Water Quality Parameters Note: 1 ppm (parts per million) = 1 mg/L, 1 ppb (parts per billion) = 1microg/L Water Quality Test Description Parameters Associated Problems BOD (Biological Oxygen Demand) DO (Dissolved Oxygen) The amount of oxygen used by microorganism in the water to decompose organic matter 1-2 mg/L is very good, 3-5 mg/Lmoderate, 6-9 mg/L somewhat polluted, > 10 mg/L very polluted , sewage treatment plants are allowed to discharge 8-150 mg/L If microorganisms are absent from the stream due to changes in pH etc. caused by excess sewage, then the organic waste does not decompose and can cause odor and health problems The amount of oxygen available to fish and macroinverterbrates in the water Min. required amt (in mg/L) for: warm water fish 5, cold water fish 6, fish when spawning 7, macroinvertebrates 5, Recreational use 3 Too little (below 5) and most aquatic animals can't survive. Biotic Index The number of different species of macroinvertebrates in the water Great diversity -- mayfly, stonefly, caddisfly, salamander, trout, bass, salmon, pike (Index value >20) Poor Diversity -- sludge worms, black fly larvae, leeches, catfish (Index value <10) Dredging,channeling, and a limited riparian area add sediment to the stream that can change the makeup of organisms there. Make sure to look in riffle areas, under large rocks, and in areas with natural debris when looking for macroinvertebrates. TDS (Total Dissolved Solids) Conductivity The measure of the amount of particulate solids that are in the water. Estimate the TDS by multiplying the conductivity reading (in micromhos/cm) by 0.67. TDS is measured in mg/L. Safe drinking water levels <500 mg/L TDS can show areas that have a high mineral base (from rock substrate) or from dissolved minerals from industry, agriculture, or waste water treatment. TSS (Total Suspended Solids) Turbidity The measure of the amount of sediment that is in the water. A Secchi disk is usually used for lakes and rivers. Using a Transparency Tube for Streams: (The equivalent parameters for lakes) Poor visibility <25 cm = 25 NTU, Visibility for recreational use 50-60 cm = 5 NTU, Extreme clarity > 60 cm = 0.5 NTU Sedimentation from agriculture, housing, etc. can clog the gills of fish, suffocate freshwater clams and other macroinvertebrates. pH The measure of acidity (hydronium ion, H+) in the water Range for most aquatic life is 6.5 - 8.2 Below 6.5 is too acidic: Above 8.2 is too basic Increased use of fossil fuels increases the amount of SO2 that mixes with water to lower the pH. Most organisms can't survive in a pH less than 4.5 Nitrates (NO3) NO3, NO2, NH3 and organic N are all found in water. The nitrate test is a NO3-N complex. To find the nitrate amount multiply the value by 4.4 Reading of: <1.0 mg/L good, < 5.0 mg/L fair > 10 mg/L very poor Excess nitrates and ammonia from fertilizer causes eutrophication of phytoplankton in streams & lakes Phosphates (PO4) The measure of phosphates in the water <0.1 mg/L good, < 0.5 mg/L fair > 1.0 mg/L very poor Excess phosphates from fertilizer causes eutrophication of phytoplankton in streams & lakes. (Phosphate problems were found before nitrate problems) Hardness (Ca+2 or Mg+2) The measure of Calcium and Magnesium in water 0-60 mg/L indicates soft water, 120-180 indicates hard water, < 250 mg/L is acceptable for drinking, > 500 mg/L is hazardous to human health Although aquatic organsims are not affected by an increase of water hardness, it does play a role in human lives. Water that is <10 mg/L are oligotrophic and those containing >25 mg/L are usually eutrophic. Temperature Change oC The measure of temperature CHANGE in the stream water over a 24 hour period < 2 oC/ 24 hr good, 2-5 oC/24 hr fair, > 5 oC/24 hr poor Since water has a great heat holding capacity (from its high specific heat) temp. shouldn't change very much from day- night. A constant temp. > 18 oC is deleterious to aquatic life Heavy Metals (Toxic) The measurement of lead, arsenic, copper, cadmium, cyanide, mercury, and other man-made compounds in water The following numbers reflect DRINKING water standards (in mg/L): Lead 0 , Arsenic 0, Copper 1.3, Cadmium 0.005, Cyanide 0.2, Mercury 0.002, Benzene 0, Dioxin 0, PCB's 0 Miniscule amounts (in ppb) of these chemicals cause a variety of human problems ranging from liver kidney, neurological, and reproductive damage. Problems for aquatic animals has not yet been determined for most of them. Fecal Coliform The measure of E. coli bacteria (in colonies present/ 100 ml sample) of water Number of allowable colonies/ 100 ml sample of water: Drinking water -- 0, Swimming -- 100, Boating/Fishing -- 1000 E. coli, a harmless bacteria, is found in the digestive tract of warm blooded animals along with pathogenic bacteria that might be in the fecal material. The presence of E. coli shows that fecal material is present in he water and might be harboring those pathogens.