Waste Management Procedures Nitrogen Contents The section on Nitrogen contains the following: Topic Version 0, October 2013 See Page Before You Begin 2 Nitrogen (compressed) 4 Nitrogen, refrigerated liquid (cryogenic liquid) 7 Page 1 of 8 Waste Management Procedures Nitrogen Before you begin Description Inert gas transported in: cylinders as a compressed gas tanks as a cryogenic liquid Regulated by DOT only because of the pressure and temperature at which it is transported. Leaks of nitrogen (while a temperature or pressure hazard to personnel) are not a serious environmental issue. Seventy-eight percent of the air we breathe is nitrogen. Category Unused nitrogen is not a waste. Any quantity of nitrogen remaining in the cylinder or tank can be used and should be returned to the vendor as unused product. Analysis Not required Accumulation Compressed nitrogen should remain in the original cylinder. Cryogenic liquid nitrogen should remain in the original tank. If cylinder is unusable [damaged], empty, punctured or has the valve removed: It may be placed in scrap metal bin. Waste Reduction Minimize wasteful practices (i.e., overuse or excessive usage, return excess purchases to vendor) Use all of contents Send to another location which can use it Return empty cylinder (or tank) or any unused portion of a cylinder (or tank) to vendor Disposal Return to vendor for credit Continued on next page Version 0, October 2013 Page 2 of 8 Waste Management Procedures Nitrogen Before you begin, Recordkeeping (continued) If non-hazardous waste (Cylinder empty and valve removed or cylinder punctured): List on General Cargo Manifest as scrap metal If returning cylinder or tank to vendor for refill: Complete entry as “nitrogen” in Hazardous Materials Section [Section I] of the Fieldwood Energy Shipping Manifest, prior to transportation. Maintain a copy of manifest offshore and at shore base facilities while shipping papers are active. Send original manifest with shipment. Version 0, October 2013 Page 3 of 8 Waste Management Procedures Shipping Instructions: NITROGEN (Compressed) 1. Call or FAX Dock/Base to schedule shipment. a. Contact owner to schedule pick-up of material. 2. Package Nitrogen as follows: a. Ship Nitrogen Bottles in the bottle rack intended. b. Do not ship in any cylinder other than the original Specification 3, 3A, 3AA, 3B, 3C, 3D, 3E, 4, 4A, 4B, 4BA, 4BW, 4C, 25, 26, 33, or 38, 3AX, 3AAX, 3T, 39, 3AL Cylinder. c. Secure cylinder valve cap when applicable. 3. Mark Package: a. Mark container “Nitrogen, Compressed, 2.2, UN1066” b. Stencil container-“Fieldwood Energy” and the generator’s location (i.e. Eugene Island 158) 4. Label Package: a. "Non Flammable Gas" label 5. Prepare shipping papers: a. Complete entry in Hazardous Materials Section [Section I] of the Fieldwood Energy Shipping Manifest (See example). 6. Placard Vehicle/Vessel: a. For cargoes of more than 1000 pounds: "Non Flammable Gas" Placard. The number "2" should appear in the lower corner. b. For cargoes less than 1000 pounds: No Placard required on transport vehicle. c. See attached placard 7. Load cargo in accordance with the following shipping limitations: AIR RESTRICTIONS (49 CFR 172.101) Passenger Aircraft 165 pounds (75 kg) Cargo Aircraft 330 pounds (150 kg) WATER 8. RESTRICTIONS (49 CFR 172.101) Cargo and Passenger vessels May be stowed either on deck or under deck Other Requirements None Include MSDS with shipment Version 0, October 2013 Page 4 of 8 Waste Management Procedures Version 0, October 2013 Page 5 of 8 Waste Management Procedures Description: NITROGEN, (Refrigerated Liquid - Cryogenic Liquid) 1. Call or Fax Dock/Base to schedule shipment. a. Contact owner to schedule pick up of material. 2. Package Nitrogen as follows: a. Ship Nitrogen Bottles in the bottle rack intended b. Do not ship in any cylinder other than the original Specification DOT-4L cylinder when carried in the vertical position. c. Secure cylinder valve cap when applicable d. Cargo Tanks The regulations governing transportation of cryogenic liquid by cargo tank are very technical. They are found in 49 CFR 173.318 and include: (1) general requirements (2) pressure relief systems and pressure control valves (3) weight of loading requirements (4) outage (5) temperature (6) additional requirements for specification MC-338 cargo tanks (7) one way travel time marking The vendor of the cryogenic liquid will assist in determining if these requirements have been met. 3. Mark Package: a. Mark container, “Nitrogen, refrigerated liquid (cryogenic liquid), 2.2, UN1977” b. Stencil Container-“Fieldwood Energy” and the generator’s location (i.e. Eugene Island 158) 4. Label Package a. “Non Flammable Gas” label b. For packages having a volume over 64 cubic feet (478 gallons) and for portable tanks of less than 1000 gallons: place labels on at least two ends (other than the bottom) or two sides. 5. Prepare shipping papers: a. Complete entry in Hazardous Materials Section [Section I] of the Fieldwood Energy Shipping Manifest (See example). Continued on next page Version 0, October 2013 Page 6 of 8 Waste Management Procedures Description: NITROGEN, (Refrigerated Liquid - Cryogenic Liquid) (continued) 6. Placard Vehicle/Vessel: a. For cargoes of more than 1000 pounds: "Non Flammable Gas" Placard with UN number 1977. The number "2.2" should appear in the lower corner. b. For cargoes less than 1000 pounds: No Placard required on transport vehicle c. Cargo or portable tanks shall be placarded as above on opposing sides if capacity is between 119 and 999 gallons and on all four sides if 1000 gallons or more. d. See attached placard 7. Load cargo in accordance with the following shipping limitations: RESTRICTIONS (49 CFR 172.101) AIR Passenger Aircraft 110 pounds (50 kg) Cargo Aircraft 1100 pounds (500 kg) WATER 8. RESTRICTIONS (49 CFR 172.101) Cargo and up to 25 passengers Must be stowed on the weather deck only Passengers Prohibited when vessels under 246 feet length overall exceed 25 passengers on board Other Requirements None Include MSDS with shipment Version 0, October 2013 Page 7 of 8 Waste Management Procedures Version 0, October 2013 Page 8 of 8