LECTURE NOTES: ENVIRONMENTAL BIOLOGY (ENVS 105) SNYDER, L. Ozone Depletion, Global Warming, Water Pollution Ozone (O3) Depletion Protects us from Ultraviolet (UV) light exposure from sun O3 formed in stratosphere o Oxygen (O2) formed in troposphere rises up in the atmosphere to the stratosphere where UV light breaks down O2 o O2 Reforms as O3 Ozone destruction by CFC’s & Other Chemicals (halocarbons, methyl bromide, carbon tetrachloride, etc.) 1. Ozone depleting chemicals (ODC’s) spewed into atmosphere from industry (factories), homes, farms, etc. 2. ODC’s rise up into atmosphere where they are broken down by sunlight EX: CFCL3 → CFCl2 + Cl (Chlorine (Cl) atoms are freed) 3. These breakdown products bond with ozone & destroy ozone. EX: CFC’s Cl atom breaks up ozone (Cl + O3→Cl+ O + O2) 4. Chlorine (or bromine, etc.) atom not used up in reaction: One Chlorine atom can break up 100,000 O3 molecules As CFC’s & other Ozone Depleting Chemicals increase in the atmosphere, ozone in the stratosphere decreases But, ozone depletion has leveled off in last ~ decade. Why? Ozone Hole (Thinning Ozone Layer) Greatest at South Pole (Antarctica) From Aug–Dec (Southern spring-summer) In warm months, Solar radiation increases & breaks up CFC’s Results in decreased Phytoplankton productivity (photosynthesis) from Aug-Dec UV Radiation hitting Earth Increases as Ozone Decreases Results in increased skin cancer rates Malignant Melanoma (what to look for in moles, freckles, lesions, etc.) o A (Asymmetry) o B (Border) o C (color)& Growth In the past thirty years, skin cancer has tripled in women under age 40. Melanoma is the second most common cancer in women aged 25-29. Melanoma, the deadliest form of skin cancer, is rising faster than that of any other cancer. There are now nearly 8,000 melanoma deaths every year. While melanoma is uncommon in African-Americans, Latinos, and Asians, it is most deadly for these populations. More than 90 percent of all skin cancers are caused by sun exposure, yet fewer than 33% of adults, adolescents, & children routinely use sun protection. A person's risk for skin cancer doubles if he or she has had five or more sunburns. Effects of Ozone Depletion Increased exposure to UV rays: Cataracts (wear UV protective sunglasses) Skin cancers: 1% decrease in O3 causes 5-8% increase in skin cancer Australia (close to Antarctic ozone hole): 4% decrease O3 has resulted in a 20% increase in cancer o Sunscreen, hat, protective clothing, etc., avoid sun (10 – 4 pm) Increase in DNA mutations results in other types of cancers Photosynthesis decreases (phytoplankton, algae, & plants decrease in productivity) Stratospheric Ozone Replenishment 1987 Montreal Protocol: Global phaseout of CFCs by 2000 (53 nations) o US ban 1993 o Developing nations (2010) Methyl Bromide (pesticide) phaseout by 2005! o Many nations (U.S.A included) ask for exemptions CFC’s take 50-100 yrs. to leave atmosphere o 2100 to reach “safe” O3 levels Global Warming: Earth’s climate fluctuates slowly (geologic time) Warming since last ice age (18,000 yr ago) Since industrial revolution rate of increase has accelerated Result of enhanced greenhouse effect Trapping of heat by atmospheric gases Necessary for life on Earth Without it, Earth’s Avg. temp ~ 0°F (-18°C) Greenhouse Gases: Carbon dioxide & Nitrogen oxides (fossil fuel burning, wood burning), methane (cows, landfills), CFC’s (coolants, propellants) Absorb & trap escaping heat Industrial Revolution: Unnatural levels of CO2 added to atmosphere by burning fossil fuels CO2 = #1 greenhouse gas We generate CO2 faster than Ocean & plants can absorb it Global Temp. has increased 5°C (9°F) since last ice age Greenhouse gases responsible for ~ 50% of increase 10 warmest yrs on record all occurred since 1990 1998 hottest yr. Some Effects of Global Warming Increased Air pollution (increased ozone in troposphere) o Ozone created in troposphere is unnatural (created by burning fossil fuels) o More ozone is created during warm weather periods Species migration (shift) toward poles (Extinction of species that can’t migrate) Increases storms, more intense storms (some areas, coasts, etc.) Increased drought (some areas) Increased incidence of pest-borne diseases (malaria) Loss of coastal land due to rising sea level Global Warming Impacts Sea level rising (melting ice sheets & caps, glaciers, etc.) Loss of low-lying coastal land o Many shallow islands would be submerged (Ex: Maldives) Alter strength of ocean currents (Gulf stream = ice age in N. Atlantic) Increased Tropical storms (greater number & intensity) Warmer ocean: o Decrease in phytoplankton o Extinction of species with limited temperature ranges (coral, polar bears) Thermohaline Circulation (Global Ocean Conveyer Belt): Some Cold water warms near Equator Deep, cold, salty water moves under Warm Surface Currents Global Conveyer Belt: Movement of Deep, Cold, Salty Water From Atlantic To Pacific Dense, sinking water causes convection that helps drive Deep Circulation Excess Freshwater entering N. Atlantic may stop Thermohaline circulation (Melting ice & River inflow from ice sheets, glaciers, etc.) Halt movement of Gulf Stream in Atlantic Ocean Global Warming could cause N. Europe & America to Cool Significantly! The Role of Industrialized Nations Industrialized nations currently use 60% of world's fossil fuels (USA 25%) U.S.A. (5% of world's population), 30% of world's global warming pollution (#1) U.S. imports more than we export ($55 million trade deficit) What if everyone used resources & polluted as much as us? Kyoto Protocol – world agreement to reduce greenhouse gases (U.S has not signed) Effect of World Population on Global Warming & Pollution As World Population Grows, Resource use & Pollution increase & global warming increases On 14 May 2006: 6.52 Billion People on Earth In 1850 (beginning of industrial Revolution) there were 1 billion people What Can Be Done? Global temp. estimated to increase 10.5 °F in next century as energy demands increase We all share Earth’s resources & we ALL contribute to its degradation Individual action Recycle, Buy recycled & EnergyStar products Conserve resources Plant trees & gardens Reduce Chemical use Use Mass transit, carpool Stop cutting down forests (rainforest) Fuel alternatives, fuel-efficient autos, hybrid vehicles Proper tire inflation Don’t idle car Educate others Choose seafood wisely Clean up after yourself! “Never doubt that a small group of thoughtful, committed citizens can change the world. Indeed, it's the only thing that ever has.” – Margaret Mead Water Pollution Point source: Clear origin or source o Sewage outfall, oil tanker spills, industrial plant, utilities Non-point-source: Many diffuse sources o Urban runoff, boats (harbors & marinas), invasive species, agriculture, trash & debris, construction, air pollution Solid Waste Pollution in Ocean Most discarded on land & carried to ocean via storm drains, rivers as urban runoff 10% plastic Biodegrades SLOWLY (6-pk holder =400 yr) Americans produce 1,100 lbs plastic waste/person/yr. Cigarettes: thrown in streets, out of cars, etc. makeup HUGE percentage of beach/coastal pollution (filters don’t biodegrade) Plastic in Marine Environment: Floats Ingested by and entangles marine animals 100,000 marine mammals die each yr. 2 million seabirds Sea Turtles: mistake plastic bags for their sea jelly (jellyfish) prey Fishing line, cups, bags, straws…. Sewage Treatment & Outfalls Primary Tr. - large solids, grease removed Secondary Tr. – Good bacteria eats organic solids, chlorine kills bacteria, chlorine removed (via chemicals) 22% of biosolids used by farmers or compost centers Many chemical toxins, heavy metals, pharmaceuticals not removed & enter ocean Oceanic Oil Spills Oil released in sea will eventually float to & rest in intertidal Most oil in marine environment enters via urban runoff, dumping Effects of spilled oil depends on type: Light refined petroleum (diesel & gas) – mixes in H2O column, more toxic, but evaporates quickly & doesn’t persist in environment Crude – less toxic, but remains on water surface or shoreline much longer, sinks Oil Tanker Spills Small portion of total marine spills Locally devastating, major cleanup U.S. Oil Pollution Act 1990 (response to Exxon Valdez): all oil-carrying vessels must have double-hull Exxon still appealing $5 billion fine (17 yrs) Oil Spills & Marine Life Clogs gills of fish & benthic species Damages digestivesystem Mammals & birds (fur, feathers) lose bouyancy & insulation Oil Spill Cleanup Scrubbing w/ high pressure, hot water increases damage Leave it alone, rely on natural processes Shovels, buckets, absorbent materials, booms Bioremediation by oil digesting bacteria