THAI JOURNAL OF PHYSICS, SERIES 9, (2013) Interpolation Equation for Calibration Results of Thermo-Hygrometers T. Sinhaneti*, P. Phuauntharo, and T. Keawprasert National Institute of Metrology Thailand, 3/4-5 Moo 3 Klonghar Klong Luang, Pathum Thani, 12120 Thailand *Corresponding author. E-mail: thasorn@nimt.or.th Abstract Most of commercial thermo-hygrometers applied the linear equation as its calibration equation for both relative humidity and temperature, so three calibration points for each parameter are required for the thermo-hygrometer calibration by their manufacturer. Meanwhile calibration laboratories calibrate thermo-hygrometers in terms of correction at points. As a result, it is rather difficult for users to apply any calibration results for a whole range since the instrument’s behavior is non-linear and sensitive to temperature. In this paper, two selected types of high accuracy thermo-hygrometer were intensively calibrated for their relative humidity corrections throughout the relative humidity range of 30 % to 80 % at different temperatures of 15 °C to 30 °C. For each type, the resulting corrections were evaluated by fitting to different polynomial equations to determine its best interpolation equation. It was found that the quadratic polynomial equation of two variables for the relative humidity with the linear function of temperature is accurate enough to use as an interpolation equation for these two types of thermo-hygrometers. Moreover, for one type of them, the quadratic polynomial equation of two variables both for relative humidity and temperature is very accurate, yielding the residual error of lower than 0.1% for relative humidity. From this result, this type of thermo-hygrometer and its best appropriate interpolation equation will be implemented for the next inter-laboratory comparison in humidity measurement among calibration laboratories in Thailand. Keywords: Thermo-hygrometer, Calibration, Interpolation equation Introduction Problem Presently thermo-hygrometers are widely used in many applications especially for environment control and industrial process control. For traditional application, a narrow operating temperature range is enough, while a wide range is required for industry. Normally thermohygrometer manufacturers require sensors which their response is linear for relative humidity measurement so that a linear equation can be used as their calibration equation. Moreover, relative humidity at a given temperature is defined as the ratio between the actual partial vapor pressure to the saturation vapor pressure of the air temperature [1]. That is the air temperature is a main factor affecting to the accuracy of thermo-hygrometers, including non-linearity, thermal radiation, hysteresis, contamination and condensation. Fig. 1 show measurement results of a thermohygrometer in terms of relative humidity correction for the range of 40% to 80% at different temperatures. It can be clearly seen that the correction values at any relative humidity are changed by the air temperature. Moreover the non-linearity can be found at the results of 40%, 50% and 60% since the manufacture use a linear equation as its calibration equation. A main task of this work is to study the relationship between the thermo-hygrometer output and the actual relative humidity at any temperatures. The aim is to find out an appropriate interpolate equation which can describe the behavior of thermo-hygrometer. It is expected that the resulting equation will be used to determine correction values of relative humidity at any temperatures accurately. Fig.1 Corrections at difference temperatures For properly use, thermo-hygrometers must be used at same temperature on certificate of calibration to avoid such a problem. Moreover 3 calibration points for each parameter (temperature and relative humidity) are not enough for a whole range calibration. * Corresponding author. Tel: 02-577-5100 Fax: 02-577-5092 ; E-mail: thasorn@nimt.or.th © 2013 Thai Physics Society T. Sinhaneti Methodology In this work, two types of high accuracy thermohygrometer were selected in this work. Firstly these thermo-hygrometers were intensively calibrated for their correction covering their measuring range as much as possible. A dew-point hygrometer and a platinum resistance thermometer were used as reference thermometers to calibrate the test thermo-hygrometers by comparison method in a 4.5 ft2 climatic chamber. An accuracy of the used dew-point hygrometer and the PRT is traceable to NIMT national standard in humidity and temperature respectively. The climatic chamber used to generate humid air was characterized for its stability and uniformity for a whole operation range. The calibration for each item was started from the lowest temperature to the highest temperature. For each temperature, at least 5 calibration points in the relative humidity range from 30% to 80% are required. Measuring relative humidity of thermo-hygrometer, and the relative humidity and the air temperature measured by the dewpoint hygrometer and the PRT were the main parameters which must be recorded in this measurement. Next the correction values at the calibration points H(R,t) can be calculated by subtracting the actual relative humidity value obtaining from the reference thermometers (RSTD) with the reading value of the test thermo-hygrometer (RUUC.) as follows H ( R, t ) RSTD (t ) RUUC (t ) Fig 2. Measured correction and estimate correction calculated from the interpolate equation for sensor A From the measurement result of the sensor A, the nonlinearity behavior can be clearly observed at low temperatures. (1). After that, the resulting corrections were fitted to different polynomial function both for the relative humidity and the air temperature using the regression method. Finally the resulting interpolation equation was used to estimate correction values at any relative humidity and temperature in order to compare to the measuring correction values. Figure 3 shows residual errors of within ±0.6% from the measured value for the whole relative humidity range. It seems the residual errors increases with increasing relative humidity. Results and Discussion Measurement results of one sensor for each type are shown and analyzed. Here the first type and the other one are defined as sensor A and sensor B respectively. From the method mentioned above, it was found that the polynomial function of the two variables in Equation (2) to be sufficiently accurate for both of them. H ( R, t ) b0 b1 R b2 R 2 b3t b4 R t b5 R 2t b6t 2 b7 R t 2 (2), where H(R,t) is resulting correction of the test thermohygrometer at the relative humidity R and the air temperature t measured by the dew-point thermometer and the PRT. The bi parameter is fitting coefficient calculated from the measurements results of R and t. Figure 2 shows the measured correction values of the sensor A in comparison to estimate correction values calculated from the interpolate equation above. Fig 3. Residual error from the measured value for the thermo-hygrometer sensor A For the sensor A, a poor fitting result was found with the r2 of lower than 0.9. Even increasing the order of the polynomial function, the measurement results are still unable to fit accurately. T. Sinhaneti 237 each type must be investigated to ensure their behavior. Therefore an ultimate goal of the subsequent work is to identify the characteristic of frequently used types of thermo-hygrometer. Conclusions Two types of high accurate thermo-hygrometer were investigated to find out the sufficiently general interpolation equation for each type. With the quadratic polynomial equation of two variables for relative humidity and temperature, a good agreement between the measured values and the estimate values was found for the calibration result of one sensor. As a result, this type of thermohygrometer and its appropriate interpolation equation are already implemented for the in progress inter-laboratory comparison in humidity measurement of Thailand. 1. Fig 4. Measured correction and estimate correction calculated from the interpolate equation for sensor B Figure 4 shows the measured correction values of the sensor B and its estimate correction values calculated from the interpolate equation in Equation 2. For the sensor B, a good fitting result was found for its measurement results with r2 of greater than 0.99. Furthermore, this sensor seems to response to relative humidity linearly for all test temperatures. For the sensor B, the associate residual errors from the measuring value are not larger than +0.1% for the whole range of 30% to 80%. The advantage of applying this interpolate equation for the calibration results is that the calibrated thermo-hygrometer can be used at any temperatures cover the whole calibration range with much lower error. At this stage, the maximum of residual error is considered as an uncertainty for the whole range calibration. Fig 5. Residual error from the measured value for the thermo-hygrometer sensor B Even a good agreement was found for this type of thermohygrometer, it should be noted that this is the results from one sample of this type. In fact, more than two sensors for REFERENCES J. W. Lovell-Smith and H. Pearson, “On the concept of relative humidity”, Metrologia 43 (2006), 129-134.