Flashpoint #2 A Marine Chemist Association Newsletter “Sewage Hazards” FOR INFORMATIONAL PURPOSES ONLY. DOES NOT SUPERSEDE ANY FEDERAL, STATE, LOCAL REGULATIONS OR EXISTING COMPANY PROCEDURES. Summary Sewage poses unique exposure hazards to shipyard employees Atmospheric hazards such as hydrogen sulfide, oxygen deficiency, and flammable gases are compounded by the potential biological hazards present in all sewage tanks and sewage piping systems. The OSHA Maritime Standard, 29 CFR 1915 Subpart B, “Confined and Enclosed and Other Dangerous Atmospheres, does not specifically address biological hazards associated with sewage. It does however cover the atmospheric hazards (oxygen, flammability and toxicity) but a case can be made that Marine Chemists and Employers are expected to consider the biological hazards as potential toxic exposures. Marine Chemists and Employers are faced with a dilemma because there are no real time measurement devices nor are there exposure limits for the biological hazards present in sewage, however, there are recognized hazards such as hepatitis, typhoid fever, dysentery and cholera Efforts should be taken to reduce the biological hazards associated with sewage. Marine Chemists will typically use the “Enter with Restrictions” standard safety designation based on their visual inspection and will proscribe PPE and other controls because they recognize the potential for a biological hazard to exist but have no real time monitoring equipment or exposure concentration guidelines to evaluate the hazard. A biological hazard is assumed to be present and precautions are stipulated based on the Marine Chemist’s professional judgment. Sewage Hazards in the Maritime Industry There are several issues the Marine Chemist faces when dealing with entry into sewage tanks and/or work on sewage piping systems. Marine Chemists agree that some precautions should be taken to reduce the potential biological hazards associated with sewage and other wastes but accurately and consistently proscribing those precautions is difficult for the following reasons: Issue #1 Using the standard safety designation “Enter with Restrictions” has historically meant that the chemist: Has determined atmospheric concentrations for a contaminant in a space Compared them to either regulatory (OSHA) or recommended (ACGIH) exposure limits, and Prescribed specific engineering or administrative controls or PPE. There are no real time tests or exposure limits for biological hazards. Without this information it is difficult for a chemist to specify PPE or administrative controls. Issue #2 Using an indicator (marker) such as coliform to make an assessment for other biological hazards is not feasible There is no real time coliform test nor is there exposure criteria for coliform Coliform tests require contact with the surface of a space. This impacts the validity and accuracy of the test as one cannot presume that the contamination is consistent throughout, nor that the sample is representative of the space. Coliform testing does not provide a valid representation of other biological hazards. No single test can be used as a marker. Issue #3 Various methods of disinfection (chlorine, NaOH, steam, UV, ozone) all pose the same problem. Absent a test to determine safe concentrations of a contaminant, it is difficult for a Marine Chemist to scientifically evaluate the effectiveness of the cleaning method. At best these methods are of disinfection are effective of surface contamination only and contamination below the surface may not be adequately treated. Disinfection should be viewed as a method to reduce, not eliminate, biological hazards. Issue #4 The atmospheric requirements for “Atmosphere Safe For Workers” in NFPA 306 may be met during initial opening of a tank or pipeline or shortly after ventilation Sewage Hazards in the Maritime Industry has been applied. However, once the residues are disrupted atmospheric hazards such as hydrogen sulfide and methane are easily re-created. Most chemists would insist that cleaning be performed to reduce this potential. It is also apparent to chemists that the “Enter with Restrictions” designation more appropriately protects employees who are cleaning dirty sewage tanks. However, when the cleaning is complete the chemist is left with the decision of how to remove the restrictions absent some quantitative measurement to evaluate the effectiveness of the cleaning operation. Many chemists choose to use “Enter with Restrictions” even after the cleaning is complete. The PPE requirements placed on the certificate are due to the absence of exposure data, the inability to evaluate the hazard and the results of the chemist’s visual inspection. It really comes down to whether the chemist feels a biological hazard exists – in other words professional judgment. A logical approach to this problem is to take steps to reduce the potential contamination and to use the “Enter with Restriction” or “Atmosphere Safe for Workers” designations but to specify common sense protective measures on the certificate. These measures may include protective clothing, gloves, boots or a simple note stating that good personal hygiene (washing up) should be used upon leaving the contaminated space. Sewage Hazards in the Maritime Industry A Logical Approach to Certification of Sewage Tanks and/or Sewage Systems Flush, Disinfect and Clean Initial Flush of the Piping System and/or the Tank with Water System - this can be accomplished by flushing urinals and toilets several times Tanks – fill with water and drain as appropriate Disinfection - will help reduce the amount of atmospheric contamination Add a disinfectant to the piping system and tank Allow the disinfectant to remain in the system/tank for an appropriate time period Flush the Piping System and the Tank with Water – Remove the Disinfectant Flush the piping system/tank to remove the disinfectant Open the System or Tank Exhaust ventilation on site Monitoring equipment on site Open the piping systems or tank slowly Be prepared for spillage Test the Atmosphere Test the atmosphere in the piping system or tank. Chemist’s Visual Inspection Perform a visual inspection of the piping system or tank and re-flush or mechanically clean as necessary. Initial Entry by Personnel for Mechanical Cleaning It is recommended that an “Enter with Restrictions” certificate be issued for this initial entry proscribing appropriate protective clothing and possibly respiratory protection based on the outcome of the visual inspection. The certificate should recommend good personal hygiene practices. Certification If you chose to issue an “Enter with Restriction” standard safety designation Specify PPE required to enter the tank IAW NFPA 306 Recommend adding a note to the certificate about good personal hygiene If you chose to issue an “Atmosphere Safe for Workers” standard safety designation Recommend adding a note to the certificate on good personal hygiene Safety Alert: Deadly Hydrogen Sulfide and Shipyard Sewage Shipyard employers and employees must be fully aware of the hazards and dangers of sewage systems on ships and at shipyard shore facilities. In recent years there have been several fatal accidents where up to four workers were killed while working on a sewage system. The principal cause of these worker deaths was the inhalation of hydrogen sulfide (H2S) gas, which can be generated by sewage. H2S gas smells like “rotten eggs” and, when inhaled, can render a worker unconscious in seconds and kill them. With proper training and procedures, employers can prevent accidents involving H2S gas from sewage systems. (Note: On Navy and Coast Guard vessels, the term “Collection, Holding and Transfer system” (CHT system) is commonly used for sewage systems.) For more information about H 2S, please review the Hydrogen Sulfide Quick Card at www.osha.gov. BEFORE OPENING OR OTHERWISE BREAKING INTO A SEWAGE HANDLING SYSTEM, TAKE PRECAUTIONS: SUPERVISION & MANAGEMENT: Consult with shipyard safety personnel before assigning work on sewage systems. They should be aware of and ready to help deal with these hazards. Ensure you and your workforce have carefully reviewed and understand the position, function, condition and use of all piping, valves, and back-flow prevention associated with the sewage system. (In vessel repair situations, discuss and review the intended work with the vessel's engineering staff or ship superintendent if available.) Verify that the system has been chlorinated or otherwise sanitized to kill potentially infectious waste. Verify that the system has been emptied, flushed with clean water and discharged to appropriate sewage disposal. Verify that the system is isolated (using positive mechanical means) from shore-based sewage disposal systems, and that back-flow prevention, such as check valves and vacuum breakers, is in place and functioning. (Remember, a vessel or pier-side tank connected to shore-side sewage discharge lines is usually downhill from the sewage treatment plant it is discharging to. Failure of isolation may result in the shore-side system's sewage flowing to the pier or into the ship!) Ensure that your shipyard competent person, a marine chemist or industrial hygienist are available to inspect and test the atmosphere of the piping or space before it is broken into. This will help verify how effective the flushing was. Investigate whether the system piping flows through sealed and otherwise inaccessible spaces, and have those spaces inspected and tested before work begins on the system. (Corroded and failed piping may allow the accumulation of dangerous sewage gases in connected sealed spaces.) When uncertain and until the system is proven to have no hazard potential, post a safety watch at the opening of the space who can summon rescue. On systems that are enclosed and aboard vessels, ensure that the system-containing space is supplied with exhaust (negative pressure) mechanical ventilation before breaking into the system. Ensure the discharge of the ventilation is to the weather-air and away from the vessel. Ensure there is an easy and unobstructed escape path for employees if sewage is released into the work area. Train and require that your employees evacuate the work area immediately if they smell sewage, if they sense anything unusual, or if unexpected amounts of liquid begin to enter the space from the system! Hydrogen sulfide smells terrible (like “rotten eggs”) but will quickly disable worker's sense of smell, make them dizzy, unconscious, and then kill them! Train and require that when employees must evacuate such a space, they must NEVER RE-ENTER until a shipyard competent person, a marine chemist or industrial hygienist tests the atmosphere and certifies that the work area is safe to enter. ASSIGNED AND AFFECTED WORKERS: Follow direction of shipyard safety personnel when opening or working on a sewage system. They will help you do it safely. Ensure you have carefully reviewed and understand the position, function, condition and use of all piping, valves and back-flow prevention associated with the sewage system. Get answers to your questions about these systems - they are potentially very dangerous. (In a vessel repair situation, discuss and review the intended work with the vessel's engineering staff or ship superintendent if available.) Verify that the system has been emptied, flushed with clean water and discharged to appropriate sewage disposal. Verify that the system has been chlorinated or otherwise sanitized to kill potentially infectious waste. Verify employer has isolated the sewage system. Ensure that your shipyard competent person, a marine chemist or industrial hygienist has inspected and tested the atmosphere of the piping or space before you break into it. This will help verify how effective the flushing was. If the system piping flows through sealed and otherwise inaccessible spaces, make sure those spaces have been inspected and tested before breaking into the system. (Corroded and failed piping may allow the accumulation of sewage and dangerous gases in connected sealed spaces.) Until the system is proven to have no hazard potential, check that a safety watch is posted at the opening of the space who can summon rescue. On systems that are enclosed and aboard vessels, ensure that the space you are in is supplied with exhaust (negative pressure) mechanical ventilation before breaking into the system. Ensure the discharge of the ventilation is to the weather-air and away from the vessel. Ensure there is an easy and unobstructed path you can use to escape if sewage is released into the work area. Evacuate the work area immediately if you smell sewage, if you sense anything unusual, or if unexpected amounts of liquid begin to enter the space from the system! Hydrogen sulfide smells terrible (like “rotten eggs”) but will quickly disable your sense of smell, make you dizzy, unconscious, and then kill you! When a space has been evacuated, NEVER RE-ENTER until a shipyard competent person, a marine chemist or industrial hygienist tests the atmosphere and certifies that the work area is safe to enter. Talk to the tester and read their posted report before re-entering the space. Through OSHA’s Alliance Program, this Safety Alert was developed through the American Industrial Hygiene Association, the American Shipbuilding Association, the National Shipbuilding Research Program and the Shipbuilders Council of America Alliances for informational purposes only. It does not necessarily reflect the official views of OSHA or the U.S. Department of Labor. Question and Answer Page Question: Is sewage hazardous? Answer: There is no doubt that the atmospheric hazards associated with sewage can be deadly. Exposure to hydrogen sulfide in particular has caused several recent deaths in the maritime industry. The biological hazards, on the other hand, are much more difficult to quantify and there are a variety of opinions as to the degree of hazard. Question: How do you deal with an unknown such as biological contamination? Answer: It is always better to air on the side of safety and take precautions that can help minimize the risk. If you’re not sure why not wear PPE and apply good personal hygiene to eliminate the potential. Question: What can be done to address the deadly hazard associated with hydrogen sulfide? Answer: Proper planning and engineering controls are critical. Utilizing experienced individuals to set up the job site, having proper ventilation, lock out tag out, flushing, disinfection and being prepared for the unexpected are all crucial to performing work on a sewage system or tank.