Pennsylvania 2007 Area Source Criteria Air Pollutant Emission Estimation Methods December 2009 Prepared by Pennsylvania Department of Environmental Protection Bureau of Air Quality Rachel Carson State Office Building PO Box 8468 Harrisburg, PA 17105-8468 Contact: Sherry Bogart, 717-783-5974, sbogart@state.pa.us 2 TABLE OF CONTENTS AREA SOURCE DEFINITION .......................................................................................................................................5 METHODS FOR ESTIMATING AREA SOURCE ACTIVITY AND EMISSIONS ....................................................5 ADHESIVES AND SEALANTS (SCC 2460600000) ...................................................................................................12 AIRCRAFT COATING (SCC 2401075000) .................................................................................................................14 APPLIANCES (SCC 2401060000) ................................................................................................................................16 ARCHITECTURAL SURFACE COATINGS (SCC 2401001000) ..............................................................................18 ASPHALT PAVING (2 SCCs) ......................................................................................................................................20 AUTOMOTIVE AFTERMARKET PRODUCTS (SCC 2460400000) .........................................................................25 AUTOMOTIVE REFINISHING (SCC 2401005000) ...................................................................................................27 BAKERIES (SCC 2302050000) ....................................................................................................................................29 COATINGS AND RELATED PRODUCTS (SCC 2460500000) .................................................................................31 COMMERCIAL COOKING – (5 SCCs) .......................................................................................................................33 CONSTRUCTION DUST (3 SCCs: SCC 2311010000, SCC 2311020000, SCC 2311030000) ..................................41 DEGREASING (4 SCCs: SCC 2415360000, SCC 2415300000, SCC 2415230000, SCC 2415200000).....................53 DRY CLEANERS (SCC 2420000000) ..........................................................................................................................56 ELECTRONIC AND OTHER ELECTRIC COATINGS (SCC 2401065000) ..............................................................58 FACTORY FINISHED WOOD (SCC 2401015000) .....................................................................................................60 FIFRA-REGULATED PRODUCTS (SCC 2460800000) .............................................................................................61 FUEL COMBUSTION – COMMERCIAL/INSTITUTIONAL (7 SCCs: SCC 2103001000, SCC 2103002000, .......64 SCC 2103004000, SCC 2103005000, SCC 2103006000, SCC 2103007000, SCC 2103011000) ................................64 FUEL COMBUSTION – INDUSTRIAL (7 SCCs: 2102001000, ................................................................................79 SCC 2102002000, SCC 2102004000, SCC 2102005000,..............................................................................................79 SCC 2102006000, SCC 2102007000, SCC 2102011000) .............................................................................................79 GASOLINE MARKETING (5 SCCs) .........................................................................................................................102 GRAPHIC ARTS (SCC 2425000000) .........................................................................................................................107 HOUSEHOLD PRODUCTS (SCC 2460200000)........................................................................................................108 INDUSTRIAL MAINTENANCE COATINGS (SCC 2401100000) ..........................................................................110 3 MACHINERY AND EQUIPMENT (SCC 2401055000) ............................................................................................111 MARINE COATING (SCC 2401080000) ...................................................................................................................113 METAL CANS (SCC 2401040000).............................................................................................................................116 METAL FURNITURE (SCC 2401025000) .................................................................................................................118 METAL SHEETS, STRIPS, COILS (SCC 2401045000) ............................................................................................119 MISCELLANEOUS MANUFACTURING (SCC 2401090000).................................................................................121 MISCELLANEOUS PRODUCTS (NOT OTHERWISE COVERED) (SCC 2460900000) .......................................123 OPEN BURNING (3 CCs) ...........................................................................................................................................125 OTHER SPECIAL PURPOSE COATINGS (SCC 2401200000)................................................................................130 PAPER, FOIL AND FILM (SCC 2401030000) ..........................................................................................................132 PERSONAL CARE PRODUCTS (SCC 2460100000) ................................................................................................134 PORTABLE FUEL CONTAINERS – GASOLINE DISTRIBUTION (10 SCCs) .....................................................136 PUBLIC OWNED TREATMENT WORKS (SCC: 2630020000) ..............................................................................139 RAILROAD SOLVENTS (SCC 2401085000) ............................................................................................................141 RESIDENTIAL COAL FOSSIL FUEL COMBUSTION (2 SCCs: SCC 2104001000, SCC 2104002000)...............143 RESIDENTIAL FUEL OIL/KEROSENE COMBUSTION (2 SCCs: SCC 2104004000, SCC 2104011000) ...........150 RESIDENTIAL LIQUIFIED PETROLEUM GAS (LPG) (SCC 2104007000) ..........................................................155 RESIDENTIAL NATURAL GAS (SCC 2104006000) ...............................................................................................158 TRAFFIC LINE PAINTING (SCC 2401008000)........................................................................................................162 WINERIES (SCC 2302070005) ...................................................................................................................................164 WOOD FURNITURE AND FIXTURES (SCC 2401020000) ....................................................................................166 ACKNOWLEDGEMENTS..........................................................................................................................................168 4 [This page intentionally left blank.] 5 AREA SOURCE DEFINITION For emission inventory development purposes, the term “area sources” traditionally refers to stationary air pollutant emission sources that are not inventoried at the facility-level. While point sources are inventoried individually, area sources are typically inventoried at the county level (Introduction to Area Source Emission Inventory Development Volume III: Chapter 1)1. Sources such as gasoline stations and dry cleaning establishments are often treated as both point and area sources. The main reason they are not exclusively treated as point sources is that the effort required to gather data and estimate emissions for each individual facility is very great, while emissions per facility are generally small. For these sources, a cut-off point, typically based on annual emissions, usually defines the distinction between point and area. The Consolidated Emissions Reporting Rule (CERR) specifies reporting criteria air pollutant (CAP) thresholds for point and area sources, which vary depending on the pollutant and the attainment status of a county (see http://www.epa.gov/ttn/chief/cerr/index.html). Individual emissions sources are grouped with other like sources into source categories. These source categories are grouped in such a way that they can be estimated collectively using one methodology. Most area source categories do not have an analogue in the point source inventory. Commercial/consumer product use is such an example. The boundaries of the individual activities associated with these sources are often hard to determine or are, at best, arbitrary. Even within a point source facility, some activities occur that are more easily treated as area source emissions. Some emissions associated with surface coating operations such as equipment cleaning, for example, can be more practically estimated using area source methods even though other surface coating operations may be reported as part of the point source inventory. METHODS FOR ESTIMATING AREA SOURCE ACTIVITY AND EMISSIONS Area source emissions are generally estimated by multiplying an emission factor by some known indicator or collective activity for each area source category at the county level. Several methodologies are available for estimating area source activity levels and emissions. For this 2007 area source inventory, estimates were derived by (1) treating area sources as point sources, (2) obtaining Eastern Research Group, Inc., “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 1, Introduction to Area Source Emission Inventory Development (Revised Final),” prepared for the Area Sources Committee, Emission Inventory Improvement Program, January 2001. 1 6 county-level activity data, (3) apportioning national or statewide activity data to counties, (4) use of per capita emission factors, and (5) use of per employee emission factors. Each approach has distinct advantages and disadvantages as discussed below. Small sources that would normally be treated as area sources may be handled as point sources for several reasons. First, county level activity data may not be readily determinable for certain source categories. Municipal landfills provide an example of this situation. For some source categories, county activity estimates were available. For example, monthly wine production data for 2007 were available by county from the Alcohol & Tobacco Tax and Trade Bureau, Department of Treasury. If county activity data were not available, Commonwealth totals were apportioned to counties using data for a surrogate of the emissions activity. For example, the quantity of highway gasoline consumed in the Commonwealth was apportioned to the county level on the basis of vehicle miles traveled per county. Residential, commercial, and industrial fuel combustion were other categories that were handled in this manner. The major drawbacks of this approach are that additional data and resources are needed to apportion activity levels to the local level, and accuracy is lost in the process. If Commonwealth level data were not available, then national data were used in a similar manner. Sources in certain area source categories were not only numerous and diffuse, but were too difficult to inventory by any of the above procedures. As an example, solvent evaporation from consumer and commercial products such as waxes, aerosol products and window cleaners cannot be routinely determined by DEP. In addition, it would be resource-intensive to develop and implement a survey that would yield such information. Per capita or per employee emission factors are used to estimate emissions for these source categories. The use of per capita emission factors is based on the assumption that, for a given source category, emission activity can be reasonably associated with population. This assumption is valid over broad areas for certain categories such as Architectural Surface Coating and solvent evaporation from Consumer and Commercial Products. For categories that rely on a per capita emission factor, county population estimates for 2007 were obtained from the U.S. Bureau of the Census. When emissions are calculated from per employee emission factors, county-level employment data for 2006 were obtained. Because county employment data for 2007 was not be available from the Bureau of the Census’ County Business Patterns (CBP) until July 2009, data for the appropriate North American Industrial Classification System (NAICS) codes were obtained by E. H. Pechan & Associates from the 2006 CBP1. The Commonwealth-level employment data were obtained at the NAICS code level from the U.S. Bureau of Labor Statistics.2 1 U.S. Department of Commerce, Bureau of the Census, County Business Patterns 2006, Pennsylvania, available from http://www.census.gov/epcd/cbp/view/cbpview.html,. 2 U.S. Bureau of Labor Statistics, Current Employment Statistics, available from http://www.bls.gov/sae/home.htm. 7 In some cases, the Census does not report the employment value for a particular NAICS code/county combination because of confidentiality concerns. In these cases, the Census provides employment data as a range (e.g., between 20 and 99 employees). When a precise number of employees was not available from CBP, an initial estimate was developed based on the mid-point of the reported range (e.g., 60 employees was used for the 20 to 99 employment range). For a given NAICS code, the mid-point estimates were then adjusted up or down to yield the Commonwealth-level employment for that NAICS code as reported in the CBP. The adjustments were computed by first calculating the difference between the Commonwealth-level CBP employment and the total of the employment values for counties for which actual employment values were reported in the CBP. The resulting value represents employment for the counties for which the CBP reports an employment range value. This value was then divided by the sum of the mid-point employment estimates for the counties for which employment was reported as a range. The resulting ratio was multiplied by the mid-point estimates to yield the final county employment estimates. The calculation spreadsheets provide each of the steps used in this estimation procedure. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor was performed by E.H. Pechan & Associates. Control Efficiency (CE) Control efficiency is the emission reduction percentage associated with a control device, process change or reformulation. Control efficiencies can vary widely by source within an area source category. Area source control efficiency values represent the weighted average control for the category. Rule Penetration (RP) Because lower-emitting sources within a source category may not be covered by a regulation, it is important to reflect the extent to which total source category emissions are affected. Rule penetration represents the percentage of total source category emissions that are affected by a regulation. 8 Rule Effectiveness (RE) Rule effectiveness is a factor used to adjust the control efficiency to account for failures and uncertainties that affect the actual performance of the control. For example, control equipment performance may be adversely affected by age of the equipment, lack of maintenance, or improper use. With the exception of Federal regulations, a default RE value of 80 percent was applied when information was not available to substantiate the true RE value1. An RE of 100 percent was applied to all Federal regulations that require national compliance. The RE factor is applied to the estimated control efficiency in the calculation of emissions from a source. The formula for the application of CE, RP, and RE is displayed below: Uncontrolled Emissions Control Efficiency Rule Penetration Rule Effectiveness = = = = 50 pounds per day 90 percent 60 percent 80 percent Controlled Emissions = Uncontrolled Emissions × (1 – CE/100 × RP/100 × RE/100) Controlled Emissions = 50 × (1 – 0.9 × 0.6 × 0.8) = 50 × (1 – 0.432) = 28.4 pounds per day An RE and/or RP value can substantially increase emission estimates when high control efficiencies are involved. For example, if RP was not applied in the above example (equivalent to a 100 percent RP assumption), then estimated emissions are: Controlled Emissions = 50 × (1 – 0.9 × 0.8) = 50 × (1 – 0.72) = 14 pounds per day. Eastern Research Group, Inc., “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 1, Introduction to Area Source Emission Inventory Development (Revised Final),” prepared for the Area Sources Committee, Emission Inventory Improvement Program, January 2001. 1 9 Point Source Subtractions Source categories can appear in both the area source and point source inventory. For example, emissions from large dry cleaning establishments may be included in the point source inventory, while emissions from smaller dry cleaners (below some specified cutoff) are included in the area source inventory. When a point source inventory and an area source inventory include emissions from the same process, the area source emission estimates are adjusted to avoid double counting. Although many area source categories (e.g., Architectural Surface Coating) do not have companion point source categories, there are many source categories in the area source inventory for which emissions are reported in the Pennsylvania point source inventory (see Table 1). For these source categories, point source emissions are subtracted from total emission estimates to yield area source emissions. Ideally, this adjustment would occur in the area source emission calculation by subtracting point source emission activity (throughput) from total emission activity as shown below. Area Source Activity Total Activity Point Source Activity However, the Pennsylvania point source inventory does not report throughput for most sources. Therefore, it was necessary to calculate the point source subtractions using total and point source emission estimates as identified below. Area Emissionsp Total Emissionsp Point Source Emissionsp where: p = pollutant Separate point source inventories were developed for Allegheny and Philadelphia counties and for all other counties. Except for ammonia and lead, the Allegheny inventory reports annual emissions for all pollutants included in the area source inventory. These pollutants are also missing from the Philadelphia County annual inventory. Unlike the Allegheny inventory, the Philadelphia County inventory does not report PM emissions on a filterable and condensable basis, but rather on a primary basis. The inventory for the remaining counties reports annual emissions for the same pollutants as the Philadelphia County inventory, with the exception of primary PM2.5 (PM25-PRI), which is not reported for the remaining counties. Given the different ways in which PM emissions are reported in the 2002 Pennsylvania point source inventory, it was necessary to develop PM emissions on a consistent basis to facilitate the point source subtractions. Therefore, for Allegheny County, Pechan summed the condensable and the filterable PM emissions to obtain PM10-PRI and PM25-PRI emission values for use in the point source subtractions. 10 To facilitate the point source subtractions, the annual emission records for all point SCCs associated with an area source category were summed to the county level. The county-level point source annual emissions were then subtracted from the area source category annual emissions using an area source category-to-point source category crosswalk developed for this project. Note that in keeping with EIIP guidance, when the resulting area source emission estimate was negative, the area source emission value was set to zero. The following presents an example of point source NOx emission subtraction calculations for the Commercial/Institutional Bituminous/Sub-bituminous Coal Combustion category (SCC 2103002000). Area Source NOx Emissions for SCC 2103002000 Total NOx Emissions Po int NOx Emissions Total NOx Emissions for SCC 2103002000 ( Allegheny Cnty) 1,054.3025 tons per year Po int Source NOx Emissions ( Allegheny Cnty) 152.0751 tons (SCC 10300207 ) 6.2277 tons (SCC 10300208 ) Area Source NOx Emissions for SCC 2103002000 1,054.3025 tons 158.3028 tons 895.9997 tons The following individual sections describe the annual and seasonal emission estimation methodology for each area source category. Each section contains a brief description of the source category, identifies whether the category’s emission estimates were subject to point source emission subtractions, and presents sample emission calculations (point source subtractions are not included in these sample calculations). All referenced sources are displayed in Appendix A. 11 Table 1. Area Source Inventory Categories with Point Source Emission Subtractions SCC 2102001000 2102002000 2103001000 2103002000 2103004000 2102004000 2103005000 2102005000 2103006000 2102006000 2103007000 2302070001 2401015000 2401020000 2401040000 SCC1DESC Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Industrial Processes Solvent Utilization Solvent Utilization Solvent Utilization SCC3DESC Industrial Industrial Commercial/Institutional Commercial/Institutional Commercial/Institutional Industrial Commercial/Institutional Industrial Commercial/Institutional Industrial Industrial Food and Kindred Products: SIC 20 Surface Coating Surface Coating Surface Coating 2401050000 2401055000 2401080000 2401085000 2401090000 2415200000 2415300000 2425000000 2501060053 2501060101 2501060102 2601010000 2601020000 2620030000 Solvent Utilization Solvent Utilization Solvent Utilization Solvent Utilization Solvent Utilization Solvent Utilization Solvent Utilization Solvent Utilization Storage and Transport Storage and Transport Storage and Transport Waste Disposal, Treatment, and Recovery Waste Disposal, Treatment, and Recovery Waste Disposal, Treatment, and Recovery Surface Coating Surface Coating Surface Coating Surface Coating Surface Coating Degreasing Degreasing Graphic Arts Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage On-site Incineration On-site Incineration Landfills SCC6DESC Anthracite Coal Bituminous/Sub-bituminous Coal Anthracite Coal Bituminous/Sub-bituminous Coal Distillate Oil Distillate Oil Residual Oil Residual Oil Natural Gas Natural Gas Liquefied Petroleum Gas (LPG) Fermentation/Beverages Factory Finished Wood: SIC 2426 thru 242 Wood Furniture: SIC 25 Metal Cans: SIC 341 Miscellaneous Finished Metals: SIC 34 - (341 + 3498) Machinery and Equipment: SIC 35 Marine: SIC 373 Railroad: SIC 374 Miscellaneous Manufacturing All Industries: Conveyerized Degreasing All Industries: Cold Cleaning All Processes Gasoline Service Stations Gasoline Service Stations Gasoline Service Stations Industrial Commercial/Institutional Municipal SCC8DESC Total: All Boiler Types Total: All Boiler Types Total: All Boiler Types Total: All Boiler Types Total: Boilers and IC Engines Total: Boilers and IC Engines Total: All Boiler Types Total: All Boiler Types Total: Boilers and IC Engines Total: Boilers and IC Engines Total: All Combustor Types Breweries Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Total: All Solvent Types Stage 1: Balanced Submerged Filling Stage 2: Displacement Loss/Uncontrolled Stage 2: Displacement Loss/Controlled Total Total Total 12 ADHESIVES AND SEALANTS (SCC 2460600000) Adhesives are formulated organic polymer compounds that adhere to, or form a bond between, one or more substrates. They are commonly referred to as cements, glues and pastes. Adhesives can be classified as water-based, solventbased, hot melts, or radiation curable. Sealants and caulking compounds are organic polymers used to fill or seal gaps between surfaces. The primary solvents used in formulating adhesives and sealants are aliphatic hydrocarbons and keytones. County-level emissions were calculated using a per capita emission factor which was obtained from the Emission Inventory Improvement Program (EIIP)1 and U.S. Bureau of the Census 2007 population data2. The emission factor represents pre-control emission rates. A CE of 8.3 percent3 and an RP of 48.6 percent4 were applied to reflect the Federal Rule for consumer products. There are no point sources associated with this category. Each county’s emissions are estimated per the sample calculations listed below. Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 5, Consumer and Commercial Solvent Use,” Table 5.4-1, prepared for the Area Sources Committee, Emission Inventory Improvement Program, August 1996, available from http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed March 2009 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 2 3 4 ERTAC Recommendation, Midwest RPO Inventory Comparability Project, revised June 2, 2009, accessed June 2009. E.H. Pechan & Associates, Inc., Control Measure Development Support Analysis of Ozone Transport Commission Model Rules, prepared for the Ozone Transport Commission, March 2001. 13 SAMPLE VOC EMISSION CALCULATIONS: CE RP RE Annual VOC Emissions Emission Factor Population 1 100 100 100 where: Emission Factor = 0.57 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County)2 Control Efficiency = 8.3%3 RP (Rule Penetration) = 48.6%4 RE (Rule Effectiveness) = 100% 0.57 lbsVOC person 8.3 48.6 100 Annual VOC Emissions 1,219,2101 year 100 100 100 1 ton 333.47 tons VOC per year Annual VOC Emissions 666,916.82 pounds per year 2000 lbs 14 AIRCRAFT COATING (SCC 2401075000) This source category includes aircraft building and repairing. The emissions were calculated using an employmentbased emission factor1 and employee data from NAICS code 3364XX. The number of employees in each county for 2006 was collected by E.H. Pechan and Associates, who calculated the midpoints from any given ranges2. Each county’s emissions were estimated per the following sample calculations below. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 15 lbs VOC /employee/year Employees = 4494 employees (Delaware County) 1 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed October, 2009. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 15 15 lbsVOC Employee Annual VOC Emissions year 4494 Employees 1 ton Annual VOC Emissions 67,410 pounds VOC per year 33.705 tons VOC per year 2000 lbs 16 APPLIANCES (SCC 2401060000) The VOC emissions from this source category result from the evaporation of the solvent used in the coating process in the manufacture of electrical appliances such as refrigerators, freezers, laundry equipment, and electric house wares. Emissions for each county were estimated per the sample calculations below using an employment-based emission factor1 and the number of 2006 employees in the NAICS codes 3352XX. . The number of Appliance employees was collected from U.S. Census Bureau’s County Business Patterns2 by E. H. Pechan and Associates who calculated midpoints for any ranges obtained. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 249 lbs VOC/employee/year Employees = 41 (Berks County) 1 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed September 2009. National, state and county level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 17 249 lbsVOC employee Annual VOC Emissions 41 employees year 1ton Annual VOC Emissions 10,209 pounds VOC per year 5.1045 tons VOC per year 2000 pounds 18 ARCHITECTURAL SURFACE COATINGS (SCC 2401001000) Architectural surface coatings are used by homeowners and painting contractors to coat the interior and exterior of buildings and other structures. The coatings are applied by spray, brush, or roller and dry or cure at ambient conditions. The VOC emissions from this source category result from the evaporation of the paint and cleanup solvents. Each county’s emissions were calculated using a per capita emission factor1 and U.S. Bureau of the Census 2007 county population data2. The Federal architectural surface coating regulations call for a 20 percent reduction in the solvent content of architectural surface coatings manufactured after September 1999, which reduction was accounted for in the development of the new per capita emission factor for states with AC rules (2.41 lbs VOC/person/year)1. Each county’s emissions are estimated per the sample calculations listed below. SAMPLE VOC EMISSION CALCULATIONS: RP RE Annual VOC Emissions Emission Factor Population 1 100 100 1 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed August 2009. U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 2 19 where: Emission Factor = 2.41 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County) CE (Control Efficiency) =0%, integral with new EF, for states with AC rules1 RP (Rule Penetration) = 100% RE (Rule Effectiveness) = 100% 2.41lbsVOC person 100 100 Annual VOC Emissions 1,219,210 people 1 year 100 100 1 ton 1469.1481 tons VOC per year Annual VOC Emissions 2,938,296.10 pounds per year 2000 lbs 20 ASPHALT PAVING (2 SCCs) SCC category’s emissions for 2461021000 (Cutback Asphalt) and 2461022000 (Emulsified Asphalt) were calculated by E.H. Pechan and Associates. The following documentation was prepared by E.H. Pechan and Associates with footnotes located at the end of this section: Asphalt paving is the process of applying asphalt concrete to seal or repair the surface of roads, parking lots, driveways, walkways, or airport runways. Asphalt concrete is a composite material comprised of a binder and a mineral aggregate. The binder, referred to as asphalt cement, is a byproduct of petroleum refining and contains the semi-solid residual material left after the more volatile chemical fractions have been distilled off.1 a. Emulsified Asphalt Asphalt cements thinned with water and an emulsifying agent are known as cutback asphalts. This thinning reduces the viscosity of the asphalt making it easier to work with the mixture. The primary uses of emulsified asphalt include tack and seal operations, priming roadbeds, and paving operations for pavements up to several inches thick. Emulsified asphalt may contain up to 12 percent organic solvents by volume.1 Emissions from emulsified asphalt result from the evaporation of VOCs after the mixture is laid down. Compared to cutback asphalt, emulsified asphalt has lower VOCs emissions per ton used. b. Cutback Asphalt Asphalt cements thinned with petroleum distillates are known as cutback asphalts. The primary uses of cutback asphalt include tack and seal operations, priming roadbeds, and paving operations for pavements up to several inches thick. Cutback asphalt is produced by thinning the binder in a diluent containing 25 to 45 percent petroleum distillates by volume prior to mixing with the aggregate. This reduces the viscosity of the asphalt making it easier to work with the mixture. Emissions from cutback asphalt result from the evaporation of VOCs and HAPS after the mixture is laid down. Of all asphalt types, cutback asphalt has the highest diluent content and, as a result, emits the highest levels of VOCs per ton 21 used. The timeframe and quantity of VOC and HAP emissions depend on the type and the quantity of organic solvent used as a diluent. For these source categories, the following SCCs were assigned: SCC 2461022000 2461021000 SCC Level 1 Solvent Utilization Solvent Utilization SCC Level 2 Misc. Non-industrial: Commercial Miscellaneous Nonindustrial: Commercial SCC Level 3 Emulsified Asphalt Cutback Asphalt SCC Level 4 Total: All Solvent Types Total: All Solvent Types The general approach to calculating emissions from emulsified asphalt and cutback asphalt paving is to multiply the estimated county-level emulsified asphalt usage by emission factors for VOCs. State-level emulsified asphalt and cutback asphalt usage in 2008 was obtained from the Asphalt Institute’s 2008 Asphalt Usage Survey.2 State-level data were allocated to county-level according to the fraction of paved road vehicle miles traveled (VMT) in each county. Total annual VMT estimates by State and roadway class were obtained from the Federal Highway Administration’s (FHWA) annual Highway Statistics report.3 Paved road VMT was calculated by subtracting the State/roadway class unpaved road VMT from total State/roadway class VMT. State-level paved road VMT was spatially allocated to counties according to the fraction of total VMT in each county for the specific roadway class as shown by the following equation: VMTx,total = ∑VMTST,y * VMTx,y / VMTST,y where: VMTx,total = VMT (million miles) in county x on all paved roadways VMTST,y = paved road VMT for the entire State for roadway class y VMTx,y = total VMT (million miles) in county x and roadway class y VMTST,y = total VMT (million miles) in entire State for roadway class y 22 The county-level total VMT by roadway class used in this calculation was previously developed by E.H. Pechan and Associates, Inc. to support the on-road national emissions inventory.4 c. Emission Factors Emission factors for emulsified asphalt and cutback asphalt usage were obtained from the Technical Report Series produced by the U.S. EPA’s Emission Inventory Improvement Program and are reported in Table 1 below.1 d. Emissions Emissions were calculated by multiplying the county-level asphalt usage (barrels) by the emission factors listed in Table 1 and then dividing by 2000 to convert pounds to tons. Emissionsx,y = (Asphalt Usagex * EFy) / 2000 where: Emissionsx,y = emissions (tons) of pollutant y in county x Asphalt Usagex = emulsified asphalt (barrels) used in county x EFy = emission factor for pollutant y To convert tons of asphalt reported in the 2008 Asphalt Usage Survey to barrels, it was assumed that the density of asphalt is similar to that of water, 8.34 lbs/gal, and that one barrel equals 42 gallons. Barrels of Asphalt = (tons of asphalt * 2000 lbs / 8.34 lbs/gal) / 42 gal/barrel Note that one barrel of asphalt weights approximately 350 pounds. 23 e. Sample Calculation VOC emissions from emulsified asphalt usage in Allegheny County, Pennsylvania: From the 2008 Asphalt Usage Survey, the state of Pennsylvania used 69,671 tons of emulsified asphalt in 2008. The fraction of paved road VMT traveled in Allegheny County is 10,516.10 million miles divided by 104,400.2 million miles which equals 0.10073. Asphalt Usage Allegheny = ((69,671 tons * 2000 lbs / 8.34 lbs/gal) / 42 gal/barrel) * 0.10073 Asphalt Usage Allegheny = 40,070.571 barrels VOC Emissions Allegheny = (40,070.571 barrels * 9.2 lbs/barrel) / 2000 lbs/ton VOC Emissions = 184.32 tons Table 1. Criteria Emission Factors for Emulsified and Cutback Asphalt Paving Pollutant Description Pollutant Code VOLATILE ORGANIC COMPOUNDS VOC VOLATILE ORGANIC COMPOUNDS VOC Emission Factor Emission Factor (LBS/BARRE Reference L) 9.2 Emulsified Asphalt 88.00 Cutback Asphalt 24 f. References 1. U.S. Environmental Protection Agency, Emissions Inventory Improvement Program, Technical Report Series, Volume III – Area Sources, Chapter 17, “Asphalt Paving,” prepared by Eastern Research Group, Inc. for EPA, Research Triangle Park, NC, 2001. Available at http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html. 2. Asphalt Institute, 2008 Asphalt Usage Survey for the United States and Canada, http://www.asphaltinstitute.org/. 3. U.S. Department of Transportation, Federal Highway Administration, Highway Statistics 2007, Office of Highway Policy Information, Washington, DC, 2008. Available at http://www.fhwa.dot.gov/policyinformation/statistics/2007/. 4. E.H. Pechan & Associates, Inc. “Documentation for the On-road National Emission Inventory (NEI) for Base Years 1970 - 2002,” report prepared for U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Research Triangle Park, NC. January 2004. 25 AUTOMOTIVE AFTERMARKET PRODUCTS (SCC 2460400000) The EPA has divided automotive consumer products into two different major categories: (1) detailing products, and (2) maintenance and repair products. It is often difficult to distinguish the automotive aftermarket product subcategories and formulations for distinct product types because category descriptions and designations may overlap. In some cases varying formulations may be due to the product form. There are a large number of individual VOCs in these products, including HAPs. County-level emissions were calculated using a per capita emission factor which was obtained from the Emission Inventory Improvement Program (EIIP)1 and U.S. Bureau of the Census 2007 population data2. The emission factor represents pre-control emission rates. A CE of 8.97 percent3 and an RP of 48.6 percent4 were applied to reflect the Federal Rule for consumer products. There are no point sources associated with this category. Each county’s emissions are estimated per the sample calculations listed below. Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 5, Consumer and Commercial Solvent Use,” Table 5.4-1, prepared for the Area Sources Committee, Emission Inventory Improvement Program, August 1996, available from http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed March 2009 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 2 3 4 ERTAC Recommendation, Midwest RPO Inventory Comparability Project, revised June 2, 2009, accessed June 2009. E.H. Pechan & Associates, Inc., Control Measure Development Support Analysis of Ozone Transport Commission Model Rules, prepared for the Ozone Transport Commission, March 2001. 26 SAMPLE VOC EMISSION CALCULATIONS: CE RP RE Annual VOC Emissions Emission Factor Population 1 100 100 100 where: Emission Factor = 1.36 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County)2 Control Efficiency = 8.97%3 RP (Rule Penetration) = 48.6%4 RE (Rule Effectiveness) = 100% 1.36 lbsVOC person 8.97 48.6 100 Annual VOC Emissions 1,219,2101 year 100 100 100 1 ton 792.92 tons VOC per year Annual VOC Emissions 1,585,840.94 pounds per year 2000 lbs 27 AUTOMOTIVE REFINISHING (SCC 2401005000) Automotive refinishing is the painting of worn or damaged automobiles, light trucks, and other vehicles. The coating of new cars, however, is considered in the point source inventory, and therefore not included in this inventory. Countylevel emissions were calculated using a per capita emission factor which was obtained from the ERTAC Area Inventory Comparability Project solvent working group1 and U.S. Bureau of the Census 2007 population data2. The automotive refinishing VOC emission factor is 0.5 lb/person. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions Emission Factor Population where: Emission Factor =0.5 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County)2 1 ERTAC Area Inventory Comparability Project, revision August 14, 2009. Factor is derived from national numbers and so represents an average for the entire country; Freedonia 2007; accessed August 2009. U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 2 28 0.5 lbsVOC person Annual VOC Emissions 1,219,210 people year Annual VOC Emissions 609,605 pounds per year 1 ton 304.8025 tons VOC per year 2000 lbs 29 BAKERIES (SCC 2302050000) Bakery emissions, primarily ethanol, result from yeast fermentation during the baking process of bread and bakery products. Ethanol is emitted through a vent with any combustion product gases. Relevant NAICS codes for bakeries are 311811 and 311812. County-level VOC emissions were calculated using an employment-based emission factor and the number of NAICS code 311811 and 311812 employees in each county. The number of employees in each county for 2007 was obtained from County Business Patterns1 The Bakeries emission factor is 0.11 tons VOC/employee/year2. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Employees) where: Emission Factor = 0.11 tons VOC /employee/year Employees = 863 (Allegheny County) 1 U.S. Census Bureau, 2007 County Business Patterns, http://factfinder.census.gov/servlet/GQRGeoSearchByListServlet?ds_name=CB0700A1&_lang=en&_ts=286 805349530 Lucy Adams, Radian Corporation, memorandum to SIP inventory preparers and EPA Regions, “VOC Emissions from Bakeries,” prepared under contract to the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency (EPA Contract No. 68-D0-0125), April 24, 1992. 2 30 0.11 tons VOC employee Annual VOC Emissions (863 employees) = 94.93 tons VOC per year year 31 COATINGS AND RELATED PRODUCTS (SCC 2460500000) Aerosol spray paints and related products such as paint removers make up this consumer and commercial solvent product group. Other forms of coatings (besides aerosols) are not included in this group, but are included under architectural or industrial coatings, or auto body refinishing. Aerosols spray paints contain VOCs that function as both solvents and propellants. The most commonly used propellants in aerosol paints are propane, butane and isobutane. Paint removers are classified as either application removers or immersion removers. Solvents such as methanol, ethanol and isopropanol are also used to enhance the action of the paint remover. Methylene chloride (53 percent) and methanol (41 percent) account for the majority of paint-removing solvents consumed (Frost & Sulllivan, Inc., 1990). County-level emissions were calculated using a per capita emission factor which was obtained from the Emission Inventory Improvement Program (EIIP)1 and U.S. Bureau of the Census 2007 population data2. The emission factor represents pre-control emission rates. A CE of 0 percent3 and an RP of 48.6 percent4 were applied to reflect the Federal Rule for consumer products. There are no point sources associated with this category. Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 5, Consumer and Commercial Solvent Use,” Table 5.4-1, prepared for the Area Sources Committee, Emission Inventory Improvement Program, August 1996, available from http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed April 2009. 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 2 3 4 ERTAC Recommendation, Midwest RPO Inventory Comparability Project, revised June 2, 2009, accessed June 2009. E.H. Pechan & Associates, Inc., Control Measure Development Support Analysis of Ozone Transport Commission Model Rules, prepared for the Ozone Transport Commission, March 2001. 32 Each county’s emissions are estimated per the sample calculations listed below. SAMPLE VOC EMISSION CALCULATIONS: CE RP RE Annual VOC Emissions Emission Factor Population 1 100 100 100 where: Emission Factor = 0.95 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County)2 Control Efficiency = 0%3 RP (Rule Penetration) = 48.6%4 RE (Rule Effectiveness) = 100% 0.95 lbsVOC person 0 48.6 100 Annual VOC Emissions 1,219,2101 year 100 100 100 1 ton 579.12 tons VOC per year Annual VOC Emissions 1,158,249.50 pounds per year 2000 lbs 33 COMMERCIAL COOKING – (5 SCCs) Source Category Description Commercial Cooking emissions are for 5 source categories (2302002100, 2302002200, 2302003000, 2302003100, and 2302003200) based on equipment type. Emissions estimates are for all types of meat cooked in a particular piece of equipment. Deep fat frying of french fries was also included. The following documentation was prepared by E.H. Pechan and Associates: For this source category, the following SCCs were assigned: Source SCC Level One Classification Code 2302002100 Industrial Processes 2302002200 Industrial Processes 2302003000 Industrial Processes 2302003100 Industrial Processes 2302003200 Industrial Processes SCC Level Two Food and Kindred Products: SIC 20 Food and Kindred Products: SIC 20 Food and Kindred Products: SIC 20 Food and Kindred Products: SIC 20 Food and Kindred Products: SIC 20 SCC Level Three Commercial Cooking Charbroiling Commercial Cooking Charbroiling Commercial Cooking Frying Commercial Cooking Frying Commercial Cooking Frying SCC Level Four Conveyorized Charbroiling Under-fired Charbroiling Deep Fat Frying Flat Griddle Frying Clamshell Griddle Frying 34 Activity Data Activity data was collected from the US Census Bureau’s county level population estimates for July 1, 2007.1 Control Factors No controls were assumed for this category. Emission Factors Emission factors were developed and reviewed by an ERTAC advisory panel composed of state and EPA personnel (Contact: Roy Huntley, huntley.roy@epa.gov). They were created by taking 2002 emissions in the NEI and dividing by the 2002 population to develop per capita emission factors. These emission factors are listed in Table 1. Sample Calculations Emissions are calculated for each county using emission factors and activity as: Ex,p = Ax × EFx,p U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 1 35 where: Ex,p = annual emissions for category x and pollutant p; Ax = population data associated with category x; EFx,p = emission factor for category x and pollutant p. Example: Using conveyorized charbroiling in Allegheny County, PA as an example: According to the US Census Bureau, population on July 1, 2007 is 1,219,210 The emission factor for VOC is 0.01205 lb/person EVOC= 1,219,210 people × 0.012056 lb VOC/ person = 14,698.81 lb VOC or 7.3494 ton VOC Table 1: Commercial Cooking Emission Factors Developed by ERTAC SCC 2302002100 2302002200 2302002100 2302002200 2302002100 2302002200 SCC description Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Pollutant Code 100027 100027 100414 100414 100425 100425 Factor Numeric Value 1.326E-05 6.385E-05 7.668E-05 5.312E-04 3.730E-04 2.747E-03 Factor Unit Numerator LB LB LB LB LB LB Factor Unit Denominator EACH EACH EACH EACH EACH EACH 36 SCC 2302002100 2302002200 2302002100 2302002200 2302002100 2302002200 2302002100 2302002200 2302002100 2302002200 2302003100 2302002100 2302002200 2302002100 2302002200 2302003100 2302002100 2302002200 2302003100 2302002100 2302002200 2302002100 2302002200 SCC description Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Pollutant Code 106445 106445 107062 107062 108883 108883 108952 108952 120127 120127 120127 123386 123386 129000 129000 129000 130498292 130498292 130498292 1330207 1330207 191242 191242 Factor Numeric Value 7.003E-06 4.214E-05 2.682E-05 2.183E-04 3.597E-04 2.496E-03 4.421E-05 3.063E-04 5.943E-06 1.914E-05 8.487E-06 1.466E-04 1.113E-03 8.852E-06 3.587E-05 3.139E-05 2.709E-04 7.911E-04 2.589E-04 7.799E-07 1.560E-06 1.309E-06 2.542E-06 Factor Unit Numerator LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB Factor Unit Denominator EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH 37 SCC 2302002100 2302002200 2302002100 2302002200 2302003100 2302002100 2302002200 2302003100 2302002100 2302002200 2302002100 2302002200 2302003100 2302002100 2302002200 2302003100 2302002100 2302002200 2302002100 2302002200 2302002100 2302002200 2302003100 SCC description Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Pollutant Code 193395 193395 206440 206440 206440 208968 208968 208968 50000 50000 50328 50328 50328 56553 56553 56553 71432 71432 75070 75070 83329 83329 83329 Factor Numeric Value 1.278E-06 1.723E-06 6.484E-06 2.638E-05 2.371E-05 2.476E-05 6.372E-05 4.886E-06 7.796E-04 5.876E-03 1.450E-06 2.332E-06 1.154E-06 1.772E-06 5.432E-06 2.918E-06 1.006E-03 7.351E-03 5.562E-04 4.242E-03 1.613E-06 2.776E-06 1.357E-06 Factor Unit Numerator LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB Factor Unit Denominator EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH 38 SCC 2302002100 2302002200 2302002100 2302002200 2302003100 2302002100 2302002200 2302003100 2302002100 2302002200 2302003100 2302002100 2302002200 2302003100 2302002100 2302002200 2302002100 2302002200 2302002100 2302002200 2302002100 2302002200 2302003000 SCC description Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Deep Fat Flying Pollutant Code 84742 84742 85018 85018 85018 86737 86737 86737 91203 91203 91203 92524 92524 92524 95476 95476 95487 95487 98862 98862 CO CO CO Factor Numeric Value 4.140E-06 2.413E-05 2.771E-05 8.647E-05 6.021E-05 6.408E-06 2.003E-05 6.484E-06 1.135E-04 2.649E-04 1.308E-04 1.271E-05 2.613E-05 2.788E-06 6.167E-05 4.387E-04 3.482E-06 2.111E-05 4.991E-06 3.250E-05 4.245E-02 1.350E-01 0.000E+00 Factor Unit Numerator LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB Factor Unit Denominator EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH 39 SCC 2302003100 2302003200 2302002200 2302002100 2302002200 2302003100 2302003200 2302002100 2302002200 2302003000 2302003100 2302003200 2302002100 2302002200 2302003100 2302003200 2302002100 2302002200 2302003000 2302003100 2302003200 2302002200 2302002100 SCC description Flat Griddle Frying Clamshell Griddle Frying Under-fired Charbroiling Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Clamshell Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Deep Fat Flying Flat Griddle Frying Clamshell Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Flat Griddle Frying Clamshell Griddle Frying Conveyorized Charbroiling Under-fired Charbroiling Deep Fat Flying Flat Griddle Frying Clamshell Griddle Frying Under-fired Charbroiling Conveyorized Charbroiling Pollutant Code CO CO NOX PM10-FIL PM10-FIL PM10-FIL PM10-FIL PM10-PRI PM10-PRI PM10-PRI PM10-PRI PM10-PRI PM25-FIL PM25-FIL PM25-FIL PM25-FIL PM25-PRI PM25-PRI PM25-PRI PM25-PRI PM25-PRI SO2 VOC Factor Numeric Value 1.269E-02 0.000E+00 0.000E+00 1.648E-04 1.048E-03 2.727E-04 1.981E-05 4.980E-02 3.528E-01 0.000E+00 1.031E-01 6.994E-03 1.597E-04 1.013E-03 2.074E-04 1.685E-05 4.827E-02 3.415E-01 0.000E+00 7.834E-02 5.910E-03 0.000E+00 1.206E-02 Factor Unit Numerator LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB LB Factor Unit Denominator EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH EACH 40 SCC 2302002200 2302003000 2302003100 2302003200 SCC description Under-fired Charbroiling Deep Fat Flying Flat Griddle Frying Clamshell Griddle Frying Pollutant Code VOC VOC VOC VOC Factor Numeric Value 4.148E-02 1.261E-02 5.943E-03 2.316E-04 Factor Unit Numerator LB LB LB LB Factor Unit Denominator EACH EACH EACH EACH 41 CONSTRUCTION DUST (3 SCCs: SCC 2311010000, SCC 2311020000, SCC 2311030000) RESIDENTIAL CONSTRUCTION Emissions from residential construction activity are a function of the acreage disturbed and volume of soil excavated for residential construction. Residential construction activity is developed from data obtained from the U.S. Department of Commerce (DOC)’s Bureau of the Census. The following documentation was prepared by E.H. Pechan and Associates with footnotes located at the end of this section: For this source category, the following SCC was assigned: Source Classification Code 2311010000 SCC Level One Industrial Processes SCC Level Two Construction: SIC 15 - 17 SCC Level Three General Building Construction SCC Level Four Total Activity data: There are two activity calculations performed for this SCC, acres of surface soil disturbed and volume of soil removed for basements. Surface soil disturbed The US Census Bureau has 2008 data for Housing Starts - New Privately Owned Housing Units Started1 which provides regional level housing starts based on the groupings of 1 unit, 2-4 units, 5 or more units. A consultation with the Census Bureau in 2002 gave a breakdown of approximately 1/3 of the housing starts being for 2 unit structures, and 2/3 being for 3 and 4 unit structures. The 2-4 unit category was then divided into 2-units, and 3-4 units based on this ratio. 42 To get the number of structures for each grouping, the 1unit category was divided by 1, 2 unit category was divided by 2, and the 3-4 unit category was divided by 3.5. The 5 or more unit category listed may be made up of more than one structure. New Privately Owned Housing Units Authorized Unadjusted Units2 gives a conversion factor to determine the ratio of structures to units in the 5 or more unit category. For example if a county has one 40unit apartment building, the ratio would be 40/1. If there are 5 different 8 unit buildings in the same project, the ratio would be 40/5. Structures started by category are then calculated at a regional level. The table Annual Housing Units Authorized by Building Permit3 has 2007 data at the county level to allocate regional housing starts to the county level. This results in county level housing starts by number of units. The following surface areas were assumed disturbed for each unit type: Table 1: Surface Soil removed per unit type 1-Unit 1/4 acre/structure 2-Unit 1/3 acre/structure Apartment 1/2 acre/structure The 3-4 unit category was considered to be an apartment. Multiplication of housing starts to soil removed results in number of acres disturbed for each unit category. Basement soil removal To calculate basement soil removal, 2007 Characteristics of New Houses4 is used to estimate the percentage of 1 unit structures that have a basement (on the regional level). The county level estimate of number of 1 unit starts is multiplied by the percent of 1 unit houses in the region that have a basement to get the number of basements in a county. Basement volume is calculated by assuming a 2000 square foot house has a basement dug to a depth of 8 feet (making 16,000 ft3 per basement). An additional 10% is added for peripheral dirt bringing the total to 17,600 ft3 per basement. 43 Emission Factors: Initial PM10 emissions from construction of single family, two family, and apartments structures are calculated using the emission factors given in Table 2. The duration of construction activity for houses is assumed to be 6 months and the duration of construction for apartments is assumed to be 12 months. Table 2. Emission Factors for Residential Construction Type of Structure Emission Factor Duration of Construction Apartments 0.11 tons PM10/acre-month 12 months 2-Unit Structures 0.032 tons PM10/acre-month 6 months 1-Unit Structures w/o Basements 0.032 tons PM10/acre-month 6 months 0.011 tons PM10/acre-month 6 months 1-unit Structures with Basements 0.059 tons PM10/1000 cubic yards Regional variances in construction emissions are corrected using soil moisture level and silt content. These correction parameters are applied to initial PM10 emissions from residential construction to develop the final emissions inventory. To account for the soil moisture level, the PM10 emissions are weighted using the 30-year average precipitationevaporation (PE) values from Thornthwaite’s PE Index. Average precipitation evaporation values for each State were estimated based on PE values for specific climatic divisions within a State. These values range from 7 to 41. 44 To account for the silt content, thePM10 emissions are weighted using average silt content for each county. A data base containing county-level dry silt values was complied. These values were derived by applying a correction factor developed by the California Air Resources Board to convert wet silt values to dry silt values.5 The equation for PM10 emissions corrected for soil moisture and silt content 24 S Corrected E PM 10 Initial E PM 10 PE 9% is: where: Corrected EPM10 = PM10 emissions corrected for soil moisture and silt content, PE = precipitation-evaporation value for each State, S = % dry silt content in soil for area being inventoried. Once PM10 adjustments have been made, PM25 emissions are set to 10% of PM10 Example Calculation: PM10 Emissions = ∑( Aunit x Tconstruction x EFunit ) x AdjPM Where Aunit = HSUnit x SMUnit HSUnit = Regional Housing Starts x (county building permits/Regional building permits) SMUnit = Area or volume of soil moved for the given unit type TConstruction = Construction time (in months) for given unit type EFUnit = Unadjusted emission factor for PM10 for the given unit type AdjPM = PM Adjustment factor 45 References: 1. New Privately Owned Housing Units Started for 2008 ( Not seasonally adjusted) http://www.census.gov/const/startsua.pdf 2. Table 2au. New Privately Owned Housing Units Authorized Unadjusted Units for Regions, Divisions, and States http://www.census.gov/const/C40/Table2/tb2u2007.txt 3. Annual Housing Units Authorized by Building Permits CO2007A, purchased from US Department of Census 4. Type of Foundation in New One-Family Houses Completed, http://www.census.gov/const/C25Ann/sftotalfoundation.pdf 46 NON-RESIDENTIAL CONSTRUCTION Emissions from non-residential construction activity are a function of the acreage disturbed for non-residential construction. The following documentation was prepared by E.H. Pechan and Associates with footnotes located at the end of this section: For this source category, the following SCC was assigned: Source Classification Code 2311020000 SCC Level One Industrial Processes SCC Level Two Construction: SIC 15 - 17 SCC Level Three Heavy Construction SCC Level Four Total Activity Data: Annual Value of Construction Put in Place in the U.S1 has the 2008 National Value of Non-residential construction. The national value of non-residential construction put in place (in millions of dollars) was allocated to counties using county-level non-residential construction (NAICS Code 2362) employment data obtained from County Business Patterns2 (CBP). Because some counties employment data was withheld due to privacy concerns, the following procedure was adopted: 1. State totals for the known county level employees was subtracted from the number of employees reported in the state level version of CBP. This results in the total number of withheld employees in the state. 2. A starting guess of the midpoint of the range code was used (so for instance in the 1-19 employees range, a guess of 10 employees would be used) and a state total of the withheld counties was computed. 47 3. A ratio of guessed employees (Step 2) to withheld employees (Step 1) was then used to adjust the county level guesses up or down so the state total of adjusted guesses should match state total of withheld employees (Step 1) In 1999 a figure of 2 acres/$106 was developed. The Bureau of Labor Statistics Producer Price Index3 lists costs of the construction industry from 1999-2007. 2007 acres per $106 = 1999 acres per $106 x (1999 PPI / 2007 PPI) =2 acres/$106 (132.9 / 204.3) = 1.301 acres per $106 Emission Factors: Initial PM10 emissions from construction of non-residential buildings are calculated using an emission factor of 0.19 tons/acre-month. The duration of construction activity for non-residential construction is assumed to be 11 months. Regional variances in construction emissions are corrected using soil moisture level and silt content. These correction parameters are applied to initial PM10 emissions from non-residential construction to develop the final emissions inventory. To account for the soil moisture level, the PM10 emissions are weighted using the 30-year average precipitationevaporation (PE) values from Thornthwaite’s PE Index. Average precipitation evaporation values for each State were estimated based on PE values for specific climatic divisions within a State. These values range from 7 to 41. To account for the silt content, the PM10 emissions are weighted using average silt content for each county. A data base containing county-level dry silt values was complied. These values were derived by applying a correction factor developed by the California Air Resources Board to convert wet silt values to dry silt values.7 The equation for PM10 emissions corrected for soil moisture and silt content is: Corrected E PM 10 Initial E PM 10 24 S PE 9% 48 where: Corrected EPM10 = PM10 emissions corrected for soil moisture and silt content, PE = precipitation-evaporation value for each State, S = % dry silt content in soil for area being inventoried. Once PM10 adjustments have been made, PM25 emissions are set to 10% of PM10 Example Calculation: EmissionsPM10 = NSpending x (Empcounty / EmpNational) x Apd x EFAdj x M Where NSpending = National spending Empcounty = county level employment data EmpNational = National level employment data Apd = Acres per million dollars EFAdj = Adjusted PM10 emission factor M = duration of construction activity References: 1. Annual Value of Construction Put in Place: http://www.census.gov/const/www/ototpage.html 2. County Business Patterns: http://www.census.gov/econ/cbp/index.html 3. Bureau of Labor Statistics: http://www.bls.gov/data/ Table BMNR 49 ROAD CONSTRUCTION Emissions from road construction activity are a function of the acreage disturbed for road construction. Road construction activity is developed from data obtained from the Federal Highway Administration (FHWA). The following documentation was prepared by E.H. Pechan and Associates with footnotes located at the end of this section: For this category, the following SCC was assigned: Source Classification Code 2311030000 SCC Level One SCC Level Two SCC Level Three Industrial Processes Construction: SIC 15 - 17 Road Construction SCC Level Four Total Activity Data: The Federal Highway Administration has Highway Statistics, Section IV - Highway Finance, Table SF-12A, State Highway Agency Capital Outlay1 for 2006 which outlines spending by state in several different categories. For this SCC, the following columns are used: New Construction, Relocation, Added Capacity, Major Widening, and Minor Widening. These columns are also differentiated according to the following six classifications: 1. 2. 3. 4. 5. 6. Interstate, urban Interstate, rural Other arterial, urban Other arterial, rural Collectors, urban Collectors, rural 50 The State expenditure data are then converted to new miles of road constructed using $/mile conversions obtained from the North Carolina Department of Transportation (NCDOT) in 2000. A conversion of $4 million/mile is applied to the interstate expenditures. For expenditures on other arterial and collectors, a conversion factor of $1.9 million/mile is applied, which corresponds to all other projects. The new miles of road constructed are used to estimate the acreage disturbed due to road construction. The total area disturbed in each state is calculated by converting the new miles of road constructed to acres using an acres disturbed/mile conversion factor for each road type as given in the table below: Table 1: Spending per Mile and Acres Disturbed per Mile by Highway Type Road Type Urban Areas, Interstate Rural Areas, Interstate Thousand Acres Dollars per Disturbed per mile mile 4000 15.2 4000 15.2 Urban Areas, Other Arterials 1900 15.2 Rural Areas, Other Arterials Urban Areas, Collectors Rural Areas, Collectors 1900 1900 1900 12.7 9.8 7.9 51 Residential building starts2 are used to allocate the state-level acres disturbed by road construction to the county. A ratio of the number of building starts in each county to the total number of building starts in each state is applied to the state-level acres disturbed to estimate the total number of acres disturbed by road construction in each county. Emission Factors: Initial PM10 emissions from construction of roads are calculated using an emission factor of 0.42 tons/acre-month. Since most road construction consists of grading and leveling of land, the higher emission factor more accurately reflects the high level of cut and fill activity that occurs at road construction sites. The duration of construction activity for road construction is assumed to be 12 months. Regional variances in construction emissions are corrected using soil moisture level and silt content. These correction parameters are applied to initial PM10 emissions from road construction to develop the final emissions inventory. To account for the soil moisture level, the PM10 emissions are weighted using the 30-year average precipitationevaporation (PE) values from Thornthwaite’s PE Index. Average precipitation evaporation values for each State were estimated based on PE values for specific climatic divisions within a State. These values range from 7 to 41. To account for the silt content, thePM10 emissions are weighted using average silt content for each county. A data base containing county-level dry silt values was complied. These values were derived by applying a correction factor developed by the California Air Resources Board to convert wet silt values to dry silt values. The equation for PM10 emissions corrected for soil moisture and silt content is: Corrected E PM 10 Initial E PM 10 24 S PE 9% where: Corrected EPM10 = PM10 emissions corrected for soil moisture and silt content, PE = precipitation-evaporation value for each State, S = % dry silt content in soil for area being inventoried. Once PM10 adjustments have been made, PM25 emissions are set to 10% of PM10 52 Emission Calculation: EmissionsPM10 = ∑(HDrt x MCrt x ACrt) x (HSCounty / HSState) x EFAdj x M Where HDrt = Highway Spending for a specific road type MCrt = Mileage conversion for a specific road type ACrt = Acreage conversion for a specific road type HSCounty = Housing Starts in a given county HSState = Housing Starts in a given State EFAdj = Adjusted PM10 Emission Factor M = duration of construction activity References: 1. 2006 Highway Spending : http://www.fhwa.dot.gov/policy/ohim/hs06/xls/sf12a.xls 2. Annual Housing Units Authorized by Building Permits CO2007A, purchased from US Department of Census. 53 DEGREASING (4 SCCs: SCC 2415360000, SCC 2415300000, SCC 2415230000, SCC 2415200000) (Auto Repair (Cold Cleaning) SCC 2415360000, Manufacturing (Cold Cleaning) SCC 2415300000, Electronics (Vapor/In-Line) SCC 2415230000, Other (Vapor/In-Line) SCC 2415200000) Surface cleaning, also known as “degreasing”, includes the solvent cleaning or conditioning of metal surfaces and parts, fabricated plastics, electronic and electrical components and other nonporous substrates. These cleaning processes are designed to remove foreign material, such as oils, grease, waxes and moisture, usually in the preparation for further treatment, such as painting, electroplating, galvanizing, anodizing or applying conversion coatings. Three basic types of surface cleaning operations are currently used: cold cleaning, vapor cleaning, and in-line or conveyorized cleaning, which can be either a cold or vapor cleaning process. VOC emission results from the evaporation of solvents used in these processes. Cold cleaning is a batch process in which solvents are applied at room temperature or slightly heated. Parts are immersed in a solvent, usually mineral spirits. Parts too large for immersion may be sprayed or wiped with a solvent. The primary cold cleaning application is cleaning of tools or metal parts at service and automotive repair stations and manufacturing facilities. Cold cleaning may incorporate covers or freeboards to limit the evaporative loss of solvents. In-line cleaners use automated load systems (typically conveyors) to maintain a continuous feed to the cleaning unit. These units use both cold and vapor-cleaning methods as described above, with the majority being halogenated solvent cleaning systems. These units are used for large-scale operations and are usually enclosed except to the conveyor inlet or exit. A common application of in-line cleaners is cleaning printed circuit boards for the electronic and electrical component industries. The Emission Inventory Improvement Program (EIIP) developed the following population-based methods for estimating degreasing emissions. 54 Activity data was collected from the US Census Bureau’s county level population estimates for July 1, 2007.1 Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: CE RP RE Annual VOC Emissions Emission Factor Population 1 100 100 100 where: Auto Repair (Cold Cleaning) VOC Emission Factor = 2.5 lbs VOC/person/year1 Manufacturing (Cold Cleaning) VOC Emission Factor = 1.1 lbs VOC/person/year1 Electronics and Electrical (Vapor/In-Line) VOC Emission Factor = 0.21 lbs VOC/person/year1 Other (Vapor/In-Line) VOC Emission Factor = 0.49 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County)2 Auto Repair Cold Cleaning CE (Control Efficiency) = 66%3 Manufacturing Cold Cleaning CE (Control Efficiency) = 66%3 Electronics Vapor/In-Line CE (Control Efficiency) = 63%3 Other Vapor/In-Line CE (Control Efficiency) = 63%3 All Categories RP (Rule Penetration) = 100% All Categories RE (Rule Effectiveness) = 80% Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 6,Solvent Cleaning,” Table 6.5-2 (EPA 1991), prepared for the Area Sources Committee, Emission Inventory Improvement Program, Septembert 1997. 1 2 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 2 25 Pa. Code Section 129.63, “Degreasing Operations,” available from http://www.pacode.com/secure/data/025/chapter129/s129.63.html 3 55 Allegheny County Auto Repair (Cold Cleaning) VOC Emissions Calculation: 2.5 lbs VOC person 66 100 80 Annual VOC Emissions 1,219,210 people 1 year 100 100 100 1 ton Annual VOC Emissions 1,438,667.80 pounds VOC per year 719.3339 tons VOC per year 2000 pounds 56 DRY CLEANERS (SCC 2420000000) Three types of dry cleaning operations are used: coin-operated facilities using perchloroethylene (perc); commercial/industrial facilities using perc; and commercial/industrial facilities using VOC solvents. Each county’s emissions were estimated per the sample calculations below using an employment-based emission factor1 and the number of 2006 employees in NAICS codes 81231X, 81232X, and 81233X.. The number of Dry Cleaning employees was obtained from County Business Patterns2 by E. H. Pechan and Associates who also performed midpoint calculations on any ranges obtained. Each county’s emissions were estimated per the sample calculations below. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 467 lbs VOC/ employee/ year1 Employees = 2002 (2006 Allegheny County)2 1 2 ERTAC Recommended, Freedonia 2007, accessed October 2009. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 57 467 lbs VOC person Annual VOC Emissions 2002 employees year Annual VOC Emissions 934,934 pounds VOC per year 1 ton 2000 lbs 467.467 tons VOC per year 58 ELECTRONIC AND OTHER ELECTRIC COATINGS (SCC 2401065000) The VOC emissions from this source category result from the evaporation of the solvent used in the insulation coatings applied to wire and cable and electronic parts. The emissions for each county were calculated using an employmentbased emission factor1 and the number of employees in NAICS codes 331319, 331422, 331491, 335929, 335921 and 335311. The number of Electrical Appliance employees was obtained from County Business Patterns2 and the midpoints were calculated by E. H. Pechan and Associates where obtained. Each county’s emissions were estimated per the sample calculations below. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 24.7 lbs VOC/employee/year1 Employees = 60 (Allegheny County)2 1 ERTAC Area Inventory Comparability Project solvent working group, August 8, 2009, (version 4) .xls, accessed September 2009. 2 National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 59 24.7 lbsVOC employee Annual VOC Emissions 60 employees year 1ton Annual VOC Emissions 1,482 pounds VOC per year 0.741 tons VOC per year 2000 pounds 60 FACTORY FINISHED WOOD (SCC 2401015000) The VOC emissions from this source category result from the evaporation of the solvent used in the gluing and coating process. The emissions for each county were calculated using an employment-based emission factor 1 and employees numbers in NAICS codes 321XX2. The number of employees in each county was collected from County Business patterns and the adjusted employee numbers were prepared by Pechan & Associates using employment midpoint and adjustment factors for any ranges obtained. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 43 lbs VOC/employee/year1 Employees =270 (Allegheny County)2 43 lbsVOC employee Annual VOC Emissions 270 employees year 1ton Annual VOC Emissions 11,610 pounds VOC per year 5.805. tons VOC per year 2000 pounds 1 ERTAC Area Inventory Comparability Project solvent working group, August 8, 2009, (version 4).xls, accessed September 2009. 2 National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 61 FIFRA-REGULATED PRODUCTS (SCC 2460800000) Pesticides defined by FIFRA include substances or mixtures that are used to prevent, destroy, repel, or mitigate pests, as well as substances used as plant regulators, defoliators, and desiccants. Consumer pesticides are used in the home and garden, as well as in commercial and governmental applications. Disinfectants and antimicrobial products are included. Household uses include pet care products, disinfectants and insecticides. All consumer and commercial pesticides contain VOCs. Aerosol and liquid sprays contain VOCs as solvents, usually ethanol and isobutane. Pesticides products can be grouped according to their target pest, but should also be grouped according to their form (solid, liquid or aerosol) when considering control measures. County-level emissions were calculated using a per capita emission factor which was obtained from the Emission Inventory Improvement Program (EIIP)1 and U.S. Bureau of the Census 2007 population data2. The emission factor represents pre-control emission rates. A CE of 20 percent3 and an RP of 48.6 percent4 were applied to reflect the Federal Rule for consumer products. There are no point sources associated with this category. Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 5, Consumer and Commercial Solvent Use,” Table 5.4-1, prepared for the Area Sources Committee, Emission Inventory Improvement Program, August 1996, available from http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed March 2009 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 2 3 4 ERTAC Recommendation, Midwest RPO Inventory Comparability Project, revised June 2, 2009, accessed June 2009. E.H. Pechan & Associates, Inc., Control Measure Development Support Analysis of Ozone Transport Commission Model Rules, prepared for the Ozone Transport Commission, March 2001. 62 Each county’s emissions are estimated per the sample calculations listed below. SAMPLE VOC EMISSION CALCULATIONS: CE RP RE Annual VOC Emissions Emission Factor Population 1 100 100 100 where: Emission Factor = 1.78 lbs per person/year1 Population = 1,219,210 (Allegheny County)2 Control Efficiency = 20%3 RP (Rule Penetration) = 48.6%4 RE (Rule Effectiveness) = 100% Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 5, Consumer and Commercial Solvent Use,” Table 5.4-1, prepared for the Area Sources Committee, Emission Inventory Improvement Program, August 1996, available from http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed March 2009 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST200701.html, accessed March 2009. 2 3 4 ERTAC Recommendation, Midwest RPO Inventory Comparability Project, revised June 2, 2009, accessed June 2009. E.H. Pechan & Associates, Inc., Control Measure Development Support Analysis of Ozone Transport Commission Model Rules, prepared for the Ozone Transport Commission, March 2001. 63 1.78 lbsVOC person 20 48.6 100 Annual VOC Emissions 1,219,2101 year 100 100 100 1 ton 979.6255 tons VOC per year Annual VOC Emissions 1,959,250.963 pounds per year 2000 lbs 64 FUEL COMBUSTION – COMMERCIAL/INSTITUTIONAL (7 SCCs: SCC 2103001000, SCC 2103002000, SCC 2103004000, SCC 2103005000, SCC 2103006000, SCC 2103007000, SCC 2103011000) Source Description and Classification This sub-sector covers emissions from fuel combustion at stationary non-point sources within the commercial/institutional sector. These documentation and fuel combustion emissions were calculated by E. H. Pechan and Associates. References are listed at the end of the Fuel Combustion – Commercial/Institutional section. The following are the fuel types that will be included in the inventory for the commercial/institutional non-point source subsector: anthracite coal, bituminous/sub-bituminous coal, distillate oil, residual oil, natural gas, LPG, wood, and kerosene. Motor gasoline is not included as a non-point source because it is expected that all non-point gasoline combustion in this sector is included in the non-road inventory. The approach to be used in calculating emissions for commercial/institutional fuel combustion is to first develop statelevel fuel consumption estimates, then to allocate these to the county-level, and then to multiply the resulting countylevel consumption estimates by appropriate emission factors. Source Classification. The non-point SCCs associated with commercial/institutional fuel combustion are displayed in Table 1. Table 1. Non-point Source Commercial/Institutional Fuel Combustion SCCs SCC SCC Level 1 SCC Level 2 SCC Level 3 SCC Level 4 2103001000 Stationary Source Fuel Combustion Commercial/Institutional Anthracite Coal Total: All Boiler Types 2103002000 Stationary Source Fuel Combustion Commercial/Institutional Total: All Boiler Types 2103004000 Stationary Source Fuel Combustion Commercial/Institutional Bituminous/Sub-bituminous Coal Distillate Oil 2103005000 2103006000 Stationary Source Fuel Combustion Stationary Source Fuel Combustion Commercial/Institutional Commercial/Institutional Residual Oil Natural Gas Total: All Boiler Types Total: Boilers and IC Engines Total: Boilers and IC Engines 65 SCC SCC Level 1 SCC Level 2 2103007000 Stationary Source Fuel Combustion Commercial/Institutional 2103008000 Stationary Source Fuel Combustion 2103011000 Stationary Source Fuel Combustion SCC Level 3 SCC Level 4 Total: All Combustor Types Commercial/Institutional Liquefied Petroleum Gas (LPG) Wood Commercial/Institutional Kerosene Total: All Combustor Types Total: All Boiler Types Activity Data Table 2 summarizes this sector’s non-point source activity data, units, and data source. Total state-level commercial sector energy consumption data are available from the Energy Information Administration (EIA)’s State Energy Data System (SEDS), and were used for most source categories (EIA, 2007a). However, as documented below, a number of adjustments were made to the SEDS data, and a separate EIA data source was used for distillate oil. Year 2006 SEDS data were used to estimate 2007 emissions because these were the latest year consumption data available at the time this work was performed in 2009. Table 2. Non-point Source Commercial/Institutional Fuel Combustion Activity Data SCC SCC Level 1 SCC Level 2 SCC Level 3 SCC Level 4 Activity Thousand short tons of coal consumed Thousand short tons of coal consumed Activity Data Source EIA’s SEDSa 2103001000 Stationary Source Fuel Combustion Commercial/Institutional Anthracite Coal Total: All Boiler Types 2103002000 Stationary Source Fuel Combustion Commercial/Institutional Bituminous/ Sub-bituminous Coal Total: All Boiler Types 2103004000 Stationary Source Fuel Combustion Commercial/Institutional Distillate Oil Total: All Boiler Types Thousand barrels of EIA’s Fuel Oil distillate oil consumed and Kerosene Salesa 2103005000 Stationary Source Fuel Combustion Commercial/Institutional Residual Oil Total: All Boiler Types Thousand barrels of EIA’s SEDSa residual oil consumed EIA’s SEDSa 66 SCC SCC Level 1 SCC Level 2 SCC Level 3 SCC Level 4 Total: All Boiler Types Activity Activity Data Source Million cubic feet of EIA’s SEDSa natural gas consumed Thousand barrels of EIA’s SEDSa LPG consumed 2103006000 Stationary Source Fuel Combustion Commercial/Institutional Natural Gas 2103007000 Stationary Source Fuel Combustion Commercial/Institutional Liquefied Petroleum Gas Total: All Combustor (LPG) Types 2103008000 Stationary Source Fuel Combustion Commercial/Institutional Wood Total: All Boiler Types Billion Btu of wood consumed EIA’s SEDSa 2103011000 Stationary Source Fuel Combustion Commercial/Institutional Kerosene Total: All Combustor Types Thousand barrels of kerosene consumed EIA’s SEDSa (a) With adjustments that are described in the text of this section. Fuel-Specific Activity Data Adjustments Coal - for commercial/institutional coal combustion, the SEDS data do not provide coal consumption estimates by type of coal (i.e., anthracite versus bituminous/sub-bituminous) and in some cases, CAP emission factors differ between the two. Because anthracite is mined in the eastern half of the Commonwealth, while bituminous is mined in the western half, the emission calculations assume that eastern counties burn anthracite coal while western counties burn bituminous coal. Commercial Coal Combustion: Number of County Employees where: Annual Emissions Pollutant Emission Factor Coal Consumption Number of State Employees VOC Emission Factor = 0.3 lbs/ton anthracite coal/year; 0.05 lbs/ton bituminous coal/year NOx Emission Factor = 9 lbs/ton anthracite coal/year; 11 lbs/ton bituminous coal/year CO Emission Factor = 0.6 lbs/ton anthracite coal/year; 5.0 lbs/ton bituminous coal/year Pb Emission Factor = 0.00042 lbs/ton anthracite coal/year and bituminous coal/year 67 SO2 Emission Factor =34.71 lbs/ton anthracite coal/year; 91.96 lbs/ton bituminous coal/year (EPA default values for PA) PM10-FIL Emission Factor = 14.718 lbs/ton anthracite coal/year; 12 lbs/ton bituminous coal/year PM25-FIL Emission Factor = 6.4224 lbs/ton anthracite coal/year; 1.4 lbs/ton bituminous coal/year PM-CON Emission Factor = 0.08 lbs/ton anthracite coal/year; 0.04 lbs/ton bituminous coal/year Anthracite Coal Sulfur Content = 0.89% Bituminous Coal Sulfur Content = 2.42% Anthracite Coal Ash Content = 13.38% ash Pennsylvania Commercial Coal Consumption = 574,000 tons Number of Commercial County Employees (Allegheny County) = 637,800 Number of Pennsylvania’s Commercial Employees = 4,546,525 where: NOX Emissions: 11 lbs NOX Annual NOX Emissions ton bituminous year coal 574,000 to ns Annual NOX Emissions 885,746.6307 pounds NOX per year 637,800 employees in county 4,546,525 employees in state 1 ton 442.8733 tons NOX per year 2000 lbs 68 Distillate Oil and LPG – the SEDS commercial/institutional sector distillate oil and LPG consumption data include consumption estimates for equipment that EPA includes in the non-road sector inventory. To avoid double-counting of LPG consumption, EPA ran the National Mobile Inventory Model (NMIM) for 2006 and calculated the national volume of non-road LPG consumption from commercial sector source categories. This estimate was then divided into the SEDS total industrial sector LPG consumption estimate to yield the proportion of total commercial/institutional sector LPG consumption attributable to the non-road sector in that year (approximately 18 percent). To estimate the volume of commercial/institutional sector LPG consumption that should not be included in the non-point source inventory EPA subtracted 18 percent from each state’s commercial sector LPG consumption estimate reported in SEDS. To avoid double-counting of distillate oil consumption between the non-point and non-road sector emission inventories, EPA relied on a source other than SEDS to estimate consumption. The approach uses more detailed distillate oil consumption estimates reported in EIA’s Fuel Oil and Kerosene Sales, and assumptions from the regulatory impact analysis (RIA) for EPA’s non-road diesel emissions rulemaking (EIA, 2008b; EPA, 2003). Table 4 displays the assumptions that were applied to the state-level distillate oil consumption estimates reported in Fuel Oil and Kerosene Sales to estimate total stationary source commercial/institutional sector consumption. Table 4. Assumptions Used to Estimate Commercial/Institutional Sector Stationary Source Distillate Fuel Consumption Sector Commercial a Distillate Fuel Type No. 1 Distillate Fuel Oil No. 2 Distillate Fuel Oil No. 2 Distillate/Ultra-Low, Low, and High Sulfur Diesel No. 4 Distillate Fuel Oil % of Total Consumption from Stationary Sources 80 100 0a 100 A very small portion of total commercial/institutional diesel is consumed by point sources (SCC 203001xx). 69 Commercial/Institutional Distillate Oil Combustion: Number of County Employees where: Annual Emissions Pollutant Emission Factor Oil Consumption Number of State Employees VOC Emission Factor = 0.34 lbs/thous. gal. distillate oil/year NOx Emission Factor = 20 lbs/thous. gal. distillate oil/year CO Emission Factor = 5.0 lbs/thous. gal. distillate oil/year Pb Emission Factor = 0.00126 lbs/thous. gal. distillate oil/year Sulfur Content = 0.3% SO2 Emission Factor = 42.6 lbs/thous. gal. distillate oil/year PM10-FIL Emission Factor = 1.08 lbs/thous. gal. distillate oil/year PM25-FIL Emission Factor = 0.83 lbs/thous. gal. distillate oil/year PM-CON Emission Factor = 1.3 lbs/thous. gal. distillate oil/year Pennsylvania Commercial Distillate Oil Consumption = 4,264,000 barrels = 179,088 thousand gallons where: Number of Allegheny County Commercial Employees =637,800 Number of Pennsylvania Commercial Employees = 4,546,525 NO2 Emissions: 20 lbs NO2 Annual NO2 Emissions ton distoil 637,800 employees in county 179,088, thousgallo ns year 4,546,525 employees in state Annual NO2 Emissions 502,459.9069 pounds NO2 per year 1 ton 251.2300 tons NO2 per year 2000 lbs 70 Commercial/Institutional Residual Oil Combustion: Number of County Employees Annual Emissions Pollutant Emission Factor Oil Consumption Number of State Employees where: VOC Emission Factor = 1.13 lbs/thous gal. residual oil/year NOx Emission Factor = 55 lbs/thous gal. residual oil/year CO Emission Factor = 5.0 lbs/thous gal. residual oil/year Pb Emission Factor = 0.00165 lbs/thous gal. residual oil/year SO2 Emission Factor = 353.25 lbs/thous gal. residual oil/year Sulfur Content = 2.25% PM10-FIL Emission Factor = 14.9413 lbs/thous gal. residual oil/year PM25-FIL Emission Factor = 5.5488 lbs/thous gal. residual oil/year PM-CON Emission Factor = 1.5 lbs/thous gal. residual oil/year Pennsylvania Commercial Residual Consumption = 287,000 barrels = 12,054,000 gallons where: Number of Commercial/Institutional County Employees (Allegheny County) = 637,800 Number of Pennsylvania Commercial/Institutional Employees = 4,546,525 VOC Emissions: 1.13 lbs VOC Annual VOCL Emissions 1000 gal Re s.oil 637,800 employees in county 12,054thousgallo ns year 4,546,525 employees in state Annual VOC Emissions 1910.7971 pounds VOC per year 1 ton 0.9554 tons VOC per year 2000 lbs 71 Commercial/Institutional Natural Gas Combustion: Number of County Employees Annual Emissions Pollutant Emission Factor Oil Consumption Number of State Employees where: VOC Emission Factor = 5.5 lbs/MMCF natural gas/year NOx Emission Factor = 100 lbs/MMCF natural gas/year CO Emission Factor = 84 lbs/MMCF natural gas/year Pb Emission Factor = .0005 lbs/MMCF natural gas/year SO2 Emission Factor = 0.6 lbs/MMCF natural gas/year PM10-FIL Emission Factor = 0.13 lbs/MMCF natural gas/year PM25-FIL Emission Factor = 0.11 lbs/MMCF natural gas/year PM-CON Emission Factor = 0.32 lbs/MMCF natural gas/year Pennsylvania Commercial/Institutional NG Consumption = 130,328 MMCF where: Number of Allegheny County Commercial Employees = 637,800 Number of Pennsylvania Commercial Employees = 4,546,525 72 CO Emissions: 84 lbs CO MMCFNG 130,328MMCFNG 637,800 employees in count year 4,546,525 employees in state 1 ton Annual CO Emissions 1,535,755.036 pounds CO per year 767.8775 tons CO per year 2000 lbs Annual CO Emissions Commercial/Institutional LPG Combustion: Number of County Employees Annual Emissions Pollutant Emission Factor LPG Consumption Number of State Employees where: VOC Emission Factor = 21.91 lbs/1000 barrel LPG/year NOx Emission Factor = 398.38 lbs/1000 barrel LPG/year CO Emission Factor = 501.96 lbs/1000 barrel LPG/year Pb Emission Factor = 0.001827 lbs/1000 barrel LPG/year SO2 Emission Factor = 2.39 lbs/1000 barrel LPG/year PM10-FIL Emission Factor = 0.797 lbs/1000 barrel LPG/year PM25-FIL Emission Factor = 0.438 lbs/1000 barrel LPG/year PM-CON Emission Factor = 1.28 lbs/1000 barrel LPG/year Pennsylvania Commercial/Institutional LPG Consumption = 689,000 barrels 73 where: Number of Allegheny County Industrial Employees =637,800 Number of Pennsylvania Industrial Employees = 4,546,525 VOC Emissions: 21.91 lbs VOC 1000 BBL 689,000 BBL 637,800 employees in county year 4,546,525 employees in state 1 ton Annual VOC Emissions 2,117.7102 pounds VOC per year 1.0588 tons VOC per year 2000 lbs Annual VOC Emissions Commercial/Institutional Kerosene Combustion: Number of County Employees where: Annual Emissions Pollutant Emission Factor Kerosene Consumption Number of State Employees VOC Emission Factor = 0.3278571 lbs/1000 gal Kerosene/year NOx Emission Factor = 19.28572 lbs/1000 gal Kerosene/year CO Emission Factor = 4.821429 lbs/1000 gal Kerosene/year Pb Emission Factor = 0.001215 lbs/1000 gal Kerosene/year SO2 Emission Factor = 41.07857 lbs/1000 gal Kerosene/year PM10-FIL Emission Factor = 1.041429 lbs/1000 gal Kerosene/year PM25-FIL Emission Factor = 0.8003572 lbs/1000 gal Kerosene/year PM-CON Emission Factor = 1.25 lbs/1000 gal Kerosene/year Pennsylvania Commercial Kerosene Consumption = 420,000 barrels = 17,640,000 gallons 74 where: Number of Allegheny County Industrial Employees =637,800 Number of Pennsylvania Industrial Employees = 4,546,525 SO2 Emissions: 41.07857 lbs SO 2 1000GAL 17,640,000GAL 637,800 employees in county year 4,546,525 employees in state 1ton Annual SO 2 Emissions 101,652.6791 pounds SO 2 per year 50.8263 tons SO 2 per year 2000 lbs Annual SO 2 Emissions Point Source Energy Adjustment Because the point source inventory also includes commercial/institutional fuel combustion source categories, it is necessary to subtract point source inventory fuel use from the SEDS fuel consumption estimates. Table 5 displays the crosswalk between commercial/institutional fuel combustion non-point SCCs and associated point SCCs that EPA plans to use in the subtraction procedure. The subtractions will be performed after summing the point source throughput estimates to the state-level. 75 Table 5. Point Source Subtraction SCCs Relevant to Nonpoint Source Commercial/Institutional Fuel Combustion SCC SCC Level 1 SCC Level 2 SCC Level 3 (Fuel-if not specified at level 3) 2103001000 & 2103002000 -- Commercial/Institutional; Anthracite Coal; Total: All Boiler Types and Bituminous/Sub-bituminous Coal; Total: All Boiler Types 103002xx External Combustion Boilers Commercial/Institutional Bituminous/Sub-bituminous Coal 10500202 External Combustion Boilers Space Heaters Commercial/Institutional (Coal) 50190002 Waste Disposal Solid Waste Disposal - Government Auxiliary Fuel/No Emissions (Coal) Solid Waste Disposal 50290002 Waste Disposal Commercial/Institutional Auxiliary Fuel/No Emissions (Coal) 2103004000 -- Commercial/Institutional; Distillate Oil; Total: Boilers and IC Engines 103005xx External Combustion Boilers Commercial/Institutional Distillate Oil 10500205 External Combustion Boilers Space Heaters Commercial/Institutional (Distillate Oil) 50190005 Waste Disposal Solid Waste Disposal - Government Auxiliary Fuel/No Emissions (Distillate Oil) Solid Waste Disposal 50290005 Waste Disposal Commercial/Institutional Auxiliary Fuel/No Emissions (Distillate Oil) 2103005000 -- Commercial/Institutional; Residual Oil; Total: All Boiler Types 103004xx External Combustion Boilers Commercial/Institutional Residual Oil 2103006000 -- Commercial/Institutional; Natural Gas; Total: Boilers and IC Engines 103006xx External Combustion Boilers Commercial/Institutional Natural Gas 10500206 External Combustion Boilers Space Heaters Commercial/Institutional (Natural Gas) 203002xx Internal Combustion Engines Commercial/Institutional Natural Gas 50190006 Waste Disposal Solid Waste Disposal - Government Auxiliary Fuel/No Emissions (Natural Gas) Solid Waste Disposal 50290006 Waste Disposal Commercial/Institutional Auxiliary Fuel/No Emissions (Natural Gas) 2103007000 -- Commercial/Institutional; Liquid Petroleum Gas; Total: All Combustor Types 103010xx External Combustion Boilers Commercial/Institutional Liquefied Petroleum Gas (LPG) 10500210 External Combustion Boilers Space Heaters Commercial/Institutional (LPG) 203010xx Internal Combustion Engines Commercial/Institutional Liquefied Petroleum Gas (LPG) 50190010 Waste Disposal Solid Waste Disposal - Government Auxiliary Fuel/No Emissions (LPG) Solid Waste Disposal 50290010 Waste Disposal Commercial/Institutional Auxiliary Fuel/No Emissions (LPG) 2103008000 -- Commercial/Institutional; Wood; Total: All Boiler Types 103009xx External Combustion Boilers Commercial/Institutional Wood/Bark Waste 10500209 External Combustion Boilers Space Heaters Commercial/Institutional (Wood) 2103011000 -- Commercial/Institutional; Kerosene; Total: All Combustor Types 203009xx Internal Combustion Engines Commercial/Institutional Kerosene/Naphtha (Jet Fuel) 50100603 Waste Disposal Solid Waste Disposal - Government Fire Fighting (Kerosene) County Allocation of State Activity Data Year 2007 county-level activity estimates will be developed by allocating the state-level activity resulting from the adjustments to the SEDS data described above. The EPA compiled 2006 estimates of commercial sector (NAICS codes 42 through 81) employment from the Bureau of Census’ County Business Patterns 2006 for use in this procedure (Census, 2009a). A separate document describes how withheld County Business Patterns employment data were estimated (Divita, 2008). The EPA also developed 2006 county-level estimates of institutional sector (NAICS code 92) employment from 2007 local government employment data in the 2007 Census of Governments and adjustments reflecting each state’s 2006/2007 local government employment ratio (Census, 2009b).1 State-level commercial/institutional fuel combustion by fuel type was allocated to each county using the ratio of the number of commercial/institutional sector employees in each county to the total number of commercial/institutional sector employees in the state. Emission Factors The EPA has compiled criteria and hazardous air pollutant emission factors for non-point source commercial/institutional fuel combustion categories (Huntley, 2009). These emission factors, which are too numerous to list here, are included in a spreadsheet within the ICI fuel combustion workbook. In most cases, these are the same emission factors that were used in preparing the 2002 non-point source NEI (Pechan, 2006). Commercial/institutional wood combustion emission factors were obtained from an ICI fuel combustion study being performed for the Central Regional Air Planning Association (CENRAP) (Pechan, 2009a). Potential Improvements States may wish to incorporate the following improvements in developing non-point source commercial/institutional fuel combustion emission estimates: Update SO2 emission factors to reflect coal sulfur content estimates for coal used in the industrial sector in 2006-1 County-level federal and state government employment data are not available from the Bureau of the Census. 77 a recent review of industrial and commercial coal sulfur content values for the Central Regional Air Planning Association concluded that the 2002 NEI values are based on unrepresentative data (Pechan, 2009b).1 Additional References for Fuel Combustion - Commercial/Institutional 1. Census, 2009a: Bureau of the Census, U.S. Department of Commerce, County Business Patterns 2006, available from: http://www.census.gov/epcd/cbp/download/06_data/index.html, accessed March 2009. Census, 2009b: Bureau of the Census, U.S. Department of Commerce, “Local Government Employment and Payroll, March 2006,” 2007 Census of Governments, available from: http://www.census.gov/govs/www/apesloc06.html, accessed March 2009. 2. Divita, 2008: Divita, Frank, E.H. Pechan & Associates, Inc., memorandum to Roy Huntley, U.S. Environmental Protection Agency, “County Business Patterns Calculations,” December 4, 2008. 3. EIA, 2008a: Energy Information Administration, U.S. Department of Energy, State Energy Data System – Consumption, Physical Units, 1960-2006, available from: http://www.eia.doe.gov/emeu/states/_seds.html, released November 28, 2008. 4. EIA, 2008b: Energy Information Administration, U.S. Department of Energy, Fuel Oil and Kerosene Sales, data available from: http://tonto.eia.doe.gov/dnav/pet/pet_cons_821use_dcu_nus_a.htm, release date December 23, 2008. 5. EPA, 2003: U.S. Environmental Protection Agency, “Draft Regulatory Impact Analysis: Control of Emissions from Nonroad Diesel Engines,” EPA420-R-03-008, Office of Transportation and Air Quality, April 2003. 6. Huntley, 2009: Huntley, Roy, U.S. Environmental Protection Agency, “SCCs & emission factors to be used in 2008 NEI to Bollman May 1 2009.mdb [electronic file],” May 1, 2009. 1 Actual data characterizing sulfur content of coal consumed in the commercial sector is limited, but appears to be in-line with industrial coal consumption values. Therefore, industrial sector sulfur content can reasonably be assumed to be representative of commercial sector sulfur content. 78 7. Pechan, 2009a: E.H. Pechan & Associates, Inc., “Area Combustion Source Emissions Inventory Improvement Methodology, Technical Memorandum,” E.H. Pechan & Associates, Inc., prepared for Central Regional Air Planning Association, March 20, 2009. 8. Pechan, 2009b: E.H. Pechan & Associates, Inc., “Evaluation of ICI Combustion Coal Sulfur Content, Technical Memorandum,” prepared for Central Regional Air Planning Association, March 28, 2009. 9. Pechan, 2006: E.H. Pechan & Associates, Inc. “Documentation for the Final 2002 Nonpoint Sector (Feb 06 Version) National Emission Inventory for Criteria and Hazardous Air Pollutants,” prepared for U.S. Environmental Protection Agency, July 2006. 79 FUEL COMBUSTION – INDUSTRIAL (7 SCCs: 2102001000, SCC 2102002000, SCC 2102004000, SCC 2102005000, SCC 2102006000, SCC 2102007000, SCC 2102011000) Source Category Description This sub-sector covers emissions from fuel combustion at stationary non-point sources within the industrial sector (i.e., sources that are not reported in the point source inventory because their emissions are too small). These documentation and fuel combustion emissions were calculated by E. H. Pechan and Associates. References are listed at the end of the Fuel Combustion – Industrial section. Industrial fuel combustion emissions will be computed for the following fuel types: coal, distillate oil, residual oil, natural gas, liquefied petroleum gas (LPG), kerosene, and wood. There are additional types of energy that are consumed in the industrial sector: asphalt and road oil; feedstocks, naphtha (less than 401°F); feedstocks, other oils (greater than 401°F); lubricants; motor gasoline; miscellaneous petroleum products; pentanes plus; special naphthas; and waxes. With the exception of motor gasoline, all of these additional fossil fuels are not actually combusted (oxidized) but are used as chemical feedstocks, construction materials, lubricants, solvents, or reducing agents. Therefore, there are no industrial sector combustion emissions from these fuel types. As described in more detail later, most of the fuel types that are included in the industrial combustion sector, also have a non-fuel use component. Therefore, it is necessary to exclude this component in calculating non-point source industrial fuel combustion activity/emissions. Motor gasoline is not inventoried as a non-point source because it is expected that gasoline combustion in this sector is included in the non-road inventory. The approach to be used in calculating emissions for industrial fuel combustion is to first develop state-level fuel consumption estimates, then to allocate these to the county-level, and then to multiply the resulting county-level consumption estimates by appropriate emission factors. 80 Source Classification. Table 1 displays the non-point SCCs associated with industrial fuel combustion. Table 1. Non-point Source Industrial Fuel Combustion SCCs SCC 21020010 00 21020020 00 21020040 00 21020050 00 21020060 00 21020070 00 21020080 00 21020110 00 SCC Level 1 Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion Stationary Source Fuel Combustion SCC Level 2 SCC Level 3 Industrial Anthracite Coal Industrial SCC Level 4 Total: All Boiler Types Industrial Bituminous/Sub-bituminous Total: All Boiler Types Coal Distillate Oil Total: Boilers and IC Engines Residual Oil Total: All Boiler Types Industrial Natural Gas Industrial Industrial Liquefied Petroleum Gas (LPG) Wood Industrial Kerosene Industrial Total: Boilers and IC Engines Total: All Boiler Types Total: All Boiler Types Total: All Boiler Types 81 Activity Data Table 2 summarizes this sector’s non-point source activity data, units, and data source. Total state-level industrial sector energy consumption data are available from the Energy Information Administration (EIA)’s State Energy Data System (SEDS), and were used for most source categories (EIA, 2008a). However, as documented below, a number of adjustments were made to the SEDS data, and a separate EIA data source was used for distillate oil. Year 2006 SEDS data were used to estimate 2007 emissions because these were the latest year consumption data available at the time this work was performed in 2009 Table 2. Non-point Source Industrial Fuel Combustion Activity Data SCC SCC Level 1 21020010 Stationary Source 00 Fuel Combustion 21020020 Stationary Source 00 Fuel Combustion 21020040 Stationary Source 00 Fuel Combustion SCC SCC Level Activity Data Level 2 3 SCC Level 4 Activity Source Industri Anthracite Total: All Thousand short tons of EIA’s SEDSa al Coal Boiler Types coal consumed Industri Bituminous/ Total: All al SubBoiler Types bituminous Coal Industri Distillate Oil Total: al Boilers and IC Engines Thousand short tons of EIA’s SEDSa coal consumed Thousand barrels of EIA’s Fuel Oil distillate oil consumed and Kerosene Salesa 82 SCC SCC Level 1 21020050 Stationary Source 00 Fuel Combustion 21020060 Stationary Source 00 Fuel Combustion 21020070 Stationary Source 00 Fuel Combustion 21020080 00 21020110 00 a Stationary Source Fuel Combustion Stationary Source Fuel Combustion SCC SCC Level Level 2 3 SCC Level 4 Activity Industri Residual Oil Total: All Thousand barrels of al Boiler Types residual oil consumed Industri Natural Gas Total: al Boilers and IC Engines Industri Liquefied Total: All al Petroleum Boiler Types Gas (LPG) Industri Wood Total: All al Boiler Types Industri Kerosene Total: All al Boiler Types Activity Data Source EIA’s SEDSa Million cubic feet of EIA’s SEDSa natural gas consumed Thousand barrels of LPG consumed EIA’s SEDSa Billion Btu of wood consumed Thousand barrels of kerosene consumed EIA’s SEDSa EIA’s SEDSa With adjustments that are described in the text of this section. Fuel-Specific Activity Data Adjustments Coal - for industrial coal combustion, it was necessary to compile data representing a sub-set of total sector coal consumption. Data representing non-coke plant consumption were compiled from EIA because coal consumed by coke plants is accounted for in the point source inventory. The SEDS data do not provide coal consumption estimates by type of coal (i.e., anthracite versus bituminous/subbituminous) and in some cases, CAP emission factors differ between the two. Because anthracite is mined in the eastern half of the Commonwealth, while bituminous is mined in the western half, the emission calculations assume that eastern counties burn anthracite coal while western counties burn bituminous coal. 83 Industrial Coal Combustion: Number of County Employees where: Annual Emissions Pollutant Emission Factor Coal Consumption Number of State Employees VOC Emission Factor = 0.3 lbs/ton anthracite coal/year; 0.05 lbs/ton bituminous coal/year NOx Emission Factor = 9 lbs/ton anthracite coal/year; 11 lbs/ton bituminous coal/year CO Emission Factor = 0.6 lbs/ton anthracite coal/year; 5.0 lbs/ton bituminous coal/year Pb Emission Factor = 0.00042 lbs/ton anthracite coal/year and bituminous coal/year SO2 Emission Factor =34.71 lbs/ton anthracite coal/year; 91.96 lbs/ton bituminous coal/year (EPA default values for PA) PM10-FIL Emission Factor = 14.718 lbs/ton anthracite coal/year; 12 lbs/ton bituminous coal/year PM25-FIL Emission Factor = 6.4224 lbs/ton anthracite coal/year; 1.4 lbs/ton bituminous coal/year PM-CON Emission Factor = 0.08 lbs/ton anthracite coal/year; 0.04 lbs/ton bituminous coal/year Anthracite Coal Sulfur Content = 0.89% Bituminous Coal Sulfur Content = 2.42% Anthracite Coal Ash Content = 13.38% ash Pennsylvania Industrial Coal Consumption = 2,597,000 tons Number of Industrial County Employees (Allegheny County) = 41,656 Number of Pennsylvania Industrial Employees = 800,578 where: Number of Allegheny County Industrial Employees =41,656 Number of Pennsylvania Industrial Employees = 800,578 84 CO Emissions: 5 lbs CO Annual CO Emissions ton bituminous year coal 2,597,000 tons Annual CO Emissions 675,640.7995 pounds CO per year 41,656 employees in county 800,578 employees in state 1 ton 337.8204 tons CO per year 2000 lbs Distillate Oil and LPG – the SEDS industrial sector distillate oil and LPG consumption data include consumption estimates for equipment that EPA includes in the non-road sector inventory. In particular, SEDS considers the following non-road source category activities to be part of the industrial sector: farming, logging, mining, and construction. To avoid double-counting of LPG consumption, EPA ran the National Mobile Inventory Model (NMIM) for 2006 and calculated the national volume of non-road LPG consumption from agriculture, logging, mining, and construction source categories. This estimate was then divided into the SEDS total industrial sector LPG consumption estimate to yield the proportion of total industrial sector LPG consumption attributable to the non-road sector in that year (approximately 9 percent). To estimate the volume of industrial sector LPG consumption that should not be included in the non-point source industrial fuel combustion category, EPA subtracted 9 percent from each state’s industrial sector LPG consumption estimate reported in SEDS. To avoid double-counting of distillate oil consumption between the non-point and non-road sector emission inventories, EPA relied on a source other than SEDS to estimate consumption. The approach uses more detailed distillate oil consumption estimates reported in EIA’s Fuel Oil and Kerosene Sales, and assumptions used in the regulatory impact analysis (RIA) for EPA’s non-road diesel emissions rulemaking (EIA, 2008b; EPA, 2003). Table 4 displays the assumptions that were applied to the state-level distillate oil consumption estimates reported in Fuel Oil and Kerosene Sales to estimate total stationary source industrial sector consumption. 85 Table 4. Assumptions Used to Estimate Industrial Sector Stationary Source Distillate Fuel Consumption Sector Industrial Farm Off-Highway (Construction and Other) % of Total Consumption from Stationary Distillate Fuel Type Sources No. 1 Distillate Fuel Oil 60 No. 2 Distillate Fuel Oil 100 No. 2 Distillate/Low and High Sulfur 15a Diesel No. 4 Distillate Fuel Oil 100 Diesel 0 Other Distillate Fuel Oil 100 Distillate Fuel Oil 5 This value differs from the 0% assumption adopted in EPA’s non-road diesel emissions rulemaking because it is known that some diesel fuel is used by stationary sources (a 15 percent value was selected for use as an approximate mid-point of a potential range of 8 to 24% stationary source use computed from a review of data from the EIA’s Manufacturing Energy Consumption Survey and Fuel Oil and Kerosene Sales). a Industrial Distillate Oil Combustion: Number of County Employees Annual Emissions Pollutant Emission Factor Oil Consumption Number of State Employees 86 where: VOC Emission Factor = 0.20 lbs/thous gal. distillate oil/year NOx Emission Factor = 20 lbs/thous gal. distillate oil/year CO Emission Factor = 5.0 lbs/thous gal. distillate oil/year Pb Emission Factor = 0.00126 lbs/thous gal. distillate oil/year SO2 Emission Factor = 42.6 lbs/thous gal. distillate oil/year Sulfur Content = 0.3% PM10-FIL Emission Factor = 1 lbs/thous gal. distillate oil/year PM25-FIL Emission Factor = 0.25 lbs/thous gal. distillate oil/year PM-CON Emission Factor = 1.3 lbs/thous gal. distillate oil/year Pennsylvania Industrial Distillate Oil Consumption = 2,521,000 barrels = 105,882 thouand gallons Number of Allegheny County Industrial Employees =41,656 Number of Pennsylvania Industrial Employees = 800,578 SO2 Emissions: 42.6 lbs SO 2 Annual SO 2 Emissions 1000 gal distoil 41,656 employees in county 105,882thousgallo ns year 800,578 employees in state Annual SO 2 Emissions 234,695.9787 pounds SO 2 per year 1 ton 117.3479 tons SO 2 per year 2000 lbs 87 Industrial Residual Oil Combustion: Number of County Employees where: Annual Emissions Pollutant Emission Factor Oil Consumption Number of State Employees VOC Emission Factor = 0.28 lbs/thous gal. residual oil/year NOx Emission Factor = 47 lbs/thous gal. residual oil/year CO Emission Factor = 5.0 lbs/thous gal. residual oil/year Pb Emission Factor = 0.00165 lbs/thous gal. residual oil/year SO2 Emission Factor = 353.25 lbs/thous gal. residual oil/year Sulfur Content = 2.25% PM10-FIL Emission Factor = 20.7213 lbs/thous gal. residual oil/year PM25-FIL Emission Factor = 13.4963 lbs/thous gal. residual oil/year PM-CON Emission Factor = 1.5 lbs/thous gal. residual oil/year Pennsylvania Industrial Residual Oil Consumption = 1,702,000 barrels = 71,484 thousand gallons Number of Allegheny County Industrial Employees =41,656 Number of Pennsylvania Industrial Employees = 800,578 PM10-FIL Emissions: 20.7213 lbs PM 10 FIL Annual PM 10 FIL Emissions 1000 gal Re s.oil year 71,484thousgallo ns Annual PM 10 FIL Emissions 77,072.5553 pounds PM 10 FIL per year 41,656 employees in county 800,578 employees in state 1 ton 38.5363 tons PM 10 FIL per year 2000 lbs 88 Industrial Natural Gas Combustion: Number of County Employees Annual Emissions Pollutant Emission Factor NG Consumption Number of State Employees where: VOC Emission Factor = 5.5 lbs/MMCF natural gas/year NOx Emission Factor = 100 lbs/MMCF natural gas/year CO Emission Factor = 84 lbs/MMCF natural gas/year Pb Emission Factor = .0005 lbs/MMCF natural gas/year SO2 Emission Factor = 0.6 lbs/MMCF natural gas/year PM10-FIL Emission Factor = 0.13 lbs/MMCF natural gas/year PM25-FIL Emission Factor = 0.11 lbs/MMCF natural gas/year PM-CON Emission Factor = 0.32 lbs/MMCF natural gas/year Pennsylvania Industrial NG Consumption = 193,856 MMCF where: Number of Allegheny County Industrial Employees =41,656 Number of Pennsylvania Industrial Employees = 800,578 NOx Emissions: 89 100 lbs NOx MMCF 193,856MMCF 41,656 employees in county year 800,578 employees in state 1 ton Annual NOx Emissions 1,008,679.421 pounds NOx per year 504.3397 tons NOx per year 2000 lbs Annual NOx Emissions Industrial LPG Gas Combustion: Number of County Employees Annual Emissions Pollutant Emission Factor LPG Consumption Number of State Employees where: 90 VOC Emission Factor = 21.91 lbs/ thous bbl LPG/year NOx Emission Factor = 398.38 lbs/ thous bbl LPG/year CO Emission Factor = 501.96 lbs/ thous bbl LPG/year Pb Emission Factor = 0.001827 lbs/ thous bbl LPG/year SO2 Emission Factor = 2.39 lbs/ thous bbl LPG/year PM10-FIL Emission Factor = 0.797 lbs/ thous bbl LPG/year PM25-FIL Emission Factor = 0.438 lbs/ thous bbl LPG/year PM-CON Emission Factor = 1.28 lbs/ thous bbl LPG/year Pennsylvania Industrial LPG Consumption = 3,923,000 bbl Number of Allegheny County Industrial Employees =41,656 Number of Pennsylvania Industrial Employees = 800,578 CO Emissions: 501.96 lbs CO 1000 BBL 3,923,000 BBL 41,656 employees in county year 800,578 employees in state 1ton Annual CO Emissions 102,461.6469 pounds CO per year 51.2308 tons CO per year 2000 lbs Annual CO Emissions Industrial Kerosene Combustion: Number of County Employees Annual Emissions Pollutant Emission Factor Kerosene Consumption Number of State Employees where: 91 VOC Emission Factor = 0.1928471 lbs/ thous gal Kerosene/year NOx Emission Factor = 20.0 lbs/ thous gal Kerosene/year CO Emission Factor = 5.0 lbs/ thous gal Kerosene/year Pb Emission Factor = 0.001215 lbs/ thous gal Kerosene/year SO2 Emission Factor = 42.6 lbs/ thous gal Kerosene/year PM10-FIL Emission Factor = 1.0 lbs/ thous gal Kerosene/year PM25-FIL Emission Factor = 0.25 lbs/ thous gal Kerosene/year PM-CON Emission Factor = 1.3 lbs/ thous gal Kerosene/year Number of Allegheny County Industrial Employees =41,656 Number of Pennsylvania Industrial Employees = 800,578 SO2 Emissions: 42.6 lbs SO 2 1000Gal 1,638,000 41,656 employees in county year 800,578 employees in state 1ton Annual SO 2 Emissions 3,630.7589 pounds SO 2 per year 1.8158 tons SO 2 per year 2000 lbs Annual SO 2 Emissions Non-Fuel Use Energy Adjustment Some industrial sector energy is consumed for non-fuel purposes. For example, natural gas is used as a feedstock in chemical manufacturing plants and to make nitrogenous fertilizer, and LPG is used to create intermediate products that are made into plastics. To estimate the volume of fuel that is associated with industrial combustion, it is necessary to subtract the volume of fuel consumption for non-energy uses from the volume of total fuel consumption. The EPA’s State Greenhouse Gas Inventory Tool (SIT) provides national defaults representing the percentage of total industrial fuel consumption from non-energy uses. These default values have an additional limitation beyond their lack of geographic detail - they represent the EIA’s definition of the industrial sector, which includes fuel consumption from industrial, farm, mining, and construction sectors that is accounted for in the non-road inventory. 92 Furthermore, a review of the SIT default data indicates that all residual oil is consumed as a fuel source. However, the EIA’s 2002 Manufacturing Energy Consumption Survey (MECS) indicates significant non-fuel use of residual oil in the manufacturing sector (EIA, 2007a). In discussions about this issue, EIA noted that the non-fuel use data in the SIT appeared to be incorrect, and that the MECS data were representative of 2002 non-fuel use (Lorenz, 2009). Given this concern, a review was conducted of the non-fuel use assumptions incorporated into the EIA’s GHG emissions inventory for 2005 (EIA, 2007b). For each type of industrial sector energy consumed in 2006, Table 5 summarizes EIA’s non-fuel use assumptions. Table 5. Non-Fuel Use Information from EIA’s 2005 GHG Inventory Fuel Asphalt and Road Oil Coal (non-coke) Distillate Oil Feedstocks, Naphtha <401°F Feedstocks, Other oils >401°F Kerosene LPG Lubricants Misc. Petroleum Products Motor Gasoline Natural Gas Pentanes Plus Residual Oil Special Naphthas Waxes Non-Fuel Use Assumption 100% Yes (<100%) Yes (<100%) 100% 100% None Yes (<100%) 100% 100% None Yes (<100%) 100% Yes (<100%) 100% 100% In calculating the emission activity for industrial fuel combustion, EPA excluded all SEDS fuel types for which EIA assumes 100 percent of consumption is non-fuel use. 93 For fuel types for which non-fuel use occurs, but is less than 100 percent, Pechan reviewed two information sources to identify the non-fuel use percentage to apply in the NEI. The first source was that listed by EIA in its 2005 national GHG inventory; the second was the EIA’s 2002 MECS. The MECS data has the advantage of providing region-specific estimates as well as values that exclude fuel consumption that is already accounted for in the non-road inventory. For distillate and residual fuel and natural gas, the EIA GHG inventory source was MECS. For LPG, it was not possible to use the EIA GHG inventory source for non-fuel consumption as it is a proprietary source published by the American Petroleum Institute. For non-coke coal, EIA extrapolated data from 1994. The MECS non-fuel consumption data treat coal that is used to produce coke as a feedstock, and therefore, MECS can not be used to represent non-coke coal consumption. The 2002 MECS data treat “synthetic coal” that is ultimately combusted as regular coal, as a non-fuel (feedstock) use. Because of the limitations of the MECS data, EPA obtained from EIA a rough estimate of the percentage of non-coking coal that is used for non-fuel purposes (while also treating “synthetic coal” as a fuel use). Based on the EIA’s estimate that 5-10 percent of non-coke coal is used for non-fuel purposes, EPA assumed that 7 percent of noncoke plant industrial sector coal consumption is for non-fuel purposes (Lorenz, 2009). Table 6 presents the non-fuel use percentages that were applied to estimate industrial fuel combustion activity. Table 6. Industrial Sector Non-Fuel Use Estimates Fuel Distillate Oil LPG Natural Gas Non-Coke Coal Residual Oil a Northeast 5a 41a 1 7c 0 % Non-Fuel Use by Region South Midwest b 9 9b 98 88 15 6 c 7 7c 25b Due to withheld data, value represents combination of Northeast and West region data. b Due to withheld data, value represents combination of Midwest and South region data. c Region-specific values not available. 25b West 5a 41a 41 7c 8 Source 2002 MECS 2002 MECS 2002 MECS Lorenz, 2009 2002 MECS 94 Source Energy Adjustment Because the point source inventory also includes industrial fuel combustion categories, it is necessary to subtract point source inventory fuel use from the SEDS fuel consumption estimates. Table 7 displays a crosswalk between industrial fuel combustion non-point SCCs and associated point SCCs that EPA plans to use in the subtraction procedure.1 The subtractions will be performed after summing the point source throughput estimates to the state-level. County Allocation of State Activity Data Year 2005 county-level activity estimates will be developed by allocating the state-level activity resulting from the adjustments to the EIA data described above. The EPA compiled 2006 estimates of manufacturing sector employment from the Bureau of Census’ County Business Patterns 2006 for use in this procedure (Census, 2009). State-level industrial fuel combustion by fuel type will be allocated to each county using the ratio of the number of manufacturing sector (NAICS codes 31-33) employees in each county to the total number of manufacturing sector employees in the state. A separate document describes how withheld County Business Patterns employment data were estimated (Divita, 2008). Table 7. Point Source Subtraction SCCs Relevant to Non-point Source Industrial Fuel Combustion SCC SCC Level 1 102002xx 10500102 390002xx 50390002 External Combustion Boilers External Combustion Boilers Industrial Processes Waste Disposal 102005xx 10201403 External Combustion Boilers External Combustion Boilers 1 SCC Level 2 SCC Level 3 (Fuel-if not specified at level 3) 2102002000 – Industrial; Bituminous/Sub-bituminous Coal; Total: All Boiler Types Industrial Bituminous/Sub-bituminous Coal Space Heaters Industrial (Coal) In-Process Fuel Use Bituminous Coal Solid Waste Disposal – Industrial Auxiliary Fuel/No Emissions (Coal) 2102004000 – Industrial; Distillate Oil; Total: All Boilers and IC Engines Industrial Distillate Oil Industrial CO Boiler (Distillate Oil) As noted in a footnote to Table 7, it is important to exclude any natural gas pipeline fuel use from the point source subtraction procedure because SEDS includes such use in the Transportation sector rather than the Industrial sector. 95 SCC SCC Level 1 10500105 202001xx 20200401 20200405 20200406 20200407 27000320 30190001 30190011 30190021 30290001 30390001 30390011 30390021 30400406 30490001 30490011 30490021 30490031 30500208 30505022 30590001 30590011 30590021 30600901 30609901 30790001 30790011 30790021 External Combustion Boilers Internal Combustion Engines Internal Combustion Engines Internal Combustion Engines Internal Combustion Engines Internal Combustion Engines Internal Combustion Engines Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes 30890001 Industrial Processes 30890011 Industrial Processes 30890021 Industrial Processes 30990001 30990011 31000401 Industrial Processes Industrial Processes Industrial Processes SCC Level 2 Space Heaters Industrial Industrial Industrial Industrial Industrial Off-Highway Diesel Engines Chemical Manufacturing Chemical Manufacturing Chemical Manufacturing Food and Agriculture Primary Metal Production Primary Metal Production Primary Metal Production Secondary Metal Production Secondary Metal Production Secondary Metal Production Secondary Metal Production Secondary Metal Production Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Petroleum Industry Petroleum Industry Pulp and Paper and Wood Products Pulp and Paper and Wood Products Pulp and Paper and Wood Products Rubber and Miscellaneous Plastics Products Rubber and Miscellaneous Plastics Products Rubber and Miscellaneous Plastics Products Fabricated Metal Products Fabricated Metal Products Oil and Gas Production SCC Level 3 (Fuel-if not specified at level 3) Industrial (Distillate Oil) Distillate Oil (Diesel) Large Bore Engine (Diesel) Crankcase Blow-by (Diesel) Evaporative Losses (Fuel Storage and Delivery System) (Diesel) Exhaust (Diesel) Industrial Equipment Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Lead (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Asphalt Concrete (Distillate Oil) Asphalt Processing (Blowing) (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Flares (Distillate Oil) Incinerators (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Fuel Fired Equipment (Distillate Oil) Process Heaters (Distillate Oil) 96 SCC SCC Level 1 31000411 31390001 390005xx 39900501 39990001 39990011 39990021 40201002 40290011 49090011 49090021 50390005 Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Waste Disposal 102004xx 10201404 202005xx 30190002 30190012 30190022 30290002 30390002 30390012 30390022 30490002 30490012 30490022 30490032 30500207 30505021 30590002 30590012 30600111 30600902 30609902 30790002 30790012 30790022 30890002 External Combustion Boilers External Combustion Boilers Internal Combustion Boilers Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes SCC Level 2 SCC Level 3 (Fuel-if not specified at level 3) Oil and Gas Production Process Heaters (Distillate Oil) Electrical Equipment Process Heaters (Distillate Oil) In-Process Fuel Use Distillate Oil Miscellaneous Manufacturing Industries Process Heater/Furnace (Distillate Oil) Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Distillate Oil) Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Distillate Oil) Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Distillate Oil) Surface Coating Operations Coating Oven Heater (Distillate Oil) Surface Coating Operations Fuel Fired Equipment (Distillate Oil) Organic Solvent Evaporation Fuel Fired Equipment (Distillate Oil) Organic Solvent Evaporation Fuel Fired Equipment (Distillate Oil) Solid Waste Disposal – Industrial Auxiliary Fuel/No Emissions (Distillate Oil) 2102005000 – Industrial; Residual Oil; Total: All Boiler Types Industrial Residual Oil Industrial CO Boiler (Residual Oil) Industrial Residual/Crude Oil Chemical Manufacturing Fuel Fired Equipment (Residual Oil) Chemical Manufacturing Fuel Fired Equipment (Residual Oil) Chemical Manufacturing Fuel Fired Equipment (Residual Oil) Food and Agriculture Fuel Fired Equipment (Residual Oil) Primary Metal Production Fuel Fired Equipment (Residual Oil) Primary Metal Production Fuel Fired Equipment (Residual Oil) Primary Metal Production Fuel Fired Equipment (Residual Oil) Secondary Metal Production Fuel Fired Equipment (Residual Oil) Secondary Metal Production Fuel Fired Equipment (Residual Oil) Secondary Metal Production Fuel Fired Equipment (Residual Oil) Secondary Metal Production Fuel Fired Equipment (Residual Oil) Mineral Products Asphalt Concrete (Residual Oil) Mineral Products Asphalt Processing (Blowing) (Residual Oil) Mineral Products Fuel Fired Equipment (Residual Oil) Mineral Products Fuel Fired Equipment (Residual Oil) Petroleum Industry Process Heaters (Residual Oil) Petroleum Industry Flares (Residual Oil) Petroleum Industry Incinerators (Residual Oil) Pulp and Paper and Wood Products Fuel Fired Equipment (Residual Oil) Pulp and Paper and Wood Products Fuel Fired Equipment (Residual Oil) Pulp and Paper and Wood Products Fuel Fired Equipment (Residual Oil) Rubber and Miscellaneous Plastics Fuel Fired Equipment (Residual Oil) 97 SCC SCC Level 1 30890012 Industrial Processes 30890022 Industrial Processes 30990002 30990012 31000402 31000412 31390002 390004xx 39990002 39990012 39990022 40201003 40290012 49090012 49090022 Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation 102006xx 10201401 10500106 202002xxa 30190003 30190013 30190023 30290003 30291001 30390003 30390013 30390023 30400407 30490003 30490013 30490023 30490033 30500206 30505020 External Combustion Boilers External Combustion Boilers External Combustion Boilers Internal Combustion Engines Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes SCC Level 2 SCC Level 3 (Fuel-if not specified at level 3) Products Rubber and Miscellaneous Plastics Fuel Fired Equipment (Residual Oil) Products Rubber and Miscellaneous Plastics Fuel Fired Equipment (Residual Oil) Products Fabricated Metal Products Fuel Fired Equipment (Residual Oil) Fabricated Metal Products Fuel Fired Equipment (Residual Oil) Oil and Gas Production Process Heaters (Residual Oil) Oil and Gas Production Process Heaters (Residual Oil) Electrical Equipment Process Heaters (Residual Oil) In-Process Fuel Use Residual Oil Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Residual Oil) Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Residual Oil) Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Residual Oil) Surface Coating Operations Coating Oven Heater (Residual Oil) Surface Coating Operations Fuel Fired Equipment (Residual Oil) Organic Solvent Evaporation Fuel Fired Equipment (Residual Oil) Organic Solvent Evaporation Fuel Fired Equipment (Residual Oil) 2102006000 – Industrial; Natural Gas; Total: Boilers and IC Engines Industrial Natural Gas Industrial CO Boiler (Natural Gas) Space Heaters Commercial/Institutional (Natural Gas) Industrial Natural Gas Chemical Manufacturing Fuel Fired Equipment (Natural Gas) Chemical Manufacturing Fuel Fired Equipment (Natural Gas) Chemical Manufacturing Fuel Fired Equipment (Natural Gas) Food and Agriculture Fuel Fired Equipment (Natural Gas) Food and Agriculture Fuel Fired Equipment (Natural Gas) Primary Metal Production Fuel Fired Equipment (Natural Gas) Primary Metal Production Fuel Fired Equipment (Natural Gas) Primary Metal Production Fuel Fired Equipment (Natural Gas) Secondary Metal Production Lead (Natural Gas) Secondary Metal Production Fuel Fired Equipment (Natural Gas) Secondary Metal Production Fuel Fired Equipment (Natural Gas) Secondary Metal Production Fuel Fired Equipment (Natural Gas) Secondary Metal Production Fuel Fired Equipment (Natural Gas) Mineral Products Asphalt Concrete (Natural Gas) Mineral Products Asphalt Processing (Blowing) (Natural Gas) 98 SCC SCC Level 1 30590003 30590013 30590023 30600105 30600903 30602401 30609903 30622003 30622403 30790003 30790013 30790023 Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes 30890003 Industrial Processes 30890013 Industrial Processes 30890023 Industrial Processes 30990003 30990013 30990023 31000404 31000414 31390003 390006xx 39900601 39990003 39990013 39990023 40201001 40290013 40290023 49090013 49090023 50390006 Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Petroleum and Solvent Evaporation Waste Disposal 102010xx 10500110 External Combustion Boilers External Combustion Boilers SCC Level 2 SCC Level 3 (Fuel-if not specified at level 3) Mineral Products Fuel Fired Equipment (Natural Gas) Mineral Products Fuel Fired Equipment (Natural Gas) Mineral Products Fuel Fired Equipment (Natural Gas) Petroleum Industry Process Heaters (Natural Gas) Petroleum Industry Flares (Natural Gas) Petroleum Industry Reciprocating Engine Compressors (Natural Gas) Petroleum Industry Incinerators (Natural Gas) Petroleum Industry Underground Storage and Other Remediation: Soil: Natural Gas Petroleum Industry Underground Storage and Other Remediation: Air Stripping: Natural Gas Pulp and Paper and Wood Products Fuel Fired Equipment (Natural Gas) Pulp and Paper and Wood Products Fuel Fired Equipment (Natural Gas) Pulp and Paper and Wood Products Fuel Fired Equipment (Natural Gas) Rubber and Miscellaneous Plastics Fuel Fired Equipment (Natural Gas) Products Rubber and Miscellaneous Plastics Fuel Fired Equipment (Natural Gas) Products Rubber and Miscellaneous Plastics Fuel Fired Equipment (Natural Gas) Products Fabricated Metal Products Fuel Fired Equipment (Natural Gas) Fabricated Metal Products Fuel Fired Equipment (Natural Gas) Fabricated Metal Products Fuel Fired Equipment (Natural Gas) Oil and Gas Production Process Heaters (Natural Gas) Oil and Gas Production Process Heaters (Natural Gas) Electrical Equipment Process Heaters (Natural Gas) In-process Fuel Use Natural Gas Miscellaneous Manufacturing Industries Process Heater/Furnace (Natural Gas) Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Natural Gas) Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Natural Gas) Miscellaneous Manufacturing Industries Miscellaneous Manufacturing Industries (Natural Gas) Surface Coating Operations Coating Oven Heater (Natural Gas) Surface Coating Operations Fuel Fired Equipment (Natural Gas) Surface Coating Operations Fuel Fired Equipment (Natural Gas) Organic Solvent Evaporation Fuel Fired Equipment (Natural Gas) Organic Solvent Evaporation Fuel Fired Equipment (Natural Gas) Solid Waste Disposal – Industrial Auxiliary Fuel/No Emissions (Natural Gas) 2102007000 – Industrial; LPG; Total: All Boiler Types Industrial Liquefied Petroleum Gas Space Heaters Industrial (LPG) 99 SCC 202010xx 27300320 30290005 30490035 30500209 30505023 30590005 30600107 30600905 30609905 SCC Level 1 SCC Level 2 SCC Level 3 (Fuel-if not specified at level 3) Industrial Liquefied Petroleum Gas Off-highway LPG-fueled Engines Industrial Equipment Food and Agriculture Fuel Fired Equipment (LPG) Secondary Metal Production Fuel Fired Equipment (Propane) Mineral Products Asphalt Concrete (LPG) Mineral Products Asphalt Processing (Blowing) (LPG) Mineral Products Fuel Fired Equipment (LPG) Petroleum Industry Process Heaters (LPG) Petroleum Industry Flares (LPG) Petroleum Industry Incinerators (LPG) Rubber and Miscellaneous Plastics 30890004 Industrial Processes Fuel Fired Equipment (LPG) Products 31000406 Industrial Processes Oil and Gas Production Process Heaters (Propane/Butane) 390010xx Industrial Processes In-process Fuel Use Liquefied Petroleum Gas 39901001 Industrial Processes Miscellaneous Manufacturing Industries Process Heater/Furnace (LPG) 40201004 Petroleum and Solvent Evaporation Surface Coating Operations Coating Oven Heater (LPG) 50390010 Waste Disposal Solid Waste Disposal - Industrial Auxiliary Fuel/No Emissions (LPG) 2102008000 – Industrial; Wood; Total: All Boiler Types 102009xx External Combustion Boilers Industrial Wood/Bark Waste 390009xx Industrial Processes In-process Fuel Use Wood 2102011000 – Industrial; Kerosene; Total: All Boiler Types 202009xx Internal Combustion Engines Industrial Kerosene/Naphtha (Jet Fuel) a Note that EIA’s SEDS includes natural gas used as pipeline fuel (e.g., for use in compressor engines) in the Transportation sector rather than the Industrial sector Therefore, such pipeline use should not be included in the point source subtraction procedure. d. Internal Combustion Engines Internal Combustion Engines Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Emission Factors The EPA has compiled criteria and hazardous air pollutant emission factors for non-point source industrial fuel combustion categories (Huntley, 2009). These emission factors, which are too numerous to list here, are included in a spreadsheet within the ICI fuel combustion workbook. In most cases, these are the same emission factors that were used in preparing the 2002 non-point source NEI (Pechan, 2006). Industrial LPG and wood combustion emission factors were obtained from an ICI fuel combustion study being performed for the Central Regional Air Planning Association (CENRAP) (Pechan, 2009a). 100 Potential Improvements The following are potential improvements that states may wish to incorporate in developing non-point source industrial fuel combustion emission estimates: Investigate the availability of more geographic and year-specific estimates of non-fuel use consumption of industrial energy (e.g., MECS is planning to release 2006 year data in the coming months); Consider implementing a county allocation procedure that Pechan developed for the Central Regional Air Planning Association (CENRAP) that reflects the energy-intensity of each industrial sector--current methods only reflect number of employees in each industry sector (Pechan, 2009a); and Update SO2 emission factors to reflect coal sulfur content estimates for coal used in the industrial sector in 2006--a recent review of industrial coal sulfur content values for CENRAP concluded that the 2002 NEI values are based on unrepresentative data (Pechan, 2009b). Additional References for Fuel Combustion - Industrial Census, 2009: Bureau of the Census, U.S. Department of Commerce, County Business Patterns 2006, Washington, DC, available from: http://www.census.gov/epcd/cbp/download/06_data/index.html accessed March 2009. 101 Divita, 2008: Divita, Frank, E.H. Pechan & Associates, Inc., memorandum to Roy Huntley, U.S. Environmental Protection Agency, “County Business Patterns Calculations,” December 4, 2008. EIA, 2008a: Energy Information Administration, U.S. Department of Energy, State Energy Data System – Consumption, Physical Units, 1960-2006, available from http://www.eia.doe.gov/emeu/states/_seds.html, released November 28, 2008. EIA, 2008b: Energy Information Administration, U.S. Department of Energy, Fuel Oil and Kerosene Sales, data available from http://tonto.eia.doe.gov/dnav/pet/pet_cons_821use_dcu_nus_a.htm, release date December 23, 2008. EIA, 2007a: Energy Information Administration, U.S. Department of Energy, 2002 Manufacturing Energy Consumption Survey, U.S. Department of Energy, Energy Information Administration, accessed from http://www.eia.doe.gov/emeu/mecs/mecs2002/data02/shelltables.html, issued January 2007. EIA, 2007b: Energy Information Administration, US Department of Energy, Documentation for Emissions of Greenhouse Gases in the United States 2005, DOE/EIA-0638 (2005), October 2007. 102 GASOLINE MARKETING (5 SCCs) (Stage I SCC 2501060053, Stage II Uncontrolled SCC 2501060101, Stage II Controlled SCC 2501060102, Underground Storage Tank Breathing and Emptying SCC 2501060201, Truck Transit SCC 2505030120) Gasoline marketing involves the operations typically associated with transporting gasoline from refineries to final consumption in gasoline-powered vehicles. Evaporative emissions of VOCs occur at all points in the distribution process. The operations that were inventoried as area sources are gasoline dispensing outlets and gasoline tank trucks in transit. Bulk terminals and outlets are inventoried as point sources. VOC emissions result from the following sources: 1) Stage I (tank truck unloading into underground storage tanks), 2) Stage II (vehicle fueling), 3) Underground Storage Tank Breathing and Emptying, and 4) Truck Transit. Each category’s emission factors were obtained from AP-42 Fire factors1. Throughputs were calculated from monthly data obtained from the Pennsylvania Department of Revenue Bureau of Motor Fuel Taxes2. County and state populations3 were used to apportion the gasoline throughput to each county. Control efficiency (CE)4,5 rule penetration (RP)4,5 and rule effectiveness (RE) factors were 1 U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Compilation of Air Pollutant Emission Factors, Volume I: Stationary Point and Area Sources, AP-42, Fifth Edition, Chapter 5: Petroleum Industry, Table 5.2-7., January 1995, Accessed October 2009. http://www.epa.gov/ttn/chief/ap42/ch05/index.html Pennsylvania Department of Revenue, “Monthly Revenue Report”, accessed October 2009. http://www.revenue.state.pa.us/revenue/cwp/view.asp?a=13&q=201148 2 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 3 25 Pa. Code Section 129.60, “Bulk Gasoline Plants,” available from http://www.pacode.com/secure/data/025/chapter129/s129.60.html 4 25 Pa. Code Section 129.61, “Small Gasoline Storage Tank Control (Stage I Control),” available from http://www.pacode.com/secure/data/025/chapter129/s129.61.html 5 103 applied to Stage I for each county to reflect the application of vapor balance systems. A RE factor was applied to Stage II to each regulated county. CE, RP, and RE factors were applied to Underground Storage Tank Breathing to reflect the application of pressure relief valves. There were no point sources for this source category. Each county’s emissions were estimated per the following sample calculations. SAMPLE VOC EMISSION CALCULATIONS: Stage I: County Pop Annual VOC Emissions Emission Factor State Annual Gasoline Sales State Pop where: Emission Factor = 7.3 lbs VOC/1000 gallons State Annual Gasoline Sales = 2,360,855,769 gallons/year County Population = 1,219,210 (Allegheny County) State Population = 12,432,792 Control Efficiency (CE) = 96% Rule Penetration (RP) = 96% Rule Effectiveness (RE) = 80% 7.3 lbs VOC 2,360,855,769 gallons 1,219,210 96 96 80 Annual VOC Emissions 1 year 12,432,792 100 100 100 1000 gallons 1 ton Annual VOC Emissions 444,012.605 pounds VOC per year 222.0063 tons VOC per year 2000 pounds 104 Stage II: Vehicle refueling VOC emissions were estimated using AP-42 factors, monthly gasoline sales estimates and county populations. These are the same gasoline sales figures that are used to estimate Stage I emissions. Stage II control program information was included for the counties with controls based on program information regarding control efficiency from Pennsylvania. The Pennsylvania counties with Stage II controls are Allegheny, Armstrong, Beaver, Bucks, Butler, Chester, Delaware, Fayette, Montgomery, Philadelphia, Washington, and Westmoreland. Population data were used to allocate monthly Pennsylvania gasoline sales to each county. Stage II Controlled: County Pop Allegheny VOC Emissions VOC Emission Factor State Gasoline Sales State Pop where: Emission Factor = 1.1 lb/1000 gallons State Gasoline Consumption =2,360,855,769 gallons 2007 Allegheny County Pop = 1,219,210 2007 State Population = 12,432,792 1.1 lbs VOC 2,360,855,769 gallons 1,219,210 pop 100 100 80 1 Annual VOC Emissions year 12,432,792 pop 100 100 100 1000 gallons 1 ton Annual VOC Emissions 50,933.3199 pounds VOC per year 25.4667 tons VOC per year 2000 pounds 105 Underground Storage Tank Breathing and Emptying: County pop Annual VOC Emissions Emission Factor State Annual Gasoline Sales State pop where: Emission Factor = 1.0 lbs VOC/1000 gallons 2007 State Gasoline Sales = 2,360,855,769 gallons/year County Population = 1,219,210 (Allegheny County) State Population = 12,432,792 Control Efficiency (CE) = 90% Rule Penetration (RP) = 96% Rule Effectiveness (RE) = 80% 1.0 lbs VOC 2,360,855,769 gallons 1,219,210 90 96 80 Annual VOC Emissions 1 1000 gallons year 12 , 432 , 792 100 100 100 1 ton Annual VOC Emissions 71,491.8599 pounds VOC per year 35.7459 tons VOC per year 2000 pounds 106 Truck Transit: County Pop Annual VOC Emissions Emission Factor State Annual Gasoline Sales State Pop where: Emission Factor = 0.06 lbs VOC/1000 gallons State Annual Gasoline Sales = 2,360,855,769 gallons/year County Pop = 1,219,210 (Allegheny County) State Pop = 12,432,792 (The emission factor is based on the assumption that gasoline delivery is via single trips and accounts for both full and empty truck travel.) 0.06 lbs VOC 2,360,855,769 gallons 1,219,210 pop Annual VOC Emissions day 12,432,792 pop 1000 gallons 1 ton Annual VOC Emissions 13,890.9054 pounds VOC per year 6.9454 tons VOC per year 2000 pounds 107 GRAPHIC ARTS (SCC 2425000000) The graphic arts industry can be divided by technology into six different printing segments: rotogravure, flexographic, offset lithographic, letterpress, screen, and plateless (xerographic,electrostatic, magnetic, thermal, ink-jet, etc.). Graphic arts include operations that are involved in the printing of publications, such as newspapers, magazines, books, and advertising, and also printed packaging on various substrates such as paper, plastic, foil bags, wrappers, cardboard cartons, and metal cans. Paper can be coated or uncoated. Films include polyethylene and a number of other polymers. Other products include wall and floor coverings, greeting cards, and paper towels. Textiles are specifically excluded from the graphic arts operations source category. Emissions of VOCs result from evaporation of solvents used in inks and cleaning. The emissions for each county were calculated using a per capita emission factor1 and U.S. Census Bureau population data2. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Population) where: Emission Factor = 4.4 lbs VOC/person/year3 Population = 1,219,210 (Allegheny County)2 1 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed October 2009. U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 2 108 HOUSEHOLD PRODUCTS (SCC 2460200000) Household products consist primarily of cleaning products for hard surfaces, clothing, carpet, dishes waxes and polishes. Other products include air fresheners and charcoal lighter fluids. These products have air emissions such as special napthas, alcohols, carbonyls and other organics that contain VOCs. The amount of VOCs emitted primarily depends on the VOC content of the product and the amount of product used. County-level emissions were calculated using a per capita emission factor which was obtained from the Emission Inventory Improvement Program (EIIP)1 and U.S. Bureau of the Census 2007 population data2. The emission factor represents pre-control emission rates. A CE of 10.94 percent3 and an RP of 48.6 percent4 were applied to reflect the Federal Rule for consumer products. There are no point sources associated with this category. Each county’s emissions are estimated per the sample calculations listed below. SAMPLE VOC EMISSION CALCULATIONS: Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 5, Consumer and Commercial Solvent Use,” Table 5.4-1, prepared for the Area Sources Committee, Emission Inventory Improvement Program, August 1996, available from http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed March 2009 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 2 3 4 ERTAC Recommendation, Midwest RPO Inventory Comparability Project, revised June 2, 2009, accessed June 2009. E.H. Pechan & Associates, Inc., Control Measure Development Support Analysis of Ozone Transport Commission Model Rules, prepared for the Ozone Transport Commission, March 2001. 109 CE RP RE Annual VOC Emissions Emission Factor Population 1 100 100 100 where: Emission Factor = 0.79 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County)1 Control Efficiency = 10.94% RP (Rule Penetration) = 48.6%4 RE (Rule Effectiveness) = 100% 0.79 lbsVOC person 10.94 48.6 100 Annual VOC Emissions 1,219,2101 year 100 100 100 1 ton 455.98 tons VOC per year Annual VOC Emissions 911,965.38 pounds per year 2000 lbs 110 INDUSTRIAL MAINTENANCE COATINGS (SCC 2401100000) The VOC emissions from this source category result from the evaporation of solvents from surface coating of objects and materials that may exist in extreme conditions. There were no point sources. The emissions for each county were calculated using a per capita emission factor1 and U.S. Census Bureau population data2. Each county’s emissions were estimated per the following sample calculations. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions Emission FactorPopulation where: Emission Factor = 0.15 lbs VOC/person/year1 Population = 1,219,210 people (Allegheny County)2 1 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed September 2009. U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 2 111 0.15 lbs VOC Annual VOC Emissions person year 1,219,210 people Annual VOC Emissions 182,881.5000 pounds VOC per year 1 ton 91.4408 tons VOC per year 2000 lbs MACHINERY AND EQUIPMENT (SCC 2401055000) The VOC emissions from this source category result from the evaporation of the solvent used in the coating process in manufacturing facilities of such as engines, turbines, farm and garden equipment, computers, and office machinery. The emissions for each county were calculated using an employment-based emission factor1 and employee data2 from NAICS Codes 3331XX, 3332XX, 3333XX and 33341XX obtained from County Business Pattern, with midpoints calculated by E.H. Pechan and Associates. Point source emissions, where present, were subtracted from the Machinery and Equipment category emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) 1 2 ERTAC Area Inventory Comparability Project, revised August 18, 2009, accessed September 2009. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 112 where: VOC Emission Factor = 109 lbs VOC /employee/year1 Employees = 1,119 employees (Allegheny County)2 109 lbs VOC employee Annual VOC Emissions year 1,119 employees 1 ton Annual VOC Emissions 121,971 pounds VOC per year 60.9855 tons VOC per year 2000 lbs 113 MARINE COATING (SCC 2401080000) This source category includes ship and boat building and repairing. The emissions were calculated using an employment-based emission factor1 and employee data from NAICS codes 3366XX and 488390. The number of employees in each county for 2006 was 1 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed October, 2009. 114 collected by E.H. Pechan and Associates, who calculated the midpoints from any given ranges1. Each county’s emissions were estimated per the following sample calculations below. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 198 lbs VOC /employee/year Employees = 5 employees (Allegheny County) 1 National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 115 198 lbsVOC Employee Annual VOC Emissions year 5 Employees 1 ton Annual VOC Emissions 990 pounds VOC per year 0.489 tons VOC per year 2000 lbs 116 METAL CANS (SCC 2401040000) This source category includes the manufacturing of metal cans, barrels, drums, kegs, and pails. The emissions from point sources, where present, were subtracted from the emissions of the corresponding county. The emissions for each county were calculated per the calculation below using an employment-based emission factor1 and employee data from NAICS Code 332431, obtained from County Business Patterns2. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATION: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 2,326 lbs VOC/employee/year1 Employees =10 employees (Allegheny County)2 1 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed September 2009. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 117 2,326 lbsVOC Employee Annual VOC Emissions 10 Employees year Annual VOC Emissions 23,260 pounds VOC per year 1 ton 11.63 tons VOC per year 2000 lbs 118 METAL FURNITURE (SCC 2401025000) This source category includes manufacturing metal household and office furniture, such as beds, cabinets, desks, bookcases, and chairs. The emissions for each county were calculated per the sample calculations below using an employment-based emission factor1 and employee data for NAICS codes 337124, 337214, and half of NAICS codes 337127, 339111 and 337215. The number of employees in each county for 2007 was obtained from County Business Patterns2 for year 2006 by E. H. Pechan and Associates, who performed calculations for midpoints and adjustment factors for any ranges that were obtained. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 772 lbs VOC /employee/year Employees = 102 employees (Allegheny County) 1 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed September 2009. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 119 METAL SHEETS, STRIPS, COILS (SCC 2401045000) This source category includes the manufacturing of metal sheets, strips and coils, of which functional coatings may be added for protective purposes. This can be accomplished by brushing, rolling, spraying, dipping, flow coating, electro-coating, or specialized combinations or variations of these methods. Emissions result from the evaporation of the paint solvent and any additional solvent used to thin the coating and from the use of solvents in cleaning the surface prior to coating and in cleaning coating equipment after use. Emissions for each county were calculated per the calculation below using an employment-based emission factor1 and employee data from NAICS Codes 339911, 339914, 332812 and 339912. The number of employees in each county for 2006 was obtained from County Business Patterns2 by E. H. Pechan and Associates, who also performed the calculations of midpoints and adjustment factors Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 8, Industrial Surface Coating,” Table 8.5-1, Principal Industrial Surface Coating SIC, September 1997, accessed September 2009. 1 2 National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 120 from any associated ranges obtained. The emissions from point sources, where present, were subtracted from the emissions of the corresponding county. SAMPLE VOC EMISSION CALCULATION: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 2,877 lbs VOC/employee/year1 Employees =514 employees (Allegheny County)2 2,877 lbsVOC Employee Annual VOC Emissions 514 Employees year Annual VOC Emissions 1,478,778 pounds VOC per year 1 ton 739.389 tons VOC per year 2000 lbs 121 MISCELLANEOUS MANUFACTURING (SCC 2401090000) This source category includes small industrial surface coating establishments primarily engaged in manufacturing products not classified in any other group such as jewelry, silverware, musical instruments, dolls, toys, games, pens, pencils, buttons, brooms, and caskets. Operations involve applying a thin layer of coating, such as paint, lacquer, enamel and varnish, to an object for decorative purposes. The surface coating products are either water-based or solvent based liquid carriers that mostly evaporate in the drying or curing process. The emissions for each county were calculated per the sample calculations below using a per capita emission factor 1 and U.S. Census Bureau population data2. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Population) where: Emission Factor = 0.6 lbs VOC/person/year Population =1,219,210 (Allegheny County) Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 8, Industrial Surface Coating,” Table 8.5-2, National Default Per Capita VOC Emission Factors, September 1997, accessed March 2009. 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 2 122 0.6 lbs VOC person Annual VOC Emissions 1,219,210 people year 1 ton Annual VOC Emissions 731,526 pounds VOC per year 365.763 tons VOC per year 2000 lbs 123 MISCELLANEOUS PRODUCTS (NOT OTHERWISE COVERED) (SCC 2460900000) Miscellaneous consumer products not covered in the other product groups include arts and crafts supplies, non-pesticidal veterinary and pet products, and pressurized food products. County-level emissions were calculated using a per capita emission factor which was obtained from the Emission Inventory Improvement Program (EIIP)1 and U.S. Bureau of the Census 2007 population data2. A CE of 0 percent3 and an RP of 48.6 percent4 were applied to reflect the Federal Rule for consumer products. There are no point sources associated with this category. Each county’s emissions are estimated per the sample calculations listed below. SAMPLE VOC EMISSION CALCULATIONS: CE RP RE Annual VOC Emissions Emission Factor Population 1 100 100 100 where: Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 5, Consumer and Commercial Solvent Use,” Table 5.4-1, prepared for the Area Sources Committee, Emission Inventory Improvement Program, August 1996, available from http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed March 2009. 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 2 3 4 ERTAC Recommendation, Midwest RPO Inventory Comparability Project, revised June 2, 2009, accessed June 2009. E.H. Pechan & Associates, Inc., Control Measure Development Support Analysis of Ozone Transport Commission Model Rules, prepared for the Ozone Transport Commission, March 2001. 124 Emission Factor = 0.07 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County)2 Control Efficiency = 0%3 RP (Rule Penetration) = 48.6%4 RE (Rule Effectiveness) = 100% 0.07 lbsVOC person 0 48.6 100 Annual VOC Emissions 1,219,2101 year 100 100 100 1 ton 42.67 tons VOC per year Annual VOC Emissions 85,344.7 pounds per year 2000 lbs 125 OPEN BURNING (3 CCs) (Residential Household Waste SCC 2610030000; Residential Yard Waste – Leaves, SCC 2610000100; Residential Yard Waste Brush SCC 2610000400) Open burning can be done in open drums or baskets, in fields and yards, and in large open dumps or pits. Materials commonly disposed of in this manner include household waste, landscape refuse, agricultural field refuse, wood refuse, and leaves. For emission inventory purposes, Open Burning is divided into four categories: Residential Household Waste; Residential Leaf; Residential Brush; Land Clearing. County-level emissions were calculated for Residential Household Waste using an emission factor which was obtained from the Emission Inventory Improvement Program (EIIP)1 and U.S. Bureau of the Census 20002 and 20073 population data. There are no point sources associated with this category. Throughput data was obtained from the percent Rural 2000 county population numbers applied to the 2007 county populations. The average household size4 was considered to be 2.5 residents and the average amount of waste produced per household4 was considered Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 16, Open Burning,” Table 16.4-1, Emission Factors for Open Burning of Municipal Refuse (EPA, 1997 & EPA,1995a) available at http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed December 2009. 1 2 U.S. Department of Commerce, Bureau of the Census, 2000 Census Data, http://factfinder.census.gov/servlet/DownloadCenterServlet U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009 3 Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 16, Open Burning,” Example 16.4-1, http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed December 2009. 4 126 to be 5.37 lbs/day or 1960.05 lbs/year or 0.9800 tpy. The loading factor4 was 6.7% to reflect the percent of rural households who actually burn their household trash. For counties with areas labeled as Air Basins it was assumed that no open burning of household waste was being accomplished and therefore no emissions were calculated. SAMPLE CALCULATIONS: Residential Household Waste Burning: VOC Emission Factor = 8.560 lbs/ ton waste/year NOx Emission Factor = 6 lbs/ ton waste/year CO Emission Factor = 85 lb/ ton waste/year SO2 Emission Factor = 1.0 lbs/ ton waste/year PM10 Emission Factor = 38.0 lbs/ton waste/year PM2.5 Emission Factor = 34.8 lbs/ ton waste/year CO Emission Factor = 85.0 lbs/ ton waste/year Loading Factor = 0.067 tons waste/2.5 person household Rural Households = 24,109 (Adams County – this is non-air basin county) CE (Control Efficiency) = 0% RP (Rule Penetration) = 100% RE (Rule Effectiveness) = 80% (reflects PA’s Solid Waste rules) 127 VOC Emissions for Adams County: 8.560 lbs VOC ton waste 0 100 80 Annual VOC Emissions 0.98tons 24,109households 0.067lf 1 year 100 100 100 1 ton Annual VOC Emissions 13,550.45 pounds VOC per year 6.775 tons VOC per year 2000 lbs Yard Wastes Yard waste burning is the open burning of materials such as grass clippings, leaves, and trimmings from trees and shrubs. Yard waste burning takes place where the waste is generated (i.e., residences, parks, institutions such as universities or hospitals, office complexes or other areas where grounds maintenance generates this type of waste) or waste disposal sites where wastes have been collected. Many municipalities, who provide leaf removal and composting, prohibit or restrict the burning of yard wastes. County-level emissions were calculated for the Open Burning categories of Residential Yard Waste - Leaves and Residential Yard Waste - Brush using emission factors obtained from AP-42 factors1, 1995. Throughput data was obtained by applying the percent Rural 2000 county population2 to the 2007 county populations3. The average amount of leaf waste produced per person1 was considered to be 0.64 lbs/day or 0.00728 tpy calculated for the months of September, 1 U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Compilation of Air Pollutant Emission Factors, Volume I: Stationary Point and Area Sources, AP-42, Fifth Edition, January 1995. 2 U.S. Department of Commerce, Bureau of the Census, 2000 Census Data, http://factfinder.census.gov/servlet/DownloadCenterServlet U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009 3 128 October and November. The loading factor2 of 28% was applied to reflect the percent of rural population who actually burn their yard leaf waste. For counties with areas labeled as Air Basins it was assumed that no open burning of household waste was being accomplished and therefore no emissions were calculated. Leaf Open Burning: where: VOC Emission Factor = 28 lbs/ton waste/year NOx Emission Factor = 6.2 lbs/ton waste/year CO Emission Factor = 112 lbs/ton waste/year SO2 Emission Factor = 0.76 lbs/ton waste/year PM2.5 Emission Factor = 22 lbs/ton waste/year PM10 Emission Factor = 22 lbs/ton waste/year Average amount Leaf Waste/person = 0.64 lbs/day or 58.24 lbs/person for (Sept. Oct. Nov.) Yard Waste Average Composition = 50% grass/ 25% brush/25% leaves Average Leaf Waste per person = 14.56 lbs or 0.00728 tpy Loading Factor = 0.28 tons waste/person Population = 94,437 people (Adams County – this is a non-air basin county) CE (Control Efficiency) = 0% RP (Rule Penetration) = 100% RE (Rule Effectiveness) = 80% Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 16, Open Burning,” 4.1.3 Yard Wastes, example (16.4-5) available at http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed December 2009. 1 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed December 2009. 129 Leaf Open Burning; Example PM10 Calculation for Adams County: 22 lbs PM 10 0 100 80 ton waste 0.00728 60,273 rural 0.281 Annual PM 10 Emissions year 100 100 100 person 1 ton Annual PM 10 Emissions 2702.9306 pounds PM 10 per year 1.3514 tons PM 10 per year 2000 lbs Additional References for Open Burning: E.H. Pechan & Associates, Inc., “Open Burning in Residential Areas, Emissions Inventory Development Report,” prepared for MidAtlantic/Northeast Visibility Union, January 31, 2004. Pennsylvania Code, Section 25, Chapter 129.14 , available at http://www.pacode.com/secure/data/025/chapter129/s129.14.html 130 OTHER SPECIAL PURPOSE COATINGS (SCC 2401200000) This category includes special purpose coatings used for applications such as maintenance operations at industrial and other facilities, auto refinishing, traffic paints, marine finishes, and aerosol sprays. Note that this category covers those specific coating processes not already included in other source categories (e.g., Industrial Maintenance Coatings). Emissions for this category were estimated using a per capita emission factor1 and U.S. Bureau of the Census population data2. Each county’s emissions were calculated per the following sample calculations. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions Emission FactorPopulation where: VOC Emission Factor = 0.007 lbs VOC/person/year1 Population 1,219,210 (Allegheny County)2 1 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed August 2009. U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 2 131 0.007 lbs VOC person Annual VOC Emissions 1,219,210 people year 1 ton Annual VOC Emissions 8,534.47 pounds VOC per year 4.2672 tons VOC per year 2000 lbs 132 PAPER, FOIL AND FILM (SCC 2401030000) This source category includes the manufacturing of paper, foil and film. The emissions from point sources, where present, were subtracted from the emissions of the corresponding county. Emissions for each county were calculated per the calculation below using an employment-based emission factor1 and employee data from NAICS Codes 322221, 322222, 322223, 322225 and 322226. The number of employees in each county for 2006 was obtained from County Business Patterns2 by E. H. Pechan and Associates, who also performed the calculations of midpoints and adjustment factors from any associated ranges. SAMPLE VOC EMISSION CALCULATION: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 735 lbs VOC/employee/year Employees =862 employees (York County) 1 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed September 2009. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 133 735 lbsVOC Employee Annual VOC Emissions 862 Employees year Annual VOC Emissions 633,570 pounds VOC per year 1 ton 316.785 tons VOC per year 2000 lbs 134 PERSONAL CARE PRODUCTS (SCC 2460100000) Personal care products include hair care products, deodorants and antiperspirants, perfumes, colognes, and nail care products. Ethanol and isopropanol are the primary solvents used in the formulation of these products. Each county’s emissions were calculated using a per capita emission factor1 which was obtained from the Emission Inventory Improvement Program (EIIP) and U.S. Bureau of the Census 2007 population data2. A control efficiency of 12.11%3 and a rule penetration of 48.6%4 are applied in the 2007 inventory to reflect the Federal Rule for consumer products. There are no point sources associated with this category. SAMPLE VOC EMISSION CALCULATIONS: CE RP RE Annual VOC Emissions Emission Factor Population 1 100 100 100 where: Emission Factor = 2.32 lbs VOC/person/year1 Population = 1,219,210 (Allegheny County)1 Eastern Research Group, “Emission Inventory Improvement Program, Document Series, Volume III, Area Sources, Chapter 5, Consumer and Commercial Solvent Use,” Table 5.4-1, prepared for the Area Sources Committee, Emission Inventory Improvement Program, August 1996, available from http://www.epa.gov/ttn/chief/eiip/techreport/volume03/index.html, accessed March 2009 1 U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 2 3 4 ERTAC Recommendation, Midwest RPO Inventory Comparability Project, revised June 2, 2009, accessed June 2009. E.H. Pechan & Associates, Inc., Control Measure Development Support Analysis of Ozone Transport Commission Model Rules, prepared for the Ozone Transport Commission, March 2001. 135 Control Efficiency = 12.11%3 RP (Rule Penetration) = 48.6%4 RE (Rule Effectiveness) = 100% 2.32 lbsVOC person 12.11 48.6 100 Annual VOC Emissions 1,219,2101 year 100 100 100 1 ton 1331.05 tons VOC per year Annual VOC Emissions 2,662,093.01 pounds per year 2000 lbs 136 PORTABLE FUEL CONTAINERS – GASOLINE DISTRIBUTION (10 SCCs) The following SCC (2501011011, 2501011012, 2501011013, 2501011014, 2501011015, 2501012011, 2501012012, 2501012013, 2501012014, 2501012015) category’s emissions were calculated by E.H. Pechan and Associates. The following documentation was prepared by E.H. Pechan and Associates: 1. GASOLINE DISTRIBUTION – PORTABLE FUEL CONTAINERS Portable fuel containers (PFCs, or gas cans) are consumer products used to refuel a wide variety of gasoline-powered equipment. The general approach to calculating emissions for this SCC is to take the inventories already prepared by the EPA for 2002 and 2010 and apply a linear fit between to get 2008 emissions. For this source category, the following SCCs were assigned: SCC Descriptor 1 2501011011 Storage and Transport 2501011012 Storage and Transport 2501011013 Storage and Transport 2501011014 Storage and Transport 2501011015 Storage and Transport 2501012011 Storage and Transport Descriptor 3 Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage Descriptor 6 Descriptor 8 Residential Portable Gas Cans Permeation Evaporation (includes Diurnal losses) Spillage During Transport Refilling at the Pump - Vapor Displacement Refilling at the Pump - Spillage Residential Portable Gas Cans Residential Portable Gas Cans Residential Portable Gas Cans Residential Portable Gas Cans Commercial Portable Gas Cans Permeation 137 2501012012 Storage and Transport 2501012013 Storage and Transport 2501012014 Storage and Transport 2501012015 Storage and Transport Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage Commercial Portable Gas Cans Commercial Portable Gas Cans Petroleum and Petroleum Product Storage Petroleum and Petroleum Product Storage Commercial Portable Gas Cans Commercial Portable Gas Cans Evaporation (includes Diurnal losses) Spillage During Transport Refilling at the Pump - Vapor Displacement Refilling at the Pump - Spillage Activity data for the 2002 and 2010 inventories were developed using EPA’s Non-road Model which uses a variety of variables like equipment size, equipment population, equipment age, RVP, and air temperature to estimate activity. There are at least 15 states which have enacted or are considering rules for PFCs. Due to the complexities in calculating emissions, these rules have already been accounted for in the emissions, but will not be listed in the control table. Section 2.2 of the EPA PFC report details emission factors used for each of the activities associated with PFCs. Emissions are calculated in the formula: EmisCounty, Pollutant = m x yeardiff + Emis2002 where: m = (Emis2010 – Emis2002) / (2010 – 2002) 138 Example: Using SCC 2501011011 in Allegheny County PA as an example: Emis2010 = 60.7 tons VOC Emis2002 = 181.7 tons VOC m = (60.7 – 181.7) / (2010 – 2002) = -15.125 EmisAlegheny, VOC = -15.125 x (2008-2002) + 181.7 = 90.95 tons VOC Reference: U.S. Environmental Protection Agency. Estimating Emissions Associated with Portable Fuel Containers (PFCs). Ann Arbor Michigan. February 2007. 139 PUBLIC OWNED TREATMENT WORKS (SCC: 2630020000) Public Owned Treatment Works (POTWs) are wastewater treatment plants typically owned by municipalities in Pennsylvania. Year 2007 POTW flow rate data for Pennsylvania facilities was extrapolated by E.H. Pechan and Associates from EPA national projections1 and allocated to county-level by population2. VOC Emission Factor based on a TriTAC study 3 per E.H. Pechan and Associates. SAMPLE VOC CALCULATIONS: 2007 County Wastewater Flow = (Nat. Wastewater Flow)(County Population/Nat. Population) where: 2007 National Wastewater Flow = 13,423,660 million gallons1 2007 County Population (Allegheny) = 1,219,2104 2007 National Population = 301,290,3325 1 Projected national POTW flow rates from EPA 2 National flow rate allocated to county-level by population, by E.H. Pechan and Associates. 3 VOC Emission Factor based on a TriTAC study. Prakasam Tata, Jay Witherspoon, Cecil Lue-Hing (eds.), VOC Emissions from Wastewater Treatment Plants: Characterization, Control, and Compliance, Lewis Publishers, 2003, p. 261. U.S. Department of Commerce, Bureau of the Census, “Population Estimates Program,” T1. Population Estimates [10] data Set: 2007 Population Estimates, available from http://www.census.gov/popest/counties/CO-EST2007-01.html, accessed March 2009. 4 5 2007 US population found at U.S. Census Bureau, http://factfinder.census.gov/servlet/GCTTable?_bm=y&-geo_id=01000US&_box_head_nbr=GCT-T1-R&-ds_name=PEP_2008_EST&-_lang=en&-format=US-40S&-_sse=on 140 2007( AlleghenyC o.)WastewaterFlow 1,219,210 / 301,290,332 13,423,660 E 6 gal 54,320.5632 E 6 gal SAMPLE VOC CALCULATIONS: Annual VOC Emissions Emission FactorCounty Wastewater Flow where: Emission Factor = 0.85 lbs VOC/millions of gallons flow3 Wastewater Flow = 54,320.5632 million gallons (Allegheny County)2 0.85 lbs VOC E 6 gals Annual VOC Emissions 54,320.5632 E 6 gallons 46,172.4787lbs ( AlleghenyC o.) year 1 ton 23.0862 tons VOC Annual VOC Emissions 46,172.4787 lbs 2000 lbs 141 RAILROAD SOLVENTS (SCC 2401085000) This source category includes Railcar building and repairing. The emissions were calculated using an employment-based emission factor1 and employee data from NAICS code 3365XX. The number of employees in each county for 2006 was collected by E.H. Pechan and Associates, who calculated the midpoints from any given ranges2. Each county’s emissions were estimated per the following sample calculations below. Point source emissions, where present, were subtracted from these emission estimates. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (Emission Factor)(Number of Employees) where: Emission Factor = 222 lbs VOC /employee/year Employees = 1722.89 employees (Allegheny County) 1 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed October 2009. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 142 222 lbsVOC Employee Annual VOC Emissions year 1,722.89 Employees 1 ton Annual VOC Emissions 382,481.58 pounds VOC per year 191.24079 tons VOC per year 2000 lbs 143 RESIDENTIAL COAL FOSSIL FUEL COMBUSTION (2 SCCs: SCC 2104001000, SCC 2104002000) Residential Coal Combustion is coal that is burned to heat residential housing. These documentation and fuel combustion emissions were calculated by E. H. Pechan and Associates. References are listed at the end of the Residential Coal Fossil Fuel Combustion section. The general approach to calculating emissions for these two SCCs is to take state coal consumption values from the EIA and allocate it to the county level using methods described below. County-level coal consumption is multiplied by the emission factors to calculate emissions. For this source category, the following SCCs were assigned: SCC Descriptor 1 2104001000 Stationary Source Fuel Combustion 2104002000 Stationary Source Fuel Combustion Descriptor 3 Residential Descriptor 6 Anthracite Coal Descriptor 8 All Boiler Types Residential Bituminous/ Subbituminous Coal All Boiler Types Activity Data The mass of coal consumed by residential combustion in the U.S. was used to estimate emissions. Coal consumption by energy use sector is presented in State Energy Data 2006 Consumption tables published by the Energy Information Administration (EIA). 1 Year 2006 consumption data were used as a surrogate for 2007 emissions because year 2006 data were the latest data available when this inventory was prepared. Fuel-Specific Activity Data Adjustments Coal - for residential coal combustion, the EIA data do not distinguish between anthracite and bituminous coal consumption estimates. (i.e., anthracite versus bituminous/sub-bituminous) Because anthracite is mined in the eastern half of the Commonwealth, while 144 bituminous is mined in the western half, the emission calculations assume that eastern counties burn anthracite coal while western counties burn bituminous coal. State-level coal consumption was allocated to each county using the US Census Bureau’s 2000 Census Detailed Housing Information.3 These data include the number of housing units using a specific type of fuel for residential heating. State coal consumption was allocated to each county using the ratio of the number of houses burning coal in each Anthracite or Bituminous coalburning county to the total number of Anthracite or Bituminous coal-burning housing units in the State. No controls were assumed for this category Emission Factors In some cases (see Table 2), SO2 and PM emission factors required information on the sulfur and/or ash content of the coal burned. State-specific sulfur and ash contents of anthracite and bituminous coal were obtained from data compiled in preparing the 1999 residential coal combustion emissions estimates.4 This study mostly relied on data obtained from USGS COALQUAL database. States not included in the database but that reported coal usage were assigned values based on their proximity to coal seams or using an average value for Pennsylvania (see report for details of the analysis). Table 3 presents the bituminous coal sulfur content values used for each state. For anthracite coal, an ash content value of 13.38% and a sulfur content of 0.89% were applied to Pennsylvania. The remaining criteria pollutant and HAP emissions were calculated by multiplying the total coal consumed in each county per year by an emission factor. All emission factors except ammonia are from AP-42.5 Table 4 presents a summary of the emission factors for residential anthracite coal combustion (SCC 2104001000). Table 5 presents a summary of the emission factors for residential bituminous coal combustion (SCC 2104002000). Sample Calculations Annual emissions are calculated for each county using emission factors and activity as: Ex,p = FCx × EFx,p 145 where: Ex,p = annual emissions for fuel type x and pollutant p (lbs/year), FCx = annual fuel consumption for fuel type x, EFx,p = emission factor for fuel type x and pollutant p. County level fuel consumption is calculated using: FCx = AState x RatioCounty houses where: AState = total tons of coal reported by the EIA, RatioCounty houses = county allocation ratio based on number of houses burning coal per Anthracite coal-burning counties or per Bituminous coal-burning counties. Example: Using Allegheny County, PA as an example: Allegheny County, PA, labeled a Bituminous coal-burning county, had 183 houses out of the state total of 19,921 Bituminous coalburning houses that use coal as the primary heating fuel. This equates to a share of 0.9186 % of the 9,687.54 tons of coal used for residential heating in the state. The emission factor for PM2.5-FIL Bituminous (See Table 2) is 3.8 lb/ton of coal burnt FCAllegheny, anth = 9,687.54 × 0.9186% = 88.9897 tons Bituminous coal EmisAllegheny, anth, PM2.5-FIL = 88.9897 tons Bituminous coal × 3.8 lbs PM2.5-FIL per ton coal = 338.1610 lbs PM2.5-FIL 146 Table 2. SO2 and PM Emission Factors for Industrial Anthracite and Bituminous Coal Combustion Emission Factor AP-42 Table (lb/ton) Anthracite Emission Factors (SCC 2104001000) PM-CON 0.08* % Ash 1.2-3 PM10-FIL 10 1.2-4 PM25-FIL 0.6 * % Ash 1.2-4 Pollutant Sulfur Dioxide 39 * % Sulfur 1.2-1 Bituminous Emission Factors (SCC 2104002000) PM-CON .04 1.1-5 PM10-FIL 6.2 1.1-9 PM25-FIL 3.8 1.1-9 Sulfur Dioxide 31 * % Sulfur 1.1-3 NOTE: PM10, PM2.5, and condensable PM emission factors for bituminous coal do not require ash content, nor does the condensable PM emission factor for anthracite coal. 147 Table 3. State-Specific Sulfur Content for Bituminous Coal (SCC 2104002000) State Alabama Alaska Arizona Arkansas California Colorado Connecticut Delaware District of Columbia Florida Georgia Hawaii Idaho Illinois Indiana Iowa Kansas Kentucky Louisiana Maine Maryland Massachusetts Michigan Minnesota Mississippi Missouri Percent Sulfur Content 2.08 0.31 0.47 1.20 0.47 0.61 2.42 1.67 1.67 1.28 1.28 1.00 0.31 3.48 2.49 4.64 5.83 1.93 0.86 2.42 1.67 2.42 1.20 0.97 1.24 3.39 Montana Nebraska Nevada New New Jersey Hampshire New Mexico New York North Carolina North Dakota Percent Sulfur Content 0.60 2.43 2.30 2.42 2.42 0.75 2.42 1.62 0.97 Ohio Oklahoma Oregon Pennsylvania Rhode Island South South Dakota Carolina Tennessee Texas Utah Vermont Virginia Washington West Virginia Wisconsin Wyoming 3.45 3.08 0.50 2.42 2.42 1.28 0.97 1.62 1.14 0.80 2.42 1.19 0.50 1.25 1.00 0.87 State 148 Table 4. National Criteria Emission Factors for Residential Coal Combustion (SCC 2104001000 and 2104002000) 7439921 CO NOX VOC NOX LEAD CARBON MONOXIDE NITROGEN OXIDES/Anthracite VOLATILE ORGANIC COMPOUNDS NITROGEN OXIDES/Bituminous 0.00042 275 3 10 9.1 LB LB LB LB LB TON TON TON TON TON References 1. U.S. Department of Energy, Energy Information Administration (EIA). State Energy Data 2006 Consumption. Washington, DC 2008. Internet Address: http://www.eia.doe.gov/emeu/states/sep_use/total/csv/use_all_phy.csv accessed November 2008. 2. EIA, 2008. U.S. Department of Energy, Energy Information Administration, “Domestic Distribution of U.S. Coal by Destination State, Consumer, Origin and Method of Transportation”, 2006. Available from: http://www.eia.doe.gov/cneaf/coal/page/coaldistrib/coal_distributions.html, accessed December 2008. 3. U.S. Census Bureau. "Table H40. House Heating Fuel Type", Census 2000: Summary File 3. Internet address: http://factfinder.census.gov/servlet/DatasetMainPageServlet?_program=DEC&_submenuId=&_lang=en&_ts=, accessed July 2009. 149 4. U.S. Environmental Protection Agency. Emission Factor and Inventory Group. Final Summary of the Development and Results of a Methodology for Calculating Area Source Emissions from Residential Fuel Combustion. Prepared by Pacific Environmental Services, Inc. Research Triangle Park, NC. September 2002. Internet address: http://www.epa.gov/ttn/chief/eiip/techreport/volume03/draft1999_ residfuel_inven_apr2003.zip accessed November 2004. 5. U.S. Environmental Protection Agency. Compilation of Air Pollutant Emission Factors, 5th Edition, AP-42, Volume I: Stationary Point and Area Sources. Research Triangle Park, North Carolina. 1996. 6. U.S. Environmental Protection Agency. Emission Factor and Inventory Group. Estimating Ammonia Emissions from Anthropogenic Sources, Draft Report. Prepared by E.H. Pechan and Associates, Inc. Research Triangle Park, NC. September 2003. 150 RESIDENTIAL FUEL OIL/KEROSENE COMBUSTION (2 SCCs: SCC 2104004000, SCC 2104011000) Distillate oil and kerosene combustion sources emit VOC, NOx, CO, SO2, Pb, and PM. Fuel oil and kerosene emissions were calculated for each county using fuel use estimates derived by allocating Commonwealth consumption estimates from the Energy Information Administration to individual counties. The county allocations were performed using data obtained from the American Community Survey and the U.S. Census Bureau. SAMPLE CALCULATIONS: Residential Distillate Fuel Oil/Kerosene: Residential fuel oil and kerosene usage was determined by allocating the residential fuel oil and kerosene use to each county. The residential fuel consumption was allocated by the ratio of dwelling units (DU) using distillate fuel oil/kerosene in a county to the number of dwelling units burning distillate fuel oil/kerosene in the Commonwealth. The following is the general equation for the calculation of usage for residential sources of fuel oil and kerosene combustion. County Distillate /Kerosene - Burning DU Annual Fuel Usage PA Residentia l Distillate FuelorKerosene Usage State Distillate /Kerosene - Burning DU where: PA Residential Fuel Oil = 706,956 thousand gallons1 2007 County Fuel Oi/Kerosene Burning DUs = 6916 Dwelling Units (Allegheny County)2 2007 State Fuel Oil/Kerosene-Burning DUs = 1,118,774 Dwelling Units1 1 Energy Information Administration, Pennsylvania Sales of Distillate Fuel Oil and Kerosene by End Use, http://tonto.eia.doe.gov/dnav/pet/pet_cons_821use_dcu_SPA_a.htm, accessed May 2009. U.S. Department of Commerce, Bureau of the Census, B25040, “House Heating Fuel, Occupied Housing Units, 2005-2007 American Community Survey 3-year Estimates, accessed May 2009. 2 151 VOC Emissions: where: Distillate Fuel Oil: VOC Emission Factor = 0.7 lbs/1000 gallons/year1 NOx Emission Factor = 18 lbs/1000 gallons/year1 CO Emission Factor = 5 lbs/1000 gallons/year1 SO2 Emission Factor = 142 lbs/1000 gallons/year 0.3% sulfur content = 0.426 lbs/1000 gallons/year1 PM10-FIL Emission Factor = 1.08 lbs/1000 gallons/year2 PM25-FIL Emission Factor = 0.83 lbs/1000 gallons/year2 PM-CON Emission Factor = 1.3 lbs/1000 gallons/year2 Lead Emission Factor = 0.001268 lbs/1000 gallons/year3 Distillate Fuel Sulfur Content = 0.3%4 1 VOC, NOx, CO and SO2 emission factors are from WEBFIRE (3//19/09). 2 PM emission factors are from US EPA Document - A National Methodology and Emission Inventory for Residential Fuel Combustion by Bernd H. Haneke presented at 2003 EPA EI conference. These emission factors are primarily from AP-42. U.S. Environmental Protection Agency, Emission Factors and Inventory Group. “Documentation for the 1999 Base Year Non-point Area Source National Emission Inventory for Hazardous Air Pollutants.” Prepared by Eastern Research Group, Inc. Morrisville, NC. September 2002. 3 4 AP-42 152 VOC Emissions for Distillate Oil: 0.7 lbs VOC 6916 Distillate FuelBurnin gDwelling Units 706,956 thousands of gallons 1000 gallons 1,118,774 Distillate FuelBurnin gDwelling Units 1ton Annual VOC Emissions 3059.1660 pounds VOC per year 1.5295 tons VOC per yearforAlleghenyCo. 2000 pounds Annual VOC Emissions Where: Kerosene: VOC Emission Factor = 0.672 lbs/1000 gallons/year1 NOx Emission Factor = 17.3 lbs/1000 gallons/year1 CO Emission Factor = 4.8 lbs/1000 gallons/year1 SO2 Emission Factor = 142 lbs/1000 gallons/year 0.3% sulfur content = 0.426 lbs/1000 gallons/year1 PM10-FIL Emission Factor = 1.03 lbs/1000 gallons/year1 PM25-FIL Emission Factor = 0.8 lbs/1000 gallons/year1 1 Emission factors for kerosene were obtained by multiplying the emission factors for distillate oil by a factor of 135/140 to convert them for this use. This factor is based on the ratio of the heat content of kerosene (135,000 Btu/gallon) to the heat content of distillate oil (140,000 Btu/gallon). Criteria pollutant emission factors are from AP-42. Distillate sulfur content (0.30%) was used for kerosene as well. 153 PM-CON Emission Factor = 1.25 lbs/1000 gallons/year1 Lead Emission Factor = 0.001268 lbs/1000 gallons/year1 Distillate Fuel Sulfur Content = 0.3%1 2007PA Residential Kerosene Usage = 39,702,000 gallons1 County Dwelling Units Heating with Distillate Oil or Kerosene = 6916 (Allegheny County)2 2007 State Fuel Oil/Kerosene-Burning DUs = 1,118,774 Dwelling Units1 CO Emissions for Kerosene: 4.8 lbs VOC 6916 Dwelling Units 39,702 thousands of gallons 1000 gallons 1,118,774 Dwelling Units 1ton Annual CO Emissions 1178.0568 pounds CO per year 0.5890 tons CO per yearforAlleghenyCo. 2000 pounds Annual CO Emissions Since the 2005-2007 American Community Survey did not include the six small populated counties in Pennsylvania (namely Cameron, Forest, Fulton, Montour, Potter and Sullivan counties) in their estimations of Occupied House Heating Fuel Units, these omissions were accounted for by taking the ratio of 2005-7 Averaged Total County Fuel Oil/Kerosene Heated Housing Units (not including the 6 Small Counties) to the 2007 Total State Housing Units (minus the 6 Small Counties' Housing Units) and by that percent find the 6 Small County Fuel Oil/Kerosene Heated Housing Units (HU). The following is the general equation for the calculation of the 6 Small County Fuel Oil/Kerosene Heated Housing Units. 1 Energy Information Administration, Pennsylvania Sales of Distillate Fuel Oil and Kerosene by End Use, http://tonto.eia.doe.gov/dnav/pet/pet_cons_821use_dcu_SPA_a.htm, accessed May 2009. 154 where: PA Total Housing Units (minus the 6 Small Counties) = 5,430,2341 Pa Total Fuel-Oil/Kerosene-Burning DUs (not including the 6 Small Counties) = 1,109,0462 County (Cameron) Total Housing Units= 4,5921 CountyFuelOil / KeroseneHe atingDwell ingUnits 1,109,046 FuelOil / KeroseneDUs 4,592 937.8489(CameronCounty) 5,430,234 HUs 1 U.S. Department of Commerce, Bureau of the Census, Housing Unit Estimates, Data Set 2007 Population Estimates, Note: For information on errors stemming from model error, sampling error, and non-sampling error, see: http://www.census.gov/popest/topics/methodology, accessed May 2009. U.S. Department of Commerce, Bureau of the Census, B25040, “House Heating Fuel, Occupied Housing Units, 2005-2007 American Community Survey 3-year Estimates, accessed May 2009. 2 155 RESIDENTIAL LIQUIFIED PETROLEUM GAS (LPG) (SCC 2104007000) Liquefied petroleum gas (LPG) is used in residential heating. Area source LPG was estimated using fuel consumption data and AP-42 emission factors. Consumption data were apportioned according to the number of dwelling units heating with LPG, which was available from U.S. Census Bureau data. LPG consumption was obtained from the Energy Information Administration’s State Energy Data 2001.1 Each county’s emissions were estimated using the sample calculations below. SAMPLE CALCULATIONS: Residential LPG for Allegheny Co.: Annual Emissions Emission Factor Residentia l LPG Consumption LPG Burning County Dwelling Units LPG Burning State Dwelling Units where: VOC Emission Factor = 0.52 lbs/1000 gallons/year2 NOx Emission Factor = 13.40 lbs/1000 gallons/year2 CO Emission Factor = 3.80 lbs/1000 gallons/year2 SO2 Emission Factor = 0.06 lbs/1000 gallons/year2 1 Energy Information Administration (eia), State Energy Data System (SEDS) 2007, released March 2009, accessed May 2009, found at 'http://www.eia.doe.gov/states/_seds_whats_new.html. 2 Based on AP-42 natural gas emission factors, converted to LPG using heat contents. ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed August, 2009. 156 PM10-FIL Emission Factor = 0.02 lbs/1000 gallons/year2 PM25-FIL Emission Factor = 0.01 lbs/1000 gallons/year2 PM-CON Emission Factor = 0.03 lbs/1000 gallons/year2 Residential LPG Consumption = 222,936,000 gallons1 County Dwelling Units Heating with LPG = 5318 units (Allegheny County)1 PA Dwelling Units Heating with LPG = 178,821 units ( plus prorated values for 6 smaller counties, see below for calculation)1 VOC Emissions: 0.52 lbs VOC 5318( Allegheny ) LPGBurning Dwelling Units 222,936 thousands of gallons 1000 gallons / year 178,821 LPGBurning Dwelling Units 1ton Annual VOC Emissions 3,447.5721 pounds VOC per year 1.72378 tons VOC per year 2000 pounds Annual VOC Emissions CO Emissions: 3.80 lbs VOC 5318 Alleghenyc ounty dwelling units 1000 gallons Annual CO Emissions 222,936 thousandgallons year 178,821 county dwelling units 1 ton Annual CO Emissions 25,193.7963 pounds CO per year 12.5969 tons CO per year 2000 lbs U.S. Department of Commerce, Bureau of the Census, B25040, “House Heating Fuel, Occupied Housing Units, 2005-2007 American Community Survey 3-year Estimates, accessed May 2009. 1 157 Since the 2005-2007 American Community Survey did not include the six small populated counties in Pennsylvania (namely Cameron, Forest, Fulton, Montour, Potter and Sullivan counties) in their estimations of Occupied House Heating Fuel Units, these omissions were accounted for by taking the ratio of 2005-7 Averaged Total County LPG Heated Housing Units (not including the 6 Small Counties) to the 2007 Total State Housing Units (minus the 6 Small Counties' Housing Units) and by that percent find the 6 Small County LPG Heated Housing Units (HU). The following is the general equation for the calculation of the 6 Small County LPG Heated Housing Units. where: PA Total Housing Units (minus the 6 Small Counties) = 5,430,2341 Pa Total LPG-Burning DUs (not including the 6 Small Counties) = 178,8212 County (Cameron) Total Housing Units= 4,5921 CountyLPGHeatingDwellingUnits 178,821LPGDUs 4,592 150(CameronCounty) 5,430,234 HUs 1 U.S. Department of Commerce, Bureau of the Census, Housing Unit Estimates, Data Set 2007 Population Estimates, Note: For information on errors stemming from model error, sampling error, and non-sampling error, see: http://www.census.gov/popest/topics/methodology, accessed May 2009. U.S. Department of Commerce, Bureau of the Census, B25040, “House Heating Fuel, Occupied Housing Units, 2005-2007 American Community Survey 3-year Estimates, accessed May 2009. 2 158 RESIDENTIAL NATURAL GAS (SCC 2104006000) Area source natural gas was estimated using fuel consumption data1 and AP-42 emission factors2 and adjusted PM emission factors3. Consumption data were apportioned according to the number of dwelling units heating with natural gas, which was available from U.S. Census Bureau data for residential sources). Each county’s emissions were estimated using the sample calculations below. SAMPLE CALCULATIONS: Natural Gas: Residential Natural Gas: Annual Emissions Emission Factor StatewideResidential NaturalGasConsumption Natural - Gas - Burning CountyDwelling Units Natural - Gas - Burning State Dwelling Units 1 Energy Information Administration, Pennsylvania Natural Gas Residential Consumption (MMCF), see:http://tonto.eia.doe.gov/dnav/pet/hist/n3010us2m.htm, accessed May 2009. 2 3 VOC (TOC*.95), NOx, CO and SO2 efs are from WEBFIRE (3//19/09). PM emission factors were adjusted lower than the 2002 NEI to account for lower estimates for condensable emissions. ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed August, 2009. 159 where: VOC Emission Factor = 5.5 lbs/MMCF (million cubic feet)/year2 NOx Emission Factor = 94 lbs/MMCF/year2 CO Emission Factor = 40 lbs/MMCF/year2 SO2 Emission Factor = 0.6 lbs/MMCF/year2 PM10-FIL Emission Factor = 0.2 lbs/MMCF/year3 PM25-FIL Emission Factor = 0.11 lbs/MMCF/year3 PM-CON Emission Factor =0.32 lbs/MMCF/year3 Pb Emission Factor = 0.0005 lbs/MMCF/year2 where: 2007 PA Residential Natural Gas Consumption = 231,258 MMCF1 County Dwelling Units Heating with Natural Gas = 455,921(Allegheny County)2 State Dwelling Units Heating with Natural Gas = 2,516,263 Units2 VOC Emissions: 1 Energy Information Administration, Pennsylvania Natural Gas Residential Consumption (MMCF), see:http://tonto.eia.doe.gov/dnav/pet/hist/n3010us2m.htm, accessed May 2009. U.S. Department of Commerce, Bureau of the Census, B25040, “House Heating Fuel, Occupied Housing Units, 2005-2007 American Community Survey 3-year Estimates, accessed May 2009. 2 160 5.5lbsVOC MMcf Annual VOC Emissions year 455,921 County NGdwelling units 231,258MMCF 2 , 516 , 263 State NGdwelling units 1 ton Annual VOC Emissions 230,458.6533 pounds VOC per year 115.2293 tons VOC per year 2000 lbs Since the 2005-2007 American Community Survey did not include the six small populated counties in Pennsylvania (namely Cameron, Forest, Fulton, Montour, Potter and Sullivan counties) in their estimations of Occupied Natural Gas Heating Dwelling Units, these omissions were accounted for by taking the ratio of 2005-7 Averaged Total County Natural Gas Heated Dwelling Units (not including the 6 Small Counties) to the 2007 Total State Housing Units (minus the 6 Small Counties' Housing Units) and by that percent find the 6 Small County Natural Gas Heated Housing Units (HU). The following is the general equation for the calculation of the 6 Small County Natural Gas Heated Dwelling Units. 161 where: PA Total Housing Units (minus the 6 Small Counties) = 5,430,2341 Pa Total NG-Burning Dwelling Units (not including the 6 Small Counties) = 2,494,3842 County (Cameron) Total Housing Units= 4,5921 CountyNGHeatedDwelli ngUnits 2,494,384 NGDwelling Units 4,592 2,109(CameronCounty) 5,430,234 DwellingUn its 1 U.S. Department of Commerce, Bureau of the Census, Housing Unit Estimates, Data Set 2007 Population Estimates, Note: For information on errors stemming from model error, sampling error, and non-sampling error, see: http://www.census.gov/popest/topics/methodology, accessed May 2009. U.S. Department of Commerce, Bureau of the Census, B25040, “House Heating Fuel, Occupied Housing Units, 2005-2007 American Community Survey 3-year Estimates, accessed May 2009. 2 162 TRAFFIC LINE PAINTING (SCC 2401008000) Traffic paints are used to mark pavement in applications such as dividing lines for traffic lanes, parking space markings, crosswalks, and arrows. The markings are usually applied by Commonwealth or local highway maintenance crews. VOC emissions result from the evaporation of organic solvents during and shortly after application of the marking paint. Each county’s emissions were calculated by using county-level lane miles totals1 and a lbs VOC/lane mile emission factor2. There are no point sources associated with this category. SAMPLE VOC EMISSION CALCULATION: Annual VOC Emissions Emission FactorLane Miles where: Emission Factor = 10.5 lbs VOC/lane mile Lane Miles =12,525.22 (Allegheny County) 1 Penn DOT Bureau of Planning and Research, http://www.dot.state.pa.us/Internet/Bureaus/pdPlanRes.nsf/PlanningAndResearchHomePage?OpenFrameset 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed October, 2009. 163 10.5 lbs VOC lanemile Annual VOC Emissions year 12,525.22lanemiles Annual VOC Emissions 131,514.81 pounds VOC per year 1 ton 65.7574 tons VOC per year 2000 lbs 164 WINERIES (SCC 2302070005) Winery emissions result from the entrainment of ethanol by carbon dioxide during wine fermentation. Factors affecting ethanol emissions are handling techniques, temperature, process equipment design, and fermenting parameters. Other sources of emissions from the wine making process are blending, transferring, racking and storing of the wine. Emissions were determined using 2007 county-level wine production data provided by the U.S. Department of the Treasury, Alcohol and Tobacco Tax and Trade Bureau.1 Because monthly production data were available, these data were used to develop the seasonal allocation factors for this category. The emission factors for both red and white wines were obtained from AP-42.2 Since the emission factors for the two types of wines are different, but wine type production data are not available, wine production in the Commonwealth was assumed to be 60 percent white wine and 40 percent red wine. Point source emissions, where present, were subtracted from these emission estimates. Each county’s emissions were estimated per the following sample calculations. SAMPLE VOC EMISSION CALCULATIONS: Annual VOC Emissions = (0.6 White Wine Emission Factor + 0.4 Red Wine Emission Factor) (2007 Total Wine Production) Alcohol and Tobacco Tax and Trade Bureau, Department of the Treasury, 2007 – Wine Statistical Information. http://www.ttb.gov/statistics/07winestats.shtml and http://www.ttb.gov/foia/frl.shtml, accessed March 2009. 1 2 From Table 9.12.2-1 of emission factor documentation for AP-42 Section 9.12.2 Wines and Brandy, October 1995, available from http://www.epa.gov/ttn/chief/ap42/ch09/final/c9s12-2.pdf, accessed March 2009. 165 where: White Wine Emission Factor = 1.8 lbs VOC/1000 gallons white wine/year2 Red Wine Emission Factor = 4.6 lbs VOC/1000 gallons red wine/year2 2007 Total Wine Production = 23.78 thousand gallons (Allegheny County)1 2007 Summer Wine Production = 3.000 thousand gallons (Allegheny County)1 White Wine Production Factor = 60% of wine produced Red Wine Production Factor = 40% of wine produced where: 1.8 lbs 4.6 lbs 23.78 thousand gallons Annual VOC Emissions 0.6 0.4 1000 gallons 1000 gallons 1 ton Annual VOC Emissions 69.4376 lbs VOC per year 0.03472 tons VOC per year 2000 lbs 166 WOOD FURNITURE AND FIXTURES (SCC 2401020000) This source category includes establishments engaged in the manufacture of wood home or office furniture. VOC emissions result from the evaporation of solvents used in the finish coats and cleanup procedures. Point source emissions, where present, were subtracted from these emission estimates. Each county’s emissions were calculated according to the sample calculations below using a per employee emission factor1 and the number of employees in NAICS codes 337110, 337121, 337122, 337219, 337211, 337212 and one half of NAICS codes 337127, 337215 and 339111. The number of employees in each county for 2006 was obtained from County Business Patterns2. SAMPLE VOC EMISSION CALCULATION: Annual VOC Emissions = (Emission Factor)(Employees) where: Emission Factor = 244 lbs VOC/employee/year Employees =387 employees (Allegheny County) 1 2 ERTAC Area Inventory Comparability Project, revised August 14, 2009, accessed September, 2009. National, State and County level employment data downloaded from US Census Bureau, mapping of employment flag letters reported by County Business Patterns to the range and midpoints of the range, and calculated final activity data using the employment midpoint and adjustment factor. 167 244 lbs VOC employee Annual VOC Emissions 387 employees year 1 ton Annual VOC Emissions 94,428 pounds VOC per year 47.214 tons VOC per year 2000 lbs 168 ACKNOWLEDGEMENTS The format and some of the wording of this document were originally created by E.H. Pechan & Associates, Inc., 3622 Lyckan Parkway, Suite 2002, Durham, NC 27707. Updated values were inserted in place of those originally entered to reflect changes between years 2002 and 2007. Some changes were made to correct or update comments in the document. THE END