Intro GIS for Urban and Environmental Analysis Assignment 7 – Initial Project Description & Data Documentation Li Wang Naturally-occurring arsenic is often bonded to iron oxide minerals in soil and bedrock materials in New England area due to specific geological and geochemical conditions. Only in recent years have people found out that the degradation of organicrich leachate migrating from landfills may cause the reductive dissolution of iron oxide minerals and subsequently the release of adsorbed arsenic to groundwater. This has been identified in a number of superfund sites. The objective of my project is to conduct a groundwater vulnerability study for this specific contamination scenario. The state of Maine is selected as my study area. Groundwater vulnerability usually refers to the potential of contamination from nonpoint sources or areally distributed point sources of pollution, such as pesticides or nitrate from fertilizer in agricultural practices. Since the development of DRASTIC model (Aller, Bennett et al. 1987) for groundwater vulnerability assessment by USEPA in late 1980s, this type of index method has become very popular and numerous applications have been done in US and worldwide. The DRASTIC model considers factors including Depth to water table, natural Recharge rates, Aquifer media, Soil media, Topographic aspect, Impact effect of vadose zone and hydraulic Conductivity. Usually different ratings are assigned to each factor and then summed together with respective weights to a numerical value as the vulnerability index (Eq. 1): DRASTIC Index (Di) = DrDw + RrRw + ArAw + SrSw + TrTw + IrIw + CrCw (Eq. 1) where D, R, A, S, T, I, and C are the parameters, r is the rating value, and w the weight assigned to each parameter. Plotting the spatial distribution of this index will generate a vulnerability map of the study area. Although this method is rather subjective and lacks quantitative information, it is often preferred because it is relatively easy to implement and the data needed are generally more available. In recent years, with the development of GIS techniques, the geographic display of results from such vulnerability studies is greatly improved and more advanced spatial analysis methods are also increasingly incorporated. Other vulnerability study methods such as process based modeling and 1 statistical methods usually need more data and are more complicated, therefore not adopted in this project. The GIS based DRASTIC model for assessing groundwater vulnerability in shallow aquifers in Aligarh, India by (Rahman 2008) is one of the many groundwater vulnerability studies using the classic DRASTIC model in Asia, Africa, South America and Europe in recent years. Seven data layers provided input to the modeling. ILWIS 3.0 (Integrated Land and Water Information System) and Arcview 3.2a GIS software were used to find out the water vulnerable zones in shallow aquifers. The GIS technique involved proved to be an efficient tool for assessing and analyzing the groundwater vulnerability to contamination. Some index methods have adapted the DRASTIC model by modifying the factors and respective weights or incorporating surrogate data on human activities such as land use and contaminant loading. A good example is the groundwater vulnerability assessment to agricultural pesticides in North Carolina by (Moreau and Danielson 1990), in which DRASTIC scores were used in combination with estimated pesticide use rates to produce vulnerability maps for selected pesticides. More recently, (Al-Hanbali and Kondoh 2008) combined a human activity impact (HAI) index derived from land use/cover data with the DRASTIC model and showed that human activities are affecting groundwater quality and increasing its pollution risk in the Dead Sea groundwater basin, Jordan. In addition to the DRASTIC model, a number of other index methods have been developed for groundwater vulnerability studies. For example, the GLA method developed by the German State Geological Surveys and the Federal Institute of Geosciences and Natural Resources evaluates the vulnerability essentially by estimation of the transit time of the percolation water using three factors: the thickness of each layer in the unsaturated zone, the permeability of each stratum of the unsaturated zone and the amount of percolating water. GLA is similar to DRASTIC in that they are both designed to assess groundwater vulnerability independent of the aquifer characteristics, while some other index methods were specifically developed for certain aquifers such as karst areas. (Neukum, Hötzl et al. 2007) compared these vulnerability mapping methods with field investigations and numerical modeling in a study area in southern Germany and 2 suggested that vulnerability maps produced with DRASTIC, EPIK, and related methods should be used with care when employed in vulnerability assessments for land use planning and related decision-making. Only limited studies have been done on groundwater vulnerability from specific contamination sources using the GIS and index methods. It is possibly because that the concept of groundwater vulnerability was originally defined for non-point sources. But the index methods combined with site-specific information such as hydrogeology and contamination history may still be very useful for evaluating the pollution risk of groundwater in both local and larger scales. For example, (Rapti-Caputo, Sdao et al. 2006) estimated the environmental compatibility of the controlled landfills by applying an integrated method based on the hydrogeological behaviour of the area surrounding the landfill according to the map of the intrinsic vulnerability of the aquifer(s) and the setup, the management and the control of the landfill defined by its own risk index. The application of this approach to several landfills located in different geological conditions in Italy provided an effective tool to evaluate the efficiency of the control system of the existing landfills and the priority list of the intervention to be performed to improve the future management and to protect the surrounding environment. The problem that I am studying here is about a specific contamination scenario caused by a combination of natural conditions and human activities. It is different from the intrinsic vulnerability that is often studied using models like DRASTIC. It is also not about non-point sources from human activities on ground surface. More information on geology, geochemistry and contaminated sites is needed for this study. I may need to incorporate new factors or modify factors and their weights in existing index models, such as adding soil organic content and cation exchange capacity that are used in some modified DRASTIC models for specific contaminants. Similar to (Rapti-Caputo, Sdao et al. 2006), additional index may need to be developed for the potential of landfill leakage, migration and redox condition change in the subsurface. In addition to using available GIS tools such as extract, overlay, geocoding, simple statistics and spatial analysis, I may need to incorporate some simple geochemical modeling, although more rigorous process based modeling is not necessary. 3 I have found quite a lot of data that can be used in my study (See Table 1), but still lack some important data, especially geochemical data like arsenic and iron oxide mineral distribution in soil and bedrock. I may be able to get information from some USGS research reports on arsenic in New England area and convert some of their data to the format I need. I may need help for converting some printed or digital maps as well as accessing extra data sources. Spatial accuracy is significantly crucial in my study. For change of geological units, 10m accuracy might be enough. For distance to contaminated sites, groundwater wells or water source protection areas, an accuracy of 5-10m might be good enough. However, because I don’t have much experience in GIS applications, I’d like hear more comments on this issue if possible. Table 1 Available data layers for term project Data layer Data level Source General geography and hydrography Maine GIS Geology: bedrock, surficial material, soil, aquifer Maine GIS, Maine Geological Survey Water use and quality: watershed for direct water supply, source water protection area for wells, bedrock source water protection area and sandy/gravel Maine GIS State aquifer areas, public supply wells, water quality monitoring points Contaminated sites: remediation sites, hazardous oil spill system spill sites, Maine DEP* registered petroleum tanks Geochemistry (soil, sediment, water, bedrock), mineral resources, and mines Geochemical atlas (distribution of elements such as As and Fe in natural USGS National USGS environment, raster data) National bedrock, surficial deposits and materials USGS National aquifers National Atlas As in groundwater National Atlas EPA geospatial data (superfund national priority list sites, RCRA Treatment, USEPA Storage, Disposal facilities, Toxic Release Inventory system, etc.) *Data from Maine DEP are in Google Earth kml format. Conversion to shapefile format to used in ArcGIS is in process. References Al-Hanbali, A. and A. Kondoh (2008). "Groundwater vulnerability assessment and evaluation of human activity impact (HAI) within the Dead Sea groundwater basin, Jordan." Hydrogeology Journal. Aller, L., T. Bennett, et al. (1987). DRASTIC: A Standardized System for Evaluating Ground Water Pollution Potential Using Hydrogeologic Settings. Ada, Oklahoma, U.S. Environmental Protection Agency. 4 Moreau, D. H. and L. E. Danielson (1990). Agricultual Pesticides and Ground Water in North Carolina: Idenfication of the Most Vulnerable Areas. North Carolina, Water Resources Research Institute of the University of North Carolina, North Carolina State University. Neukum, C., H. Hötzl, et al. (2007). "Validation of vulnerability mapping methods by field investigations and numerical modelling." Hydrogeology Journal. Rahman, A. (2008). "A GIS based DRASTIC model for assessing groundwater vulnerability in shallow aquifer in Aligarh, India." Applied Geography 28(1): 32-53. Rapti-Caputo, D., F. Sdao, et al. (2006). "Pollution risk assessment based on hydrogeological data and management of solid waste landfills." Engineering Geology 85(1-2): 122-131. 5