Milk, Soap, and Dye Unit - Sample Lesson by Tim Sorey Lesson Title: Milk Unit Lesson Description Lesson Description: This is a one day lesson that teaches students the properties of soap and how it surrounds grease, fat, and oil. Subject: Properties of Matter Duration: 45 minute lesson Grade Levels: K-8th Standards: NSES-S.K-4.A.2 STANDARD: Science As Inquiry -- As a result of activities in grades K-4, all students should develop understanding about scientific inquiry NSES-S.K-4.B.1 STANDARD: Physical Science -- As a result of the activities in grades K-4, all students should develop an understanding of properties of objects and materials NSES-S.K-4.F.1 STANDARD: Science in Personal and Social Perspectives -- As a result of activities in grades K-4, all students should develop understanding of personal health WA-GLE.SC.1.1 Component 1.1 Properties: Understand how properties are used to identify, describe, and categorize substances, materials, and objects and how characteristics are used to categorize living things. Component 1.2 Structures: Understand how components, structures, organizations, and interconnections describe systems. WA-COMP-2007.CHEM.1.1.4.1 Physical and Chemical Properties of Matter WA-COMP-2007.CHEM.1.2.6 Analyze why curiosity, honesty, cooperation, openness, and skepticism are important to scientific explanations and investigations. WA-COMP-2007.CHEM.2.1.1.6 Able to design investigations. WA-GLE.SC.1.2 Standards Rationale: Justification In this lesson, students are asked to scientifically inquire about the action of soap as it reacts with the milk fat (Standards - NSES-S-K-4.A.2 and WA-COM.K-4.1.2.2). It is also necessary that they recognize how solving problems helps to gather data that arise. Ultimately, this experiment is built to offer the students some resolution as to how the properties of oil and soap interact such that they may better understand personal health and hygiene (Standards - WA-GLE.SC.1.1, WA-GLE.SC.1.2, and NSES-S.K-4.F.1 ). Vocabulary Lesson vocabulary from OSPI website, found within STC Kit (Properties of Matter Part 2), and defined using Brown, LeMay and Bursten – 10th Ed. of Chemistry: The Central Science. liquid (5th) – pure matter that has a distinct volume but no specific shape solution (5th) – a mixture of substances that has a uniform composition – homogeneous mixture density (8th) – an intensive property that defines the ratio of an object’s mass to its volume – density = mass/volume mixture (8th) – a combination of two or more substances in which each substance retains its own chemical identity solubility (10th) – the amount of a substance that dissolves in a given quantity of solvent at a given chelating agent (11th) – a polydentate ligand that is capable of occupying two or more sites in the coordination sphere. dipole moment (11th) – a measure of the separation and magnitude of the positive and negative charges in polar molecules extensive property(11th) – the property that depends on the amount of material considered hydrocarbon (11th) –a molecule that contains only hydrogen and carbon atoms hydrogen bond (11th) (pages 170-173 on Properties of Matter) – bonding that results from intermolecular attractions between molecules containing hydrogen bonded to an electronegative element. The most important examples involve OH, NH, and HF. hydrophobic (11th) (water repelling) and hydrophilic (11th) (water attracting) indicators (11th) (pH, protein, glucose, starch, etc.) – a substance added to a solution to indicate whether a solute exists within a solvent mixture intensive property(11th) – the property that is independent of the amount of material considered immiscible (11th) – liquids that do not dissolve into one another to a significant extent temperature to form a saturated solution. miscible (11th) – liquids that mix in all proportions non-polar molecules (11th) – a molecule that possesses no dipole moment polar molecule (11th) - a molecule that possesses a nonzero dipole moment solvent (11th) – the dissolving medium of a solution solute (11th) – the substance dissolved into a solvent to form a solution surfactant or surface-active agent (11th) - (detergent, foaming agent, emulsifiers, conditioning agents solubilizers) – a molecule that usually has both hydrophobic and hydrophilic nature and acts as a type of chemical stabilizer Components Objectives The student objectives of this lesson include measurable quantities in both knowledge (What the student should KNOW) and in skill (what the student should be able to DO, hands-on). Know: Students should be able to know: how to create a hypothesis. how to make predictions prior to their experimentation. how to make experimental observations. the basic parts of a soap molecule. the definitions of hydrophobic and hydrophilic. Do: Students should be able to: perform experimentation that have pre-defined steps and procedures. design new experiments as an individual and in a group with newly defined steps and procedures. Materials and Equipment Primary List: Skim, 2%, Whole milk food coloring - various colors Dish soap Petri dishes Pipe cleaners Styrofoam balls water vegetable oil olive oil cranberry juice Extended List: Dry Soap, bar soap, shampoo, anti-bacterial soap Rubbing Alcohol, Karo syrup, soda pop sugar, salt, flower Prior Knowledge Prior to this experiment, students should know: soap helps to clean their hands and bodies Prior to this experiment, students should be able to do: experiments that are pre-defined and that include following stepwise instructions. Safety Students should be reminded that placing any of the materials in their mouths or on their neighbors is strictly prohibited. The teacher may consider having students wear their painting shirts during this experiment so that none of these materials would cause staining o f their school clothes. They should also be warned that some materials, such as the soap, rubbing alcohol, and food dye, can cause irritation of the skin or eyes. If they get any of the soap or rubbing alcohol in their eyes or mouth, they should immediately get them flushed with water for no less than 15 minutes. When the experiment is complete, students should place their materials into a waste container that is provided for them. Once thier pitri dish is emptied, they should be encouraged to wash them out at the sink and place them on a paper towel for drying. Engage Have team of students, no more than two students, place a pitri dish in front of them. Have them fill it 1/2 full with 2% milk. Next, have them place a drop of food dye in the middle of the pitri dish. Once all of the students have done this, pass around a SINGLE BOTTLE of soap, dropping a single drop of soap in the middle of the food dye. Students should observe a 'REACTION', where the soap spreads from the middle to the outer edges of the pitri dish. Next, have a classroom discussion and make a list of observations on the chalkboard or whiteboard. You may wish to have a couple students to come up and actually draw what they observed. Ask them a single question, "What do you think is CAUSING this observed reaction?" or "Can you tell me what materials cause this reaction?" Once you have a list of materials and have written them on the board, ask them to use these materials to form a testable question. For example, "Does the different color of food dye cause this reaction?" Time should be taken to explain that a testable question is referred to as a 'HYPOTHESIS'. Once a HYPOTHESIS is formed, students should be encouraged to PREDICT what will happen. For example, "The RED FOOD DYE will cause the REACTION to behave differently than the GREEN FOOD DYE." Even though this may or may not be true, a prediction helps students to 'STAKE A CLAIM' , getting them involved within a type of mental experimentation before they actually DO the experiment. The idea is to stimulate interest - DO NOT give the punchline away! HAND OUT THE STUDENT WORK SHEETS AT THIS TIME! (Please see attachments!) Explore Once the students have made their initial observations, they should be encouraged to test the 'pre-made' hypothesis on the hand-out sheet. Be sure that they read and understand this hypothesis, "Is milkfat an important factor in this reaction?" You may need to explain that milk is made up of fat molecules and that SKIM MILK contains less milk fat than 2% and whole milk. On their sheets, they should circle whether they think Milk Fat DOES or DOES NOT effect theREACTION. The only thing that they change, for this first experiment, is the % of milk fat. They should test the Skim milk and the Whole Milk only. The instructor should passively participate in observing the REACTIONS. The REACTION in SKIM MILK should be faster than WHOLE MILK. It may not be obvious, but the REACTION in SKIM MILK should be faster than the reaction in 2% MILK. Once the students have completed this exercise, make sure that they carefully write their observations down. Be sure to intervene at this time in order to discuss eachother's results in class. The instructor may want to write some key words down on the blackboard/whiteboard. Explain Have 6 glasses ready to go. Two glasses of 1/2 full of water, two glasses of 1/2 filled with vegetable oil, one glass of 1/2 full of cranberry juice, and one glass of Olive Oil. Pour one glass of water into the oil and let the students observe the separation between water and oil. Explain this phenomenon as oil being 'Hydrophobic' or 'WATER FEARING'. These layers don't tend to mix and the scientific way of describing this is the term : 'IMMISCIBLE'. Pour the other glass of water into the cranberry juice and let the students observe that there is NO separation between water and cranberry juice. Explain this phenomenon as fruit juice being 'Hydrophilic' or 'WATER LOVING'. These layers DO mix and the scientific way of describing this is the term: 'MISCIBLE'. Proof of the mixing can also be observed in comparing the mixture to an original glass of cranberry juice, where the mixture looks diluted. Finally, pour the glass of vegetable oil into the glass of Olive Oil. The students should observe that these two liquids are MISCIBLE and that there is no separation between the two liquids. You should explain to the students that some hydrophobic materials, such as oils, greases, and fats, tend to mix with one-another. Different types of Water Analyses include – Colorimetry, Turbidimetry, Nephalometry, Fluorimetry, Conductance, pH (CO2) and temperature See attached sheet of "TEACHER EXPLANATION OF SOAP" for further discussion of the soap molecule. See Student Hand-out of Teacher Explanation Elaborate If time permits, students should extend these concepts and skills toward investigation with other materials. They may wish to try using the other materials, such as different types of soap, colored food dyes, and liquids. They should test out at least 2 other hypotheses with the materials given. You can say, " "Can you come up with at least two other hypotheses and test them?" and "Don't forget to PREDICT before you experiment!" Evaluate You can assess both what the student KNOWS (knowledge) and what the student CAN DO (skills) with regards to this milk unit. The attached worksheet and a rubric-based performance assessment are used to assess student learning and alignment with the previous objectives. Performance assessment rubrics are explicitly aligned with the state and federal science education standards. Performance: Assessment Criteria The primary assessment materials measure my students ability to achieve this lesson's student objectives. Attached is a grading sheet that is used to help grade my students' performance. I have also chosen to a grading rubric, seen below, in order to quantify may students' overall achievement with this unit and its alignment with WA-COMP, NSES-S, and EALR requirements. See Student Hand-out of Teacher Explanation Performance Assessment Exceptional (5 pts) Knowledge Student is able to provide a clear, 50% concise, and accurate description of all steps in the milk unit experimental procedure and the testing of other hypotheses. Clearly articulates how steps are related and how to apply process to answering a scientific question and testing a prediction through observations. Skill 50% Student is able to develop a novel experiment testing other variables that Performance Assessment Good Quality In (4 pts) Development (3 pts) Student is mostly able to provide a clear, concise, and accurate description of all steps in the milk unit experiment and the testing of other hypotheses. Articulates how to apply process to answering a scientific question and in testing a prediction through observations. Student is somewhat able to provide a description of steps in the milk unit experimental procedure, but is still working on forming hypotheses. Has some trouble explaining how to apply process to answering a scientific questions and in testing a prediction through observations. Student is able to Student is able to develop an original develop an experiment testing experiment but a single variable in combines Needs Rethinking (2 pts) Not Scorable (1 pt) Student has trouble providing a description of steps in the milk unit experiment and forming other testable hyptheses. Has considerable trouble explaining how to apply process to answering a scientific question and recognizing if the prediction is true or false form observations. Student is unable to provide any kind of description of the scientific method or hypothesis in the milk unit experiment. Is unable to apply method to answering a scientific question and cannot recognize if prediction is true or false from observations. Student is able to develop an experiment but uses more than one Student does not develop an experiment...only plays with the the class has not yet considered. Experiment is controlled by changes to single variables within the milk experiment. Explanation for results is clear, concise, succinct and accurate. Can efficiently and effectively work as a team member who codesigns new experiments. the milk experiment. Experiment is controlled. Explanation for results is clear, concise, succinct and accurate. Can make contributions in team work to design experimentation. variables or does not control the experiment to single cause and effect relationships. Explanation for results is adequate. Can perform positively with a partner to accoplish major tasks. variable without recognizing it. Explanation for results is only partial, at best. Has difficulty in working as a team member in performing experiments. variables or generally observes them. Explanation for results is missing. Teamwork tends to be more of a distraction than benefit during experimentation. Supplemental Info.: Teacher Background Info Sodium oleate is a soap made from olive oil. A protonated carboxylic ending would produce Oleic Acid. Experience from practicing lesson: This lesson seems to work best when done with partners and teams working face to face. Students should be encouraged to not only write observations, but also to DRAW before and after pictures. This helps the students to recognize that non-scientific words and pictures are VALID forms of observations. Some pitfalls to this lesson include lack of understanding the size of a molecule in regards to oil, grease and fatty molecules. It may be important to offer a size examples, along with information manipulatives to express what level this soap is working. A college-level explanation of the Soap Molecule. A soap molecule is formed from a process known as saponification. It is usually a process that includes rendering of lard into large hydrocarbon or "Fatty" chains. When heated to a boil, lye is added (NaOH), and molecules called 'FATTY SALTS" or "FATTY ACIDS" are formed. Upon drying, the soap molecule contains a carboxyllic ending, as shown in the molecular diagram below. The hydrocarbon chain is made up of hydrogen and carbon bonds and is referred to as the 'HYDROPHOBIC TAIL'. The Carboxillic ending, C-OO-Na, is soluble in water and is considered the 'HYDROPHILIC HEAD'. See: http://chemistry.about.com/library/glossary/bldef825.htm and http://www.drgreene.com/21_1760.html Three content areas that could be integrated into this lesson include social studies, art, and health. In regards to social studies and health, the westward movement and settling of the west depended a great deal on making soap. Lye (NaOH) was one of the important staples within a wagon train. When a carcass, pig or beef, was cooked, its' lard was rendered and soap was made. Soap helped to keep health and hygeine within a wagon train, reducing illnesses and bacterial spread diseases, such as typhoid and influenza. (WA.R.5-7.1.2.1 and NSES-S.K-4.F.1) Students should develop their skills in regards to art. Students could be asked to draw micelles, grease, and soap molecules during this lesson. They could also be asked to create them with pipe cleaners and Styrofoam balls. (WA.ART.1.2) Resources: Resources Saponification http://www.kcpc.usyd.edu.au/discovery/9.5.5-short/9.5.5_saponification.html This is a website that shows a molecular representation of a fatty acid and the process of making soap, called "saponification". Science: Teachers Guide To Science http://tlc.ai.org/scienclp.htm Teacher Resource Science Lesson Plans referenced with Indiana state standards. Covers many topics from caterpillars and bubbles to physics and nuclear energy. Grades K-12 Rating** Chapter 13.6, pages 558-562 of Brown and Lemay’s “Chemistry: The Central Science”, Tenth Edition. This entry describes colloids and how micelles are produced from soap molecules of sodium stearate.