Identification of optimal strategies for energy management and reducing carbon dioxide emission within the Blue Plains advanced wastewater treatment plant. Steven A. Gabriel, M.ASCE1; Chalida U-tapao2; Christopher Peot, P.E.3; and Mark Ramirez4 1 Associate Professor, Project Management Program, Dept. of Civil &Environmental Engineering, Univ. of Maryland, College Park, MD 20742. Email: sgabriel@eng.umd.edu. 2 Ph.D. Graduate Student, Environmental Engineering Program, Dept. of Civil & Environmental Engineering, Univ. of Maryland, College Park, MD 20742. Email: cutapao@umd.edu. 3 Biosolids Manager, District of Columbia Water and Sewer Authority, 5000 Overlook Ave. SW, Washington, D.C. 20032. E-mail:chris_peot@dcwasa.com 4 Biosolids Process Engineer, District of Columbia Water and Sewer Authority, 5000 Overlook Ave. SW, Washington, D.C. 20032. Email:mark_ramirez@dcwasa.com. Abstract Wastewater treatment operation has a high potential to be a net energy producer by producing significant renewable energy from byproducts; biosolids. The best performing wastewater treatment plants: optimizing their operation, recovering and reusing resource, and using new technologies, can produce a high percent of the energy they need to operate the whole process. Most large wastewater treatment plants can generate energy by producing biogas from the anaerobic digestion process. The objective of this research is to find optimal strategies for energy management at the Blue Plains Advanced Wastewater Treatment Plant (AWTP) and to use energy sources that can reduce the carbon footprint emitted from the whole wastewater treatment process. More than 330 million gallons a day (MGD) of raw sewage, wastewater and storm flow into the Blue Plains Advance Wastewater Treatment Plant (AWTP). This is expected to rise to 370 MGD by 2010, with flows coming from municipal wastewater in the Washington, D.C., the D.C. metro area (including areas of Maryland and Virginia), and to produce over 1,163 metric ton per day of biosolids. The energy consumption of the wastewater treatment utilities and the operations processes consume an estimated 736,087 kilowatt hours per day, which is bought from other contractors. From the present data, the Blue Plains AWTP is highly efficient in recovering energy by using biosolids in order to produce biogas, which is estimated at 95.6x103 cubic meters per day and generates electricity from methane gas at approximately 534.5x103 kilowatt hours per day. This data shows the generated electricity is not enough for Blue Plain AWTP energy consumption. Therefore, other renewable energy sources such as wind or solar energy might be used together. On the other hand, the electricity that is generated from methane gas also reduces the total amount of carbon dioxide emission, which is considered a carbon dioxide credit trading in the global market. Biosolids are used in an anaerobic digester tank before they are applied for land application, creating a high potential to reduce the carbon footprint by 930 metric ton carbon dioxide per day. 1 Introduction Major cities in the world are facing problems from increasing of population to excessive natural resource consumption. Shortage and pollution can emerge when the consumption is not cautiously and concisely planned. Management of wastes, e.g. wastewater, from household, which contribute constantly large amount of quantity, is thus challenging. Wastewater treatment is currently a drain on the economic health of many countries. Sustainability requires a suitable measure increasing worthwhile values to the management. In a large wastewater treatment system capable of treating a large quantity of wastewater, a tremendous amount of electricity is consumed during the plant operation. Various wastewater treatment units must improve their efficiency in order to utilize less energy while increasing treatment. These include mechanical dewatering equipment, automated process control systems and aeration systems. However, the end-products are biosolids or byproducts of wastewater, which must be carefully treated before being released to natural rivers. Wastewater treatment plants have a high potential to produce energy from byproducts of operation processes such as methane gas. The huge wastewater treatment plant can be produced and the energy can be applied in the treatment plant itself. In addition, this reprocessing can reduce external energy consumption. The amount of generated methane gas depends on the quantity and quality of wastewater. This methane production process does not increase the greenhouse gas in the atmosphere due to the fact that the process applies the renewable source. The objective of this research is to examine how the production of renewable energy in the form of methane gas and electricity at the Blue Plains Advanced Wastewater Treatment Plant (AWTP) can be used as energy sources that that reduce the carbon footprint emitted from whole wastewater treatment process. The Blue Plains AWTP operation process The raw sewage, wastewater and storm flow into the Blue Plains AWTP is more than 330 million gallons a day (MGD), with flows coming from municipal wastewater in the Washington, D.C. (including areas of Maryland and Virginia) and produces over 1,163 metric ton per day of biosolids. The Blue Plains AWTP operation process is shown in Fig1. These biosolids are used for land applications in order to improve soil efficiency for agriculture. The biosolids are stabilized by adding lime in order to reduce pathogens. Therefore, these products can be classified in the biosolids class B. According to the methane production process, the total amount of biosolids has to eliminate the lime that was added. The average amount of biosolids which the Blue Plains AWTP can use for generate methane gas is 1,139 metric ton per day (Fig2). 2 Figure 1 Overview of the wastewater treatment process ( DCWASA 2003 with permission) [1] Preliminary process: Liquid process Wastewater and storm water initially pass through bar screens for trash removal and are then treated with iron salts (FeCl3) for phosphorus removal. After dosing with iron salts, grit is removed (settled) from the wastewater as the flow passes through aeration tanks. The wastewater continues to flow to the primary sedimentation tanks. 3 Primary process: Liquid process Organic suspended solids and phosphorus are removed from the wastewater flow by slowing the flow and allowing gravity settling in primary sedimentation tanks. The scum that floats to the surface in these tanks is skimmed off and combined with the settle solids on the bottom. Both scum and settled solids are next processed for additional removal of detritus and gravity thickened. The thickened solids are pumped to the blend tank. The primary wastewater effluent flows to secondary reactors. Secondary process: Liquid process Primary effluent flows in a step feed mode to the secondary aeration reactors, where the effluent is mixed with waste pickle liquor FeCl3 for additional phosphorus removal and with secondary and nitrification return activated sludge (RAS). This mixture (mix liquor) is aerated in the secondary reactors and aerobic microorganisms are grown at a high rate to remove suspended and colloidal carbon and phosphorus. The mix liquor from the aeration reactors flows to the secondary sedimentation tanks and the solids gravity is settled. A portion of these settled solids (RAS) is returned to the aeration reactor. The rest of the settled solids is pumped to dissolve air floatation thickening tanks. The secondary effluent flows to the nitrification/denitrification process. Nitrification/denitrification: Liquid process The nitrification/denitrification process removes ammonia from the secondary effluent. Methanol and RAS from the nitrification sedimentation tanks are mixed with the secondary effluent (mixed liquor) in the nitrification reactors. This flow is processed through a series of aerobic and anoxic tanks for the conversion and removal of ammonia to N2 gas. The mix liquor subsequently flows to sedimentation tanks and the solids are gravity settled. A portion of this settle solids (RAS) are returned to the nitrification reactor, and the rest of the settled solids are pumped to either the secondary reactors or to dissolved air flotation thickening tanks. Dissolved air floating (DAF): Solid process Settled solids from the secondary and nitrification/denitrification sedimentation tanks are pumped to air floatation tanks and mixed with compressed air and polymer to coagulate and thicken the solids. After thickening, the solids are pumped to the blend tank. Blend tank: Solid process Gravity-thickened primary solids and DAF thickened secondary are mixed together in the blend tank. Primary and secondary solids are first stored in separation tanks and then fed at a calculated blend ratio into the blend tank. 4 Dewatering and lime stabilization: Solid process The solids from the blend tank are mixed with polymer and then dewatered by high solid centrifuges and belt presses. The dewater cake is then mixed with lime (CaO) for pathogen reduction to EPA class B level [1]. The amount of biosolids per day amount of biosolids per day(tons) 1,400 1,200 1,000 800 600 400 200 Jun-08 Jul-08 Sep-08 Oct-08 Dec-08 Feb-09 Mar-09 May-09 Jul-09 data in day (2008-2009) Figure 2 the average amount of biosolids that the Blue Plains AWTP products per day Energy consumption at Blue Plains AWTP The Blue Plains AWTP Operation process uses electricity in order to generate energy for wastewater treatment process. This plant does not generate the electricity by itself, but uses electricity that it buys from other contractors. The energy consumption, electricity for operation process data, fluctuates greatly in each day and month. Nevertheless, it has increased in each year. The average data are 736,087 kilo watt hours per day (Fig 3). 5 kWH 25,000,000 Blue Plains Electrical Consumption( generation part) 2006-2008 24,000,000 23,000,000 22,000,000 21,000,000 20,000,000 2008 2007 19,000,000 2006 18,000,000 Jan Feb Mar Apil May Jun Jul Aug Sep Oct Nov Dec Figure 3 the Blue Plains AWTP electricity consumption for operation process in 2006 -2008 Biogas production by anaerobic digestion Biosolids are a byproduct of the wastewater treatment process that causes significant problems such as odor and residues. Many plants spend much of their budget in order to manage this problem. In the case of the Blue Plains AWTP, biosolids are classified in class B, and all of them are used for land applications because the chemical properties (N P K; plant nutrients) can be applied instead of biological fertilizers. However, these chemical properties can be used in case of biodegradation for renewable energy. Byproducts of anaerobic biodegradation are not only methane gas that is high potential energy source but also residual that is effluent of anaerobic digestion can be used for land applications. The anaerobic biodegradation can be considered for an anaerobic digester at the Blue Plains AWTP because it plays a crucial rule in the reduction of the high amount of methane in biogas composition. Anaerobic digestion produces biogas that is a composition of CH4 and CO2 and that stabilizes biomass in the following the reaction[2]: Active biomass + C-substance CH4 + CO2 + stabilized biomass + H2O+ traces gas Moreover, the biogas composition is 55-65% of methane gas, 30-40% of carbon dioxide, and 0-5% of Water vapor, traces of H2S and H2 [3]. 6 Figure 4 Subsequent steps in the anaerobic digestion process [3] The anaerobic biodegradation plays significant role in the transformation of organic matter into biogas: 55-65 vol.% of methane gas and it also reduces the amount of final residual for disposal as the same time as destroying almost of all the pathogens present in the biosolids and limiting odor problems associated with residual matter. In this research, anaerobic digestion is also used in order to estimate the amount of biogas. The biogas that generates from anaerobic the digester tank is affected by many factors such as pH, temperature, solid retention time, and type of digester. The amount of biogas is predicted by fixing the other parameters and thinking about how solid retention time can be used in the relation between biogas productions (as shown in fig 5). Time is a significant factor which anaerobic bacteria need to spend in order to transform the organic matter to biogas. For instance, a 20-day BOD is considered sufficient time for measurement aerobically, due to the lower growth rate of anaerobic to 30, 60 or even in some cases 90 days is accommodated acclimation of the biomass to toxic and/or unusual pollutants in the industrial wastewater[4]. Nevertheless, this research is focused on the maximum potential to produce the methane gas from biosolids, and the Blue Plains AWTP is able to supply the biosolids continuously. Therefore, it is not necessary to spent time more than the high potential rate that means solid retention time is supposed to be 40 days. According to Fig 5, the biogas amounts, which are generated from anaerobic digester and related to the solid retention time, can be estimated; however, the important property of biosolids that affect the biogas amount is the fraction of organic matter in 7 biosolids. The average fraction of dry organic matter in the Blue Plains AWTP biosolids is 21.01 % of biosolids, so the average organic dry matter in the Blue Plains AWTP biosolids is 239.08 metric ton per day (Fig 6). From this correlation, the approximate amount of the Blue Plains biogas is 95.6x103 cubic meters per day, and the methane gas that is 60% of biogas is 57.4x103 cubic meters per day. Figure 5 biogas productions VS SRT [3] ODS: organic dry solids of the sludge (wt %) The average amount of organic dry matter of biosolids per day organic dry matter of biosolids per day(tons) 300 250 200 150 100 50 Jun-08 Jul-08 Sep-08 Oct-08 Dec-08 Feb-09 Mar-09 May-09 Jul-09 data in day (2008-2009) Figure 6 the average amount of organic dry matter of the Blue Plains AWTP 8 Energy recovers from methane gas The Blue Plain AWTP usually buys electricity for operation process from out side contractor. The energy consumption of the whole plant normally present in electricity consumption, so the methane gas that generate from anaerobic digester have to transform to electricity by a kind of generator. However, the approximate amount of electricity can be estimated by using the heat value capacity of methane gas; methane heat value is 3,412 BTU can generate electricity 1 kilowatt hour (http://tonto.eia.doe.gov). Therefore, the Blue plains AWTP has high ability to generate 534.5x103 kilowatt hour per day. Carbon dioxide emission According to the Blue plains wastewater treatment process, liquids phase, preliminary, primary and secondary treatment, has the carbon dioxide (CO2) emission from endogenous respiration and oxygen requirement. The objective of this research does not need to change any process of liquids phase, so the carbon dioxide emission are negligible. On the other hands, the total amount of carbon footprint from wastewater treatment operation process might consider from solids phase of operation process. The important factor is which one is biosolids handling process. A lot of research articles show many biosolids treatment processes have a lot of result of carbon dioxide emission. In case, anaerobic digestion process that generate methane gas in order to generate electricity gain a huge carbon dioxide credit more than land application process. Furthermore, the wastewater treatment plant will gain higher carbon dioxide credit from biosolids management by including anaerobic digester and land application process. Carbon dioxide gas release from anaerobic digestion is about 30-40% by vol. of biosolids, and methane gas is about 55-60% by vol. of biosolids. After electricity is generated by methane, carbon dioxide gas will be released again by this process. The approximate ratio of carbon dioxide credit per weight of biosolids is 0.8 Mg CO2 credit per dry Mg biosolids[5] (tons CO2 credit per dry tons biosolids).The total amount of carbon dioxide gas that the Blue plains AWTP can keep by using anaerobic digestion is 930 metric ton carbon dioxide per day. Conclusion The main objective of wastewater treatment plant is treating wastewater by using highest potential, so the result of this purpose is the operation process normally spends a lot of energy especially the huge wastewater treatment plant like the Blue Plains AWTP. If this plant can not decrease the efficiency of operation process by decreasing energy consumption, it has to generate energy from byproduct in order to use on site. The Blue Plains AWTP has a lot of biosolids from production process that have high potential in order to transform to electricity by using anaerobic digester. This process can handle the significant problems like how to disposal them and where is the landfill area. In addition, the carbon emission from this process also decreases. This is a good opportunity to 9 change from a crisis to a chance. From this research, the Blue Plains AWTP has significant energy source such as biosolids, which has high efficiency in order to generate methane and electricity respectively. In addition, the carbon emission from anaerobic digestion decreases when compare with using for land application. The Blue plains AWTP will gain carbon dioxide credit 930 metric ton carbon dioxide per day. Nevertheless, the electricity that generate from biosolids is not enough for the Blue Plains AWTP in order to use on site. This plant needs 736x103 kilowatt hours per day, but it can generate only 534.5x103 kilowatt hour per day. The Blue plains have to find the other energy sources to fulfill this requirement in order to complete highest efficiency of plant. Reference: 1. 2. 3. 4. 5. Gabriel, S.A., et al., Statistical Modeling to Forecast Odor Levels of Biosolids Applied to Reuse Sites. Journal of Environmental Engineering, 2006. 132(5): p. 479-488. Rosso, D., M.K. Stenstrom, and et al, The carbon-sequestration potential of municipal wastewater treatment. Chemosphere, 2008. 70: p. 1468-1475. Appels, L., et al., Principles and potential of the anaerobic digestion of wasteactivated sludge. Progress in Energy and Combustion Science, 2008. 34: p. 755781. Speece, R.E., Anaerobic Biotechnology for Industrial Wastewater. 1996. Brown, S., H. Gough, and et al., Green Aspects of Biosolids Processing and Use. 2009. 10