2. Anthropic impact and natural disasters 2.1. Air 2.1.1. Pollution sources and ambient air quality The quality of the ambient air in the Republic of Moldova is influenced by internal and external pollution sources. The background concentrations of air pollutants are largely determined by transboundary fluxes (fig. 2.1). All over the world, industrial and energy sectors and transport are the main sources of air pollution and Moldova makes no exception. The pollution level is significantly higher in urban agglomerations and residential areas where the main industrial sites and power generation units are located and where there is intense traffic. In many of such areas, air pollution is a priority issue. The volume of emissions into the atmosphere from stationary pollution sources (including the largest national power generation station in Dnestrovsk, Transnistrian region, 2520 MW) amounted to 32,600 tons, including: particulates – 15.6%, carbon monoxide – 13.5%, NOx – 29.1%, sulphur dioxide – 39.4%. From these, the emissions of the Dnestrovsk PGS accounted for 16,992 tons or 52% of the total amount released from the stationary sources (fig. 2.2). Without taking into account the Transnistrian region (which is out of central government jurisdiction), the emissions from stationary sources increased from 14,500 tons in 2001 to 15,600 tons in 2002 (+ 8.1 %) (fig. 2.1, 2.2). In 2002, a slight increase of total air emissions was recorded comparing to the year 1999 (which was the minimum year in terms of polluting emissions), a fact attributed to some recovery of the energy sector. However, comparing to the year 1990, the total emissions decreased in 2002 by a factor of 6 (in 1990 – 1045 kt, in 1999 – 147 kt, in 2002 – 187 kt). 20 02 20 01 20 00 19 99 19 98 19 97 19 96 19 95 19 94 19 93 19 92 19 91 19 90 th. tons stationary mobile Fig. 2.1. Air emissions from stationary and mobile pollution sources The large power generation units are the main stationary sources of pollution at the national level. In small towns, the communal boiler-houses can be a significant local air pollution source. By switching those units from coal/fuel oil to natural gas, air emissions can diminish. In 2002, 56 boiler-houses have been transferred to natural gas, additionally to 531 such units existing in 2001. The power and heat generation units account for 84% of the emissions from stationary sources. However, the mobile sources dominate in the total air pollution structure. 250 th. tons 200 150 100 50 0 1990 1991 hydrocarbons 1992 1993 particulates 1994 1995 1996 nitrogen dioxide 1997 1998 1999 sulphur trioxide 2000 2001 2002 carbon monoxide Fig. 2.2. Major air pollutants from stationary sources During the last decade, the share of cars in the transportation of passengers and goods increased. In the same time, the number of private cars had a spectacular evolution since the early 1990s. Most of the imported cars, however, are second-hand cars, some of them in poor condition. Together with the limited capacity of the authorities to check the quality of exhaust gases and to control the technical condition of cars, and the poor service of transport units in many car companies, this has leaded to the deterioration of the air quality in urban areas with a negative impact on the health of the population. The share of electrical public transport is, unfortunately, continuously declining. The number of trolley-buses in the cities decreased from 605 units in 1990 to 393 in 2001. From the greenhouse gases, carbon dioxide emissions in 2001 decreased to 6343 Gg or 23.1% from the reference year 1990 (fig.2.4). 160000 140000 1996 120000 1997 100000 1998 80000 1999 2000 60000 2001 40000 2002 20000 yre ne be nz (a) p lea d tes r ti cu la pa lph ur dio xid e su rio xid e su lph ur t on s hy dro ca rb ca rb on mo no xid e 0 Fig. 2.3. Major air pollutants from mobile sources The quality of the atmospheric air in Moldova is monitored by the Hydrometeorological Service at 17 stationary stations located in 5 main cities/industrial centres and at the background monitoring station Hancesti. In 2002, the following parameters were monitored in the cities: sulphur dioxide, carbon monoxide, nitrogen dioxide, particulates, phenols, formic aldehide, sulphates. In 2002, the national annual average of the integrated air pollution index was 5.85, with seasonal variations between 3.26 in December and 11.23 in March. The air quality monitoring network in Chisinau consists of 6 stationary posts located within the city boundaries. During 2002, 13114 ambient air samples were taken and analysed at these monitoring stations. The average annual concentration of nitrogen dioxide exceeded the existing air quality standard (maximum admissible concentration, MAC) by a factor of 1.29, the formic aldehide, by 1.9. According to monthly averages, the highest pollution levels were recorded: for particulates, in January (1.3 MAC); for carbon monoxide, in January and February (0.8 MAC); for nitrogen dioxide, in October (2.7 MAC); for sulphur dioxide, in November (1.5 MAC). Comparing to the year 2001, the pollution with nitrogen dioxide (annual average values) increased while the particulates, carbon monoxide and formic aldehide, decreased. In the city of Balti, the average air pollution index in 2002 was 8.61, with monthly variations from 7.59, in August to 9.49, in September. The admissible average annual concentrations were exceeded for particulates (1.9 MAC); nitrogen dioxide (1.5 MAC); sulphur dioxide (1.1 MAC) and formic aldehide (2.6 MAC). As regards monthly average values, the highest exceedances were recorded for particulates (2.3 MAC), in May; for sulphur dioxide (1.3 MAC), in Year 1990, Total CO2 - 289233 Gg 5% 8% 25% natural gas fuel oil 23% diesel coal petrol others 27% 12% Year 1998, Total CO2 - 8900 Gg 9% 7% natural gas fuel oil 9% diesel coal 58% 9% petrol others 8% Year 2001, Total CO2 - 6543 Gg 10% 6% natural gas 11% fuel oil diesel coal petrol 60% 10% 3% Fig. 2.4. Dynamics of CO2 emissions from combustion of fossil fuels others September; for nitrogen dioxide (1.7 MAC), in September and for formic aldehide (3.1 MAC), in April. Comparing to the year 2001, pollution with nitrogen dioxide and formic aldehide (annual average values) increased while the level for particulates, carbon monoxide and sulphur dioxide decreased. In the city of Tiraspol, the average air pollution index was 4.25, showing an insignificant rise comparing to the last year. Along the year, the index varied between 3.03 in October and 6.19 in August. The admissible annual mean was exceeded only for formic aldehide (1.8 MAC). The highest level of pollution, according to monthly means, was recorded for particulates (1.45 MAC), in April, for nitrogen dioxide (1.1 MAC), in December, for phenols (1.6 MAC), in July, for formic aldehide (3.0 MAC), in September. Comparing to 2001, pollution with nitrogen dioxide, formic aldehide, phenols and carbon monoxide (annual average values) increased while the particulates, carbon monoxide and sulphur dioxide decreased. In the city of Ribnita, no significant changes in air quality were recorded in 2002, comparing to 2001. The air pollution index was 2.29, with variations between 1.76, in January, and 2.85, in May. The admissible annual mean was exceeded only for nitrogen dioxide (1.1 MAC). In terms of monthly average values, the highest level of pollution was registered for nitrogen dioxide (1.5 MAC), in May. Other ingredients did not exceed the admissible levels. Comparing to the previous year, air pollution with sulphur dioxide increased while the level of soluble sulphate, particulates and carbon monoxide, decreased. In the city of Bender, no significant changes in air quality were recorded in 2002, comparing to 2001. The air pollution index was 1.29, with variations between 0.91, in October, and 1.77, in June. The admissible annual average values were not exceeded. Average annual concentrartion, q/MAC At the national level, the average annual concentrations of formic aldehide increased, the sulphur dioxide and nitrogen dioxide decreased and the carbon monoxide and particulate level remained the same (fig.2.5). 3 2,5 2 1,5 1 0,5 0 Chisinau Balti Tiraspol Rabnita carbon monoxide suspended solids nitrogen dioxide formaldehide sulphur dioxide sulphate Fig. 2.5. Air pollution in urban areas in 2002. Bender fenol In spatial perspective, the air pollution indexes varied between 0.91 (Bender) and 11.23 (Chisinau). The highest average annual concentrations of pollutants were recorded as follows: for particulates (1.7 MAC), sulphur dioxide (1.2 MAC), nitrogen dioxide (1.5 MAC) and formaldehide (2.6 MAC) - in Balti; for carbon monoxide (0.5 MAC) - in Tiraspol; for phenols (0.8 MAC) in Chisinau and for soluble sulphate (0.07 MAC) in Ribnita. Singular high concentrations were recorded for: particulates (3.8 MAC), sulphur dioxide (0.9 MAC), carbon monoxide (2.0 MAC), nitrogen dioxide (8.9 MAC), phenols (9.6 MAC) – all in Tiraspol; soluble sulphate (0.1 MAC) in Ribnita and formic aldehide (1.7 MAC) in Bender. In terms of annual average concentrations, the situation in Balti seems to be the worst since the recorded concentrations exceed the quality standards in 4 monitored ingredients out of 5. In terms of singular („peak”) concentrations, in Chisinau si Tiraspol such values were recorded for 5 ingredients out of the monitored 6; in Balti – for 2 ingredients out of 5; in Bender and Ribnita – for 3 ingredients out of 5. During 2002, there were 7 cases of extreme air pollution, exceeding the existing quality standards by more than 5 times (tab. 2.1): 5 cases in Tiraspol and 2 cases in Chisinau. Table 2.1 Extreme air pollution cases recorded in 2002: concentrations (qm) exceeding 5 MAC Pollutant City Tiraspol Chisinau Month March July July April August November Nitrogen dioxide mg/m3 qm/MAC 0,76 8,9 0,48 5,6 0,64 7,2 0,6 7,1 0,43 5,1 mg/m3 0,096 0,077 - Phenols qm/MAC 9,6 7,7 - One of the major consequences of intensive air pollution are the acid rains. Systematic investigations carried out by the National Institute of Ecology at the Hancesti station in 19982002 revealed that hydrocarbonates dominated in the rain precipitation in that period (on average, 46.7% from the total amount of analised components). In previous years, the sulphates dominated in rain deposition (52.6% from total).