Safety Data Sheet in accordance with 91/155/EU
Issue Date 10.01.96( Second Edition)
Page 1 of 3
1. Material, Preparation and Company Identification
BETOCHEM PU-2575 Injection Resin 1 component
Manufacturer/Supplier
Deys Betontechniek Nederland BV
Gelreweg 5
3843 AN Harderwijk/Netherlands
Phone 0031341415148- 24 hours service
WWW.DEYS.NL
INFO@DEYS.NL
Bij noodgevallen raadpleeg uw huisarts.
Voor informatie vergiftigingen informatiecentrum 030-2748888
2. Composition/Statement of Components
Contents
CAS No.
EG No.
: Polyisocyanate ( Prepolymer ) from Diphenylmethane di-isocyanate and
Methylphenylenediisocyanate and auxiliaries
: Does not apply ( Preparation )
: Does not apply ( Preparation )
3. Possible Dangers
Danger Identification
Special danger directions
Special danger directions for people
for the environment
: Xn, Harmful to health.
: Harmful to health when swallowed. Irritates the eyes, respiratory organs and the skin.
: None.
4. First Aid Directions.
General Direction
Upon inhallation
Upon skin contact
Upon eye contact
Upon swallowing
: Immediately change product-stained clothes.
: Call a doctor.
: Remove mechanically,wash with soap and water and rinse well.
: With the eye-lid open, rinse with running water. Consult a doctor.
: Drink plenty of water. Go in the fresh air. Call a doctor. Take care with vomiting
.
5. Fire-Fighting Directions.
Suitable Extinguishing Materials
Equipment
: Carbon dioxide, powder or water jet.
In the event of a large fire, use water spray or foam.
: Breathing apparatus with independent air supply necessary.
6. Directions for Unintended Spillage
Personnel Environment
Procedure for cleaning and removal
: Do not allow into drainage or groundwater.
: Remove with liquid-adsorbing materials ( Kieselguhr, sawdust, oil binder ). Place in waste bins.
Do not close. Carbon dioxide development. Danger of bursting. Store in a safe place for
a number of days. Products reacts with moisture and sets.
7. Handling and Storage
Directions for rotation
Directions for Fire Protection
Storage
Requirements for storeroom
and containers
Directions for storage
with other products
Further instruction
Maximum Storage Temp.
: Keep containers dry and tightly closed. Avoid heating over 60°C and cooling under 10°C.
Ensure adequate ventilation or extraction of the work place.
: Protect from heat. In the event of fire, cool the containers with water
: Store in a cool place.
: Do not store with oxidising materials
: Do not store more than 12 months.
: 60°C.
8. Exposure Limitation and Personal Protection.
Additional directions for the use
of technical equipment
: No further additions to Point 7.
Components with workplace exposure limits
CAS No.
Description of Material
%
:: MDI/4,4 diphenylmethanedi-isocyanate prepolymers.
: Approx. 50
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Form
Value
Standard
Additional Information
: Does not apply
: Does not apply
: Does not apply
: Basically, from the lists shown.
Personnel Protection
General Protection and Hygiene
Breathing protection
Hand protection
Eye protection
Body protection
: Keep away from food, drinks and animal feeds.
: Immediately change clothes soiled by the product.
: Wash hands before meals and at the end of work.
: Not necessary
: Protective gloves.
: Safety glasses.
: Protective clothing
9. Physical and Chemical Properties
Form
Colour
Odour
Change of State
Melting Zone
Boiling Zone
Density
Vapour Pressure
Water Solubility
pH value
Flash Point
Ignition Temperature
Explosion limits
: Liquid
: Yellowish
: Typically faint
:
: 275°C
: 1.15 g/ml at 20°C.
: 3/4 0.001 hPa at 20°C.
: Totally miscible. Product emulsifies.
:: 180°C.
: 250°C.
: No danger of explosion
10.Stability and Reactivity
Avoiding Circumstances
Stable to
Dangerous Reactions
Dangerous
Decomposition Products
: No decomposition by correct storage and handling.
: Does not apply
: Exothermic reaction with alkalis, amines and alcohol.
Carbon dioxide developed with water, causing pressure
to build up in closed containers. Danger of bursting.
: Upon burning,carbon monoxide, nitric oxide, isocyanate
vapour and traces of isocyanide.
11. Toxicology Directions
Acute Toxicity
Primary irritation effect of the skin
Primary irritation effect of the eyes
Sensitivity
: By over-exposure, especially inhalation of aerosol vapours. Danger is dependent upon
concentration. Irritation of the respiratory organs in over-sensitive people, breathing
difficulties, coughing, asthma.
: Can irritate the skin and mucous membrane.
: Irritation
: Possible on contact with skin.
12. Ecology Directions.
Water Harmfulness (WKG)
General Instructions
: Class 1- slightly harmful to water ( own classification )
: Do not discharge into ground water, drainage or rivers.
13. Disposal Instructions.
Recommendation for the Product
: Product reacts with moisture and sets to a physiologically harmless Polyurea gel.
The product can therefore be rendered inert by mixing with water and disposed of in
rendered inert by mixing with water and disposed of in the set form similar to domestic
refuse. rendered harmless by filling the containers with water
Soiled Packaging
Recommended Cleaning Material
: Dispose according to local laws. The product can be and leaving to set in open bins.
: Remove mechanically with sand, sawdust or oil binder or wash with water.
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14. Transport Specifications.
ADR/RID and GGVS/GGVE
ADR/RID-GGVS/GGVE/
E-Class
Numbers/letters
UN No.
Mail delivery
Express goods
: None
: None
: None
: 2489
: Not allowed (in Germany).
:
15. Specifications
Identification according to EU Laws.
Identification letters and
danger identification
R-Clauses
S-Clause
National Specifications Chemical
Water Danger Class (Germany)
: Xn, slightly toxic. Contains Diphenylmethanedi isocyanate
: 20, inhalation dangerous to health.
36/37/38, irritates eyes, respiratory organs and skin
42, possible sensitivity through inhalation.
: 26, upon contact with eyes, wash with plenty of water. Consult a doctor
28, upon contact with the skin, wash off immediately with soap and water.
38, with insufficient ventilation, wear breathing apparatus.
45, In the event of accident or feeling unwell, call a doctor.
If possible, present this safety data sheet/label.
: Pay attention to the memorandum M 044 " Polyurethane Manufacture, Isocyanate "
: WGK 1 ( own specification ), slightly harmful to water.
16. Other Information.
The information provided is based on our current state of knowledge of the product and does not provide assurance of product properties. The
information does not form the basis of a contract of rights under law. The information is not necessarily valid if the product is mixed with another
product or included in any given process. It is the responsibility of the receiver of our products to pay attention to the existing laws,
interpretations and rights of a third party and to determine the suitability of our products for specific applications.