08-1. http://response.restoration.noaa.gov/book_shelf/12 2_NEW-SQuiRTs.pdf. The table used was Screening Quick Reference Table for Inorganics in Soil, pages 3 and 4, the Eco-SSL section. These values are more protective than those published by the EPA. EPA Residential Soil -- Screening levels provided by EPA’s Region III online calculator. EPA. Regional Screening Levels for Chemical Contaminants at Superfund Sites, online calculator for Risk Assessment Region III. http://epa-prgs.ornl.gov/cgibin/chemicals/csl_search. EPA Soil to Groundwater -- Screening levels provided by EPA’s Region III online calculator and are MCL based risk levels. EPA. Regional Screening Levels for Chemical Contaminants at Superfund Sites, online calculator for Risk Assessment Region III. http://epa-prgs.ornl.gov/cgibin/chemicals/csl_search. WV Soil to Groundwater -- Screening levels come from Table 60-3B in 60CSR3. http://www.wvdep.org/show_blob.cfm?ID=17897& Name=deminimis%20table%20from%2060%20CSR% 203%20VRRA%20rule%206-5-09.pdf. EPA Drinking Water MCL (Maximum Contamination Limit) -- EPA. 2003. National Primary Drinking Water Standards. U.S. Environmental Protection Agency, Office of Water (4606M), EPA 816-F-03-016 (includes National Secondary Drinking Water Standards). http://www.epa.gov/safewater/consumer/pdf/mc l.pdf. This site risk assessment soil screening levels table is for the exposed pit waste at a natural gas well site in Kanawha County, West Virginia. Two blog posts on our blog at sootypaws.livejournal.com deal with the site and material on this table: Risk Assessment, Parts One and Two. Those links are, respectively: http://sootypaws.livejournal.com/16516.html and http://sootypaws.livejournal.com/16314.html. The well completion report for this well as filed with the state can be seen at: http://downloads.wvgs.wvnet.edu/BatchInfo/ kanawha/4703905714compO.tif. Materials related to waste management can be seen at our website at: http://members.citynet.net/sootypaws/Woods /gaswell/comments/waste_index.html.