GROUNDWATER AND HUMAN DEVELOPMENT Bocanegra, E - Martínez, D - Massone, H (Eds.) 2002 - ISBN 987-544-063-9 GROUNDWATER QUALITY MONITORING NETWORKS Jaroslav Vrba Chairman of IAH Commission on Groundwater Protection Prague, The Czech Republic e-mail : javr@mymail.cz 1 INTRODUCTION Groundwater quality monitoring supports sustainable management of groundwater protection and quality conservation and strengthents anti-pollution policy on national, regional or local level. Groundwater quality monitoring provides valuable data about groundwater chemical composition for assessment of the current state and forecasting trends in groundwater quality. A holistic approach should be implemented in the policy and management of groundwater resources protection, considering the close connection between groundwater and surface water and giving the same attention to both quantitative and qualitative aspects. The holistic concept appears in co-ordination or even the integration of national groundwater monitoring programmes with surface water, precipitation, climatic and soil monitoring networks. Establishment of pilot monitoring stations with observation of all components of the hydrological cycle and soil helps to reduce the costs of operation of monitoring networks. 2 DEFINITION OF GROUNDWATER QUALITY MONITORING In general terms monitoring is defined as the continuous, standardised measurement and observation of the environment (UNESCO/ WHO 1978). Groundwater quality monitoring can be understood (Vrba, 2000) as a methodologically and technically standardised programme of observations, measurements and analysis of selected physical, chemical and biological variables of groundwater with the objectives: 1. To collect, process and analyse the data on groundwater quality as a baseline for assessing the current state and forecasting trends in groundwater quality due to natural processes and human impacts in time and space; 2. To provide information for improvements in the planning, policy and management of groundwater protection and quality conservation. 3 OBJECTIVES AND STRATEGY OF GROUNDWATER QUALITY MONITORING PROGRAMMES Groundwater quality monitoring programmes support the data to analyse the chemical composition and evolution of natural groundwater, to address groundwater quality problems, risks and conflicts in relation to the existing or potential pollution sources, as well as to define the priorities in groundwater resources protection with respect to land use. Groundwater quality monitoring programmes operate at the international, national, regional and local levels. The objectives of each of the above programmes govern the extent of monitoring activities, such as design of monitoring networks, construction of monitoring wells, frequency and methods of sampling and measurements and number of variables to be analysed. 1953 GROUNDWATER QUALITY MONITORING NETWORKS International and national groundwater quality monitoring programmes are typically background monitoring activities, whereas provincial and local monitoring programmes are oriented to the specific monitoring purposes (van Lanen et al. 1998). Both background and specific monitoring activities should also include early warning groundwater quality monitoring. Groundwater quality monitoring programme is composed by monitoring, information and management systems (Table 1). Clearly defined objectives of monitoring are essential to achieve the expected results. The requested output information by the users (planners, policy and decision makers, scientists, public) cannot be defined precisely when monitoring objectives are not stated clearly. Only rarely a monitoring system can cover more than one objective. The design of monitoring network, well construction and sampling methods differ particularly in local monitoring programmes concern mostly on particular pollution problem. Definition of objectives and requested output information is the first critical point of groundwater monitoring programme and have to be defined before the first monitoring station is located and the first sample of water is taken. Prior to outlining the strategy for the monitoring system, initial inventory of accessible data is made to gain a basic knowledge about groundwater chemical composition and contemporary state of its quality and to define the extent of the required complementary hydrogeological investigation. Groundwater quality monitoring system includes the following activities: Delimitation of the monitoring area; Analysis of the geological framework, the groundwater flow system and groundwater quality; Identification and inventory of existing and potential pollution sources; Design of monitoring network; Designation of field and laboratory monitoring methods; Determination of sampling frequency and selection of variables to be analysed, including field and trip blanks samples as part of quality assurance (QA) and quality control (QC) process; Database management, especially methods of data handling, processing and evaluation. Data analysis and transformation of analysed monitoring data into a user tailored information product is an other critical point of groundwater quality monitoring programme (Table 1). It is being emphasized that however high the quality of monitoring data, is as long they are not transmitted in an intelligible information to the user, the outputs of the groundwater quality monitoring programme are not effectively utilised and the expenditures on its operation are not vindicated. The output information on groundwater quality can be used for technical, socioeconomic, ecological, scientific or public purposes. Simple, easy to understand information is required for the public and non-professionals. Planners, decision and policy makers and managers need broad-ranging, comprehensive but intelligible information concern on specific groundwater quality problems. Groundwater quality management system as a final stage of groundwater quality monitoring programme (Table 1) is based on monitoring results and aspires to implement groundwater quality protective measures in the frame of existing legal basis and institutional structure. 3.1 International Groundwater Quality Monitoring Programme 1954 Jaroslav Vrba An international groundwater quality monitoring programme was initiated by the United Nations Environment Programme and operates over the world within the Global Environment Monitoring System (GEMS) since 1974. 3.2 National Groundwater Quality Monitoring Programme National groundwater quality monitoring programmes are concerned with data collection of the natural background level and current state of groundwater quality of main country aquifers. These can support national policy of groundwater protection and quality conservation. Monitoring of groundwater quality on a national level is an organisationally and technically demanding and expensive process in terms of both, the capital and operation costs. The benefits derived from expended financial means are therefore always compared with the value of the information obtained. Groundwater quality monitoring programme Objective Groundwater quality monitoring system Critical point Definition of requested output information Strategy Delimitation of monitoring area Determination of groundwater system geometry and parameters, evaluation of relevant data of groundwater quality Identification and inventory of potential and existing pollution sources Data acquisition Sample collection Transmission Laboratory analysis Data handling Processing Database management system Data analysis Groundwater quality information system Groundwater quality management system Critical point Information products Information communication Information utilization Legislative and institutional implementation of protective measures TABLE 1 Groundwater quality monitoring 1955 programme Storage Feedback Design and establishment of monitoring network and designation of monitoring methods GROUNDWATER QUALITY MONITORING NETWORKS Baseline and trend stations, according to the classification of Maybeck (1985), play dominant roles in national groundwater monitoring networks (Table2). They have to represent natural hydrogeological conditions and are located outside the influence of pollution sources and groundwater abstraction sites. Using of existing wells drilled for other purposes without casing and screening adequate to the objective of national monitoring programme is not considered suitable. Groundwater quality monitoring stations are mostly identical with monitoring stations measuring groundwater quantitative parameters. National groundwater quality monitoring networks are in operation in a few countries only. However, monitoring methods and procedures are not standardized and vary in each country. This causes difficulties in mutual comparison of monitoring data particularly in internationally shared groundwaters. Importance of groundwater as a drinking water source and ecological phenomena and vulnerability of aquifers control the design of national groundwater quality monitoring network. 3.3 Regional Groundwater Quality Monitoring Programmes Regional groundwater quality monitoring programmes are concern on specific purposes and complement the national monitoring programme. The main objective of regional programmes is to acquire statistically significant sets of data as a basis for creating the regional policy of groundwater resources protection, management of their quality and for supporting groundwater quality data for decision making in land use planning. Monitoring activities are concerned with the specific potential or existing diffuse pollution problems (particularly the impact of agriculture on groundwater quality) and on protection of catchment areas of groundwater supply sources. The trend stations dominate in the design of regional groundwater quality monitoring networks (Table 2). However through selected baseline stations of national monitoring network, both monitoring programmes are interconnected. Frequency of sampling in regional monitoring programmes is higher compared with national monitoring programme (up to 12 times per annum); variables analysed are selected according to the specific groundwater quality problems. Design of monitoring wells should permit vertical hydrochemical profiling of particular aquifers of groundwater system. Monitoring of vertical movement of pollutants in the unsaturated zone (lysimeters, centrifugal extraction of interstitial water from core samples, sampling by means of compressed gas injection or other methods) should be recommended especially in areas with a high potential for aquifer pollution (e.g. shallow aquifers bellow arable sandy soil). Regional groundwater quality monitoring programmes are often established in catchment areas of groundwater supply sources. Water supply companies in many countries are legally obliged to operate groundwater monitoring programme as part of protection policy of water supply systems. The objects of monitoring are water supply wells or springs and monitoring wells located in designating protection areas (wellhead protection areas in US terminology) of the groundwater supply source. By reason of preventive protection of groundwater resource quality, monitoring networks are established in outer or second degree protection areas encompassing usually the whole catchment area. However, several water supply companies carry out groundwater quality monitoring of water supply wells or springs only. The number of monitoring stations and frequency of monitoring strongly depends on aquifer vulnerability and related risk to pollution. Drinking water standards valid in individual countries control the extent of variables analysed. Sampling frequency is high; some variables from water supply wells sensitive to human impacts are analysed daily. Monitoring of organic chemicals is less frequent (as little as once per year). 1956 Jaroslav Vrba 3.4 Site Specific Groundwater Quality Monitoring Programmes Site specific groundwater quality monitoring programmes are established around: 1. Potential point pollution sources, with the objective to give an early warning about groundwater quality deterioration; 2. Existing point pollution sources with the purpose to observe and control movement of pollution plume or effects of pollution remediation. Good knowledge of the hydrogeological properties of the unsaturated zone and aquifer, groundwater flow nets and pollutant source and behaviour is desirable before designing a local monitoring programme. Local monitoring programmes operate independently of national or regional programmes. A site specific extent of monitoring networks, great density of monitoring stations, high sampling frequency and field and laboratory analyses of variables selected according to the type and properties of pollutants are typical for local monitoring programmes. Design of monitoring wells, particularly well casing and screen material, setting of well screen with respect to pollutants physical and chemical properties, type and placement of annular seal material, all affect the quality and reliability of groundwater sample. The impact monitoring stations dominate in local monitoring networks (Table 2). Monitoring of unsaturated zone and remote sensing methods applied with respect to pollutant properties supplement groundwater monitoring activities. Some of monitoring wells are located close to the point pollution source and should be used as a remediation wells when pollution occurs. Monitoring programme International Category and importance of monitoring station Baseline Trend D C Station density Sampling frequency Variables analysed VL L B+ Impact LS ONational D C LS D LS L L C M M B+ O+ Local LS LS Station’s significance: Station density: Sampling frequency: List of variables analysed: D H H Baseline station: natural background groundwater quality B+ O- Privincial Monitoring stations characteristics O+ Trend station: trends in groundwater quality due to natural processes and human impacts Impact station: changes of groundwater quality due to various human impacts D Dominant, C Complementary, LS Low significance Station per km2: H High – m2 to 10, M Medium – 10 to 100, L Low – 100 to 1 000, VL Very low – 1 000 and more H High – more than 12 times a year, M Medium – 2 to 12 times a year, L Low – 1 to 4 times a year B Basic – physical, chemical and biological variables included into the drinking water standards O Optional – heavy metals, organochlorine compounds, oil hydrocarbons and other variables depending on monitoring program objectives + Regular analysis - Occasional analysis TABLE 2 Categories of groundwater monitoring stations operating in groundwater quality monitoring programmes 1957 GROUNDWATER QUALITY MONITORING NETWORKS A refinement of the local groundwater quality monitoring networks based on pollution control and the effect of remediation procedures is frequent. Fast and simple methods of data recording and retrieval should be used to submit the monitoring results and information to the individual users in time and in a intelligible form. Operational costs of local monitoring programmes are high, however they are covered by the polluters (polluter pays principal). Operation of site specific monitoring networks is mostly limited for a certain period only. 3.5 Early Warning Groundwater QualityMonitoring Existing monitoring strategies tends to focus attention primarily on the movement of pollutants within the saturated zone. Monitoring programmes are mostly concern on identification and control of the concequences of groundwater pollution and not for preventive protection of groundwater quality. An early warning monitoring strategy is needed that detects contaminant before massive pollution of groundwater system occurs and solution of pollution problem is still at a controllable and manageable stage. The early detection of changes in groundwater quality requires application of various monitoring methods which may facilitate the observation of contaminant migration, in the gaseous and liquid phases, through the unsaturated zone and the uppermost part of the aquifer. These methods include mainly retrieval of sediment, gas and water samples through specially located and designated monitoring wells, installation of lysimeters, soil gas surveys, photographic imaging and geobotanical and geophysical prospecting. Early warning groundwater quality monitoring should be implemented within regional and local monitoring programmes oriented on specific pollution impacts on groundwater system. 4 ESTABLISHEMENT OF NATIONAL GROUNDWATER QUALITY MONITORING NETWORKS Several experiences have been acquired about groundwater quality monitoring in countries where national groundwater quality monitoring programme were designated and carried out. Even though natural, social and economic conditions and land use vary from country to country it is possible to give some generalization about national monitoring programmes. An elaboration of conceptual models of main country aquifers, determination of groundwater flow systems, assessment of groundwater vulnerability, inventory of groundwater supplies protection zones and identification of pollution sources are essential, before the works on groundwater quality monitoring programme are initiated. Existing land–use practices and land-use planning should also be considered. Monitoring wells of national monitoring networks should be located beyond the influence of pollution sources or groundwater abstraction sites. In the monitoring network formed by monitoring wells with standing water is not suitable to incorporate wells in dynamic stage (e.g. water supply wells, irrigation wells). Groundwater samples taken within a different hydraulic and hydrochemical conditions are not mutually comparable. Automatic data acquisition system is recommended to install on pilot monitoring stations. In case of a groundwater system formed by two or more aquifers, it is preferable to have separate monitoring of each aquifer, both quantitative and qualitative, by individual small diameter wells. Employment of the packer technique on the separation of sampling segments in deep monitoring well is less suitable. When packers operate in the long term, the monitoring well should be affected by natural and human impacts, aquifers should be interconnected and monitoring data depreciated. However in shallow unconfined aquifers intercalated by low permeable sediments two or three small diameter piezometers of different depths should be placed into a large diameter borehole. 1958 Jaroslav Vrba Water samples are taken from the bottom part of the piezometer. Such a national groundwater monitoring system successfully operates in the Netherlands (Duijvenbooden 1987). When designing a monitoring network in area with fissured rock permeability the orientation and geometry of the fracture system (preferred flow path) should be carefully studied. However, the location of monitoring wells representing such complicated hydrogeological conditions is always difficult. In karst regions where groundwater flow is in conduits or in large open fissures, springs allow more representative observation of groundwater quality than monitoring wells. Sampling of groundwater in karst regions must be frequent, because groundwater is moving through the karst system quickly and water quality changes as a consequence of pollution are usually fast. Selection of suitable methods of taking representative sample of groundwater is the most problematic part of sampling procedure. The water is standing in the monitoring well several weeks or even months in the column above the screen without direct contact with the groundwater flow system and under the impact of atmosphere and casing material which all affect its chemical composition. Purging the well is, therefore, desirable to take groundwater samples at a dynamic stage. The main sampling methods implemented according to the aquifer and groundwater flow conditions are 1) sampling after removing the volume of water accumulated above the well screen, 2) in low yielding wells sampling by suction or sample collection after pumping the well dry and the recuperation of water column, 3) purging the well until selected field measured parameters (usually pH, Eh, temperature, electrical conductivity, oxygen demand) are stabilised.In case of deeper unconfined high yielding aquifers with lateral groundwater flow, simple or special multistage samplers combine with packer techniques should be used to take water sample from a define depth. A mixed water sample from the entire profile of the aquifer is not considered satisfactory. Sampling collection and field and laboratory analysis are usually carried out by various companies. The state agency responsible for the operation and management of groundwater monitoring programmes has the responsibility to coordinate and control applied monitoring methods and procedures. Groundwater quality monitoring of internationally shared groundwater requires close cooperation among neighbouring countries. Sampling collection methods have to be unified as much as possible to minimise potential problems with data evaluation and implementation. Feedback is an essential future of the monitoring process (Table 1). Modification of the monitoring system (number and location of monitoring wells, sampling frequency, extent of chemical analyses) is based on a long-term data sets evaluation. 5 CONCLUSIONS The objective of groundwater protection policy is timely identification and evaluation of potential conflicting issues, validation of competitive factors and their hierarchical screening with the aim to find a balance between groundwater resources protection, sustainable economic development and potential social and health implications with a view to both, the short term and long term prospects. Groundwater quality monitoring programme is one of the effective methods supporting groundwater protection policy and management. However establishment and operation of groundwater quality monitoring programmes, especially on national level, is a technically and financially demanding process in terms of capital, operational and maintenance costs. A cost-benefit analysis is, therefore, required to compare the value of data and information with the cost involved. Importance of early warning groundwater quality monitoring in preventive protection policy is pointed out. Early warning monitoring is nearly every time less expensive than the cost related to aquifer remediation and investments needed to overcome social and ecological damages of groundwater pollution, in case, that early warning monitoring system was not in operation. 1959 GROUNDWATER QUALITY MONITORING NETWORKS REFERENCES European Commission – DG XI 1996. Evaluation of the Costs of Groundwater Inspection in the Member States. Final report: 1-79 Maybeck, M. 1985. The Gems Water Programme 1978-1983. Water quality bull., volume 10, no.4, Canada: 167-173 UNESCO and WHO 1978. Water Quality Surveys. Studies and reports in hydrology, 23. Paris Van Lanen, H. et al. 1998. Monitoring for Groundwater Management in (Semi-) Arid Regions. Studies and reports in hydrology 57, UNESCO Vrba, J. 2000. The Role of Groundwater Quality Monitoring in the Strategy of Groundwater Protection.Proceedings of the XXX IAH Congress, Balkema/Roterdam: 1057-1063 1960