CHARACTERISTICS OF LAKE WATER, SEDIMENT AND ITS IMPACT ON GROUNDWATER Praveen Kumar S* and Santhaveerana Goud B** * Environmental Engineering, Department of Civil Engineering, Bangalore University, Bangalore – 56. ** Department of Civil Engineering, Bangalore University, Bangalore – 56. Allasandra and Bellandur lakes were considered for the present study. These lakes are located in the outskirts of Bangalore City and cover an area of 21.06 and 365 hectares respectively. The lake water, sediment and a groundwater sample near the lakes were collected and analysed for Cu, Pb, Cd, Ni, Mn, Zn and Cr using Atomic Absorption Spectrophotometer (AAS). Elevated concentrations of physico-chemical parameters were recorded in the lake and groundwater. The heavy metal concentration in Allasandra lake is well with in the limits and can be used for agricultural soils. The study revealed that the lakes were polluted because of untreated municipal waste water entering the lakes, there by polluting the surface water. Spatial distribution of BOD was analysed using GIS software. INTRODUCTION: Lakes in urban areas are available natural resources which provide several beneficial uses for urban population such as harvesting rainwater, recharging the ground water table, mitigation of floods, pisciculture, capacity to supply water in emergencies such as fire fighting and plenty of recreational opportunities such as boating, swimming, walking and jogging in the lake bund. . Lakes are often seen as main targets for development in urban areas due to pressure of human activities like urbanisation, industrialisation etc. As a result of these activities most of the urban lakes are getting degraded beyond the point of recovery. Encroachments, siltation, weed infestation, discharge of domestic sewage, industrial effluents, surface run off carrying pesticides and other chemicals used in agriculture are the main cause for degradation of these lakes. The overall impact of these activities has resulted in 1. Deterioration of lake water quality 2. Sedimentation and shrinkage 3. Increase in mosquito breeding causing health hazards 4. Increase in productivity to support flora and fauna 5. Loss of aesthetic values and decrease in tourism potential Description: Two lakes namely Allalasandra and Bellandur lakes were selected for the study. They are located between 77 35’ and 13 05’ and 77 40’ and 13 55’ respectively. The water spread area of the Allalasandra lake is 16.84 hectares and Bellandur lake is 365 hectares. The maximum depth at the deepest point is 1.5 m in Allalasandra and Bellandur lake is 5 m . The capacity of Allalasandra lake is 0.43 MCM (Million cubic meter) and Bellandur lake is 17.67 MCM. The total quantity of wastewater from the catchment area due to different activities such as domestic and commercial was about 10 MLD entering into the Allalasandra lake. The quantity of wastewater from the catchment area entering Bellandur lake is about 62 MLD i.e., from C valley 22 MLD, K valley 21 MLD, Agaram and Madivala 16 MLD and from earthen drain is 3 MLD and 162 MLD treated water from K and C valley secondary treatment plant is entering the lake. The total quantity of treated and untreated water entering the Bellandur lake is about 224 MLD. Objectives: 1. To study the characteristics of Allasandra and Bellandur lake water 2. To study the groundwater quality in the vicinity of the selected lakes. 3. To study the characteristics of sediment with respect to heavy metals of the selected lakes. 4. To study the spatial distribution of BOD by using MapInfo and Surfer software. Methodology Five sampling points were selected at appropriate places for sample collection of lake water in Allalasandra and Bellandur lakes. The location of the points is as shown in Figure 1 and 2 respectively for Allalasandra and Bellandure lakes . Several water quality parameters such as pH, electrical conductivity, temperature, turbidity, dissolved oxygen, total hardness, calcium hardness, magnesium hardness, potassium, BOD, iron, copper, lead, cadmium, nickel, manganese, total chromium and zinc were analysed for lake and ground water. Similarly lead, cadmium, nickel, total chromium and zinc parameters were selected for sediment analysis. Three sampling points for sediment analysis and two points for groundwater were taken for analysis. The samples were analysed as per the standards (standard methods for the examination of water and wastewater 1998). The lake water data collected was analysed by using Map Info and Surfer Software to know the spatial distribution of pollutants in the lake water. RESULTS AND ANALYSIS The quality of the surface water of Allalasandra lake is shown in Table 1 and that of Bellandur lake in Table 3. The concentration of heavy metals in the sediments of Allalasandra and Bellandur are shown in the Table 2 and 4. The groundwater quality in the vicinity of the selected lakes is shown in Tables 2 and 4 respectively. DISCUSSIONS. Allalasandra lake Concentration of some of the parameters like pH, electrical conductivity, turbidity, chlorides, total hardness, calcium, magnesium, total dissolved solids, sulphates, nitrates, and iron ranged between 7.4-7.6, 0.8-1.2, 0.6-30, 88-288, 257-244, 135-230, 60-198, 686-804,16-34, 0.4-0.8 and 0.24-1.3mg/l respectively. When compared to drinking water standards, the concentration exceeds the limits for most of the parameters. With respect to few parameters namely pH, sulphates, nitrates, Cu, Pb, Mn, Cr and Zn are with in the limits specified for drinking water. The sodium absorption ratio and percentage of sodium estimated for the Allalasandra lake water was found to be good (BIS 1991) for irrigation. The lake water can be used for irrigation as per FAO (1979) standards for heavy metals. The concentration of lead, cadmium, nickel, total chromium and zinc in the sediment of Allalasandra lake was found to be 6.8, 0.1, 2.0, 7.2 and 20.2 mg/Kg respectively. Comparing it with the permissible limits as per Csillag et. al., 1998 shows that the concentration are well within the limits. The groundwater quality adjacent to Allalasandra lake is as shown in Table 2. The concentration of some of the parameters such as pH, chlorides, total hardness, calcium, magnesium, total dissolved solids, sulphates, iron and manganese are exceeding the permissible limits of drinking water standards (IS: 10500 – 1991). The concentration of heavy metals such as copper, lead, cadmium, total chromium and zinc are within the permissible limit. The reason for the deterioration of groundwater quality may be due to the continuous percolation of polluted surface water. The spatial distribution of BOD in Allalasandra lake as shown in Figure 1, depicts that at the inlet points the BOD is high (164mg/l) and it goes on to decrease with increase in the distance towards the outlet point. Compared to outlet point i.e. 3 and middle point 2 and 5 (i.e. at the left bank) the BOD is less at 3. At point 5 (left bank) which is also located in the middle portion of the lake, the concentration of BOD is comparatively high, so the reason may be due to the inflow of wastewater just on the upstream side of point 5 on the left bank. The decrease in the BOD of the lake water during its retention in the lake may be due to the process of self purification and the results shows that the decrease in the BOD is very significant. BELLANDUR LAKE Concentration of some of the parameters like pH, turbidity, chlorides, total hardness, calcium, magnesium, total dissolved solids, sulphates, nitrates, and iron ranged between 7.0-8.0, 12-35, 48-140,170-290,148-240, 22-116, 542-812, 12-35,0.25-7 and 0.2–0.4mg/L. The concentration of pH, turbidity, calcium, magnesium, total dissolved solids, sulphates and iron are exceeding the drinking water limits (IS: 10500 – 1991). With respect to a few parameters namely chlorides, total hardness, nitrates are within the limits specified for drinking water. Concentrations of heavy metals like copper, lead, cadmium, manganese, total chromium and zinc are 0.013, BDL, BDL, 0.178, 0.0015 and 0.5 mg/l respectively. When compared with drinking water standards the concentration of manganese is exceeding the limits. The sodium absorption ratio value and percentage sodium estimated for the Bellandur lake water was found to be good (BIS 1991) for irrigation. The lake water can be used for irrigation as per FAO (1979) standards for heavy metal concentration. The concentration of lead, cadmium, nickel, total chromium and zinc in the sediment of Bellandur lake was found to be 23.03, 0.767, 65.5, 81.0 and 110 mg/kg. Comparing it with the permissible limits as per Csillag et. al., 1998 it shows that the concentrations are not within the limits. The ground water quality adjacent to Bellandur lake is as shown in Table 4. The concentration of some of the parameters such as chlorides, total hardness, calcium, magnesium, total dissolved solids, sulphates, nitrates, manganese are exceeding the permissible limits of drinking water standards (IS: 10500 – 1991). The spatial distribution of BOD in Bellandur lake as shown in Figure 2, depicts that at the inlet points the BOD is high (215 mg/l) and it goes on to decrease towards the outlet . The decrease in the BOD of the lake water during its stay in the lake may be due to the process of self-purification and the results shows that the decrease in the BOD is very significant. Conclusion Allalasandra lake The lake water quality is poor with respect to turbidity, chlorides, total hardness, calcium, magnesium, total dissolved solids, iron and manganese, which restricts its use for domestic purpose. The sediment quality with respect to heavy metals is with in the permissible limit to use it for agricultural applications. The groundwater quality is poor with respect to pH, chlorides, total hardness, calcium, magnesium, total dissolved solids, sulphates, iron and manganese to use it for drinking purpose. The phosphate concentration is greater than 100 µg, therefore the lake water can be categorised as eutrophic lakes. The dissolved oxygen is below 4 ppm, therefore no aquatic life was found. The decrease in BOD level from 164 to 6 mg/l with in the lake during its movement from inlet to outlet showed, 96.34% reduction, therefore the lake system has very good self purification potential. The lake water is good for agricultural use as per SAR (Sodium Absorption Ratio) for irrigation water quality classification. The lake water can be used for irrigation as it satisfies FAO (1979) standards for heavy metals namely Cd, Cr, Cu, Fe, Pb, Ni and Mn. Bellandur lake The lake water quality is poor with respect to pH, turbidity, calcium, magnesium, total dissolved solids, sulphates, iron and manganese, restricts its use for domestic purpose. The sediment quality with respect to heavy metals is not with in the limits and it cannot be used for agricultural applications. The ground water quality is poor with respect to chlorides, total hardness, calcium, magnesium, total dissolved solids, sulphates, nitrates, lead and manganese to use it for drinking purpose. The phosphate concentration is greater than 100 µg, therefore the lakes can be categorized as hypereutrophic lakes. The dissolved oxygen is below 4 ppm, therefore no aquatic life was found. The decrease in BOD level with in the lake during its movement from inlet to outlet is 91.16% (from 215 to 19 mg/l) , therefore the system is very significant in decreasing the BOD. The lake water is good for agricultural use as per SAR (Sodium Absorption Ratio) for irrigation water quality classification. The lake water can be used for irrigation as it satisfies FAO (1979) standards for heavy metals namely Cd, Cr, Cu, Fe, Pb, Ni and Mn. References (1) Proceedings of National Seminar on Resurrection of Lakes, 8th Jun-2002. (2) Ramachandra T. V. and Ahalya N, Limgis2001, Monograph on “Essentials in limnology and Geographic Information System (GIS)” (3) International workshop on Integrated Water Management, Bangalore University (June 2001). (4) Arnold E. Greenberg, APHA, Chairman (1998), 20th Edition, “Standard methods for the examination of water and waste water”. (5) IS 3025: Methods of Sampling and Test (Physical and Chemical) for Water and Wastewater. (6) UNEP/WHO/UNESCO/WMO Programme on Global Water quality monitoring and assessment gems/water operational guide, National Water Research Institute, Canada. (7) Erin Carison et. al., (2002) University of Northern Iowa, Department of Mathematics, A Statistical Examination of Water Quality in Two Iowa lakes; American Journal of Underground Water Research, Volume 1. Table1: Allasandra Lake water quality Parameters Sample Sample Sample Sample 1 2 3 4 Sample Rang 5 e P.L. (IS:10 500) PHYSICAL PARAMETERS PH 7.4 7.5 7.4 7.6 7.5 7.4- 6.5- 7.6 Electrical 0.9 1.2 1 0.8 0.95 conductivity Temperature 8.5 0.81.2 25 C 25 25.4 23.7 24.2 23.725.4 Turbidity 30 21.4 10.8 0.6 7.5 0.6- 10 30 CHEMICAL PARAMETERS Dissolved 1.0 1.0 2.6 1.7 1.02 oxygen Total alkalinity 112.6 280 266 251 238 258 230280 Chlorides 150 288 88 176 144 88- 250 288 Total hardness 257 315 333 311 344 257- 300 344 Calcium 197 230 135 210 204 135- 75 230 Magnesium 60 102 198 101 140 60198 Sodium 110 101 100 120 98 98- 30 120 Total dissolved 740 804 710 686 686- 738 solids 500 804 Sulphates 34 31 31 16 33 16-34 150 Nitrates 0.8 0.8 0.4 0.63 0.42 0.4- 45 0.8 Phosphates 0.6 0.5 0.3 0.4 0.3- 0.62 0.62 Potassium 42 45 34 42 34 34-45 BOD 164 38 06 06 44 6-164 Table2:Allalasandra Ground Water Quality Physical Sample 1 Sample 2 parameters P.L. (IS:10500) PH 6.6 6.2 Electrical 1.3 1.5 Total alkalinity 266 242 Chlorides 419 323 250 Total hardness 379 214 300 6.5-8.5 conductivity CHEMICAL PARAMETERS Calcium 347 168 75 Magnesium 32 46 30 Sodium 130 164 1080 1140 500 Sulphates 82 168 150 Nitrates 2.2 7.36 45 Phosphates 0.01 0.02 Potassium 10 16 Total dissolved solids Table3:Heavy metal concentration in lake water, sediment and groundwater. Heavy Lake Ground P.L. metals water water (IS:10500) Sedimen Standards t of lake bed for agricultural soils Copper 0.013 0.018 0.05 37.4 Lead 0.001 0.03 0.1 6.8 8.33 Cadmium 0.005 0.001 0.05 0.1 0.125 Nickel 0.08 0.075 - 20 1.67 Manganese 0.178 0.82 0.1 54 Total 0.0015 0.024 0.05 7.2 8.33 0.001 0.04 5.0 20.2 25 chromium Zinc Table4:Bellandur lake water quality Parameters S1 S2 S3 S4 S5 Range P.L. (IS:105 00) PHYSICAL PARAMETERS PH 7.5 7.0 8.0 7.6 7.0 7.0-8.0 Electrical 1.2 1.1 0.946 1.1 1.0 1-0.946 24.2 30 29.2 31 290 24.2-31 35 31 12 30 31 12-35 Dissolved oxygen 0.3 1.4 3.0 6 0.5 0.3-6 Total alkalinity 584 284 330 530 560 284- 6.5-8.5 conductivity Temperature Turbidity 10.0 CHEMICAL ARAMETERS 560 Chlorides 140 124 115 48 130 48-140 250 Total hardness 286 254 170 290 280 290- 300 170 Calcium 170 209 148 240 230 148- 75 240 Magnesium 116 45 22 50 50 22-116 Sodium 90 100 70 98 110 70-110 Totaldissolved 812 750 542 780 640 542- solids Sulphates 30 500 812 16 18 20 12 35 12-35 150 Nitrates 0.36 0.4 0.25 0.8 7 0.25-7 45 Phosphates 0.85 0.3 0.4 0.6 0.95 0.30.95 Potassium 42 34 38 35 30 30-42 BOD 215 19 10 20 50 19-215 Table5:Bellandur Ground water quality Physical parameters Sample 1 Sample P.L. 2 (IS:10500) 6.5-8.5 PH 6.3 6.2 Electrical 2.6 2.2 conductivity CHEMICAL PARAMETERS Total alkalinity 144 192 Chlorides 907 640 250 Total hardness 339 610 300 Calcium 286 590 75 Magnesium 53 20 30 Sodium 86 220 3254 2080 500 Sulphates 176 110 150 Nitrates 27.2 65.4 45 Phosphates 0.06 0.04 Potassium 18 22 Total dissolved solids Table6:Heavy metal concentration in lake water, sediment and groundwater. Heavy Lake Ground P.L. Sediment metals water water (IS:10500) of lake bed Standard Copper 0.013 0.018 0.05 64.96 Lead BDL 3.7 0.1 23.03 8.33 Cadmium BDL 0 0.05 0.767 0.125 Nickel 0.08 0.075 65.5 1.67 Manganese 0.178 0.82 0.1 211.3 Total 0.0015 0.024 0.05 81.0 8.33 0.5 0.52 5.0 110 25 chromium Zinc